LithosPub Date : 2024-09-13DOI: 10.1016/j.lithos.2024.107800
Françoise Boudier, David Mainprice, Adolphe Nicolas
{"title":"Very high-T hydration in the lower gabbro section of Semail ophiolite, Hydrous components of the lower crust at fast-spreading ridge","authors":"Françoise Boudier, David Mainprice, Adolphe Nicolas","doi":"10.1016/j.lithos.2024.107800","DOIUrl":"10.1016/j.lithos.2024.107800","url":null,"abstract":"<div><p>Totally fresh black gabbros are observed locally at the very base of the gabbro section in southern Semail ophiolite. Devoid of medium to low-temperature diffuse alteration, the black gabbros are characterized by cloudy plagioclase marked by a high density of hydrothermal inclusions below the optical microscope resolution, evolving into diopside and pargasite crystals ∼10 μm sized. They record hydration at temperature over 900 °C as shown by their major elements composition. Focused Electron Backscattered Electron Diffraction (EBSD) study of the crystalline inclusions, suggests a phase transition from diopside to amphibole, and traces consistent crystallographic relationships of diopside inclusions with their host plagioclase. The detailed geometry of the microcrack system traces a complete fluid path from inter-grain cracking, to plagioclase intra-grain network, possibly thermally-induced. The evidence of solid-state deformation overprinting the magmatic textures suggests that twinning mechanism in plagioclase controls the intra-grain diffusion of hydrous fluids. Located at the interface of the Moho Transition Zone (MTZ) and semi-brittle lithosphere, the ‘black gabbros’ record a narrow domain where focused fluid flow induces rapid cooling below the gabbro solidus at the lowest limit of the magma chamber.</p></div>","PeriodicalId":18070,"journal":{"name":"Lithos","volume":"488 ","pages":"Article 107800"},"PeriodicalIF":2.9,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142274269","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LithosPub Date : 2024-09-11DOI: 10.1016/j.lithos.2024.107801
Francesco Giuntoli , Giulio Viola , Igor M. Villa
{"title":"Dating syn-orogenic exhumation of subducted continental crust: The case of the Northern Apennines","authors":"Francesco Giuntoli , Giulio Viola , Igor M. Villa","doi":"10.1016/j.lithos.2024.107801","DOIUrl":"10.1016/j.lithos.2024.107801","url":null,"abstract":"<div><p>Dating deformation is key to unravel the evolution of orogens. Unfortunately, this is commonly challenged by the occurrence in the rock record of multiple overprinting deformation stages that lead to repeated blastesis and form multiple fabrics during both prograde and retrograde evolutions. Additionally, recrystallization is not always complete, which causes a mixture of inherited and neoblastic mineral phases. Therefore, an approach integrating age dating with microstructural and petrographic analyses is necessary to extract structurally constrained ages from the rock record. We used this approach to contribute to the long-lasting debate about exhumation of continental metamorphic units subducted to high-pressure conditions. We studied continental metasedimentary sequences of the Tuscan Metamorphic Units of the Northern Apennines (Italy) from two localities: the Island of Giglio to the west and the Monticiano-Roccastrada Unit to the east. We obtained two analytically distinct <sup>40</sup>Ar/<sup>39</sup>Ar age ranges: an older 21–16 Ma age cluster is related to syn-orogenic top-to-the E contractional deformation occurring at ca. 1 GPa and 350 °C. A younger 15–11 Ma age group is related, instead, to exhumation to shallower structural levels and retrogression of these units to greenschist facies conditions. The interpretation of the results is based on white mica chemical compositions and rock fabrics. By integrating our results with published literature, we conclude that the investigated high-pressure continental metasedimentary sequences experienced early syn-orogenic exhumation from blueschist to greenschist facies conditions predominantly by a combination of extrusion and out- and in-sequence thrusting, with only minor contributions by extensional shearing during regional crustal thinning. Therefore, this study highlights the role of contractional fabrics in accommodating significant exhumation amounts of deeply subducted continental rocks.</p></div>","PeriodicalId":18070,"journal":{"name":"Lithos","volume":"488 ","pages":"Article 107801"},"PeriodicalIF":2.9,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0024493724003141/pdfft?md5=f606515b2680df2a48063bc61aaca446&pid=1-s2.0-S0024493724003141-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142172523","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LithosPub Date : 2024-09-11DOI: 10.1016/j.lithos.2024.107785
