Journal of Metamorphic Geology最新文献

{"title":"Zircon Coupled Dissolution–Precipitation Replacement During Melt–Rock Interaction Modifies Chemical Signatures Resulting in Misleading Ages","authors":"Nathan R. Daczko,&nbsp;Victoria Elliott,&nbsp;Sandra Piazolo,&nbsp;Kevin Hao","doi":"10.1111/jmg.12796","DOIUrl":"https://doi.org/10.1111/jmg.12796","url":null,"abstract":"<p>Melt migration through Earth's crust drives well-documented melt–rock reactions, locally changing rock assemblage and geochemistry. However, melt–zircon interaction remains understudied. We report on three zircon-melt interaction events from the Pembroke Granulite, New Zealand. Primary zircon from gabbroic gneiss which was subject to minor post-emplacement melt migration and primary zircon from younger dykes exhibit straightforward microstructures, microchemistry, and age data. In contrast, zircon from melt-mediated reaction halos adjacent to the dykes and from melt-fluxed high-strain zones display dissolution modification of grains, micro-porosity and blurred or truncated internal zoning typical of replacement by coupled dissolution-precipitation. Replaced zircon domains show changed rare earth element patterns and redistributed or lost radiogenic Pb that generates ambiguous apparent spot date arrays, smeared over tens of millions of years. We conclude that the metamorphism and three melt–rock interaction events were brief, and the arrays misrepresent the true age and duration of the metamorphism. Pb-loss persisted beyond the metamorphism, with porosity and inclusions formed during coupled dissolution-precipitation making replaced zircon domains more susceptible to subsequent Pb-loss compared to the structurally intact, primary magmatic zircon in the host gabbroic gneiss or dykes. We recommend conducting high-resolution microstructural investigations upon recognition of spot date arrays observed in single samples to rule out the possibility of spurious arrays resulting from coupled dissolution-precipitation.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"42 9","pages":"1197-1214"},"PeriodicalIF":3.5,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12796","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142642045","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Pressure–Temperature–Time Evolution of a Polymetamorphic Paragneiss With Pseudomorphs After Jadeite From the HP–UHP Gneiss-Eclogite Unit of the Variscan Erzgebirge Crystalline Complex, Germany","authors":"Hans-Joachim Massonne","doi":"10.1111/jmg.12794","DOIUrl":"10.1111/jmg.12794","url":null,"abstract":"<p>A quartz-rich paragneiss from the Variscan Erzgebirge Crystalline Complex (ECC) was studied in detail because of abundant millimetre-sized and clearly oriented pseudomorphs after a sodic mineral interpreted to have been jadeite. This mineral, or pseudomorphs after it, is rarely found in extensive high-pressure (HP)–ultrahigh-pressure (UHP) terranes worldwide despite reported pressure–temperature (P–T) conditions suitable for the formation of jadeite in common paragneisses and orthogneisses. In the studied rock, which contains abundant large and oriented potassic white mica flakes and minor millimetre-sized garnet grains, the pseudomorphs consist of clusters of small albite grains with thin phengitic muscovite flakes in between. X-ray maps for Ca and Mg in garnet demonstrate that an early generation of this mineral (Gt1) was corroded and subsequently overgrown by a Ca-richer generation (Gt2). White mica is phengite with maximum Si contents of 3.42 atoms per formula unit. P–T conditions of 0.85 GPa and 650°C and 1.7 GPa and 660°C were derived for the formation of Gt1 and Gt2 rim + Si-rich phengite, respectively, using pseudosection modelling. The latter conditions representing the pressure peak experienced by the paragneiss are compatible with the original presence of jadeite and possibly paragonite as well. This metamorphic peak occurred at 338.4 ± 2.3 (2σ) Ma based on in situ dating of monazite grains with the electron microprobe. A single monazite age of 386.4 ± 10.5 (2σ) Ma is related to the formation of Gt1. Thus, a Late Devonian metamorphism is suggested here for the first time to have occurred in ECC gneisses before the major HP event in the Early Carboniferous. Furthermore, the study demonstrates that the eclogite-facies gneisses of the Gneiss-Eclogite Unit of the ECC experienced peak pressures of not more than 2 GPa in contrast to recent proposals of an extensive UHP area in this unit. In addition, it is suggested that the localized occurrence of UHP rocks surrounded by other lithologies otherwise lacking evidence for UHP conditions should be interpreted with caution with respect to their regional extent and significance.