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Influence of Al2O3–15 wt%ZrO2 nanocomposite addition on pseudogap characteristics in Bi1·6Pb0·4Sr2Ca2Cu3O10+δ superconductor 添加 Al2O3-15 wt%ZrO2 纳米复合材料对 Bi1-6Pb0-4Sr2Ca2Cu3O10+δ 超导物伪隙特性的影响
IF 4.3 3区 材料科学
Materials Chemistry and Physics Pub Date : 2024-10-18 DOI: 10.1016/j.matchemphys.2024.130053
Ali Aftabi
{"title":"Influence of Al2O3–15 wt%ZrO2 nanocomposite addition on pseudogap characteristics in Bi1·6Pb0·4Sr2Ca2Cu3O10+δ superconductor","authors":"Ali Aftabi","doi":"10.1016/j.matchemphys.2024.130053","DOIUrl":"10.1016/j.matchemphys.2024.130053","url":null,"abstract":"<div><div>This study, employing the local pair model, examines how the Al<sub>2</sub>O<sub>3</sub>–15 wt%ZrO<sub>2</sub> nanocomposite affects the pseudogap peculiarities and temperature dependence of fluctuation-induced conductivity in the Bi<sub>1</sub><sub>·</sub><sub>6</sub>Pb<sub>0</sub><sub>·</sub><sub>4</sub>Sr<sub>2</sub>Ca<sub>2</sub>Cu<sub>3</sub>O<sub>10+δ</sub> superconductor. The fluctuation-induced conductivity survey reveals that the experimental data for both undoped samples and those doped with low concentrations (0.0–1.0 wt%) of the Al<sub>2</sub>O<sub>3</sub>–15 wt%ZrO<sub>2</sub> nanocomposite are well explained by the 3D Aslamazov-Larkin (AL) and 2D Maki-Thompson (MT) models, with 2D fluctuations being the most significant in all samples. The results indicate that samples with 0.1 and 0.2 wt% additives exhibit a wider region of 2D fluctuations than the undoped sample. This suggests that a minor addition of nanocomposite promotes the formation of phase-coherent fluctuating Cooper pairs. The value and temperature variation of the pseudogap Δ∗(T) for different composites were deduced using the local pairs model based on experimental fluctuation-induced conductivity data. It was observed that the transition temperature from the Bose-Einstein condensate (BEC) to Bardeen-Cooper-Schrieffer (BCS) regimes of local pairs, T<sub>pair</sub>, rose from 117.5 K at the undoped sample to approximately 133.5 K at the composite containing 0.2 wt% additive. However, with higher additive concentrations, T<sub>pair</sub> decreased, reaching 120.5 K at the composite containing 1.0 wt% additive. The estimated superconducting gap value at T = 0, Δ(0), rose from 250 K (21.5 meV) for the undoped sample to 254 K (21.9 meV) at the composite including 0.2 wt% additive, then dropped to 243 K (20.9 meV) at the composite including 1.0 wt% additive.</div></div>","PeriodicalId":18227,"journal":{"name":"Materials Chemistry and Physics","volume":"329 ","pages":"Article 130053"},"PeriodicalIF":4.3,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characterization of marine hydroxyapatite and its interest in bone filling in rabbits femoral defect model: In vivo, in vitro, and in silico study 海洋羟基磷灰石的特性及其在兔子股骨缺损模型中的骨填充作用:体内、体外和硅学研究
IF 4.3 3区 材料科学
Materials Chemistry and Physics Pub Date : 2024-10-18 DOI: 10.1016/j.matchemphys.2024.130055
Oussema Abdelhedi , Najah Elmounedi , Mabrouk Horchani , Nizar Sahnoun , Ahmed Racem Guidara , Walid Bahloul , Khaled Keskes , Slim Charfi , Hassane Oudadesse , Hichem Ben Jannet , Hassib Keskes
{"title":"Characterization of marine hydroxyapatite and its interest in bone filling in rabbits femoral defect model: In vivo, in vitro, and in silico study","authors":"Oussema Abdelhedi ,&nbsp;Najah Elmounedi ,&nbsp;Mabrouk Horchani ,&nbsp;Nizar Sahnoun ,&nbsp;Ahmed Racem Guidara ,&nbsp;Walid Bahloul ,&nbsp;Khaled Keskes ,&nbsp;Slim Charfi ,&nbsp;Hassane Oudadesse ,&nbsp;Hichem Ben Jannet ,&nbsp;Hassib Keskes","doi":"10.1016/j.matchemphys.2024.130055","DOIUrl":"10.1016/j.matchemphys.2024.130055","url":null,"abstract":"<div><h3>Purpose</h3><div>Hydroxyapatite (HA) is a promising scaffold material for bone defect treatment. This study aimed to evaluate the physicochemical and biological properties of a novel marine-derived HA extracted from blue fish scales and assess its potential as a bone substitute for clinical use.