Jun He , Zeqiu Qi , Aimin Hu , Zhiyi Wang , Jiansen Li , Fukun Chen
{"title":"Compositional diversity of late Mesozoic granites rooting from the subducted crust in the Qinling–Dabie orogenic belt","authors":"Jun He , Zeqiu Qi , Aimin Hu , Zhiyi Wang , Jiansen Li , Fukun Chen","doi":"10.1016/j.lithos.2024.107785","DOIUrl":"10.1016/j.lithos.2024.107785","url":null,"abstract":"<div><p>Continental subduction has been identified in many orogens, such as the Alps, the Himalayas, and the Dabie; however, better understanding of the mechanism and outcome of different subduction processes remains desirable. The Qinling–Dabie orogen in Central China shows an asymmetric distribution of Triassic ultrahigh-pressure metamorphic rocks and <em>syn</em>- and post-tectonic granitoid plutons, thereby providing an excellent means by which to probe the diverse processes of continental subduction. Many late Mesozoic granitoid plutons that formed in post-orogenic or even anorogenic settings are widely distributed in both the Qinling and Dabie tectonic units and can be useful for studying the composition of materials beneath the crust because of their conspicuous compositional diversity. In the present study, we report zircon ages and Nd<img>Hf isotopic compositions for the Shangcheng and Heyu granite plutons, which represent late Mesozoic plutons in Dabie and Qinling. When compared with those of the Shangcheng pluton, the wide range of Nd isotopic values and the slightly depleted Hf isotopic compositions of the Heyu pluton indicate that there may be juvenile crust beneath the Qinling tectonic unit that is not present beneath the southern margin of North China. The currently undetectable juvenile material in this region may be an important candidate source of the late Mesozoic magmatism and metal mineralization in the southern margin of North China. The compositional diversity of these granites, as indicated by the Nd<img>Hf isotopic compositions, is attributed to the nature of the deep crust within the orogenic belt, and the magmatic origins of this region are discussed in the present study.</p></div>","PeriodicalId":18070,"journal":{"name":"Lithos","volume":"488 ","pages":"Article 107785"},"PeriodicalIF":2.9,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142167534","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LithosPub Date : 2024-09-10DOI: 10.1016/j.lithos.2024.107781
Manuela Durán Oreja , Pavel Pitra , Alicia López-Carmona , José R. Martínez Catalán , Puy Ayarza
{"title":"Corrigendum to “Magnetization related to late-Variscan extensional collapse in the Lugo Dome (NW Iberian Massiff): A metamorphic petrology approach” [Lithos Volumes 484–485 (2024) 107745]","authors":"Manuela Durán Oreja , Pavel Pitra , Alicia López-Carmona , José R. Martínez Catalán , Puy Ayarza","doi":"10.1016/j.lithos.2024.107781","DOIUrl":"10.1016/j.lithos.2024.107781","url":null,"abstract":"","PeriodicalId":18070,"journal":{"name":"Lithos","volume":"488 ","pages":"Article 107781"},"PeriodicalIF":2.9,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656728","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LithosPub Date : 2024-09-10DOI: 10.1016/j.lithos.2024.107803
Jin-Cheng Xie , Di-Cheng Zhu , Qing Wang , Peter A. Cawood , Zhi-Dan Zhao , Qiong-Yao Zhan , Jia-Hao Fan , Yao Wang
{"title":"Generation of isotopically enriched giant Lincang Batholith by disequilibrium melting of the heterogeneous lower crust","authors":"Jin-Cheng Xie , Di-Cheng Zhu , Qing Wang , Peter A. Cawood , Zhi-Dan Zhao , Qiong-Yao Zhan , Jia-Hao Fan , Yao Wang","doi":"10.1016/j.lithos.2024.107803","DOIUrl":"10.1016/j.lithos.2024.107803","url":null,"abstract":"<div><p>Deciphering the origin of granitoids with enriched isotopic compositions is essential to understanding the mechanism of continental growth and reworking. Establishing their origin is also an effective solution to the decoupled interpretations between geochemical and isotopic observations in competing