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"42 9","pages":"1159-1178"},"PeriodicalIF":3.5,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12794","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Experimental Replacement of Zircon by Melt-Mediated Coupled Dissolution-Precipitation Causes Dispersion in U–Pb Ages","authors":"Jeremy L. Asimus,&nbsp;Nathan R. Daczko,&nbsp;Jean-Antoine Gazi,&nbsp;Isra S. Ezad,&nbsp;Ivan Belousov,&nbsp;Thomas Rodemann,&nbsp;Jacqueline A. Halpin,&nbsp;Sandra Piazolo","doi":"10.1111/jmg.12795","DOIUrl":"10.1111/jmg.12795","url":null,"abstract":"<p>Zircon geochronology provides critical information on the rates and durations of geological processes and enables researchers to explore deep time. However, some zircon datasets show a continuum of concordant ages (‘smear’) without well-defined age populations. These age smears are typically interpreted to represent variable loss of radiogenic Pb or protracted geological events lasting tens of millions of years. Coupled dissolution-precipitation replacement of zircon has been suggested as one process that may produce these complex age datasets. Here, we react fragments of the well characterised Mud Tank zircon standard with natural intermediate and mafic melts (0.9 GPa, 1100–1180°C) to test if short-term exposure to a melt can modify the geochronological patterns of zircon. Our observations show that within a short duration (18 h to 3.5 days), most Mud Tank zircon fragments display microstructural and/or chemical evidence for modification by dissolution at fragment boundaries along with partial replacement by coupled dissolution-precipitation processes. The replaced zircon domains have U–Pb ages that smear over one hundred million years, between 764–647 Ma, illustrating variable mobility and redistribution of the U and Pb isotopes. Our experiments demonstrate that zircon modified by coupled dissolution-precipitation replacement may not faithfully record the age or duration of geological events and that investigation of zircon microstructure in high-resolution backscattered electron, cathodoluminescence imaging and/or Raman mapping is needed to better understand complex zircon geochronological datasets.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"42 9","pages":"1179-1195"},"PeriodicalIF":3.5,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12795","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142207212","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Kyanite and Cordierite-Andalusite occurrences in parts of Barrow's Staurolite zones – The effects of high ferric iron","authors":"Ben Harte","doi":"10.1111/jmg.12792","DOIUrl":"10.1111/jmg.12792","url":null,"abstract":"&lt;p&gt;George Barrow's maps (&lt;b&gt;1893&lt;/b&gt;, &lt;b&gt;1912&lt;/b&gt;) of the metamorphic zones named after him in the south-eastern Scottish Highlands, show a prominent staurolite zone running from the west of Glen Clova to the North Sea coast near Stonehaven in the east. Pelitic mica schists throughout this zone commonly show principal mineral assemblages of staurolite+biotite+garnet+muscovite +quartz (St + Bt + Grt), with sodic plagioclase, ilmenite and sometimes magnetite as common accessories; these schists have bulk compositions corresponding with those of common Dalradian metasediments. However, the mineral assemblages on the low- and high-grade margins of the staurolite zone show evidence of changes from west to east. Lower grade assemblages near Stonehaven include chloritoid+biotite, which has not been found further west in the classic ‘Barrovian’ sequence; whilst the higher grade assemblages near Stonehaven lack kyanite, which is widely seen further west. The Stonehaven area has been suggested to have under gone metamorphism at lower pressure &lt;i&gt;(P)&lt;/i&gt; than the classic region of the ‘Glens’ inland to the west.