Nicholas A. Lucas, Owen M. Weller, Alex Copley, Catherine M. Mottram, Glenn Chapman, William J. McMahon
{"title":"The Diverse Habitats of Eclogite Formation: Insights From the Mesoproterozoic Glenelg Inlier, Scotland","authors":"Nicholas A. Lucas, Owen M. Weller, Alex Copley, Catherine M. Mottram, Glenn Chapman, William J. McMahon","doi":"10.1111/jmg.12801","DOIUrl":"https://doi.org/10.1111/jmg.12801","url":null,"abstract":"<p>Eclogite-facies rocks provide important constraints on the behaviour of convergent plate boundaries and the geometries of tectonic reconstructions due to the high to ultrahigh pressure conditions at which they form. Many eclogite occurrences are documented near the suture zone of active collisional settings where they are interpreted to mark the approximate location of former ocean basin subduction. Such observations influence tectonic interpretations for older eclogites within more deeply eroded and/or less well-exposed terranes. The eclogitic Glenelg inlier in northwest Scotland is one such example, with c. 1 Ga eclogites having previously been interpreted as marking the trace of a Grenville-aged collisional suture zone that defines a third ‘arm’ to the Grenville orogen alongside well-defined sutures in North America and Scandinavia. Here we use a combination of geochronology, phase equilibrium modelling and accessory-phase thermometry to show that the eclogite-facies assemblages were produced at <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mo>∼</mo>\u0000 </mrow>\u0000 <annotation>$$ sim $$</annotation>\u0000 </semantics></math>18–19 kbar and 700°C–750°C from c. 1.1 to 1.0 Ga. Accounting for the foreland basin setting of equivalent-aged sedimentary rocks in the region and demonstrating the thermal viability of this setting, we show that eclogite formation occurred in deforming foreland crust adjacent to the Grenville orogen, in a setting broadly analogous to fault-bounded basement uplifts in the forelands of active deformation belts, such as the Himalayas and Andes. Our results demonstrate that eclogite-facies rocks can form in a greater range of tectonic settings than are sometimes considered, with implications for tectonic reconstructions of collisional zones. In this instance, our results remove the need for a third ‘arm’ of the Grenville orogen by placing Glenelg in a foreland setting, reconciling the absence of plentiful Grenville-aged metamorphic rocks in northwest Scotland, the sedimentological record and paleomagnetic data in the wider region.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 1","pages":"97-122"},"PeriodicalIF":3.5,"publicationDate":"2024-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12801","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143118779","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jonas Kaempf, Chris Clark, Tim E. Johnson, Mudlappa Jayananda, Julian Alfing, Justin Payne, Krishnan Sajeev, Martin Hand
{"title":"Archean Polymetamorphism in the Central Dharwar Craton, Southern India","authors":"Jonas Kaempf, Chris Clark, Tim E. Johnson, Mudlappa Jayananda, Julian Alfing, Justin Payne, Krishnan Sajeev, Martin Hand","doi":"10.1111/jmg.12798","DOIUrl":"https://doi.org/10.1111/jmg.12798","url":null,"abstract":"<div>\u0000 \u0000 <p>Petrochronological investigations of granulite-facies metapelitic rocks from the eastern contact of the Closepet granite in the Central Dharwar Craton (CDC), southern India, provide new pressure–temperature–age (<i>P–T–t</i>) constraints on two seemingly discrete Archean metamorphic events during the Neoarchean and late Paleoarchean eras. Phase equilibrium modelling and conventional thermobarometry coupled with in situ monazite and garnet geochronology constrain Neoarchean (ultrahigh-temperature; UHT) metamorphic peak conditions to ~930 °C and ~6.7 kbar at <i>c</i>. 2.63 Ga, then cooling and limited decompression to ~5.7 kbar at ≤810 °C. Monazite inclusions in garnet least affected by Neoarchean recrystallisation have distinct positive Eu anomalies and yield ages of <i>c</i>. 3.2 Ga, whereas garnet cores interpreted to have grown at the same time have slightly younger apparent ages of <i>c</i>. 