</div></div><div><h3>Methods</h3><div>80 female New Zealand white rabbits were assigned to 4 groups (n = 20): HA powder (EC group), 3D-printed HA cylinder (I3DFFF group), negative control group (NC group; bone defect without biomaterial), and positive control group (PC group; bone defect treated with commercially synthesized HA). The biomaterials were characterized <em>in vitro</em> using X-ray diffraction, nitrogen adsorption, scanning electron microscopy, emission spectrophotometry, and MTT assays. In vivo evaluation involved the same techniques, supplemented with histological and radiological analyses at 1, 3, 6, and 9 months post-implantation. Molecular docking studies were also performed to investigate HA's effect on RANKL-induced osteoclastogenesis and the NF-κB signaling pathway.</div></div><div><h3>Results</h3><div><em>In vitro</em> characterization showed that marine-derived HA is a mesoporous material with a crystalline structure similar to natural bone. <em>In vivo,</em> the material demonstrated biocompatibility, osteoinductivity, and osteoconductivity, providing a supportive environment for bone regeneration. Molecular docking indicated that HA could inhibit osteoclastogenesis by suppressing the NF-κB signaling pathway.</div></div><div><h3>Conclusion</h3><div>Our findings suggest that the two co-products, EC-17 and I3DFFF, possess the necessary physicochemical and biological characteristics to be developed as effective bone substitutes.</div></div>","PeriodicalId":18227,"journal":{"name":"Materials Chemistry and Physics","volume":"329 ","pages":"Article 130055"},"PeriodicalIF":4.3,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533581","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Aqueous electrophoretic deposition of yttrium-doped nanobioactive glass/collagen/chitosan orthopedic coatings on 316L SS 在 316L SS 上水电泳沉积掺钇纳米生物活性玻璃/胶原蛋白/壳聚糖矫形涂层
IF 4.3 3区 材料科学
Materials Chemistry and Physics Pub Date : 2024-10-18 DOI: 10.1016/j.matchemphys.2024.130059
Fatima A. El-Masry , Aida A. Salama , Nabil A. Abdel Ghany , Mohammad M. Farag , Zainab M. Al Rashidy
{"title":"Aqueous electrophoretic deposition of yttrium-doped nanobioactive glass/collagen/chitosan orthopedic coatings on 316L SS","authors":"Fatima A. El-Masry ,&nbsp;Aida A. Salama ,&nbsp;Nabil A. Abdel Ghany ,&nbsp;Mohammad M. Farag ,&nbsp;Zainab M. Al Rashidy","doi":"10.1016/j.matchemphys.2024.130059","DOIUrl":"10.1016/j.matchemphys.2024.130059","url":null,"abstract":"<div><div>The current study used yttrium-doped nanobioactive glass (Y-nBG), based on 62 SiO<sub>2</sub> – (33 – x) CaO – 5 P<sub>2</sub>O<sub>5</sub> – x Y<sub>2</sub>O<sub>3</sub> mole % system (x = 0 and 3 mol %), collagen, and chitosan composites for coating 316L stainless steel (316L SS) using aqueous electrophoretic deposition (EPD) technique. The corresponding coated samples are encoded as SS/Col-Chit, SS/BG-Y0/Col-Chit, and SS/BG-Y3/Col-Chit, respectively. Physicochemical characterization implied TGA, FTIR, SEM-EDX, contact angle, adhesion strength and in vitro bioactivity in SBF were performed. Following SBF immersion, FTIR and SEM-EDX investigations were also carried out. Furthermore, the coatings were loaded with gentamicin drug; the drug-release profile and mechanism were evaluated. The antibacterial efficacy of the composite coatings was also assessed. The results showed the formation of homogeneous coatings with good adhesion strength, 1.39 MPa, 0.55 MPa, and 0.81 MPa, and enhanced the wettability by decreasing the contact angle 36⁰, 22⁰ and 12⁰ for SS/Col-Chit, SS/BG-Y0/Col-Chit and SS/BG-Y3/Col-Chit coatings, respectively. In vitro bioactivity of coatings containing nBG revealed apatite formation after immersion in SBF. Furthermore, the antibiotic gentamicin showed a sustained release profile over time by diffusion mechanisms based on the Higuchi, Fickian, and Weibull models. As well, all coatings containing drugs have an antibacterial effect. Overall, these findings suggested that the prepared coatings have potential applications as orthopedic and dental implants.