{"title":"LIII.—The constituents of Indian turpentine from Pinus longifolia, roxb. Part IV","authors":"P. Pillay, J. Simonsen","doi":"10.1039/JR9280000359","DOIUrl":"https://doi.org/10.1039/JR9280000359","url":null,"abstract":"","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2013-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76817078","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"CCCXXXVIII.—The atomic weight of antimony from different sources","authors":"K. R. Krishnaswami","doi":"10.1039/JR9270002534","DOIUrl":"https://doi.org/10.1039/JR9270002534","url":null,"abstract":"","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2013-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75225864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Pigments, mediums, and technical methods of classical and mediæval painters","authors":"A. Laurie","doi":"10.1039/JR9370000163","DOIUrl":"https://doi.org/10.1039/JR9370000163","url":null,"abstract":"","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2008-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90596529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. Maarseveen, Wim J. N. Meester, J. Veerman, C. G. Kruse, P. Hermkens, F. Rutjes, H. Hiemstra
{"title":"Development and application of allyl, 2-sulfonylethyl and 2-thioethyl carbamate linkers for solid phase N-acyliminium ion chemistry.","authors":"J. Maarseveen, Wim J. N. Meester, J. Veerman, C. G. Kruse, P. Hermkens, F. Rutjes, H. Hiemstra","doi":"10.1039/B100998M","DOIUrl":"https://doi.org/10.1039/B100998M","url":null,"abstract":"We have evaluated the allyl, 2-sulfonylethyl (SEC) and 2-thioethyl (TEC) carbamate linker systems for their application in solid supported N-acyliminium ion chemistry. As model reactions the syntheses of both homoallylic amines (via a three component protocol starting from an immobilised primary carbamate) and 2-substituted pyrrolidines (via carbamate bound 4,4-diethoxy-2-phenylbutylamine) were conducted. The required precursor p-nitrophenyl carbonate resins were prepared in high yields from cheap starting materials. All linkers proved to be stable under the required cationic reaction conditions. A serious drawback of the allyl carbamate linker is the tedious work up procedure which is required for the removal of the remains of the cleavage cocktail. The SEC linker is excellently stable to both Lewis and protic acidic conditions combined with a moderate base stability thus allowing the use of amines as reactants or bases in subsequent reactions. Cleavage of SEC linker bound amines was easily effected by treatment of the resins with a cocktail of 1 M NaOMe in THF–MeOH (2 ∶ 1). The widest synthetic scope was found with the TEC linker which combined a sufficient stability against the cationic conditions required for N-acyliminium ion chemistry with complete stability under basic conditions. Cleavage of TEC linker bound amines could be effected by treatment with strong acid or by oxidation of the sulfide to the sulfone (to give the SEC linker) followed by addition of the basic cleavage cocktail.","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2001-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75199541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Sign of the Nuclear Overhauser Effect as a Function of Temperature in Contact Ion Pairs","authors":"T. Pochapsky, P. M. Stone, E. Callagari","doi":"10.1039/C39920000178","DOIUrl":"https://doi.org/10.1039/C39920000178","url":null,"abstract":"The signs and magnitudes of nuclear overhauser effects observed in closed-shell ion pairs in C2HCl3 show an unusual temperature dependence; freezing point depression measurements support the proposal that the observed dependence is due at least in part to the formation of ion aggregates.","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1992-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73884556","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Characteristic function of momentum density distribution. II","authors":"T. Koga","doi":"10.1063/1.445896","DOIUrl":"https://doi.org/10.1063/1.445896","url":null,"abstract":"Rigorous relations between the moments 〈plxpmypnz〉 and 〈pn〉 and the characteristic function B(r) of the momentum density distribution ρ(p) are here generalized to the case of negative l, m, and n. A simple application is given which illustrates that the present results enable us to obtain the moments of momenta without referring to any momentum‐space quantity.","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1982-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85848221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
R. Kind, S. P. ko, H. Arend, R. Blinc, B. ek, J. Seliger, B. L. ar, J. Slak, A. Levstik, C. Filipi, V. agar, G. Lahajnar, F. Milia, G. Chapuis
{"title":"Dynamics of the n-decylammonium chains in the perowskite-type Layer structure compound (C10H21NH3)2CdCl4","authors":"R. Kind, S. P. ko, H. Arend, R. Blinc, B. ek, J. Seliger, B. L. ar, J. Slak, A. Levstik, C. Filipi, V. agar, G. Lahajnar, F. Milia, G. Chapuis","doi":"10.1063/1.438584","DOIUrl":"https://doi.org/10.1063/1.438584","url":null,"abstract":"The two structural phase transitions in the perovskite layer structure compound (C10H21NH3)2CdCl4 at Tc1=35 °C and Tc2=39 °C have been studied by x‐ray diffractional, calorimetric and dielectric measurements, proton NMR spin–lattice relaxation and second moment investigations, 35Cl and 14N quadrupole resonance spectroscopy as well as group theoretical considerations. The results show that the transition (Tc1) from the low temperature phase (P21/n) to the intermediate temperature phase (Pmnn) is basically a dynamic order–disorder transition of rigid alkyl chains, whereas the transition (Tc2) from the intermediate to the high temperature phase (Amaa) is connected with a melting of the alkyl chains. In the intermediate phase the rigid alkyl chains are flipping around their long axes between two equivalent orientations separated by 90°. The two transitions are somewhat analogous to the ones found in the lipid bilayer membranes and can be described by order parameters used for smectic liquid crystals.","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1979-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81313887","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Cyclisation of squalene 2,3;22,23-diepoxide by microsomes from bramble (Rabus fruticosa) tissues grown in vitro","authors":"R. Heintz, P. Benveniste","doi":"10.1039/C29700000946","DOIUrl":"https://doi.org/10.1039/C29700000946","url":null,"abstract":"Incubation of squalene 2,3;22,23-diepoxide with microsomes of Rubus fruticosa gives 24,25-epoxycycloartanol.","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1970-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83358249","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"481. Radiation chemistry of carbohydrates. Part XV. Mechanism of self-decomposition of [C]D-glucose","authors":"G. Phillips, K. Davies","doi":"10.1039/JR9650002654","DOIUrl":"https://doi.org/10.1039/JR9650002654","url":null,"abstract":"","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1965-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78489060","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"1105. Electrophilic additions to alkenes. Part I. Kinetics of the reaction of 2,4-dinitrobenzenesulphenyl bromide with cyclohexene in acetic acid solution","authors":"D. Campbell, D. Hogg","doi":"10.1039/JR9650005887","DOIUrl":"https://doi.org/10.1039/JR9650005887","url":null,"abstract":"","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1965-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73516342","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}