3.1 Ga. We interpret this age mismatch to be the result of extensive resorption of garnet during Neoarchean UHT metamorphism, which led to widespread modification of the initial Lu–Hf systematics in garnet to produce younger apparent ages. The effect of retention and inward intracrystalline diffusion of Lu on the isotopic composition of garnet is most pronounced close to the resorbed grain margins and decreases towards the core, as reflected by progressively younger apparent single-spot garnet dates from core to rim. Despite extensive overprinting of the sample at <i>c</i>. 2.63 Ga, the trace element composition of Paleoarchean monazite indicates growth in equilibrium with garnet but in the absence of feldspar, which is predicted to occur over a broad stability range at <i>P</i> ≥ 8 kbar and <i>T</i> ≤ 700 °C. Such <i>P–T</i> conditions are uncommon in the metamorphic rock record prior to the Neoarchean, but are typical of Barrovian-type metamorphism, which is considered to be an expression of accretionary-to-collisional orogenesis. Rocks of similar age and metamorphic grade have been reported from the core of the Western Dharwar Craton (WDC) and may reflect regional subduction at the margins of the CDC and WDC since the late Paleoarchean. Neoarchean UHT metamorphism in the Dharwar Craton is coeval with a cluster of other UHT occurrences at 2.7–2.6 Ga, indicating the existence of globally elevated thermal gradients at that time.</p>\u0000 </div>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 1","pages":"71-95"},"PeriodicalIF":3.5,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143117657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Bernardo Cesare, Omar Bartoli, Peter Brack, Giorgio Moranduzzo, Arianna Randazzo, Salvatore Iaccarino, Lisa Santello
{"title":"Contact Metamorphism of Pelitic Rocks Constrains the Depth of Emplacement of the Re di Castello Intrusion (Adamello Batholith, Italy)","authors":"Bernardo Cesare, Omar Bartoli, Peter Brack, Giorgio Moranduzzo, Arianna Randazzo, Salvatore Iaccarino, Lisa Santello","doi":"10.1111/jmg.12802","DOIUrl":"https://doi.org/10.1111/jmg.12802","url":null,"abstract":"<p>Re di Castello is the southernmost unit of the composite Adamello batholith (central Alps, Italy). It was emplaced between 43 and 40 Ma, yet its depth of emplacement is not well constrained. We have studied the contact metamorphism of pelitic country rocks in two localities: the upper Caffaro Valley and the Borzago Valley in the southern and the northern sub-units of the Re di Castello, respectively. In the Caffaro Valley, the country rocks comprise the Triassic sedimentary Lozio Shale, a carbon-rich slate–siltstone, which was intruded by quartz-dioritic magma. Near the contact, the hornfelses display the mineralogical assemblage Kfs-Crd-Bt-Ms-Pl-Qz-Gr, with rare fibrolitic sillimanite in a single sample. Andalusite was never observed throughout the aureole at this locality. In the Borzago Valley, contact metamorphism developed on schists of the pre-Permian basement with a Variscan, regional metamorphic overprint. The sequence of contact metamorphic mineral assemblages progresses from And-Bt-bearing parageneses to the Sil-Crd-Bt-Kfs-Ms-Pl-Qz that characterizes peak conditions, at which incipient melting is also observed. K-feldspar forms slightly upgrade the first appearance of sillimanite. For samples at both localities, thermodynamic modelling in the NCKFMASHT system failed at predicting a stability field for the sequences of mineral assemblages developed during contact metamorphism. Also the Ti-in biotite thermometer did not constrain temperatures adequately. The P–T conditions at the thermal peak were thus evaluated by an alternative bathograd-like approach, considering phase relationships in the simplified NKASH-C system. To form sillimanite only as product of the incomplete Ms-Qz breakdown—divariant for the presence of Na in Ms and Kfs and shifted to lower temperature due to the presence of graphite (in the Lozio Shale)—an isobaric path typical of contact metamophism must have crossed above the Ms<sub>ss</sub>-Qz-Kfs<sub>ss</sub>-Sil-And-fluid invariant point. This constrains an