XVI ICT '97. Proceedings ICT'97. 16th International Conference on Thermoelectrics (Cat. No.97TH8291)最新文献

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Status and future prospects on the development of thermoelectric power generation systems utilizing combustion heat from municipal solid waste 城市生活垃圾燃烧热发电系统的发展现状与展望
T. Kajikawa
{"title":"Status and future prospects on the development of thermoelectric power generation systems utilizing combustion heat from municipal solid waste","authors":"T. Kajikawa","doi":"10.1109/ICT.1997.666971","DOIUrl":"https://doi.org/10.1109/ICT.1997.666971","url":null,"abstract":"The characteristics of combustion heat from the municipal solid waste are fitted for a large-scale application of thermoelectric power generation potentially. The status and future prospects of thermoelectric power generation systems to recover electricity from this heat source in Japan are reviewed and discussed. Experimental results on three different types of small-scale (500 W class) thermoelectric power generation systems installed in the real municipal solid waste processing systems to demonstrate the technological feasibility and to extract the technological problems are briefly introduced. The conceptual designs of a small scale system for the next phase of the R&D program are presented. From the view point of large-scale realization the thermoelectric material and modules configurations required for this application are also discussed. A case study on the marginal cost estimation shows the cost reduction to be less than 0.4-0.5 Million Yen/kW in order to make a profit on this system.","PeriodicalId":174813,"journal":{"name":"XVI ICT '97. Proceedings ICT'97. 16th International Conference on Thermoelectrics (Cat. No.97TH8291)","volume":"122 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123031397","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 19
Transport study of Hg-based high temperature superconductors 氢基高温超导体输运研究
M. Pękała, H. Bougrine, I. Sargánková, M. Ausloos
{"title":"Transport study of Hg-based high temperature superconductors","authors":"M. Pękała, H. Bougrine, I. Sargánková, M. Ausloos","doi":"10.1109/ICT.1997.667580","DOIUrl":"https://doi.org/10.1109/ICT.1997.667580","url":null,"abstract":"Polycrystalline superconductors Hg/sub 1/Ba/sub 2/Ca/sub 2/Cu/sub 3/O/sub 8+/spl delta// were synthesized from oxides by the solid state reaction. Thermoelectric power, thermal conductivity and electrical resistivity of the Hg-based high temperature superconductors were measured in a broad temperature range between 20 and 300 K. The influence of magnetic fields up to 0.35 T was also studied. The superconducting transition starts at about 136 K and is completed in a relatively narrow temperature interval as revealed by thermoelectric power and resistivity measurements. The transition interval broadens in a magnetic field. The experimental data are used to determine and discuss the figure of merit for the Hg1223 superconductor. The figure of merit increases in an external small magnetic field.","PeriodicalId":174813,"journal":{"name":"XVI ICT '97. Proceedings ICT'97. 16th International Conference on Thermoelectrics (Cat. No.97TH8291)","volume":"2 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131116472","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of Zn/sub 4/Sb/sub 3/ compound by PIES method pie法合成Zn/sub - 4/Sb/sub - 3/化合物
A. Yamamoto, T. Ichizuka, H. Takazawa, T. Ohta, T. Kajikawa
{"title":"Synthesis of Zn/sub 4/Sb/sub 3/ compound by PIES method","authors":"A. Yamamoto, T. Ichizuka, H. Takazawa, T. Ohta, T. Kajikawa","doi":"10.1109/ICT.1997.667578","DOIUrl":"https://doi.org/10.1109/ICT.1997.667578","url":null,"abstract":"An attempt was made to synthesize /spl beta/-Zn/sub 4/Sb/sub 3/ semiconducting compound by PIES (Pulverized and Intermixed Elements Sintering)/hot-pressing method. We found that it is possible to synthesize /spl beta/-Zn/sub 4/Sb/sub 3/ as a major phase without increased temperature when we start the ball milling process with a Zn-rich composition. The power factor /spl alpha//sup 2///spl rho/ at room temperature was 6.3/spl times/10/sup -4/ W/mK/sup 2/ and these initial data clarified that relatively high performance can be achieved with the PIES/hot-press method.","PeriodicalId":174813,"journal":{"name":"XVI ICT '97. Proceedings ICT'97. 16th International Conference on Thermoelectrics (Cat. No.97TH8291)","volume":"21 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127825342","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermoelectric generator for underwater wellhead 水下井口热电发电机