&lt;/p&gt;&lt;p&gt;This paper describes the occurrence at middle grade in the broad staurolite zone, of unusual bulk rock compositions showing high ratios of Fe&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt;/(Fe&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt; + FeO) and MgO/(MgO + FeO) (abbreviated to M/FM). The high M/FM assemblages are distinct from those of the common St-Bt-Grt schists. The high ratios of ferric to ferrous iron are thought to result from original sedimentary protolith compositions, that led to metamorphism at relatively high conditions of oxygen fugacity (ƒo&lt;sub&gt;2&lt;/sub&gt;), and resulted in the formation of haematite-bearing assemblages, rather than ones carrying accessory ilmenite and magnetite as in the common St + Bt + Grt rocks.&lt;/p&gt;&lt;p&gt;In the west (Glen Lethnot), the haematite-bearing pelites show the occurrence of kyanite at a distinctly lower grade than the common (haematite-free) pelites, and a transition from staurolite-biotite (St + Bt) through staurolite–kyanite-biotite (St + Ky + Bt) to kyanite-biotite (Ky-Bt) assemblages occurs with increasing abundance of haematite and higher bulk M/FM values. In all bulk compositions, the upgrade formation of kyanite may be associated with the movement of the St + Ky + Bt assemblage to lower M/FM bulk compositions with increasing temperature (&lt;i&gt;T&lt;/i&gt;). The difference in the temperature of lowest-grade kyanite formation in haematite-rich schists, compared with that in common haematite-free schists may approach 50°C.&lt;/p&gt;&lt;p&gt;In the east (Stonehaven section), the haematite-bearing assemblages are much rarer than in Glen Lethnot, but those found so far are very distinctive in showing large porphyroblasts of probable cordierite (typically altered to chlorite and sericite). Occasional assemblages of andalusite-cordierite-biotite (And-Crd-Bt) also occur in the haematite-bearing rocks and confirm lower pressures of metamorphism near Stonehaven than tho","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"42 8","pages":"1131-1158"},"PeriodicalIF":3.5,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12792","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141935193","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Probing intra-oceanic subduction infancy in ancient orogenic belts: Example from Chinese South Tianshan","authors":"Limin Gao,&nbsp;Wenjiao Xiao,&nbsp;Zhou Tan,&nbsp;Hao Cheng,&nbsp;Qigui Mao,&nbsp;Hao Wang,&nbsp;Xiaoliang Jia,&nbsp;Miao Sang,&nbsp;Yuhong Guo,&nbsp;Yiying Tan","doi":"10.1111/jmg.12793","DOIUrl":"10.1111/jmg.12793","url":null,"abstract":"<p>Subduction infancy corresponds to the first few million years of the start of subduction following heat transfer from the incipient mantle wedge towards the slab-top, as witnessed by metamorphic soles which represent slivers of oceanic crust metamorphosed up to granulite facies conditions welded beneath obducted ophiolites. In this study, integrated petrological, geochemical, mineralogical, geochronological, and thermodynamic studies were carried out on samples from the Yushugou high-temperature metamorphic ophiolitic complex (YHTM) in the South Tianshan Accretionary Complex (STAC), where a massive exposure of coherent granulite accompanied by a thick peridotite body is preserved. Bulk-rock compositions and Sr–Nd–Hf isotopes demonstrate the petrogenesis of meta-basalts with oceanic island basalt (OIB)-like and mid-ocean ridge basalt (MORB)-like affinities, with little infiltration by subduction-derived melts and/or fluids (e.g., no negative Nb–Ta anomalies). Thermodynamic modelling and U–Pb chronology reveal that the YHTM meta-basalts experienced granulite facies metamorphism of ~840–940°C and ~0.92–1.02 GPa at c. 392 Ma and then possibly reheating and zircon alteration in the Carboniferous. In addition, detrital zircons in sedimentary host rocks of the YHTM show limited Precambrian records and offer maximum depositional ages of c. 410–400 Ma together with the oldest Palaeozoic cluster around c. 470–450 Ma. It is suggested that the YHTM granulites could be of Ordovician–Silurian protolith and such an age pattern significantly deviates from those of adjacent terranes (the Central Tianshan, STAC, and North Tarim Craton). Combined with the compilation of pressure–temperature–time estimates of the YHTM and ages of regional ophiolites, arc intermediate-mafic rocks, A-type granites, and deformation, a model of induced, temporarily northward, intra-oceanic subduction initiation is proposed, which probably occurred along the previously existing weak zone close to a seamount or oceanic plateau in the earliest