</div></div>","PeriodicalId":18227,"journal":{"name":"Materials Chemistry and Physics","volume":"329 ","pages":"Article 130059"},"PeriodicalIF":4.3,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142663141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of multifunctional marine coatings enriched with organometallic biocides supported on ZSM-5 zeolite for biofouling prevention 评估在 ZSM-5 沸石上富含有机金属杀菌剂的多功能海洋涂料的生物防污效果
IF 4.3 3区 材料科学
Materials Chemistry and Physics Pub Date : 2024-10-18 DOI: 10.1016/j.matchemphys.2024.130056
L.F. Montoya , I. Muñoz -Rivera , A.F. Jaramillo , N.J. Abreu , G. Sánchez-Sanhueza , G. González-Rocha , K. Fernández , M.F. Melendrez
{"title":"Evaluation of multifunctional marine coatings enriched with organometallic biocides supported on ZSM-5 zeolite for biofouling prevention","authors":"L.F. Montoya ,&nbsp;I. Muñoz -Rivera ,&nbsp;A.F. Jaramillo ,&nbsp;N.J. Abreu ,&nbsp;G. Sánchez-Sanhueza ,&nbsp;G. González-Rocha ,&nbsp;K. Fernández ,&nbsp;M.F. Melendrez","doi":"10.1016/j.matchemphys.2024.130056","DOIUrl":"10.1016/j.matchemphys.2024.130056","url":null,"abstract":"<div><div>There is significant concern regarding the biocides commonly used in commercial antifouling protection systems because of their high concentrations in coastal areas and the potential harm they can cause to marine organisms. Thus, much research has been dedicated to replacing these biocides with environment-friendly alternatives. Particularly, the use of natural products that inhibit the settlement of fouling organisms is the key to antifouling coating technology. The purpose of this study was to develop antifouling paints by using eco-friendly compounds and implement a multifunctional coating factor. Natural-origin biocidal agents, such as capsaicin, and a copper-ion release system supported on synthetic zeolite ZSM-5 were used. The formulations resulted in viscosities and particle sizes similar to those of commercial antifouling paints. The capsaicin coatings exhibited less fracture damage and more resistance to deformation in the flexibility and cupping tests. In the adhesion tests, all formulations exceeded 3 MPa, thereby enhancing the adhesion values of conventional antifouling agents. However, the capsaicin coatings exhibited less abrasion resistance than those containing zeolite. Corrosion resistance tests using electrochemical impedance spectroscopy indicated good anti-corrosive properties, particularly in the coatings with 8 % and 10 % copper. All formulations proved to be bactericidal within 6 h, and some completely eliminated the cell density by 3 h, highlighting the effectiveness of the biocide against the marine strain <em>Pseudoalteromonas</em> sp. UCO92.</div></div>","PeriodicalId":18227,"journal":{"name":"Materials Chemistry and Physics","volume":"329 ","pages":"Article 130056"},"PeriodicalIF":4.3,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533476","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructure and thermal properties of the cast WMoTaNb high-entropy alloy 铸造 WMoTaNb 高熵合金的显微结构和热性能
IF 4.3 3区 材料科学
Materials Chemistry and Physics Pub Date : 2024-10-17 DOI: 10.1016/j.matchemphys.2024.130054
Bang Xiao , Wenpeng Jia , Nan Liu , Jian Wang , Lian Zhou