emplacement pressure >3.3 kbar in the Caffaro Valley, and >3.2 kbar in the Borzago Valley. Concerning temperature, the same univariant point also constrains the minimum temperature in the Caffaro Valley as >615°C–620°C, consistent with results of RSCM thermometry on graphite from the Lozio Shale. The evidence of incipient melting in some samples from the Borzago Valley indicates higher temperatures, probably approaching 670°C, near the contact to the intrusion. Assuming an average crust density of 2.7 g cm<sup>−3</sup>, the estimated pressures correspond to a minimum paleo-depth of emplacement of about 12 km. These depths are somewhat greater than normally considered and should be regarded as revised constraints on models of the emplacement dynamics of the Adamello batholith and on paleogeographic reconstructions of this part of the Southalpine domain.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 1","pages":"47-69"},"PeriodicalIF":3.5,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12802","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143117172","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Petroccia, J. B. Forshaw, P. Lanari, S. Iaccarino, C. Montomoli, R. Carosi
{"title":"Pressure and Temperature Estimation in Greenschist-Facies Metapelites: An Example From the Variscan Belt in Sardinia","authors":"A. Petroccia, J. B. Forshaw, P. Lanari, S. Iaccarino, C. Montomoli, R. Carosi","doi":"10.1111/jmg.12799","DOIUrl":"https://doi.org/10.1111/jmg.12799","url":null,"abstract":"<p>Phase equilibrium modelling is a powerful method for obtaining pressure–temperature (<i>P–T</i>) estimates in metapelites; however, the advantages, disadvantages, and limitations of applying this technique to greenschist-facies pelites have received little attention. This study uses two greenschist-facies metapelites from the Nappe Zone in Sardinia (Italy) to examine differences between currently available thermobarometric techniques. First, this work compares <i>P–T</i> estimates from chlorite–K-white mica–quartz–water and K-white mica–quartz–water multiequilibrium approaches, the latter integrated with previously published <i>T</i><sub>max</sub> results from Raman spectroscopy on carbonaceous material. Consistent <i>P–T</i> conditions are retrieved from these methods for both samples, with <i>P–T</i> estimates suggesting a difference in peak metamorphic conditions between the Internal and External Nappe Zones of Sardinia (peak <i>P–T</i> conditions of 0.6–0.8 GPa, 420°C–450°C and 0.4–0.5 GPa, 370°C–400°C for the Internal and External Nappes, respectively). Second, phase equilibrium modelling was used to assess the ability of six different sets of solution models, alongside their associated thermodynamic datasets, to constrain <i>P–T</i> conditions in the same samples, which are characterized by high-variance mineral assemblages. Significant differences were found between the six thermodynamic databases, and important discrepancies were recognized between the observed and predicted mineral assemblages and compositions (e.g., Si in K-white mica). In only one sample, three databases were able to predict the observed natural assemblage. The compositional isopleths for K-white mica, from the same databases, do not intersect, offering no assistance in constraining <i>P–T</i> conditions. However, one database predicted chlorite's natural composition, yielding a <i>P–T</i> estimate consistent with multiequilibrium methods: ~0.9 GPa, ~350°C–400°C for the Internal Nappe Zone and ~0.5 GPa, ~300°C–350°C for the External Nappe Zone. Although <i>P–T</i> conditions constrained using calculated isopleths from greenschist-facies metapelites and databases optimized for modelling low-grade to medium-grade pelitic systems may be reliable, they should be applied cautiously and compared with estimates from inverse and independent approaches.