Materials SciencePub Date : 2024-02-07DOI: 10.1007/s11003-024-00766-x
Yu. S. Borisov, N. V. Vigilianska, C. V. Iantsevitch, I. A. Demianov
{"title":"Corrosion Resistance of Pseudoalloy Copper-Iron Coatings Obtained by Electric Arc Spraying","authors":"Yu. S. Borisov, N. V. Vigilianska, C. V. Iantsevitch, I. A. Demianov","doi":"10.1007/s11003-024-00766-x","DOIUrl":"https://doi.org/10.1007/s11003-024-00766-x","url":null,"abstract":"<p>Operating costs at different enterprises increase because of high wear and corrosion of components. These components can be protected by the electric arc spraying of pseudoalloy protective coatings. The coating was obtained by simultaneous spraying of copper and iron wires. The microstructure was investigated with an electron microscope and the phase composition was assessed by X-ray diffractometry. The porosity and microhardness of the coating were also evaluated. The coating was dense and consisted of Cu and Fe metallic lamellas together with homogenously distributed minor Cu<sub>2</sub>O, FeO oxide phases. The microhardness of the coating is 2.1±0.7 GPa. An electrochemical test of the coating was performed in a 3% NaCl solution. The pseudoalloy coating of copper-iron system with a thickness of 500 μm was high corrosion resistant in this solution.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"141 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139756156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-02-07DOI: 10.1007/s11003-024-00762-1
{"title":"Assessing of the Life Time of a Shaft with a Crack in Hydrogen","authors":"","doi":"10.1007/s11003-024-00762-1","DOIUrl":"https://doi.org/10.1007/s11003-024-00762-1","url":null,"abstract":"<p>A theoretical-experimental approach for predicting the kinetics of fatigue crack growth and determining the life time of the responsible elements of structures in hydrogen is proposed. Based on the created calculation model of fatigue crack growth, experimentally constructed kinetic diagrams of fatigue failure of 35KhN3MFA steel, the residual life of the rotor shaft of the turbo generator, weakened by a surface semi-elliptical crack in air, and in gaseous hydrogen environment, are determined. Hydrogen reduces the residual life of the rotor shaft by two orders of magnitude in hydrogen, compared to its residual life in air.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"88 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139756155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-02-07DOI: 10.1007/s11003-024-00765-y
A. Dittes, T. Mehner, S. Friedrich, B. Awiszus, T. Lampke
{"title":"Quantitative Model for the Prediction of the Corrosion Rate of Cold-Rolled 316L STEEL","authors":"A. Dittes, T. Mehner, S. Friedrich, B. Awiszus, T. Lampke","doi":"10.1007/s11003-024-00765-y","DOIUrl":"https://doi.org/10.1007/s11003-024-00765-y","url":null,"abstract":"<p>The austenitic stainless steel 316L is used for numerous components due to its excellent corrosion resistance. However, forming of components influences the microstructure and can thus change the corrosion resistance of the steel. In this context, the corrosion rate of the steel 316L is determined for the case of uniform corrosion of various cold-rolled conditions by ageing tests in 0.5 M H<sub>2</sub>SO<sub>4</sub>. The microstrain, the martensite fraction, and the residual stress state are quantified using X-ray diffraction. The surface roughness is measured by laser scanning microscopy. Three different model equations are derived by means of multiple regression to predict the corrosion rate as a function of the specimen properties. The analysis shows that a particularly simple model equation, which predicts the corrosion rate only via the plastic strain, shows insufficiently large deviations from the experimentally determined corrosion rates. However, a low divergence to the experimental results with a mean deviation of less than 4% is achieved by using a model equation that takes microstructural parameters and the surface ratio into account. Within this model equation, an increased corrosion rate is achieved with higher microstrain and residual compressive stress of the austenite phase as well as a higher surface-area ratio. A higher fraction of martensite is found to lower the corrosion rate.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"5 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139755925","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-02-06DOI: 10.1007/s11003-024-00768-9
O. P. Khlopyk, I. M. Zin, B. M. Datsko, L. M. Bilyi, Z. A. Duriagina, S. A. Korniy