{"title":"Microstructure and thermal properties of the cast WMoTaNb high-entropy alloy","authors":"Bang Xiao ,&nbsp;Wenpeng Jia ,&nbsp;Nan Liu ,&nbsp;Jian Wang ,&nbsp;Lian Zhou","doi":"10.1016/j.matchemphys.2024.130054","DOIUrl":"10.1016/j.matchemphys.2024.130054","url":null,"abstract":"<div><div>WMoTaNb RHEA has been manufactured using vacuum levitation melting. The as-cast WMoTaNb RHEA has equiaxed grains with a mean grain size of 71.4 μm, and the analysis of the experimental results of thermal conductivity, thermal expansion, and TG-DSC suggests that the as-cast WMoTaNb RHEA has excellent stability at elevated temperature above 1400 °C. This result experimentally explains the previous research on phase and microstructure stability. This study can provide experimental evidence for the high-level stability and help explain the elevated temperature mechanical behaviors of the as-cast WMoTaNb RHEA at elevated temperatures.</div></div>","PeriodicalId":18227,"journal":{"name":"Materials Chemistry and Physics","volume":"329 ","pages":"Article 130054"},"PeriodicalIF":4.3,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142532990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Eco-sustainable and flexible SERS platform based on waste cellulose decorated by Ag nanoparticles 基于银纳米颗粒装饰的废纤维素的生态可持续和灵活的 SERS 平台
IF 4.3 3区 材料科学
Materials Chemistry and Physics Pub Date : 2024-10-17 DOI: 10.1016/j.matchemphys.2024.130061
D. Giuffrida , D. Spadaro , V. Strano , S. Trusso , M.L. Saladino , F. Armetta , R.C. Ponterio
{"title":"Eco-sustainable and flexible SERS platform based on waste cellulose decorated by Ag nanoparticles","authors":"D. Giuffrida ,&nbsp;D. Spadaro ,&nbsp;V. Strano ,&nbsp;S. Trusso ,&nbsp;M.L. Saladino ,&nbsp;F. Armetta ,&nbsp;R.C. Ponterio","doi":"10.1016/j.matchemphys.2024.130061","DOIUrl":"10.1016/j.matchemphys.2024.130061","url":null,"abstract":"<div><div>This paper presents an innovative and environmentally friendly technology for the fabrication of low-cost SERS (Surface-Enhanced Raman Spectroscopy) sensors based on flexible substrates made of cellulose fibers reclaimed from waste. The substrates are decorated with nanostructured silver (Ag) thin films produced by pulsed laser deposition (PLD). In this process, the deposition conditions (laser fluence, gas pressure, target-substrate distance, deposition time, etc.) were optimized to enhance the SERS response. Different types of paper with different textures were tested, as it was also observed that the paper roughness significantly influences SERS efficiency. The samples were characterized using UV–Vis absorption spectroscopy, SEM microscopy, and surface profilometry to evaluate both the paper and the deposited films' morphologies. The SERS activity was assessed by detecting Rhodamine 6G in aqueous solutions drop-casted on the sensors, with concentrations ranging from 10<sup>−2</sup> M to 10<sup>−10</sup> M. Measurements were carried out using a handheld instrument equipped with dual excitation laser lines centered at 785 nm and 833 nm. The observed lower detection limit of 10<sup>−10</sup> M was achieved across all paper types tested. These results demonstrate the potential of integrating smart, eco-friendly materials in the fabrication of chemical sensors for sustainable advancement in environmental monitoring and safety. The materials not only exhibit excellent sensing capabilities but also minimize ecological footprints through renewable sourcing and eco-friendly production processes. While the deposition protocol is well-established for other substrates, this study marks the first exploration of its use on biomass-derived substrates.</div></div>","PeriodicalId":18227,"journal":{"name":"Materials Chemistry and Physics","volume":"329 ","pages":"Article 130061"},"PeriodicalIF":4.3,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142532991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication and in vitro biological properties of hydroxyapatite-sodium potassium niobate-barium titanate piezoelectric bioceramics 羟基磷灰石-铌酸钠钾-钛酸钡压电生物陶瓷的制作和体外生物特性
IF 4.3 3区 材料科学
Materials Chemistry and Physics Pub Date : 2024-10-17 DOI: 10.1016/j.matchemphys.2024.130060