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 1","pages":"21-46"},"PeriodicalIF":3.5,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12799","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143117173","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Petrogenesis of the Scapolite-Bearing Kongurblak Shear Zone, Chinese Southwestern Tianshan: Implications for Rock-Buffered Fluid Flow Migration During Orogeny","authors":"Zeng Lü, Zhenyu Chen, Andrea Festa","doi":"10.1111/jmg.12800","DOIUrl":"https://doi.org/10.1111/jmg.12800","url":null,"abstract":"<div>\u0000 \u0000 <p>In the lower Kongurblak River, Chinese SW Tianshan, scapolite was first found in a narrow shear zone (the Kongurblak shear zone, KSZ), consisting of variably mylonitized sedimentary rocks, including marble, meta-sandstone and felsic–marly phyllonite. These rocks show varying scapolite textures and modes (from less than 1% to 15%), as a sporadic fine-grained matrix phase, porphyroblasts with abundant inclusions, or blocky aggregates. The Cl content of scapolite (0.90–2.79 wt.%) varies between different rock types, which is higher in meta-sandstone and marble than in felsic–marly phyllonite. Rare patchy lower Cl domains of scapolite and Ba zoning of K-feldspar in meta-sandstone and Cl zoning of porphyroblastic scapolite in marly phyllonite suggest pulsed fluid circulation. P–T estimates, thermodynamic modelling and mineral textures indicate scapolite formation through metasomatizing sodic feldspar and/or metamorphic reactions at amphibolite-facies conditions (470°C°C–600°C and 3–7 kbar). These findings suggest the NaCl–CO<sub>2</sub>–H<sub>2</sub>O fluids in the KSZ stem from an external source, not from evaporitic horizons, at ~200 Ma by apatite U–Pb dating. The chlorinity and X (CO<sub>2</sub>) values of fluids, calculated based on the chemistry of the assemblage scapolite–biotite and T–X (CO<sub>2</sub>) diagrams, correlate well with specific rock types they traverse, which show different mineral modes and compositions, prograde reactions, structural permeability and host rock cavities. This indicates that the chemistry of medium-grade infiltrative fluids in shear zones is strongly rock-buffered, with crucial implications for orogenic metallogenesis in specific rock types. Evidence that the lithologies within the KSZ and their tectonometamorphic histories are distinct from those of the two bounding metamorphic units suggests they represent exotic sedimentary blocks transported over long distances within a large-scale mélange, also providing new constraints on the tectonic collage of the Chinese SW Tianshan.</p>\u0000 </div>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 1","pages":"1-20"},"PeriodicalIF":3.5,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143116667","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nathan R. Daczko, Victoria Elliott, Sandra Piazolo, Kevin Hao
{"title":"Zircon Coupled Dissolution–Precipitation Replacement During Melt–Rock Interaction Modifies Chemical Signatures Resulting in Misleading Ages","authors":"Nathan R. Daczko, Victoria Elliott, Sandra Piazolo, Kevin Hao","doi":"10.1111/jmg.12796","DOIUrl":"https://doi.org/10.1111/jmg.12796","url":null,"abstract":"<p>Melt migration through Earth's crust drives well-documented melt–rock reactions, locally changing rock assemblage and geochemistry. However, melt–zircon interaction remains understudied. We report on three zircon-melt interaction events from the Pembroke Granulite, New Zealand. Primary zircon from gabbroic gneiss which was subject to minor post-emplacement melt migration and primary zircon from younger dykes exhibit straightforward microstructures, microchemistry, and age data. In contrast, zircon from melt-mediated reaction halos adjacent to the dykes and from melt-fluxed high-strain zones display dissolution modification of grains, micro-porosity and blurred or truncated internal zoning typical of replacement by coupled dissolution-precipitation. Replaced zircon domains show changed rare earth element patterns and redistributed or lost radiogenic Pb that generates ambiguous apparent spot date arrays, smeared over tens of millions of years. We conclude that the metamorphism and three melt–rock interaction events were brief, and the arrays misrepresent the true age and duration of the metamorphism. Pb-loss persisted beyond the metamorphism, with porosity and inclusions formed during coupled dissolution-precipitation making replaced zircon domains more susceptible to subsequent Pb-loss compared to the structurally intact, primary magmatic zircon in the host gabbroic gneiss or dykes. We recommend conducting high-resolution microstructural investigations upon recognition of spot date arrays observed in single samples to rule out the possibility of spurious arrays resulting from coupled dissolution-precipitation.