P. Dubourdieu, G. Tribou, S. Byrne
{"title":"Thermoelectric generator for underwater wellhead","authors":"P. Dubourdieu, G. Tribou, S. Byrne","doi":"10.1109/ICT.1997.667603","DOIUrl":"https://doi.org/10.1109/ICT.1997.667603","url":null,"abstract":"DCN CHERBOURG, the French submarine builder, has a great deal of experience in underwater equipment. The company also has experience in thermoelectric technology which is used in submarines for cooling systems. In light of this experience, DCN CHERBOURG was contacted by an oil company in order to develop a thermoelectric generator for an offshore subsea application The requirements were: (i) a thermogenerator able to be inserted as a spool in a submarine pipeline; (ii) site: North Sea (sea water temperature=4/spl deg/C); and (iii) fluid: mix of oil and gas, temperature between 90/spl deg/C and 120/spl deg/C, pressure 450 bar. The design began with thermoelectric module tests (electrical, thermal and mechanical). The objective was to select the type of thermoelectric module and the assembly system. The ceramic technology from MELCOR was chosen. DCN CHERBOURG then made and tested a prototype. The performance results were not as good as expected, however, the prototype proved that a thermoelectric generator for an offshore subsea application was feasible. The next step was the assembling of two thermogenerators (THEGS) for an offshore application. The performance measurements obtained during on-shore testing were as expected: about 100 W at 70 V.","PeriodicalId":174813,"journal":{"name":"XVI ICT '97. Proceedings ICT'97. 16th International Conference on Thermoelectrics (Cat. No.97TH8291)","volume":"783 ","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133322988","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Crystal grain size dependence of thermoelectric properties for sintered PbTe by spark plasma sintering technique 火花等离子烧结技术烧结PbTe热电性能的晶粒尺寸依赖性
S. Yoneda, E. Ohta, H. Kaibe, I. Shiota, K. Takahashi, Y. Shinohara, Y. Imai, I.A. Niskida
{"title":"Crystal grain size dependence of thermoelectric properties for sintered PbTe by spark plasma sintering technique","authors":"S. Yoneda, E. Ohta, H. Kaibe, I. Shiota, K. Takahashi, Y. Shinohara, Y. Imai, I.A. Niskida","doi":"10.1109/ICT.1997.667099","DOIUrl":"https://doi.org/10.1109/ICT.1997.667099","url":null,"abstract":"Thermal and electrical conduction parameters of the sintered PbTe with different crystal grain sizes Ds were measured over the temperature range from 77 to 350 K, to examine the possibility of improvement in thermoelectric performance for sintered PbTe by reducing D. The starting powders with particle sizes of 6, 39, 180 and 380 /spl mu/m were obtained by pulverizing an undoped PbTe boule prepared by the Bridgman method. Sintering was carried out by the spark plasma sintering technique (SPS) under the conditions of sintering temperature of 732-803 K, sintering duration of 60-90 min and sintering pressure of 45 MPa. All the sintered compacts, whose conduction type was p-type, had an apparent relative density of more than 99%. Thermal conductivity /spl kappa/ decreased with reducing D below 200 K, but showed no dependence on D above 200 K. Long-wave phonons are scattered efficiently at grain boundaries only below 200 K. Hall mobility /spl mu//sub H/ of the sintered compacts with different Ds were almost same above 200 K. It is concluded that thermoelectric performance for sintered PbTe is not directly affected by controlling D.","PeriodicalId":174813,"journal":{"name":"XVI ICT '97. Proceedings ICT'97. 16th International Conference on Thermoelectrics (Cat. No.97TH8291)","volume":"19 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134209483","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Rare earth thermoelectrics 稀土热电
G. Mahan