petrogenetic models. This paper reports on the whole-rock major and trace elements, Sr-Nd-Pb-Hf isotopes, and zircon U<img>Pb age and Hf isotope data of samples from the Late Triassic Lincang Batholith in SW China. The hornblende-bearing granodiorites are weakly peraluminous, whereas the coeval biotite monzogranites are generally strongly peraluminous. These two types of granitoids show identical and extremely enriched isotopic compositions with (<sup>87</sup>Sr/<sup>86</sup>Sr)<sub>i</sub> ratios of 0.71991 to 0.74302, whole-rock ε<sub>Nd</sub>(t) values of −13.5 to −10.1, and ε<sub>Hf</sub>(t) values of −13.4 to −10.3, as well as a large variation of zircon ε<sub>Hf</sub>(t) values of −17.6 to +0.6. The inherited zircons from both suites of samples show similar age peaks (ca. 950 Ma and ca. 1150 Ma), trace element concentrations, and ε<sub>Hf</sub>(t) variations to those of the detrital zircons from the Lancang Group. These similarities indicate that these rocks are most likely derived from the anatexis of the Lancang Group that is mainly composed of quartz schist, sericite schist, greenschist, chlorite albite schist, and minor eclogite. On the other hand, the Lancang Group is characterized by more enriched isotopic compositions than the granitic batholith with whole-rock ε<sub>Nd</sub>(225 Ma) value of −13.3 and ε<sub>Hf</sub>(225 Ma) value of −19.1, but identical to those of the average ε<sub>Hf</sub>(225 Ma) values of inherited and detrital zircons (−18.1 and − 16.3). This isotopic fractionation between the granitoids and the Lancang Group may result from disequilibrium melting of the Lancang Group with different dissolution behavior of accessory minerals (i.e., zircon, monazite, apatite, titanite, etc.). The Lincang Batholith is on average more silicic and richer in incompatible elements than the upper continental crust, suggesting that the isotopically enriched giant granitic batholith is a mature magmatic response to continental reactivation and reworking.</p></div>","PeriodicalId":18070,"journal":{"name":"Lithos","volume":"488 ","pages":"Article 107803"},"PeriodicalIF":2.9,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142240642","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Petrogenesis of magmatic charnockite-biotite granite suite from parts of the Chotanagpur Granite Gneissic Complex (CGGC), eastern Indian shield: Implication for the break down of the Columbia Supercontinent","authors":"Somdipta Chatterjee , Subham Mukherjee , Sanjoy Sanyal , Pulak Sengupta","doi":"10.1016/j.lithos.2024.107802","DOIUrl":"10.1016/j.lithos.2024.107802","url":null,"abstract":"<div><p>A rare porphyritic charnockite that is girdled by and mineralogically grades to biotite granite occurs as a part of the Chotanagpur Granite Gneissic Complex (CGGC) in and around Massanjore, Jharkhand, India. Preservation of certain textural features, including (a) euhedral to subhedral grains of orthopyroxene, (b) low dihedral angle subtended by orthopyroxene and plagioclase grains, and (c) relict intergranular and porphyritic textures, are consistent with the view that orthopyroxene in the studied rocks has a magmatic origin. Preserved magmatic features and other petrological attributes of these rocks do not support any significant mass change beyond a few tens of microns during the overprinting high-grade metamorphism. The geochemical variation of the felsic rock suite (porphyritic charnockite and biotite granite) indicates that they are cogenetic and are derived from a ferroan A-type granitoid magma by crystal fractionation. The observed geochemical trend of the studied felsic rock suites has been simulated by phase equilibria modelling in the open system using the system components Na<sub>2</sub>O-CaO-K<sub>2</sub>O-FeO-MgO-Al<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub>-H<sub>2</sub>O-TiO<sub>2</sub>-O<sub>2</sub>. The observed mineralogical and geochemical attributes and the results of the modelling study are consistent with a petrogenetic process in which high magma temperature (> 900 °C), low pressure, and low water activity in the parental melt favoured the separation of an orthopyroxene bearing cumulate assemblage (orthopyroxene + plagioclase + quartz + K-feldspar + ilmenite + magnetite) in the initial part of the magmatic differentiation. Removal of this anhydrous cumulitic assemblage raised the bulk