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"42 9","pages":"1197-1214"},"PeriodicalIF":3.5,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12796","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142642045","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Pressure–Temperature–Time Evolution of a Polymetamorphic Paragneiss With Pseudomorphs After Jadeite From the HP–UHP Gneiss-Eclogite Unit of the Variscan Erzgebirge Crystalline Complex, Germany","authors":"Hans-Joachim Massonne","doi":"10.1111/jmg.12794","DOIUrl":"10.1111/jmg.12794","url":null,"abstract":"<p>A quartz-rich paragneiss from the Variscan Erzgebirge Crystalline Complex (ECC) was studied in detail because of abundant millimetre-sized and clearly oriented pseudomorphs after a sodic mineral interpreted to have been jadeite. This mineral, or pseudomorphs after it, is rarely found in extensive high-pressure (HP)–ultrahigh-pressure (UHP) terranes worldwide despite reported pressure–temperature (P–T) conditions suitable for the formation of jadeite in common paragneisses and orthogneisses. In the studied rock, which contains abundant large and oriented potassic white mica flakes and minor millimetre-sized garnet grains, the pseudomorphs consist of clusters of small albite grains with thin phengitic muscovite flakes in between. X-ray maps for Ca and Mg in garnet demonstrate that an early generation of this mineral (Gt1) was corroded and subsequently overgrown by a Ca-richer generation (Gt2). White mica is phengite with maximum Si contents of 3.42 atoms per formula unit. P–T conditions of 0.85 GPa and 650°C and 1.7 GPa and 660°C were derived for the formation of Gt1 and Gt2 rim + Si-rich phengite, respectively, using pseudosection modelling. The latter conditions representing the pressure peak experienced by the paragneiss are compatible with the original presence of jadeite and possibly paragonite as well. This metamorphic peak occurred at 338.4 ± 2.3 (2σ) Ma based on in situ dating of monazite grains with the electron microprobe. A single monazite age of 386.4 ± 10.5 (2σ) Ma is related to the formation of Gt1. Thus, a Late Devonian metamorphism is suggested here for the first time to have occurred in ECC gneisses before the major HP event in the Early Carboniferous. Furthermore, the study demonstrates that the eclogite-facies gneisses of the Gneiss-Eclogite Unit of the ECC experienced peak pressures of not more than 2 GPa in contrast to recent proposals of an extensive UHP area in this unit. In addition, it is suggested that the localized occurrence of UHP rocks surrounded by other lithologies otherwise lacking evidence for UHP conditions should be interpreted with caution with respect to their regional extent and significance.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"42 9","pages":"1159-1178"},"PeriodicalIF":3.5,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12794","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jeremy L. Asimus, Nathan R. Daczko, Jean-Antoine Gazi, Isra S. Ezad, Ivan Belousov, Thomas Rodemann, Jacqueline A. Halpin, Sandra Piazolo
{"title":"Experimental Replacement of Zircon by Melt-Mediated Coupled Dissolution-Precipitation Causes Dispersion in U–Pb Ages","authors":"Jeremy L. Asimus, Nathan R. Daczko, Jean-Antoine Gazi, Isra S. Ezad, Ivan Belousov, Thomas Rodemann, Jacqueline A. Halpin, Sandra Piazolo","doi":"10.1111/jmg.12795","DOIUrl":"10.1111/jmg.12795","url":null,"abstract":"<p>Zircon geochronology provides critical information on the rates and durations of geological processes and enables researchers to explore deep time. However, some zircon datasets show a continuum of concordant ages (‘smear’) without well-defined age populations. These age smears are typically interpreted to represent