Ludovico G. Scorsolini, Cees van Staal, Chris Yakymchuk, John M. Hanchar, Sabastien Dyer
{"title":"Exhumation Mechanisms of High-Pressure Rocks With High-Temperature Overprinting: Insights From Eclogites of the Baie Verte Peninsula, Newfoundland","authors":"Ludovico G. Scorsolini, Cees van Staal, Chris Yakymchuk, John M. Hanchar, Sabastien Dyer","doi":"10.1111/jmg.12817","DOIUrl":"https://doi.org/10.1111/jmg.12817","url":null,"abstract":"<p>This study presents a comprehensive examination of exceptionally preserved eclogites from the Baie Verte Peninsula, Newfoundland Appalachians, which display a high-temperature overprint, thus offering insights into the metamorphic evolution and exhumation mechanisms of such terrains. Through an integrated approach combining field observations, petrographic analysis and thermodynamic modelling, we unravel the tectonometamorphic history of the Taconic eclogites within the East Pond Metamorphic Suite. The eclogites record a complex multistage metamorphic path characterized by initial A-subduction at ~2.7 GPa at ~640°C, followed by near-isothermal decompression to ~2 GPa at ~660°C, and significant heating during exhumation to the metamorphic peak (~1.5 GPa, ~800°C). We highlight the pivotal role of fluids in facilitating metamorphic reactions and influencing the rheology and buoyancy of subducting slabs. We propose a two-stage exhumation model for these eclogites: (1) initial ascent driven by buoyancy forces within a low-density and low-viscosity mantle wedge and (2) subsequent exhumation to shallower crustal levels, aided by external tectonic forces, such as shear zone displacement, erosion or extension. The relationship between the hydration history and the reconstructed pressure–temperature path, featuring a β-shaped trajectory, underscores the significance of thermal perturbations and fluid migration in the exhumation history of HP–UHP terrains in subduction–collision zones.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 5","pages":"497-521"},"PeriodicalIF":3.5,"publicationDate":"2025-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12817","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144191059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Tectonic Setting and Evolution of Anatectic Melt Composition During Prograde Metamorphism up to UHT Metamorphism: Constraints From P–T–t–Melting Path From Rundvågshetta, Lützow–Holm Complex, East Antarctica","authors":"Kota Suzuki, Tetsuo Kawakami, Tetsu Kogiso, Shuhei Sakata, Fumiko Higashino, Masanori Yokoi, Shumpei Kudo","doi":"10.1111/jmg.12815","DOIUrl":"https://doi.org/10.1111/jmg.12815","url":null,"abstract":"<p><span>The p</span>ressure–temperature–time (<i>P–T–t</i>) evolution of a metapelitic ultrahigh-temperature (UHT) granulite from Rundvågshetta (Lützow–Holm Complex, East Antarctica) and chemical evolution of partial melt during the prograde metamorphism up to UHT metamorphism are studied in detail. The presence of different phosphorus (P) concentration zones in garnet is used to distinguish four phases of garnet growth. The <i>P–T</i> conditions for the P-poor garnet core, P-rich mantle and two P-poor rim growths are estimated, respectively, at ~840°C–920°C/7.7–12.5 kbar, ~920°C–1015°C/12.5–14.3 kbar, ~950°C–1000°C/7 kbar and ~800°C/5 kbar using Al<sub>2</sub>SiO<sub>5</sub> inclusions, Zr-in-rutile thermometry, <i>P–T</i> grid and pseudosection analyses. The glassy inclusions in the P-poor core of garnet plot approximately on the Qz-Or cotectic line for 10 kbar in the CIPW normative Qz-Ab-Or diagram, representing prograde to UHT melt formed through the dehydration melting of biotite + sillimanite. Furthermore, the earlier prograde <i>P–T–t</i>–melting information was constrained from inclusions in zircon. The inner mantle of zircon dated at 564 ± 10 Ma includes prograde inclusions of muscovite + quartz + nanogranitoids (NIs) that predate the garnet growth. The NIs in zircon remelted by piston-cylinder experiments plot approximately on the Qz-Or cotectic line for 5 kbar, representing the early melt formed through dehydration melting of muscovite at ~700°C/5 kbar. The P-rich garnet mantle and the CL-bright inner rim of zircon dated at 532 ± 5 Ma were in equilibrium at 900°C–1100°C, based on the REE distribution between them. This suggests that the peak UHT metamorphism occurred at 532 ± 5 Ma, with the prograde metamorphic period lasting ~30 Myr and overall anatectic period exceeding ~40 Myr. Negligible Pb diffusion between zircon zones possibly indicates that peak UHT was short lived, lasting less than 10 Myr. The systematic compositional change of the above-mentioned two stages of melt inclusions is consistent with compositional evolutions in published melting experiments and thus reflects the near-equilibrium compositional evolution of partial melts as the <i>P</i>–<i>T</i> conditions change over ~30 Myr of prograde metamorphism. Therefore, the UHT metamorphism in Rundvågshetta was probably caused by radiogenic self-heating in the thickened crust during the continental collision.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 5","pages":"467-495"},"PeriodicalIF":3.5,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12815","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144191127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Marek Śliwiński, Mirosław Jastrzębski, Jiří Sláma, Gabriela A. Kozub-Budzyń, Aleksandra Jaźwa