H<sub>2</sub>O content in the residual melt. Orthopyroxene became unstable with respect to biotite in the evolved melt that eventually crystallised minerals that formed the biotite granite. An increase in magma <em>f</em>O<sub>2</sub> also restricts the orthopyroxene stability in felsic magma. Taken together all the petrological and geochemical attributes, we demonstrate that fractionation of an orthopyroxene-bearing crystal cumulate from the melt is essential to form the charnockites, and that the biotite granite forms from the evolved melt after the fractionation. The charnockite-biotite granite association of the studied area was formed in an extensional tectonic setting, presumably during the breakdown of the Columbia Supercontinent.</p></div>","PeriodicalId":18070,"journal":{"name":"Lithos","volume":"488 ","pages":"Article 107802"},"PeriodicalIF":2.9,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142274193","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LithosPub Date : 2024-09-07DOI: 10.1016/j.lithos.2024.107797
M.A. Finch , A. Olesch-Byrne , T. Chapman , M. Beilharz , A.G. Tomkins
{"title":"Rheology modification in a subduction channel due to eclogite facies metasomatism (Rocky Beach Metamorphic Mélange, Port Macquarie, Australia)","authors":"M.A. Finch , A. Olesch-Byrne , T. Chapman , M. Beilharz , A.G. Tomkins","doi":"10.1016/j.lithos.2024.107797","DOIUrl":"10.1016/j.lithos.2024.107797","url":null,"abstract":"<div><p>The rheological properties of the interface between the down-going and overriding plates in subduction zones provides insight into how plate convergence is accommodated and the controls on seismic and aseismic slip. This interface is known as the subduction channel and exhumed examples provide the only direct information on deformation mechanisms and the impact of metamorphism on rheology. The Rocky Beach Metamorphic Mélange in eastern Australia is one such exhumed subduction channel, composed of eclogite, blueschist and greenschist facies blocks within a mélange matrix. Previous phase equilibria modelling indicates that high pressure blocks were subducted to ca. 100 km depth and then retrogressed during return flow and exhumation. We found that the rheology of blocks is modified by metasomatism, consistent with studies on other subduction channels. However, through comparison of blocks from different metamorphic grades we found that the effect of metasomatism on rheology varied depending on the pressure and temperature conditions of metasomatism. While unmetasomatised eclogites behaved as rigid objects in the mélange matrix, rocks with mineral assemblages that equilibrated during eclogite facies metasomatism accumulated significant strain, forming isoclinal folds and refolded folds. Deformation of these blocks began at eclogite facies and continued during return flow and retrogression to blueschist facies. At blueschist facies, metasomatised blocks developed mm-scale isoclinal folds with shearing parallel to fold limbs forming rootless isoclinal folds. At the transition between blueschist and greenschist facies, pressure solution became important, preferentially focusing along layers of lawsonite, dissolving it from the rock. At greenschist facies, dissolution-precipitation processes caused significant mass loss, producing mm-spacing between pressure solution seams and cuspate folds, analogous to dewatering structures in sediments. In the Rocky Beach Metamorphic Mélange eclogite facies metasomatism reduces the competence of rigid blocks, reducing overall subduction channel heterogeneity during return flow. We suggest that subduction channels that experience widespread eclogite facies metasomatism may be less likely to generate seismic slip during return flow, since the proportion of rigid blocks and block strength are both reduced.</p></div>","PeriodicalId":18070,"journal":{"name":"Lithos","volume":"488 ","pages":"Article 107797"},"PeriodicalIF":2.9,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0024493724003104/pdfft?md5=97015ce7320717b4af856158332aa814&pid=1-s2.0-S0024493724003104-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142232133","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LithosPub Date : 2024-09-07DOI: 10.1016/j.lithos.2024.107796
Ming Yang , Tao Wu , Wen Zhang , Liyan Tian , Jianggu Lu , Taoran Song , Hengrui Zhu , Yidi Hong , Jiawang Chen
