Journal of Porphyrins and Phthalocyanines最新文献_第10页

Interfacial nanoarchitectonics with porphyrins and related molecules: Langmuir-Blodgett method and layer-by-layer assembly 卟啉及其相关分子的界面纳米结构：Langmuir-Blodgett方法和逐层组装

IF 1.5 4区化学

Journal of Porphyrins and Phthalocyanines Pub Date : 2023-03-10 DOI: 10.1142/s1088424623300045

K. Ariga

{"title":"Interfacial nanoarchitectonics with porphyrins and related molecules: Langmuir-Blodgett method and layer-by-layer assembly","authors":"K. Ariga","doi":"10.1142/s1088424623300045","DOIUrl":"https://doi.org/10.1142/s1088424623300045","url":null,"abstract":"Nanoarchitectonics is the methodology for the architecture of nano-units of atoms, molecules, and nanomaterials to create functional material systems. This will integrate nanotechnology with other fields such as organic chemistry, supramolecular chemistry, material science, microfabrication technology, and bio-related sciences. Through this review, it is shown that nanoarchitectonics is important for the development of various functional materials. Porphyrins and their analogues are exemplified as important players in nanoarchitectonics strategies. The contents of this review can be briefly summarized as follows. First, recent examples of studies on porphyrins and their analogues, ranging from organic synthesis as basic research to biomedical applications as advanced usages, are presented. This demonstrates the broad utility of porphyrins as functional nano-units, from molecular nanoarchitectonics to material nanoarchitectonics. In subsequent sections, the organization and function of porphyrin assemblies by the Langmuir-Blodgett (LB) method and layer-by-layer (LbL) assembly are described as examples of nanoarchitectonics at interfaces. The creation of functional materials through nanoarchitectonics is rich in possibilities. Conversely, the wide range of possibilities may make it difficult to easily design and control. Confine the system from free three-dimensional space to a two-dimensional field such as an interface, and design, creation, and evaluation may become easier. The nanoarchitectonics of functional structures in a two-dimensional plane are also advantageous in terms of functional expression. The use of interfacial environments is an extremely powerful tool for creating functional systems through nanoarchitectonics.","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46776026","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Recent developments in corrole radicals corrole自由基的最新进展

IF 1.5 4区化学

Journal of Porphyrins and Phthalocyanines Pub Date : 2023-03-06 DOI: 10.1142/s1088424623300057

Hu Gao, Fan Wu, Kai Wang, Zhen Shen

引用次数: 0

Photophysical characterization of a ruthenium-based tetrameric pentacene complex 钌基四聚五苯配合物的光物理性质

IF 1.5 4区化学

Journal of Porphyrins and Phthalocyanines Pub Date : 2023-03-06 DOI: 10.1142/s1088424623500645

Yuxuan Hou, Ilias Papadopoulos, Michael J. Ferguson, N. Jux, R. Tykwinski, D. Guldi

引用次数: 0

Effect of bovine serum albumin on the water solubility of hydrophobic corrinoids 牛血清白蛋白对疏水角蛋白水溶性的影响

IF 1.5 4区化学

Journal of Porphyrins and Phthalocyanines Pub Date : 2023-03-06 DOI: 10.1142/s1088424623500633

Ilia A. Dereven’kov, Ilya I. Dzvinkas, V. S. Osokin, S. Makarov

引用次数: 0

Synthesis of 31-aminopyridinio–chlorophyll-a derivatives and their optical properties 31-氨基吡啶-叶绿素-a衍生物的合成及其光学性质

IF 1.5 4区化学

Journal of Porphyrins and Phthalocyanines Pub Date : 2023-03-06 DOI: 10.1142/s1088424623500712

Yuki Takarada, Nobuyuki Hara, S. Ogasawara, H. Tamiaki

引用次数: 0

Phenylboron(III) complexes of tripyrrins: A new class of macrocycles closed by hydrogen-bonding 三吡啶类苯硼(III)配合物:一类由氢键闭合的新型大环

