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Journal of Porphyrins and Phthalocyanines最新文献

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Instability of 9-aminoporphycenes 9-氨基卟啉的不稳定性
IF 1.5 4区 化学
Journal of Porphyrins and Phthalocyanines Pub Date : 2023-06-28 DOI: 10.1142/s1088424623501122
I. Mbakara, A. Gajewska, Krzysztof Nawara, J. Waluk
{"title":"Instability of 9-aminoporphycenes","authors":"I. Mbakara, A. Gajewska, Krzysztof Nawara, J. Waluk","doi":"10.1142/s1088424623501122","DOIUrl":"https://doi.org/10.1142/s1088424623501122","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42219607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Spectral-luminescence, redox and photochemical properties of AlIII, GaIII and InIII complexes formed by peripherally chlorinated phthalocyanines and tetrapyrazinoporphyrazines 外周氯化酞菁和四吡嗪卟啉形成的AlIII、GaIII和InIII配合物的光谱发光、氧化还原和光化学性质
IF 1.5 4区 化学
Journal of Porphyrins and Phthalocyanines Pub Date : 2023-06-28 DOI: 10.1142/s1088424623501134
Daniil N Finogenov, Dmitriy A. Lazovskiy, Alina S. Kopylova, Yuriy A. Zhabanov, P. Stuzhin
{"title":"Spectral-luminescence, redox and photochemical properties of AlIII, GaIII and InIII complexes formed by peripherally chlorinated phthalocyanines and tetrapyrazinoporphyrazines","authors":"Daniil N Finogenov, Dmitriy A. Lazovskiy, Alina S. Kopylova, Yuriy A. Zhabanov, P. Stuzhin","doi":"10.1142/s1088424623501134","DOIUrl":"https://doi.org/10.1142/s1088424623501134","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":"1 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41458886","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Redox-responsive 1D-assembly built from cucurbit[8]uril and a water-soluble metalloporphyrin-based tecton 氧化还原响应的三维组装，由葫芦bbbburil和水溶性金属卟啉为基础的结构
IF 1.5 4区 化学
Journal of Porphyrins and Phthalocyanines Pub Date : 2023-06-28 DOI: 10.1142/s1088424623501146
Shagor Chowdhury, P. Hennequin, O. Cala, Sandrine Denis‐Quanquin, E. saint-Aman, Denis Frath, F. Chevallier, C. Bucher
{"title":"Redox-responsive 1D-assembly built from cucurbit[8]uril and a water-soluble metalloporphyrin-based tecton","authors":"Shagor Chowdhury, P. Hennequin, O. Cala, Sandrine Denis‐Quanquin, E. saint-Aman, Denis Frath, F. Chevallier, C. Bucher","doi":"10.1142/s1088424623501146","DOIUrl":"https://doi.org/10.1142/s1088424623501146","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43518643","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Perylenemonoimide-subphthalocyanine derivatives: Synthesis, characterization and photovoltaic performance as non-fullerene acceptors in bulk heterojunction solar cells 苝酰亚胺亚酞菁衍生物的合成、表征及其在体异质结太阳能电池中作为非富勒烯受体的光伏性能
IF 1.5 4区 化学
Journal of Porphyrins and Phthalocyanines Pub Date : 2023-06-28 DOI: 10.1142/s1088424623501110
Jorge Labella, J. García-Calvo, M. Ramírez-Como, J. Pallarès, L. Marsal, T. Torres
{"title":"Perylenemonoimide-subphthalocyanine derivatives: Synthesis, characterization and photovoltaic performance as non-fullerene acceptors in bulk heterojunction solar cells","authors":"Jorge Labella, J. García-Calvo, M. Ramírez-Como, J. Pallarès, L. Marsal, T. Torres","doi":"10.1142/s1088424623501110","DOIUrl":"https://doi.org/10.1142/s1088424623501110","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48683521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrochemistry of tri-N-methylpyridyl porphyrins 三-N-甲基吡啶基卟啉的电化学
IF 1.5 4区 化学
Journal of Porphyrins and Phthalocyanines Pub Date : 2023-06-28 DOI: 10.1142/s1088424623501158
W. R. Osterloh, T. Chilingaryan, B. Habermeyer, C. Frochot, P. Arnoux, R. Guilard, K. Kadish
{"title":"Electrochemistry of tri-N-methylpyridyl porphyrins","authors":"W. R. Osterloh, T. Chilingaryan, B. Habermeyer, C. Frochot, P. Arnoux, R. Guilard, K. Kadish","doi":"10.1142/s1088424623501158","DOIUrl":"https://doi.org/10.1142/s1088424623501158","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44050229","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of styrene, phenyl acrylate and allyloxyphenyl-functionalized porphyrins, and preliminary exploration of their utility for assembling multiple porphyrin units 苯乙烯、丙烯酸苯酯和烯丙氧基苯基功能化卟啉的合成及其在多卟啉单元组装中的应用初探
IF 1.5 4区 化学
Journal of Porphyrins and Phthalocyanines Pub Date : 2023-06-27 DOI: 10.1142/s1088424623501006
Rohan Bhimpuria, Kiran Reddy Baddigam, F. Xu, J. Wells, K. Borbas
{"title":"Synthesis of styrene, phenyl acrylate and allyloxyphenyl-functionalized porphyrins, and preliminary exploration of their utility for assembling multiple porphyrin units","authors":"Rohan Bhimpuria, Kiran Reddy Baddigam, F. Xu, J. Wells, K. Borbas","doi":"10.1142/s1088424623501006","DOIUrl":"https://doi.org/10.1142/s1088424623501006","url":null,"abstract":"Three free-base and two Zn(II) porphyrins carrying one alkene-substituted meso-aryl group and three solubilizing pentyl groups were prepared via mixed aldehyde-type syntheses. A meso [Formula: see text]-allyloxyphenyl porphyrin was obtained via the corresponding 5-([Formula: see text]-allyloxyphenyl) dipyrromethane. The porphyrins were fully characterized using a combination of NMR spectroscopy, high-resolution mass spectrometry, and UV-Vis absorption and emission spectroscopies. Two of the free-base porphyrins were heated in the presence of AIBN or benzoyl peroxide as the initiator. The major isolated products of these reactions contained two porphyrin units based on the results of MALDI-MS and 1H NMR analysis data, which was supported by the results of FTIR, UV-Vis absorption and emission spectroscopies, and gel permeation and liquid chromatographies. Additionally, the acrylamide-functionalized porphyrin could be attached to a polylysine scaffold under basic conditions. These results suggest that the olefinic handle can be used to assemble structures containing multiple porphyrinic macrocycles.","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46331218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Removal of heavy and toxic metals from wastewater using porphyrin-based covalent-organic frameworks: An emerging Field 利用卟啉共价有机框架去除废水中的重金属和有毒金属：一个新兴领域