middle Devonian during the northward subduction of the South Tianshan Ocean (STO). Anomalously high geothermal gradients could be triggered by asthenosphere upwellings, further facilitating the formation of OIB-type metamorphic soles. The YHTM, which represents the remnant of metamorphic soles and associated ophiolites, was finally emplaced to the north margin of the STAC during the relatively long-term (c. 160 million years) accretion and continuous subduction of the STO before its closure. This finding also presents a new natural example of OIB-type metamorphic soles as a snapshot of fossil intra-oceanic subduction infancy during the complex evolutionary history of the STO.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"42 8","pages":"1099-1130"},"PeriodicalIF":3.5,"publicationDate":"2024-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141770652","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Isochemical metamorphism origin of the newly discovered Baqing jadeitoid, eastern-central Tibet, China","authors":"Xin Jin,&nbsp;Donna L. Whitney,&nbsp;Yu-Xiu Zhang,&nbsp;Hannah J. Blatchford,&nbsp;Kai-Jun Zhang,&nbsp;Tatsuki Tsujimori,&nbsp;Yuan-Yuan Xiao,&nbsp;Hai-Yang Liu,&nbsp;Anette von der Handt,&nbsp;Li-Long Yan,&nbsp;Yao Liu,&nbsp;Lu Lu,&nbsp;Cong-Ying Li","doi":"10.1111/jmg.12790","DOIUrl":"10.1111/jmg.12790","url":null,"abstract":"<p>The formation of most jadeitites and other jadeite-rich rocks (jadeitoids) during subduction is thought to occur by precipitation (P-type) or metasomatism (R-type) by infiltration of Na-Al-Si-rich aqueous fluids because of the compositional similarity of the rocks to inferred subduction fluids. Whether these rocks can form by isochemical metamorphism (I-type) during subduction is still hotly debated. A characteristic of I-type jadeitoid is that it exhibits a similar prograde metamorphic record as associated eclogite, in contrast to P- and R-type jadeitite and jadeitoids that are typically enclosed in serpentinite derived from the mantle wedge and either lack a prograde metamorphic history (R-type and P-type) or probably experience a prograde history (R-type) that is difficult to discern owing to the high variance of the jadeite-dominated assemblages and alteration by subduction fluids. The recently discovered Baqing (eastern-central Tibet) jadeitoid is enclosed by quartzo-feldspathic schist and has a peak metamorphic assemblage of almandine + jadeite/omphacite + phengite/paragonite + rutile + quartz, similar to eclogite. Abundant mineral inclusions in almandine, especially rutile inclusions with increasing Zr contents from the core to rim of almandine, provide an opportunity to further decode the jadeitoid-forming processes. In this study, pseudosections and Zr-in-rutile thermometry, together with conventional geothermobarometers, were employed to decipher the metamorphic history of Baqing jadeitoids. Two analysed Baqing jadeitoids exhibit a similar clockwise <i>P</i>–<i>T</i> path, starting from early metamorphic conditions of 5–7 kbar, 350–440°C, to different peak conditions (27–29 kbar, 730–760°C, or 20–23 kbar, 670–710°C), followed by relatively consistent retrograde metamorphic conditions of 6–7 kbar, 530–600°C. This result indicates a similar subduction history to the Baqing eclogite. In addition, the Baqing jadeitoids show similar geochemical characteristics to some Na-rich, K-depleted and Ca-depleted sedimentary rocks or plagiogranite. Therefore, we propose an isochemical genesis for the Baqing jadeitoid, rather than a metasomatic origin.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"42 8","pages":"1069-1097"},"PeriodicalIF":3.5,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141611011","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hydration of mafic crustal rocks at high temperature during brittle-viscous deformation along a strike-slip plate boundary","authors":"Laura Airaghi,&nbsp;Hugues Raimbourg,&nbsp;Tsuyoshi Toyoshima,&nbsp;Laurent Jolivet,&nbsp;Laurent Arbaret","doi":"10.1111/jmg.12791","DOIUrl":"10.1111/jmg.12791","url":null,"abstract":"&lt;p&gt;The Poroshiri ophiolite (Hidaka metamorphic belt, Japan) occurs within a crustal-scale network of high-temperature, dextral shear zones that accommodated hundreds of kilometres of displacement due to the opening of the Japan Sea in the Neogene. The opholitic rocks comprise ultramafic, mafic and sedimentary protoliths that have been variably