Majid Kaboosi , Leila Nikzad , Iman Mobasherpour , S. Amir Ghaffari
{"title":"Fabrication and in vitro biological properties of hydroxyapatite-sodium potassium niobate-barium titanate piezoelectric bioceramics","authors":"Majid Kaboosi ,&nbsp;Leila Nikzad ,&nbsp;Iman Mobasherpour ,&nbsp;S. Amir Ghaffari","doi":"10.1016/j.matchemphys.2024.130060","DOIUrl":"10.1016/j.matchemphys.2024.130060","url":null,"abstract":"<div><div>The utilization of piezoelectric materials in bone implants is appealing due to the inherent piezoelectric property of natural bone. The intrinsic electrical characteristics of piezoelectric biomaterials enhance antibacterial activities, biocompatibility, and bioactivity properties. This study delves into investigating the antibacterial properties, biocompatibility, and bioactivity of three-component biocomposites: sodium potassium niobate (KNN)-barium titanate (BT)-hydroxyapatite (HA). The combination of sodium potassium niobate and barium titanate, possessing suitable piezoelectric properties, with hydroxyapatite, known for its favorable biological properties, enhances the requisite properties for a bone implant. Among the various compositions studied, the combination comprising 70 wt% of the piezoelectric component (KNN-BT) and 30 wt% hydroxyapatite, labeled as 30HKB, emerged as the most optimal blend in terms of density, morphotropic phase boundary, and other biological tests conducted. Following polarization, the antibacterial efficacy of 30HKB against S. aureus bacteria cells increased by 61 %. Furthermore, the growth and adhesion of MC3T3-E1 osteoblast cells suggest enhanced biocompatibility of the 30HKB composite attributed to surface polarization. The surface charges generated by polarization facilitated the absorption of Ca2+ ions, as well as the interaction of HPO4 - and OH- ions with the precipitated Ca2+ ions, leading to the formation of the CaP layer. Hence, polarized piezoelectric ceramics exhibit heightened bioactivity compared to their non-polarized counterparts.</div></div>","PeriodicalId":18227,"journal":{"name":"Materials Chemistry and Physics","volume":"329 ","pages":"Article 130060"},"PeriodicalIF":4.3,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Iron hematite-magnetite composite supported on mesoporous SBA-15 synthesized by using silica from cogon grass as a solid catalyst in phenol hydroxylation 利用草炭硅合成的介孔 SBA-15 上支撑的铁赤铁矿-磁铁矿复合材料作为苯酚羟基化过程中的固体催化剂
IF 4.3 3区 材料科学
Materials Chemistry and Physics Pub Date : 2024-10-17 DOI: 10.1016/j.matchemphys.2024.130057
Sittichai kulawong , Pinit Kidkhunthod , Narong Chanlek , Jatuporn Wittayakun , Nattawut Osakoo
{"title":"Iron hematite-magnetite composite supported on mesoporous SBA-15 synthesized by using silica from cogon grass as a solid catalyst in phenol hydroxylation","authors":"Sittichai kulawong ,&nbsp;Pinit Kidkhunthod ,&nbsp;Narong Chanlek ,&nbsp;Jatuporn Wittayakun ,&nbsp;Nattawut Osakoo","doi":"10.1016/j.matchemphys.2024.130057","DOIUrl":"10.1016/j.matchemphys.2024.130057","url":null,"abstract":"<div><div>Phenol hydroxylation involves the oxidation of phenol (C<sub>6</sub>H<sub>5</sub>OH) using hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) to yield benzenediol (C<sub>6</sub>H<sub>4</sub>(OH)<sub>2</sub>), mainly catechol (CTL) and hydroquinone (HQ). These products are in high demand in the pharmaceuticals industry sector. Thus, it is still worth investigating for further improvement in terms of heterogeneous iron catalysts. Herein, this research focuses on an iron hematite (Fe<sub>2</sub>O<sub>3</sub>)-magnetite (Fe<sub>3</sub>O<sub>4</sub>) composite catalyst supported on SBA-15 using silica from cogon grass for phenol hydroxylation. The extracted silica exhibited a fine white powder appearance and an amorphous structure, used as a silica source for SBA-15 