{"title":"Rare earth thermoelectrics","authors":"G. Mahan","doi":"10.1109/ICT.1997.666970","DOIUrl":"https://doi.org/10.1109/ICT.1997.666970","url":null,"abstract":"We review the thermoelectric properties of metallic compounds which contain rare-earth atoms. They are the group of metals with the largest value ever reported of the Seebeck coefficient. An increase by 50% of the Seebeck coefficient would make these compounds useful for thermoelectric devices. The largest Seebeck coefficient is found for compounds of cerium (e.g. CePd/sub 3/) and ytterbium (e.g. YbAl/sub 3/). Theoretical predictions are in agreement with the maximum observed Seebeck coefficient. We discuss the theoretical model which has been used to calculate the Seebeck coefficient. We are solving this model for other configurations (4f)/sup n/ of rare-earth ground states.","PeriodicalId":174813,"journal":{"name":"XVI ICT '97. Proceedings ICT'97. 16th International Conference on Thermoelectrics (Cat. No.97TH8291)","volume":"60 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131703890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Effects of a reduction treatment and Te doping on thermoelectric properties of (Bi/sub 1-x/Sb/sub x/)/sub 2/Te/sub 3/ fabricated by mechanical alloying 还原处理和Te掺杂对机械合金化制备(Bi/sub - 1-x/Sb/sub -x/)/sub - 2/Te/sub - 3/热电性能的影响
Hang-Chong Kim, Jae-Shik Choi, Hee-Jeong Kim, D. Hyun, T. Oh
{"title":"Effects of a reduction treatment and Te doping on thermoelectric properties of (Bi/sub 1-x/Sb/sub x/)/sub 2/Te/sub 3/ fabricated by mechanical alloying","authors":"Hang-Chong Kim, Jae-Shik Choi, Hee-Jeong Kim, D. Hyun, T. Oh","doi":"10.1109/ICT.1997.666991","DOIUrl":"https://doi.org/10.1109/ICT.1997.666991","url":null,"abstract":"(Bi/sub 1-x/Sb/sub x/)/sub 2/Te/sub 3/ (0.75/spl les/x/spl les/0.85) thermoelectric materials were fabricated by mechanical alloying and hot pressing at 550/spl deg/C for 30 minutes with and without reduction treatment of the mechanically alloyed powders. When the mechanically alloyed (Bi/sub 1-x/Sb/sub x/)/sub 2/Te/sub 3/ powders were hot-pressed without a reduction treatment, a maximum figure-of-merit of 2.92/spl times/10/sup -3//K at 300 K was obtained for x=0.8 composition. Although the electrical resistivity of the mechanically alloyed (Bi/sub 1-x/Sb/sub x/)/sub 2/Te/sub 3/ decreased with a reduction treatment of the powders, the figure-of-merit was lowered due to the substantial decrease of the Seebeck coefficient. With addition of 1 wt% excess Te, the figure-of-merit of the reduction-treated (Bi/sub 0.2/Sb/sub 0.8/)/sub 2/Te/sub 3/ could be improved to be 3.33/spl times/10/sup -3//K.","PeriodicalId":174813,"journal":{"name":"XVI ICT '97. Proceedings ICT'97. 16th International Conference on Thermoelectrics (Cat. No.97TH8291)","volume":"22 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115669753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Grain size effects on thermoelectric properties of hot-pressed CoSb/sub 3/ 晶粒尺寸对热压CoSb/ sub3 /热电性能的影响
H. Nakagawa, H. Tanaka, A. Kasama, H. Anno, K. Matsubara
{"title":"Grain size effects on thermoelectric properties of hot-pressed CoSb/sub 3/","authors":"H. Nakagawa, H. Tanaka, A. Kasama, H. Anno, K. Matsubara","doi":"10.1109/ICT.1997.667151","DOIUrl":"https://doi.org/10.1109/ICT.1997.667151","url":null,"abstract":"To get high ZT values, grain size optimization of hot-pressed CoSb/sub 3/ is very important. Although single crystals of CoSb/sub 3/ have high electrical conductivities and moderate Seebeck coefficients, the ZT values are relatively low because of the high thermal conductivities. We tried to lower the thermal conductivity of hot-pressed CoSb by reducing the grain size. Mechanical alloying of the raw material powders of Co and Sb was the very effective method to reduce the grain size of hot-pressed CoSb/sub 3/. This paper shows the relations between the thermoelectric properties (Hall mobility, Seebeck coefficient, electrical conductivity and thermal conductivity) and the grain size. The thermal conductivity of hot-pressed CoSb/sub 3/ decreased with reducing the grain size. The value of 4.19 Wm/sup -1/ K/sup -1/, which is about 40% of the single crystals, was ultimately obtained at 293 K for the hot-pressed material with an average grain size of 0.9 /spl mu/m. Although the larger grain size is preferable to attain a high ZT value at 293 K, because of the greater decrease of the carrier mobility than the thermal conductivity with reducing the average grain size, the highest ZT value of 0.10 was obtained at 673 K on the sample with an average grain size of 2.1 /spl mu/m.","PeriodicalId":174813,"journal":{"name":"XVI ICT '97. Proceedings ICT'97. 16th International Conference on Thermoelectrics (Cat. No.97TH8291)","volume":"15 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116483103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 11