{"title":"Tectonic and magmatic evolution of the southernmost Mariana convergent margin: Constraints from geochronology and geochemistry of the Challenger Deep sediments","authors":"Ming Yang , Tao Wu , Wen Zhang , Liyan Tian , Jianggu Lu , Taoran Song , Hengrui Zhu , Yidi Hong , Jiawang Chen","doi":"10.1016/j.lithos.2024.107796","DOIUrl":"10.1016/j.lithos.2024.107796","url":null,"abstract":"<div><p>The southernmost Mariana convergent margin (SMCM) is a distinct segment of the Izu-Bonin-Mariana (IBM) subduction system with unique east-west orientation, however, its nature and tectonic history remains enigmatic. Here, for the first time, we present the detailed geochemical data of detrital minerals and U<img>Pb ages of accessory minerals from two sediment samples recovered at the deepest part of Southern Marianna Trench including the Challenger Deep. Detrital magmatic zircon U<img>Pb ages can be divided into three groups. Group 1 zircons show a weighted mean age of 50.3 ± 1.2 Ma, contemporary to the published boninites from northern IBM. The ε<sub>Hf</sub>(t) of these zircons (11.1–16.4) are also similar to the boninites (12.6–16.8) and volcanic arc rocks (4.2–14.2), but lower than forearc basalts (17.8–22.1), suggesting that these zircons are from boninitic or arc magmatism. The apatite U<img>Pb dating obtained a similar age of 55.0 ± 5.5 Ma. Therefore, if they are all from boninites, then subduction initiation magmatism ended at SMCM was likely coeval with northern IBM. Group 2 and Group 3 zircons have ε<sub>Hf</sub>(t) values similar to Group 1 zircons, but recorded younger <sup>206</sup>Pb/<sup>238</sup>U ages of 16.8 ± 1.8 Ma and 11.0 ± 0.2 Ma, respectively, which are most likely related to the arc volcanism at West Mariana Ridge (WMR). Additionally, a rutile age of 19.0 ± 0.6 Ma is identified, which is also likely related to WMR. The chemical composition and calculated P-T conditions of clinopyroxenes indicate that they are mainly from the Mariana forearc basalts and arc volcanic rocks. <em>In situ</em> Sr isotopic compositions of plagioclases also show strong affinity to the Mariana forearc basalts and arc volcanic rocks. Therefore, our study indicates that sediments at the deep trench can record the long-term tectonic and magmatic evolution of the convergent margin.</p></div>","PeriodicalId":18070,"journal":{"name":"Lithos","volume":"488 ","pages":"Article 107796"},"PeriodicalIF":2.9,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142172522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LithosPub Date : 2024-09-04DOI: 10.1016/j.lithos.2024.107786
Philippe Robidoux , Yves Moussallam , Estelle F. Rose-Koga , Andrea Luca Rizzo , Guillaume Georgeais , Joao Lages , Gilles Lévresse , Simona Ferrando , Alessandro Aiuppa
{"title":"New insights from plumbing system below composite mafic volcanoes: Post-glacial volatile contents and magmatic fluids from Villarrica magmas","authors":"Philippe Robidoux , Yves Moussallam , Estelle F. Rose-Koga , Andrea Luca Rizzo , Guillaume Georgeais , Joao Lages , Gilles Lévresse , Simona Ferrando , Alessandro Aiuppa","doi":"10.1016/j.lithos.2024.107786","DOIUrl":"10.1016/j.lithos.2024.107786","url":null,"abstract":"<div><div>Villarrica volcano, in the southern Andes, is a composite mafic volcano whose persistent open-vent activity is punctuated by frequent Strombolian/Hawaiian eruptions and, more rarely, by more energetic (sub-Plinian) events. Here, we investigate the volatile composition of the parental melts that sustain this activity, and the conditions of pre-eruptive magma storage, by characterizing the composition of olivine-hosted melt and fluid inclusions. We concentrate on inclusions entrapped in minerals from pyroclastic materials erupted from both Villarrica summit and from its flank Minor Eruptive Centers (MECs) post the 14.5–13.5 kyr caldera collapse event that formed the Licán ignimbrite. Our micro-FTIR and SIMS measurements indicate that the Pucón eruption records the highest volatile contents, with 6.0 wt% H<sub>2</sub>O, >1500 ppm CO<sub>2</sub>, 1330 ppm S, 1556 ppm Cl, and 2055 ppm F. These volatile contents imply a volatile-saturated magma originating from a depth of 14.4 to 17 km below Villarrica. Results for other flank eruptions highlight a similarly deep (17–21 km depth) source for basaltic CO<sub>2</sub>-rich mafic magmas erupted at regional MECs (Los Nevados, Caburgua). Melt inclusion results also reveal that deep rising mafic magma batches, when temporarily stored at 1–5 km depth, produce the more differentiated and degassed magma batches that sustain the decadal-old persistent effusive-explosive eruptive activity at Villarrica. Helium isotope ratios (<sup>3</sup>He/<sup>4</sup>He; Rc/Ra when corrected for atmosphere) measured in bulk noble gases from olivines (Fo<sub>75</sub>–<sub>88</sub>) indicate that the parental magmatic fluid signature (Rc/Ra = 6.7–7.6; CO<sub>2</sub>/<sup>3</sup>He = 4.7–7.5E<sup>+08</sup>) is only recorded during central paroxysmal sub-Plinian eruption, and that this primitive gas signal is diluted in lateral MECs (Rc/Ra < 6.5; CO<sub>2</sub>/<sup>3</sup>He = 1.4 × 10<sup>+9</sup>–3.1E<sup>+10</sup>).</div></div>","PeriodicalId":18070,"journal":{"name":"Lithos","volume":"488 ","pages":"Article 107786"},"PeriodicalIF":2.9,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142446360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LithosPub Date : 2024-09-04DOI: 10.1016/j.lithos.2024.107787
Kent C. Condie , Stephen J. Puetz , Kurt E. Sundell , Sergei A. Pisarevsky , Christopher J. Spencer , Nick M.W. Roberts
{"title":"Geographic bias effects on interpretations of secular trends of Hf isotope times series in zircons","authors":"Kent C. Condie , Stephen J. Puetz , Kurt E. Sundell , Sergei A. Pisarevsky , Christopher J. Spencer , Nick M.W. Roberts","doi":"10.1016/j.lithos.2024.107787","DOIUrl":"10.1016/j.lithos.2024.107787","url":null,"abstract":"<div><p>The analysis of εHf(t) time series data from zircon reveals notable discrepancies based on sample type (igneous versus detrital), statistical weighting methodology, and geographic sampling bias. These differences warrant caution when interpreting data in the context of tectonic settings and the history of supercontinents. In terms of tectonic setting, accretionary orogens dominate in both sedimentary basins that host detrital zircons and in igneous zircon sources. Because of differences between the various time series, emphasis in this study is on peaks, valleys and secular trends and not on absolute εHf(t) values. Specifically, the igneous time series for εHf(t) in zircons shows more peaks and valleys than corresponding detrital time series for both weighted and unweighted data (weighting corrects for disproportionate geographic sampling). Also, sample-based (each sample considered separately) and site-based (samples grouped by geographic location and age) results align closely to the igneous time series, whereas the site-based detrital series displays more negative εHf(t) values. Regardless of the type of time series, the failure to compensate for disproportionate geographic sampling increases the prospects of producing an unrepresentative time-series. Nine zircon age peaks (both detrital and igneous) have corresponding εHf(t) peaks (3200, 2700, 2500, 2150, 1500, 1100, 750 Ma) and two have corresponding age valleys (1800–2000, 550 Ma). With exception of a geographically widespread 1500 Ma peak, most of the εHf(t) peaks and valleys are controlled by specific geographic regions and are likely not be global in extent.</p><p>Two distinct periods (200–0 and 1800–1600 Ma) display εHf(t) signatures that rise steadily for 100–200 Myr, coinciding with the final stages of supercontinent assembly and the transition to the retreat of exterior orogens. An εHf(t) peak at 750 Ma and a high at 1400–1100 Ma partly overlap with supercontinent breakup and valleys at 550 Ma and 900 Ma with supercontinent assembly. A large εHf(t) valley at 2000–1800 Ma corresponds with the onset of craton collisions that led to the final assembly of Columbia at 1800–1600 Ma. The steep rise in εHf(t) in the last 200 Myr in both igneous and detrital zircons is controlled by sites in Circum-Pacific orogens in North and South America and Southwest Asia, and it parallels the breakup of Pangea. The general increase in zircon εHf(t) in the last 500 Myr in both detrital and igneous data reflects an increase in the proportion of isotopically juvenile components in accretionary orogens.</p></div>","PeriodicalId":18070,"journal":{"name":"Lithos","volume":"488 ","pages":"Article 107787"},"PeriodicalIF":2.9,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142150141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}