synthesis. After catalyst preparation, the presence of Fe<sub>2</sub>O<sub>3</sub>, Fe<sub>3</sub>O<sub>4,</sub> and Fe<sub>2</sub>O<sub>3</sub>–Fe<sub>3</sub>O<sub>4</sub> composite on SBA-15 was confirmed by using X-ray absorption near-edge structure (XANES). X-ray photoelectron spectroscopy (XPS) analysis provided insights into the surface of the catalyst, revealing that Fe<sub>2</sub>O<sub>3</sub>–Fe<sub>3</sub>O<sub>4</sub>/SBA-15 had the highest dispersion of iron species. In terms of catalytic performance, Fe<sub>2</sub>O<sub>3</sub>–Fe<sub>3</sub>O<sub>4</sub>/SBA-15 displayed the highest conversion of 88 % and HQ selectivity of 46 % compared with lone Fe<sub>3</sub>O<sub>4</sub>/SBA-15 or Fe<sub>2</sub>O<sub>3</sub>/SBA-15. The magnetic separation approach demonstrated the easy separation of catalysts containing Fe<sub>3</sub>O<sub>4</sub>. Reusability studies showed that Fe<sub>2</sub>O<sub>3</sub>–Fe<sub>3</sub>O<sub>4</sub>/SBA-15 maintained its activity up to the 4th cycle, suggesting minimized iron leaching compared to Fe<sub>3</sub>O<sub>4</sub>/SBA-15. Overall, this study provides insights into the catalytic performance of phenol hydroxylation and iron-based catalysts, emphasizing the potential of Fe<sub>2</sub>O<sub>3</sub>–Fe<sub>3</sub>O<sub>4</sub>/SBA-15 as an effective and reusable catalyst.</div></div>","PeriodicalId":18227,"journal":{"name":"Materials Chemistry and Physics","volume":"329 ","pages":"Article 130057"},"PeriodicalIF":4.3,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Improving the foaming performance of foamed ceramics using Fe2O3 as an oxygen donor 用 Fe2O3 作为供氧体提高发泡陶瓷的发泡性能
IF 4.3 3区 材料科学
Materials Chemistry and Physics Pub Date : 2024-10-16 DOI: 10.1016/j.matchemphys.2024.130048
Xiangming Li , Zijian Su , Xianwen Li , Junlong Zhang , Qinghong Meng , Wanjun Yu , Zuju Ma , Junting Liu
{"title":"Improving the foaming performance of foamed ceramics using Fe2O3 as an oxygen donor","authors":"Xiangming Li ,&nbsp;Zijian Su ,&nbsp;Xianwen Li ,&nbsp;Junlong Zhang ,&nbsp;Qinghong Meng ,&nbsp;Wanjun Yu ,&nbsp;Zuju Ma ,&nbsp;Junting Liu","doi":"10.1016/j.matchemphys.2024.130048","DOIUrl":"10.1016/j.matchemphys.2024.130048","url":null,"abstract":"<div><div>A solution is proposed to reduce the cost of preparing foamed ceramics (FCs) by adding Fe<sub>2</sub>O<sub>3</sub> to the material system. As the Si<sub>3</sub>N<sub>4</sub> in the Fe<sub>2</sub>O<sub>3</sub>–free material system increases, the molten ceramic matrix allows a slight increase in gas generation at elevated temperatures, resulting in a slight increase in the foaming volume of FCs. The addition of Fe<sub>2</sub>O<sub>3</sub> increases the oxygen supply capacity of the molten ceramic matrix at elevated temperatures, thereby accelerating the oxidation of Si<sub>3</sub>N<sub>4</sub> and consequently increasing the foaming volume of the FCs. The FCs sintered from the 5 wt% Fe<sub>2</sub>O<sub>3</sub> and 2 wt% Si<sub>3</sub>N<sub>4</sub> material system at 1160–1180 °C have satisfactory overall performance with total/closed porosity of (73.6–79.5)%/(71.4–75.7)% and compressive strength of 10.2–15.4 MPa. The addition of Fe<sub>2</sub>O<sub>3</sub> to the material system can reduce the dosage of Si<sub>3</sub>N<sub>4</sub> for FCs preparation, thereby decreasing the cost of FCs preparation.</div></div>","PeriodicalId":18227,"journal":{"name":"Materials Chemistry and Physics","volume":"329 ","pages":"Article 130048"},"PeriodicalIF":4.3,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrochemical hydrogen storage using SrFe12O19 surface-immobilized polyoxometalate 使用 SrFe12O19 表面固定的聚氧化金属酸盐进行电化学储氢
IF 4.3 3区 材料科学
Materials Chemistry and Physics Pub Date : 2024-10-16 DOI: 10.1016/j.matchemphys.2024.130062
Mahnaz Yarkeh Salkhory, Maryam Shaterian, Mohammad Ali Rezvani
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