{"title":"Anticorrosion Properties of Composite Inhibiting Pigment Based on Natural Calcium Silicate and Zinc Monophosphate","authors":"O. P. Khlopyk, I. M. Zin, B. M. Datsko, L. M. Bilyi, Z. A. Duriagina, S. A. Korniy","doi":"10.1007/s11003-024-00768-9","DOIUrl":"https://doi.org/10.1007/s11003-024-00768-9","url":null,"abstract":"<p>A composite inhibiting pigment based on natural silicate (wollastonite) and acid salt (zinc monophosphate) was obtained by the method of mechanochemical modification. The new composite pigment wollastonite–zinc monophosphate has high protective properties on aluminum alloy in the environment of weakly acidic atmospheric precipitation, and is superior to a simple mixture of calcium silicate and zinc monophosphate in protective characteristics. An effective corrosion-resistant film consisting of calcium, zinc and aluminum phosphates is formed on the surface of the alloy in the extract of the composite pigment.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"19 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139755930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-02-06DOI: 10.1007/s11003-024-00769-8
Z. V. Slobodyan, L. A. Mahlatiuk, R. B. Kupovych, N. Yo. Sobodosh
{"title":"Inhibition of Carbon Steel Corrosion by Polyvinylpyrrolidone in Chloride-Acetate Solution and in Model Stratal Water","authors":"Z. V. Slobodyan, L. A. Mahlatiuk, R. B. Kupovych, N. Yo. Sobodosh","doi":"10.1007/s11003-024-00769-8","DOIUrl":"https://doi.org/10.1007/s11003-024-00769-8","url":null,"abstract":"<p>The influence of polyvinylpyrrolidone (PVP) with molecular mass of 12 600 and 28 000 at concentrations of 0.2; 0.5 and 1.0 g/dm<sup>3</sup> on the corrosion rate of 20 steel in the chloride-acetate solution and in the model stratal water was investigated by gravimetric and electrochemical methods. Under dynamic conditions maximum inhibition of the steel corrosion rate was observed at a PVP concentration of 0.5 g/dm<sup>3</sup> in both environments. A further increase in inhibitor concentration to 1.0 g/dm<sup>3</sup> reduces the degree of protection more significantly in chloride-acetate solution than in the stratal water. The PVP with a higher molecular mass reveals higher protective properties, which is typical of polymers capable of adsorbing both linearly and in a ball.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"33 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139756356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-02-05DOI: 10.1007/s11003-024-00770-1
M. S. Stechyshyn, M. Ye. Skyba, N. M. Stechyshyna, N. S. Mashovets, N. K. Medvedchuk
{"title":"Wear Resistance of Glow-Discharge Nitride 08Kh18N10 Steel","authors":"M. S. Stechyshyn, M. Ye. Skyba, N. M. Stechyshyna, N. S. Mashovets, N. K. Medvedchuk","doi":"10.1007/s11003-024-00770-1","DOIUrl":"https://doi.org/10.1007/s11003-024-00770-1","url":null,"abstract":"<p>The influence of the modes of anhydrous nitriding of 08Kh18N10 steel on its phase composition, distribution of the main alloying elements, and the content of nitrogen in the nitride layer, microhardness and specific wear were investigated. With an increase in the temperature and duration of 08Kh18N10 steel nitriding simultaneously with the increase in the thickness of the nitrided layer, the nitrogen content in steel decreases and a drop in the hardness of the upper part of the nitride zone was observed. At the same time, the hardness gradually increases to the maximum values typical of the boundary of the nitride and diffusion zones. Laboratory tests on hydroabrasive wear showed that, compared to the initial state, the wear resistance of 08Kh18N10 steel, nitrided at <i>P</i> = 120 Pa, <i>T</i> = 600°C for 3 h, increased twofold. Industrial tests of centrifuge rotors at concentrating mills confirmed the results of laboratory investigations.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"37 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139763015","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-02-05DOI: 10.1007/s11003-024-00753-2
V. M. Korzhyk, V. Yu. Khaskin, V. V. Kvasnytskyi, O. V. Ganushchak, I. D. Hos, S. I. Peleshenko, O. I. Demianov, O. V. Konoreva, N. M. Fialko
{"title":"Preparing Permanent Joints of Titanium Alloys with Steel (A Review)","authors":"V. M. Korzhyk, V. Yu. Khaskin, V. V. Kvasnytskyi, O. V. Ganushchak, I. D. Hos, S. I. Peleshenko, O. I. Demianov, O. V. Konoreva, N. M. Fialko","doi":"10.1007/s11003-024-00753-2","DOIUrl":"https://doi.org/10.1007/s11003-024-00753-2","url":null,"abstract":"<p>Welding processes of titanium alloys with steels are analyzed. The following research directions are distinguished: the use of prefabricated bimetallic transition elements (welded by traditional methods); minimization of energy and heat expenditure in the weld area of metals; the use of methods of welding metallurgical engineering. The advances in welding technology have led to innovative solutions such as friction welding with stirring, as well as the use of liquid-phase layers and 3D printing of nanostructured layers at the edges to accelerate diffusion processes in diffusion welding. The new methods in welding metallurgical engineering increase the efficiency of Ti–Fe compounds due to the use of multilayer compositions of tantalum or niobium from the side of titanium and bronze – from the side of steel, and also vanadium inserts and its alloys, for example, alloyed with tungsten or chromium. The urgency of further development of standards for support and dissemination of industrial technologies for welding of Ti–Fe joints, training and preparation of technical personnel for the implementation of these technologies is noted.