Journal of The Chemical Society (resumed)最新文献

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LIII.—The constituents of Indian turpentine from Pinus longifolia, roxb. Part IV LIII。-印度松节油的成分,来自长叶松,roxb。第四部分
Journal of The Chemical Society (resumed) Pub Date : 2013-06-05 DOI: 10.1039/JR9280000359
P. Pillay, J. Simonsen
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引用次数: 3
CCCXXXVIII.—The atomic weight of antimony from different sources CCCXXXVIII。-不同来源锑的原子量
Journal of The Chemical Society (resumed) Pub Date : 2013-06-05 DOI: 10.1039/JR9270002534
K. R. Krishnaswami
{"title":"CCCXXXVIII.—The atomic weight of antimony from different sources","authors":"K. R. Krishnaswami","doi":"10.1039/JR9270002534","DOIUrl":"https://doi.org/10.1039/JR9270002534","url":null,"abstract":"","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2013-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75225864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pigments, mediums, and technical methods of classical and mediæval painters 古典和中世纪画家的颜料、介质和技术方法
Journal of The Chemical Society (resumed) Pub Date : 2008-10-22 DOI: 10.1039/JR9370000163
A. Laurie
{"title":"Pigments, mediums, and technical methods of classical and mediæval painters","authors":"A. Laurie","doi":"10.1039/JR9370000163","DOIUrl":"https://doi.org/10.1039/JR9370000163","url":null,"abstract":"","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2008-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90596529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Development and application of allyl, 2-sulfonylethyl and 2-thioethyl carbamate linkers for solid phase N-acyliminium ion chemistry. 烯丙基、2-磺基乙基和2-硫乙基氨基甲酸酯固相n -酰基离子化学连接剂的开发与应用。
Journal of The Chemical Society (resumed) Pub Date : 2001-01-01 DOI: 10.1039/B100998M
J. Maarseveen, Wim J. N. Meester, J. Veerman, C. G. Kruse, P. Hermkens, F. Rutjes, H. Hiemstra
{"title":"Development and application of allyl, 2-sulfonylethyl and 2-thioethyl carbamate linkers for solid phase N-acyliminium ion chemistry.","authors":"J. Maarseveen, Wim J. N. Meester, J. Veerman, C. G. Kruse, P. Hermkens, F. Rutjes, H. Hiemstra","doi":"10.1039/B100998M","DOIUrl":"https://doi.org/10.1039/B100998M","url":null,"abstract":"We have evaluated the allyl, 2-sulfonylethyl (SEC) and 2-thioethyl (TEC) carbamate linker systems for their application in solid supported N-acyliminium ion chemistry. As model reactions the syntheses of both homoallylic amines (via a three component protocol starting from an immobilised primary carbamate) and 2-substituted pyrrolidines (via carbamate bound 4,4-diethoxy-2-phenylbutylamine) were conducted. The required precursor p-nitrophenyl carbonate resins were prepared in high yields from cheap starting materials. All linkers proved to be stable under the required cationic reaction conditions. A serious drawback of the allyl carbamate linker is the tedious work up procedure which is required for the removal of the remains of the cleavage cocktail. The SEC linker is excellently stable to both Lewis and protic acidic conditions combined with a moderate base stability thus allowing the use of amines as reactants or bases in subsequent reactions. Cleavage of SEC linker bound amines was easily effected by treatment of the resins with a cocktail of 1 M NaOMe in THF–MeOH (2 ∶ 1). The widest synthetic scope was found with the TEC linker which combined a sufficient stability against the cationic conditions required for N-acyliminium ion chemistry with complete stability under basic conditions. Cleavage of TEC linker bound amines could be effected by treatment with strong acid or by oxidation of the sulfide to the sulfone (to give the SEC linker) followed by addition of the basic cleavage cocktail.","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2001-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75199541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
The Sign of the Nuclear Overhauser Effect as a Function of Temperature in Contact Ion Pairs 接触离子对中核大修效应随温度变化的符号
Journal of The Chemical Society (resumed) Pub Date : 1992-01-01 DOI: 10.1039/C39920000178
T. Pochapsky, P. M. Stone, E. Callagari
{"title":"The Sign of the Nuclear Overhauser Effect as a Function of Temperature in Contact Ion Pairs","authors":"T. Pochapsky, P. M. Stone, E. Callagari","doi":"10.1039/C39920000178","DOIUrl":"https://doi.org/10.1039/C39920000178","url":null,"abstract":"The signs and magnitudes of nuclear overhauser effects observed in closed-shell ion pairs in C2HCl3 show an unusual temperature dependence; freezing point depression measurements support the proposal that the observed dependence is due at least in part to the formation of ion aggregates.","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1992-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73884556","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Characteristic function of momentum density distribution. II 动量密度分布的特征函数。2
Journal of The Chemical Society (resumed) Pub Date : 1982-12-15 DOI: 10.1063/1.445896
T. Koga