hydrated and metamorphosed. This work investigates the mechanisms and timing of fluid influx relative to viscous deformation in metagabbros and amphibolites deformed during exhumation from granulite- to amphibolite-facies conditions. We consider a range of microstructures, from low strain domains and 1–2 mm thick shear bands to mylonites with a thickness of a few meters. Low strain domains of metagabbros exhibit corona textures with symplectites consisting of pargasitic amphibole (Ed&lt;sub&gt;0.7&lt;/sub&gt;) - anorthitic plagioclase (An&lt;sub&gt;80–92&lt;/sub&gt;) ± orthopyroxene ± clinopyroxene forming around olivine and igneous pyroxene and with similar plagioclase–amphibole-orthopyroxene ± clinopyroxene granoblastic aggregates in micrometric-thick fractures. These textures result from hydration under low fluid-rock ratio, with elevated H&lt;sub&gt;2&lt;/sub&gt;O content only occurring locally (H&lt;sub&gt;2&lt;/sub&gt;O &gt; 1–1.2 wt%). Igneous mineral replacement leads to grain size reduction from 1 mm to ~10 μm. Amphibole exhibits a strong core-rim zonation primarily controlled by the high diffusivity of Fe, Mg and OH and the low diffusivity of Al. Mineral compositional equilibrium is achieved at the scale of 100–200 μm. In mm-thick localized shear bands and in metric-scale mylonitic amphibolites, the heterogeneous mineral composition of amphibole (Ed&lt;sub&gt;0.2–0.5&lt;/sub&gt;) and plagioclase (An&lt;sub&gt;40−&lt;/sub&gt;An&lt;sub&gt;80&lt;/sub&gt;) indicates only partial re-equilibration (at the scale of 200–500 μm) despite higher fluid-rock ratios and more pervasive fluid percolation than in metagabbros. Plagioclase–amphibole thermometry and equilibrium phase diagrams indicate that the initial fluid infiltration and corona formation occurred at 800–850°C by fracturing and percolation along grain boundaries. This was followed by the main fluid percolation and mylonitization event, which occurred during exhumation and cooling at conditions of 720–580°C, ~4 kbar. Continuous hydration during retrogression was achieved by the influx of dominantly seawater-derived fluid, as attested by the high chlorine (Cl) contents (&gt;300–400 ppm) of amphiboles in fractures. The heterogeneous distribution of fractures controls the distribution of fluid from the earliest stages of hydration, creating positive feedback where the growth of hydrous minerals as amphibole (up to +300 vol% of amphibole in high strain areas relative to the low-strain ones) and the formation of fine-grained mixed domains that led to further localization of viscous strain and mass transfer (variations of ± 30–40% in major elements). The Poroshiri ophiolite therefore represents a good fossil example of a former transpres","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"42 8","pages":"1035-1067"},"PeriodicalIF":3.5,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141587633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Carboniferous Barrovian to Permian Buchan-type metamorphic cycles in the Mongolian Altai Zone: Implication for pressure cycles in accretionary orogens","authors":"Carmen Aguilar,&nbsp;Pavla Štípská,&nbsp;Karel Schulmann,&nbsp;Andrew R. C. Kylander-Clark,&nbsp;Ondrej Lexa,&nbsp;Turbold Sukhbaatar,&nbsp;Vít Peřestý,&nbsp;Yingde Jiang,&nbsp;Pavel Hanžl","doi":"10.1111/jmg.12777","DOIUrl":"10.1111/jmg.12777","url":null,"abstract":"&lt;p&gt;In the Altai Accretionary Wedge, several periods of Barrovian- and Buchan-type metamorphic cycles were dated from Ordovician to Permian. However, the timing and link between these cycles are not clear, and their causes are debated. In order to contribute to the understanding of Barrovian- to Buchan-type evolution of the accretionary wedges, we studied an area composed of three parallel belts in the easternmost extremity of the Hovd domain located in Mongolian Altai Zone: garnet gneiss in the north, garnet–staurolite–kyanite schist overprinted by ±sillimanite±cordierite±andalusite-bearing assemblages in the centre and garnet–sillimanite gneiss in the south. Petrography, garnet zoning and thermodynamic modelling indicate that the garnet gneiss from the northern belt records burial from ~510°C and ~3–4 kbar to ~600°C and ~5 kbar, followed by heating to ~660°C and decompression to ~4.5 kbar. The garnet–staurolite–kyanite schist from the central belt records burial from ~550°C and ~3–4.5 kbar to ~640–680°C and ~7 kbar, followed by