variable loss of radiogenic Pb or protracted geological events lasting tens of millions of years. Coupled dissolution-precipitation replacement of zircon has been suggested as one process that may produce these complex age datasets. Here, we react fragments of the well characterised Mud Tank zircon standard with natural intermediate and mafic melts (0.9 GPa, 1100–1180°C) to test if short-term exposure to a melt can modify the geochronological patterns of zircon. Our observations show that within a short duration (18 h to 3.5 days), most Mud Tank zircon fragments display microstructural and/or chemical evidence for modification by dissolution at fragment boundaries along with partial replacement by coupled dissolution-precipitation processes. The replaced zircon domains have U–Pb ages that smear over one hundred million years, between 764–647 Ma, illustrating variable mobility and redistribution of the U and Pb isotopes. Our experiments demonstrate that zircon modified by coupled dissolution-precipitation replacement may not faithfully record the age or duration of geological events and that investigation of zircon microstructure in high-resolution backscattered electron, cathodoluminescence imaging and/or Raman mapping is needed to better understand complex zircon geochronological datasets.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"42 9","pages":"1179-1195"},"PeriodicalIF":3.5,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12795","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142207212","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Kyanite and Cordierite-Andalusite occurrences in parts of Barrow's Staurolite zones – The effects of high ferric iron","authors":"Ben Harte","doi":"10.1111/jmg.12792","DOIUrl":"10.1111/jmg.12792","url":null,"abstract":"<p>George Barrow's maps (<b>1893</b>, <b>1912</b>) of the metamorphic zones named after him in the south-eastern Scottish Highlands, show a prominent staurolite zone running from the west of Glen Clova to the North Sea coast near Stonehaven in the east. Pelitic mica schists throughout this zone commonly show principal mineral assemblages of staurolite+biotite+garnet+muscovite +quartz (St + Bt + Grt), with sodic plagioclase, ilmenite and sometimes magnetite as common accessories; these schists have bulk compositions corresponding with those of common Dalradian metasediments. However, the mineral assemblages on the low- and high-grade margins of the staurolite zone show evidence of changes from west to east. Lower grade assemblages near Stonehaven include chloritoid+biotite, which has not been found further west in the classic ‘Barrovian’ sequence; whilst the higher grade assemblages near Stonehaven lack kyanite, which is widely seen further west. The Stonehaven area has been suggested to have under gone metamorphism at lower pressure <i>(P)</i> than the classic region of the ‘Glens’ inland to the west.</p><p>This paper describes the occurrence at middle grade in the broad staurolite zone, of unusual bulk rock compositions showing high ratios of Fe<sub>2</sub>O<sub>3</sub>/(Fe<sub>2</sub>O<sub>3</sub> + FeO) and MgO/(MgO + FeO) (abbreviated to M/FM). The high M/FM assemblages are distinct from those of the common St-Bt-Grt schists. The high ratios of ferric to ferrous iron are thought to result from original sedimentary protolith compositions, that led to metamorphism at relatively high conditions of oxygen fugacity (ƒo<sub>2</sub>), and resulted in the formation of haematite-bearing assemblages, rather than ones carrying accessory ilmenite and magnetite as in the common St + Bt + Grt rocks.</p><p>In the west (Glen Lethnot), the haematite-bearing pelites show the occurrence of kyanite at a distinctly lower grade than the common (haematite-free) pelites, and a transition from staurolite-biotite (St + Bt) through staurolite–kyanite-biotite (St + Ky + Bt) to kyanite-biotite (Ky-Bt) assemblages occurs with increasing abundance of haematite and higher bulk M/FM values. In all bulk compositions, the upgrade formation of kyanite may be associated with the movement of the St + Ky + Bt assemblage to lower M/FM bulk compositions with increasing temperature (<i>T</i>). The difference in the temperature of lowest-grade kyanite formation in haematite-rich schists, compared with that in common haematite-free schists may approach 50°C.