Transport properties of ZrNiSn-based intermetallics zrnisn基金属间化合物的输运性质
C. Uher, Siqing Hu, Jihui Yang, G. Meisner, D. Morelli
{"title":"Transport properties of ZrNiSn-based intermetallics","authors":"C. Uher, Siqing Hu, Jihui Yang, G. Meisner, D. Morelli","doi":"10.1109/ICT.1997.667191","DOIUrl":"https://doi.org/10.1109/ICT.1997.667191","url":null,"abstract":"Intermetallic compounds of the form MNiSn, where M is titanium, zirconium, or hafnium, are semiconductors with band gaps on the order of 0.2 electron volts. Due to their large conduction band masses, they show promise as thermoelectric materials with high figure of merit. In order to assess this potential, we have studied the thermoelectric properties of pure and doped ZrNiSn and Zr/sub 0.5/Hf/sub 0.5/NiSn mixed crystals. Upon doping with Sb the resistivity can be reduced by a factor of 20-40 with a reduction in the Seebeck coefficient of only a factor of two. The resulting power factors of doped samples at room temperature are comparable to those of state of the art thermoelectric materials. The thermal conductivity of Zr/sub 0.5/Hf/sub 0.5/NiSn is reduced strongly relative to ZrNiSn but must be reduced further to obtain a large figure of merit. The transport properties of these materials are very sensitive to annealing conditions.","PeriodicalId":174813,"journal":{"name":"XVI ICT '97. Proceedings ICT'97. 16th International Conference on Thermoelectrics (Cat. No.97TH8291)","volume":"29 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"117032276","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 11
Crystalline structure and thermoelectric properties versus growing conditions of sputtering-deposited (Bi/sub 1-x/Sb/sub x/)/sub 2/Te/sub 3/ films with 0/spl les/x/spl les/0.85 0/spl les/x/spl les/0.85溅射沉积(Bi/sub 1-x/Sb/sub x/)/sub 2/Te/sub 3/薄膜的晶体结构和热电性能与生长条件的关系
M. Stolzer, V. Bechstein, J. Meusel
{"title":"Crystalline structure and thermoelectric properties versus growing conditions of sputtering-deposited (Bi/sub 1-x/Sb/sub x/)/sub 2/Te/sub 3/ films with 0/spl les/x/spl les/0.85","authors":"M. Stolzer, V. Bechstein, J. Meusel","doi":"10.1109/ICT.1997.666982","DOIUrl":"https://doi.org/10.1109/ICT.1997.666982","url":null,"abstract":"(Bi/sub 1-x/Sb/sub x/)/sub 2/Te/sub 3/ films of about 1 /spl mu/m thickness were deposited on Kapton substrates by means of DC magnetron sputtering. Four different targets were used with compositions according to (Bi/sub 1-x/Sb/sub x/)/sub 2/Te/sub 3/+20 at% Te and x=0, 0.5, 0.75 and 0.85. The substrate temperature T/sub s/ and of a hot-wall environment T/sub e/ were altered in the range of 220...320/spl deg/C and 150...390/spl deg/C, respectively. Composition and crystalline structure were studied using WDX, SEM and XRD. Films grown at T/sub s/<290/spl deg/C had rough surfaces and weak texture. Above T/sub s/=290/spl deg/C the films were strongly (0 0 n) textured and had smooth surfaces. Annealing at 300 or 350/spl deg/C increased the size of the crystallites but their orientation was unchanged. This behaviour was independent of the composition x. The transport properties depend significantly on Sb-Bi ratio x, substrate and environment temperatures and annealing. High carrier mobilities could only be achieved together with low carrier concentrations and at T/sub s//spl ap/250/spl deg/C after annealing. Films best suited for thermoelectric applications (highest power factor at room temperature) had the composition (Bi/sub 0.15/Sb/sub 0.85/)/sub 2/Te/sub 3/, the conductivity /spl sigma/=1140 /spl Omega//sup -1/ cm/sup -1/, the carrier mobility /spl mu/=360cm/sup 2//Vs and the Seebeck coefficient S=182 /spl mu/V/K.","PeriodicalId":174813,"journal":{"name":"XVI ICT '97. Proceedings ICT'97. 16th International Conference on Thermoelectrics (Cat. No.97TH8291)","volume":"23 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123574834","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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