{"title":"Characteristic function of momentum density distribution. II","authors":"T. Koga","doi":"10.1063/1.445896","DOIUrl":"https://doi.org/10.1063/1.445896","url":null,"abstract":"Rigorous relations between the moments 〈plxpmypnz〉 and 〈pn〉 and the characteristic function B(r) of the momentum density distribution ρ(p) are here generalized to the case of negative l, m, and n. A simple application is given which illustrates that the present results enable us to obtain the moments of momenta without referring to any momentum‐space quantity.","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1982-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85848221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 10
Dynamics of the n-decylammonium chains in the perowskite-type Layer structure compound (C10H21NH3)2CdCl4 钙钛矿型层状结构化合物(C10H21NH3)2CdCl4中n-癸胺链的动力学
Journal of The Chemical Society (resumed) Pub Date : 1979-09-01 DOI: 10.1063/1.438584
R. Kind, S. P. ko, H. Arend, R. Blinc, B. ek, J. Seliger, B. L. ar, J. Slak, A. Levstik, C. Filipi, V. agar, G. Lahajnar, F. Milia, G. Chapuis
{"title":"Dynamics of the n-decylammonium chains in the perowskite-type Layer structure compound (C10H21NH3)2CdCl4","authors":"R. Kind, S. P. ko, H. Arend, R. Blinc, B. ek, J. Seliger, B. L. ar, J. Slak, A. Levstik, C. Filipi, V. agar, G. Lahajnar, F. Milia, G. Chapuis","doi":"10.1063/1.438584","DOIUrl":"https://doi.org/10.1063/1.438584","url":null,"abstract":"The two structural phase transitions in the perovskite layer structure compound (C10H21NH3)2CdCl4 at Tc1=35 °C and Tc2=39 °C have been studied by x‐ray diffractional, calorimetric and dielectric measurements, proton NMR spin–lattice relaxation and second moment investigations, 35Cl and 14N quadrupole resonance spectroscopy as well as group theoretical considerations. The results show that the transition (Tc1) from the low temperature phase (P21/n) to the intermediate temperature phase (Pmnn) is basically a dynamic order–disorder transition of rigid alkyl chains, whereas the transition (Tc2) from the intermediate to the high temperature phase (Amaa) is connected with a melting of the alkyl chains. In the intermediate phase the rigid alkyl chains are flipping around their long axes between two equivalent orientations separated by 90°. The two transitions are somewhat analogous to the ones found in the lipid bilayer membranes and can be described by order parameters used for smectic liquid crystals.","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1979-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81313887","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 142
Cyclisation of squalene 2,3;22,23-diepoxide by microsomes from bramble (Rabus fruticosa) tissues grown in vitro 体外培养的黑莓(Rabus fruticosa)组织微粒体对角鲨烯2,3;22,23-二氧化物的环化
Journal of The Chemical Society (resumed) Pub Date : 1970-11-21 DOI: 10.1039/C29700000946
R. Heintz, P. Benveniste
{"title":"Cyclisation of squalene 2,3;22,23-diepoxide by microsomes from bramble (Rabus fruticosa) tissues grown in vitro","authors":"R. Heintz, P. Benveniste","doi":"10.1039/C29700000946","DOIUrl":"https://doi.org/10.1039/C29700000946","url":null,"abstract":"Incubation of squalene 2,3;22,23-diepoxide with microsomes of Rubus fruticosa gives 24,25-epoxycycloartanol.","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1970-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83358249","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
481. Radiation chemistry of carbohydrates. Part XV. Mechanism of self-decomposition of [C]D-glucose 481. 碳水化合物的辐射化学。十五。[C] d -葡萄糖自分解机理研究
Journal of The Chemical Society (resumed) Pub Date : 1965-04-01 DOI: 10.1039/JR9650002654
G. Phillips, K. Davies
{"title":"481. Radiation chemistry of carbohydrates. Part XV. Mechanism of self-decomposition of [C]D-glucose","authors":"G. Phillips, K. Davies","doi":"10.1039/JR9650002654","DOIUrl":"https://doi.org/10.1039/JR9650002654","url":null,"abstract":"","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1965-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78489060","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
1105. Electrophilic additions to alkenes. Part I. Kinetics of the reaction of 2,4-dinitrobenzenesulphenyl bromide with cyclohexene in acetic acid solution 1105. 烯烃的亲电加成。第一部分:2,4-二硝基苯磺基溴与环己烯在乙酸溶液中的反应动力学
Journal of The Chemical Society (resumed) Pub Date : 1965-01-01 DOI: 10.1039/JR9650005887
D. Campbell, D. Hogg
{"title":"1105. Electrophilic additions to alkenes. Part I. Kinetics of the reaction of 2,4-dinitrobenzenesulphenyl bromide with cyclohexene in acetic acid solution","authors":"D. Campbell, D. Hogg","doi":"10.1039/JR9650005887","DOIUrl":"https://doi.org/10.1039/JR9650005887","url":null,"abstract":"","PeriodicalId":17266,"journal":{"name":"Journal of The Chemical Society (resumed)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1965-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73516342","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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