</p><p>In the east (Stonehaven section), the haematite-bearing assemblages are much rarer than in Glen Lethnot, but those found so far are very distinctive in showing large porphyroblasts of probable cordierite (typically altered to chlorite and sericite). Occasional assemblages of andalusite-cordierite-biotite (And-Crd-Bt) also occur in the haematite-bearing rocks and confirm lower pressures of metamorphism near Stonehaven than tho","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"42 8","pages":"1131-1158"},"PeriodicalIF":3.5,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12792","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141935193","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Probing intra-oceanic subduction infancy in ancient orogenic belts: Example from Chinese South Tianshan","authors":"Limin Gao, Wenjiao Xiao, Zhou Tan, Hao Cheng, Qigui Mao, Hao Wang, Xiaoliang Jia, Miao Sang, Yuhong Guo, Yiying Tan","doi":"10.1111/jmg.12793","DOIUrl":"10.1111/jmg.12793","url":null,"abstract":"<p>Subduction infancy corresponds to the first few million years of the start of subduction following heat transfer from the incipient mantle wedge towards the slab-top, as witnessed by metamorphic soles which represent slivers of oceanic crust metamorphosed up to granulite facies conditions welded beneath obducted ophiolites. In this study, integrated petrological, geochemical, mineralogical, geochronological, and thermodynamic studies were carried out on samples from the Yushugou high-temperature metamorphic ophiolitic complex (YHTM) in the South Tianshan Accretionary Complex (STAC), where a massive exposure of coherent granulite accompanied by a thick peridotite body is preserved. Bulk-rock compositions and Sr–Nd–Hf isotopes demonstrate the petrogenesis of meta-basalts with oceanic island basalt (OIB)-like and mid-ocean ridge basalt (MORB)-like affinities, with little infiltration by subduction-derived melts and/or fluids (e.g., no negative Nb–Ta anomalies). Thermodynamic modelling and U–Pb chronology reveal that the YHTM meta-basalts experienced granulite facies metamorphism of ~840–940°C and ~0.92–1.02 GPa at c. 392 Ma and then possibly reheating and zircon alteration in the Carboniferous. In addition, detrital zircons in sedimentary host rocks of the YHTM show limited Precambrian records and offer maximum depositional ages of c. 410–400 Ma together with the oldest Palaeozoic cluster around c. 470–450 Ma. It is suggested that the YHTM granulites could be of Ordovician–Silurian protolith and such an age pattern significantly deviates from those of adjacent terranes (the Central Tianshan, STAC, and North Tarim Craton). Combined with the compilation of pressure–temperature–time estimates of the YHTM and ages of regional ophiolites, arc intermediate-mafic rocks, A-type granites, and deformation, a model of induced, temporarily northward, intra-oceanic subduction initiation is proposed, which probably occurred along the previously existing weak zone close to a seamount or oceanic plateau in the earliest middle Devonian during the northward subduction of the South Tianshan Ocean (STO). Anomalously high geothermal gradients could be triggered by asthenosphere upwellings, further facilitating the formation of OIB-type metamorphic soles. The YHTM, which represents the remnant of metamorphic soles and associated ophiolites, was finally emplaced to the north margin of the STAC during the relatively long-term (c. 160 million years) accretion and continuous subduction of the STO before its closure. This finding also presents a new natural example of OIB-type metamorphic soles as a snapshot of fossil intra-oceanic subduction infancy during the complex evolutionary history of the STO.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"42 8","pages":"1099-1130"},"PeriodicalIF":3.5,"publicationDate":"2024-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141770652","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}