IF 1.5 4区 化学
Journal of Porphyrins and Phthalocyanines Pub Date : 2023-06-19 DOI: 10.1142/s1088424623300112
P. Harvey
{"title":"Removal of heavy and toxic metals from wastewater using porphyrin-based covalent-organic frameworks: An emerging Field","authors":"P. Harvey","doi":"10.1142/s1088424623300112","DOIUrl":"https://doi.org/10.1142/s1088424623300112","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46813850","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sn(IV)-corroles reversibly bind carboxylates in the axial position Sn（IV）-corroles在轴向位置可逆地结合羧酸盐
IF 1.5 4区 化学
Journal of Porphyrins and Phthalocyanines Pub Date : 2023-06-19 DOI: 10.1142/s1088424623501080
H. Bak, P. Cavigli, A. Bond, Theis Brock‐Nannestad, M. Pittelkow, E. Iengo
{"title":"Sn(IV)-corroles reversibly bind carboxylates in the axial position","authors":"H. Bak, P. Cavigli, A. Bond, Theis Brock‐Nannestad, M. Pittelkow, E. Iengo","doi":"10.1142/s1088424623501080","DOIUrl":"https://doi.org/10.1142/s1088424623501080","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44805409","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Teaching with Arduino: Porphyrinoids’ fluorescence in olive oil Arduino教学：橄榄油中卟啉的荧光
IF 1.5 4区 化学
Journal of Porphyrins and Phthalocyanines Pub Date : 2023-06-19 DOI: 10.1142/s1088424623500566
F. Bolze
{"title":"Teaching with Arduino: Porphyrinoids’ fluorescence in olive oil","authors":"F. Bolze","doi":"10.1142/s1088424623500566","DOIUrl":"https://doi.org/10.1142/s1088424623500566","url":null,"abstract":"During the pandemic period, we were forced to reconsider teaching of practical labs, as students had mainly to work at home. It was the occasion to explore the use of cheap microcontroller kits for teaching chemistry and to work out some manipulations with household products. Back to normal life, it is important to valorize this equipment and work to design simple chemistry experiments which could be performed by students at home with Arduino kits adapted to chemistry, to illustrate various courses in addition to classical manipulations performed in the laboratory with specific equipment and products. We describe here the construction of a simple and cheap Arduino-based fluorimeter and its use to study relative porphyrinoids (mainly chlorophylls and pheophytins) contents in olive oils, and the effect of heating on the degradation of such substances. We used an Arduino Uno kit with a LED, a light-to-frequency converter associated with an excitation-blocking filter, and a 3D-printed sample holder.","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41550636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electronic properties and redox chemistry of N-confused metalloporphyrins n掺杂金属卟啉的电子性质和氧化还原化学
IF 1.5 4区 化学
Journal of Porphyrins and Phthalocyanines Pub Date : 2023-06-19 DOI: 10.1142/s1088424623500918
Frederico F. Martins, M. Swart
{"title":"Electronic properties and redox chemistry of N-confused metalloporphyrins","authors":"Frederico F. Martins, M. Swart","doi":"10.1142/s1088424623500918","DOIUrl":"https://doi.org/10.1142/s1088424623500918","url":null,"abstract":"Here we study the effect of metals on the characteristic Soret band of N-confused porphyrins. We used DFT calculations to study how this low-lying region of the spectrum of the NCP-2H isomer is affected by the introduction of transition metals with various ([Formula: see text], [Formula: see text], [Formula: see text] and [Formula: see text] d-electron configurations. The spin ground state of these complexes is mostly dependent on the number of unpaired electrons, both with and without the presence of an axial ligand. The analysis of the electronic distribution and spin density showed that these unpaired electrons are often harbored by the N-confused porphyrin ring instead of on the metal. Time-dependent DFT results indicated that the aromatic system of porphyrin is disrupted in the N-confused isomer: instead of the typical large Soret band, this now gives rise to two peaks of much lower intensity. Most metallo-porphyrins exhibited similar optical properties, with the HOMO/LUMO orbitals showing a mixed metal/porphyrin character. The only exception was the Rh metalloporphyrin that exhibited a ligand-to-metal charge transfer band with increasing intensity as function of the ligand field. This suggests Rh is the only metal whose orbitals are higher in energy than the ligand’s, indicating that it is the only system where the redox processes occur on the metal.","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44059580","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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