decompression to the sillimanite stability field at ~650°C and ~6 kbar. Crystallization of cordierite, andalusite, late muscovite and chlorite in some samples indicates cooling on decompression to ~540°C and ~3.5 kbar. In the southern gneiss belt, the garnet–sillimanite gneiss with almost unzoned garnet suggests re-equilibration at ~6 kbar and ~710°C. In situ U–Pb monazite and xenotime dating carried out inclusions in porphyroblasts and matrix grains revealed Carboniferous and Permian ages. The monazite and xenotime from gneisses of the northern and southern belts record Carboniferous and Permian ages, which are interpreted as Carboniferous crystallization at c. 347 Ma associated with metamorphic peak, followed by Permian (re)crystallization at c. 300 and 283 Ma. In the central belt, rare Carboniferous xenotime grains in a garnet–staurolite–kyanite–andalusite–muscovite schist indicate a possible Carboniferous age of the prograde metamorphism. Predominant ages between c. 280 and 260 Ma recorded by monazite are interpreted as a result of complete recrystallization during an L&lt;i&gt;P&lt;/i&gt; metamorphic overprint. The Carboniferous ages from the gneisses can be interpreted as constraining the timing of the exhumation of deep crustal rocks to shallow crustal levels. This event corresponds to the formation of crustal-scale migmatite-magmatite domes in the Mongolian Altai Zone. The prograde Barrovian assemblages in the central schist belt are interpreted as having formed contemporaneously during burial in a synform between the migmatite-magmatite domes. The Permian ages reflect L&lt;i&gt;P&lt;/i&gt;–H&lt;i&gt;T&lt;/i&gt; metamorphism, best recorded by the Buchan-type assemblages in the central schist belt, and are related to massive heat flux from tectonically mobile deep partially molten crust. Correlation with similar Barrovian- and Buchan-type episodes from the Chinese Altai Zone indicates multiple compressional and extensional events in the upper plate a","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"42 7","pages":"979-1033"},"PeriodicalIF":3.5,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12777","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141501607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Modification of the isotopic and geochemical compositions of accessory minerals controlled by microstructural setting","authors":"Chris Clark,&nbsp;Richard J. M. Taylor,&nbsp;Malcolm P. Roberts,&nbsp;Simon L. Harley","doi":"10.1111/jmg.12789","DOIUrl":"10.1111/jmg.12789","url":null,"abstract":"<p>In situ age and trace element determinations of monazite, rutile and zircon grains from an ultrahigh temperature (UHT) metapelite-hosted leucosome from the Napier Complex using laser split-stream analysis reveal highly variable behaviour in both the U–Pb and trace element systematics that can be directly linked to the microstructural setting of individual grains. Monazite grains armoured by garnet and quartz retain two concordant ages 2.48 and 2.43 Ga that are consistent with the previously determined ages for peak UHT metamorphism in the Napier Complex. Yttrium in the armoured grains is unzoned with contents of ~700 ppm for the garnet-hosted monazite and in the range 400–1,600 ppm for the monazite enclosed within quartz. A monazite grain hosted within mesoperthite records a spread of ages from 2.43 to 2.20 Ga and Y contents ranging between 400 and 1,700 ppm. This grain exhibits core to rim zoning in both Y and age, with the cores enriched in Y relative to the rim and younger ages in the core relative to the rim. A monazite grain that sits on a grain boundary between mesoperthite and garnet records the largest spread in ages—from 2.42 to 2.05 Ga. The youngest ages in this grain are within a linear feature that reaches the core and is connected to the grain boundary between the garnet and mesoperthite; the oldest ages are observed where monazite is in contact with garnet. Yttrium in the grain is enriched in the core and depleted at the rim with the strongest depletions where monazite is adjacent to grain boundaries between the silicate minerals or in contact with garnet. The unarmoured monazite grains have lower intercept ages of 1.85 Ga, which overlaps with the bulk of ages determined from the rutile and is coincident with a previously reported zircon age obtained through depth profiling from the Napier Complex. The age and chemical relationships