IF 1.5 4区化学

Journal of Porphyrins and Phthalocyanines Pub Date : 2023-03-06 DOI: 10.1142/s1088424623500694

Kyosuke Yamagata, Oscar Fernandez-Vera, S. Seki, Takayuki Tanaka

引用次数: 0

Crystal structure, stability, spectroscopy, electronic structure, and ultrafast excited-state dynamics of the elusive iron(II) phthalocyanine axially coordinated with DABCO ligands 与DABCO配体轴向配位的难以捉摸的酞菁铁的晶体结构、稳定性、光谱、电子结构和超快激发态动力学

IF 1.5 4区化学

Journal of Porphyrins and Phthalocyanines Pub Date : 2023-03-06 DOI: 10.1142/s1088424623500670

Dustin E. Nevonen, Jacob W. Schaffner, P. Hanrahan, M. Shepit, J. van Lierop, D. Blank, V. Nemykin

引用次数: 0

Synthesis of heterometallic binuclear cobalt(II) phthalocyanines and their catalytic activity in the oxidation of a mercaptan 异金属双核酞菁钴的合成及其对硫醇氧化的催化活性

IF 1.5 4区化学

Journal of Porphyrins and Phthalocyanines Pub Date : 2023-03-06 DOI: 10.1142/s1088424623500669

S. Makarov, S. Ketkov, I. Grishin, D. Wohrle

引用次数: 0

Galactosyl, alkyl, and acidic groups modify uptake and subcellular deposition of pyropheophorbide-a by epithelial tumor cells and determine photosensitizing efficacy 半乳糖基、烷基基和酸性基团改变上皮肿瘤细胞对焦磷素-a的摄取和亚细胞沉积，并决定光敏效果

IF 1.5 4区化学

Journal of Porphyrins and Phthalocyanines Pub Date : 2023-03-06 DOI: 10.1142/s1088424623500657

E. Tracy, Penny Joshi, M. Dukh, F. Durrani, R. Pandey, H. Baumann

引用次数: 1

Porphyrin building blocks bearing two or four divergent ethynes 含有两个或四个不同乙炔的卟啉构建块

IF 1.5 4区化学

Journal of Porphyrins and Phthalocyanines Pub Date : 2023-03-03 DOI: 10.1142/s1088424623500219

Phuong-Lien Doan Cao, Zhiyuan Wu, J. Rong, J. Lindsey

{"title":"Porphyrin building blocks bearing two or four divergent ethynes","authors":"Phuong-Lien Doan Cao, Zhiyuan Wu, J. Rong, J. Lindsey","doi":"10.1142/s1088424623500219","DOIUrl":"https://doi.org/10.1142/s1088424623500219","url":null,"abstract":"Tetrapyrrole building blocks are invaluable constituents in the construction of molecular architectures for use in biomimicry, functional materials, and biomedicine. The reaction of dipyrromethane and the triisopropylsilyl-protected 3,5-diethynylbenzaldehyde afforded the corresponding trans-A2-porphyrin (free base) bearing four ethynes. Subsequent meso-bromination, Suzuki coupling, and protecting group removal afforded a porphyrin building block bearing four ethynes and one benzylamine. The reaction of dipyrromethane and 3,5-bis(propargyloxy)benzaldehyde afforded the corresponding trans-A2-porphyrin (free base) bearing four ethynes. The reaction of 5-(3,5-bis(propargyloxy)phenyl)dipyrromethane and the Eschenmoser (1,9-dimethylaminomethyl) derivative of a 5-([Formula: see text]-substituted aryl)dipyrromethane was used to create two trans-AB-porphyrins (zinc chelates). The [Formula: see text]-substituent of the aryl group was cyano or an acetal moiety. Hydrolysis of the acetal and a click reaction with m-PEG24-azide gave the bis(PEGylated)porphyrin-carboxaldehyde. The porphyrins present readily derivatizable functional groups in a compact architecture.","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44546544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0