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"100 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139762889","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-02-05DOI: 10.1007/s11003-024-00756-z
{"title":"Mechanical Properties of Steel for Floating Offshore Platforms under Static and Cyclic Loading","authors":"","doi":"10.1007/s11003-024-00756-z","DOIUrl":"https://doi.org/10.1007/s11003-024-00756-z","url":null,"abstract":"<p>The results of a set of experimental tests of Q420 steel samples with quality level Q420B are presented. The chemical composition of steel and its mechanical characteristics, indicated in the certificate for products and determined experimentally, were compared with the standard values in the certificate for products. The results of steel fatigue and corrosion-fatigue tests were analyzed. The <em>S</em>–<em>N</em> curves in air and artificial seawater were constructed, and the corresponding values of endurance limits at room temperature and at 0°C were also determined. A significant influence of the corrosive environment on fatigue crack propagation rate in steel was established.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"1 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139755934","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-02-05DOI: 10.1007/s11003-024-00761-2
M. G. Chausov, P. O. Maruschak, A. P. Pylypenko
{"title":"The Influence of Impac-Oscilation Loading on the Hardness of Surface Layers of D16ChATW Aluminum Alloy","authors":"M. G. Chausov, P. O. Maruschak, A. P. Pylypenko","doi":"10.1007/s11003-024-00761-2","DOIUrl":"https://doi.org/10.1007/s11003-024-00761-2","url":null,"abstract":"<p>The effect of impact-oscillation loading of a given intensity on the hardness of the surface layers of the D16ChATW aluminum alloy was evaluated, in particular, using nanosolutions of tungsten carbide, carbon, as well as Al + Cu and Al + Cu + Mg nanosolutions at a concentration of 50:50% and 33:33:33%, respectively. The relationship between the parameters of dynamic non-equilibrium processes which change the structural phase state and mechanical properties of the alloy and the surface hardness of the material, was identified and described.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"17 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139755927","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-02-05DOI: 10.1007/s11003-024-00767-w
H. H. Veselivska, V. M. Hvozdetskyi, M. M. Student, Kh. R. Zadorozhna, Yu. V. Dzioba
{"title":"The Influence of the Electrolyte Composition for Hard Anodizing of Aluminum on Corrosion Resistance of Synthesized Coatings","authors":"H. H. Veselivska, V. M. Hvozdetskyi, M. M. Student, Kh. R. Zadorozhna, Yu. V. Dzioba","doi":"10.1007/s11003-024-00767-w","DOIUrl":"https://doi.org/10.1007/s11003-024-00767-w","url":null,"abstract":"<p>The effect of the electrolyte composition for hard anodizing of aluminum on the corrosion resistance of the synthesized anodic coatings was studied. The hard anodizing was carried out at temperatures of –4–0°C for 60 min at a current density of 5 A/ dm<sup>2</sup> . The basic electrolyte was a 20% aqueous solution of H<sub>2</sub>SO<sub>4</sub> . Hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) was added to the electrolyte in concentrations of 30; 50; 70 and 100 g/L to determine strong oxidants influence on the characteristics of the anode layers. The concentration of 70 g/L H<sub>2</sub>O<sub>2</sub> in the electrolyte, which ensures the synthesis of the thickest and least porous coating, was optimal. At the initial moment of immersion of anodic coatings synthesized in hydrogen peroxide electrolyte, their corrosion resistance decreases. When peroxide electrolyte concentration increases from 30 to 100 g/L, corrosion currents increase by 30 and 90%, respectively. However, with increasing exposure of coatings in the environment, their corrosion current density decreases more intensively with a decrease in their porosity. After 14 days, no dependence of the coatings corrosion durability on the composition of the electrolyte observed, what indicated a complete closure of the pores.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"84 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139756365","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}