接触离子对中核大修效应随温度变化的符号

Journal of The Chemical Society (resumed) Pub Date : 1992-01-01 DOI:10.1039/C39920000178

T. Pochapsky, P. M. Stone, E. Callagari

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引用次数: 4

摘要

在C2HCl3的闭壳离子对中观察到的核过载效应的符号和大小表现出不同寻常的温度依赖性;冰点下降的测量结果支持这样的建议，即所观察到的依赖性至少部分是由于离子聚集体的形成。

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The Sign of the Nuclear Overhauser Effect as a Function of Temperature in Contact Ion Pairs

The signs and magnitudes of nuclear overhauser effects observed in closed-shell ion pairs in C2HCl3 show an unusual temperature dependence; freezing point depression measurements support the proposal that the observed dependence is due at least in part to the formation of ion aggregates.

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Journal of The Chemical Society (resumed)

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