outlined above illustrate decoupling between the geochemical and geochronological systems in monazite. Individual grains are suggestive of a range of processes that modify these systems, including volume diffusion, flux-limited diffusion and fluid-enhanced recrystallization, all operating at the scale of a single thin section and primarily controlled by host mineral microstructural setting. These findings illustrate how the development of simple partitioning coefficients (cf. garnet/zircon) and geospeedometry based on experimentally determined diffusion coefficients on grain separates may not be achievable. However, it highlights the utility of combining age and trace element concentrations from multiple accessory minerals with microstructural information when trying to build a complete history of tectonothermal events experienced by an ancient rock system that has undergone a prolonged history of thermal, deformational and fluid flow events.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"42 7","pages":"957-978"},"PeriodicalIF":3.5,"publicationDate":"2024-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12789","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141501608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hydrous shear zones are sites of melt transfer in the lower arc crust: A case study from Fiordland, New Zealand","authors":"Aditi Chatterjee,&nbsp;Nathan R. Daczko,&nbsp;Joyjit Dey,&nbsp;Sandra Piazolo","doi":"10.1111/jmg.12788","DOIUrl":"https://doi.org/10.1111/jmg.12788","url":null,"abstract":"<p>Recent studies of the Cretaceous lower arc crust exposed in Fiordland, New Zealand, conclude that shear zones are sites of melt migration and mass transfer through the deep crust. Here, we investigate the 4–10 km-wide George Sound Shear Zone, which cuts the Western Fiordland Orthogneiss, comprising two main rock types: two-pyroxene gneiss and hornblende gneiss. Previous studies infer a predominantly igneous origin for the two types of gneiss. However, this study finds that melt-rock interaction within the George Sound Shear Zone formed the hornblende gneiss from the precursor two-pyroxene gneiss. Petrographic analyses of samples collected in transects across the shear zone show hydration reaction textures ranging from rims of hornblende + quartz around pyroxene grains to complete replacement of pyroxene grains. Plagioclase is recrystallized and partially replaced by clinozoisite. Additionally, biotite mode increases towards the higher strain rocks in the shear zone. Backscatter images and polarized light microscopy show microstructures indicative of former melt-present deformation, including (a) interconnected mineral films of quartz and K-feldspar along grain boundaries, (b) grains that terminate with low apparent dihedral angles, (c) interstitial grains, with some (d) undulose extinction in plagioclase and (e) serrated grain boundaries. In addition, zircon microstructures are consistent with Zr mobility, further supporting the former presence of melt; geochemical data show enrichment of Zr in the hornblende gneiss as compared to the two-pyroxene gneiss. From the above observations, it is inferred that a felsic to intermediate hydrous melt migrated through the George Sound Shear Zone reacting with the host two-pyroxene gneiss of the Western Fiordland Orthogneiss. Melt migration along grain boundaries was deformation assisted, (i) causing hydration of pyroxene to hornblende + quartz, and plagioclase to clinozoisite, (ii) increasing proportions of biotite within the shear zone and (iii) causing depletion of Cr + Ni and Zr enrichment in the hydrated rock. Our interpretation is supported by published observations of pegmatite dyke swarms that intruded into the George Sound Shear Zone, the P-T conditions of deformation and characterization of microstructures that contrast sharply with those typically found in mylonitic rocks formed under solid-state metamorphic conditions. Our results confirm that hydrous shear zones within otherwise anhydrous country rock are retrogressive and may represent evidence of melt migration through zones of deformation.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"42 7","pages":"933-956"},"PeriodicalIF":3.5,"publicationDate":"2024-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12788","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141973686","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}