{"title":"The Structure and P–T–t–d Evolution of the Saxothuringian/Brunovistulian Variscan Boundary Zone in the Bohemian Massif (Czech Republic, Poland)","authors":"Marek Śliwiński, Mirosław Jastrzębski, Jiří Sláma, Gabriela A. Kozub-Budzyń, Aleksandra Jaźwa","doi":"10.1111/jmg.12813","DOIUrl":"https://doi.org/10.1111/jmg.12813","url":null,"abstract":"<div>\u0000 \u0000 <p>The Variscan suture zone between the Saxothuringian and Brunovistulian terranes of the Bohemian Massif in Central Europe is characterized by a highly tectonized zone: the Stáre Město Belt (SMB). Despite extensive previous research, better understanding of some essential aspects regarding the metamorphic conditions and timing of the tectonic events within the SMB are needed to understand the structural architecture and the Variscan evolution of the Saxothuringian/Brunovistulian suture zone. The present study present systematic data from thermodynamic modelling and U–Pb LA-ICPMS dating of monazite, titanite and zircon on mica schists, felsic and mafic metavolcanic rocks, and leucocratic veins exposed in the SMB. The results indicate that progressive metamorphism related to the collision of the Saxothuringian margin and the rigid Brunovistulian crust started at c. 370–366 Ma (D1 stage). The mostly sedimentary outer units and the mostly volcanic middle unit of the SMB were buried to middle and lower crustal depths, respectively. The continued collision resulted in further burial of the outer units from 4–6 kbar at 510°C–550°C to c. 6.5–7.5 kbar at 650°C with coeval extrusion of the middle unit from 10.5 at 670°C to 6 kbar at 680°C. As a result of the juxtaposition of the units with slightly different prograde P–T histories, portions of the lower crust that were extruded in the middle of the SMB and portions of the middle crust forming the outer parts of the SMB, were transported to the same crustal level (6–7 kbar) at 640°C–680°C (D2 stage), together with formation of anatectic leucosomes at c. 342 Ma. The structure of the SMB was modified by D3 stage dextral transpression during which the former S2 planes were reactivated to form deep-seated, ductile strike-slip faults, with the coeval intrusion of tonalitic magmas along the SMB axis. The predominantly c. 340–330 Ma monazite U–Pb ages obtained from the metamorphic rocks of the SMB are interpreted as the time of the subsequent cooling due to exhumation. This study emphasizes that the long-lasting metamorphic history of the border zone between Saxothuringian and Brunovistulian terranes started at c. 370 Ma and continued to c. 330 Ma.</p>\u0000 </div>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 5","pages":"421-444"},"PeriodicalIF":3.5,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144190737","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Phase Equilibria Analysis for Metacarbonate With Applications to Zoned Calc-Silicate Aureoles","authors":"Zhenhao Zhou, Xu Chu","doi":"10.1111/jmg.12814","DOIUrl":"https://doi.org/10.1111/jmg.12814","url":null,"abstract":"<p>Carbonate rocks react with infiltrating hydrothermal fluids to produce zoned calcsilicate assemblages in contact aureoles. Petrogenetic grids provide valuable insights into phase relations, metamorphic temperature (<i>T</i>) and the fluid composition (<i>X</i>) of the metacarbonate systems, as well as semi-quantification of the prograde decarbonation at convergent boundaries. In this study, we constructed <i>T</i>-<i>X</i><sub>CO2</sub> (composition of H<sub>2</sub>O–CO<sub>2</sub> binary fluid) grids in the system CFMASHc (CaO–FeO–MgO–Al<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub>–H<sub>2</sub>O–CO<sub>2</sub>), supplemented with Fe<sub>2</sub>O<sub>3</sub> or TiO<sub>2</sub>, and its subsystems (CMASHc, CMSHc, CFSHc and CASHc). The grids were constructed to encompass upper crustal conditions, with temperatures ranging from 300°C to 1000°C at 2 kbar and 4 kbar, and <i>X</i><sub>CO2</sub> from 0 to 0.8 (0 = pure water). We adopted internally consistent thermodynamic datasets and compatible activity–composition models for solid solutions. The grids illustrate the index minerals and field gradients observed in classical aureoles. Typical calcsilicate assemblages in these contact aureoles appear along a heating trajectory at a relatively low <i>X</i><sub>CO2</sub>, in the sequence of talc, tremolite, diopside (±olivine), garnet and wollastonite. The grids in the CASHc, CMSHc and CMASHc subsystems are sufficient to cover important reactions that lead to the formation and decomposition of these minerals. The grids with an additional TiO<sub>2</sub> component help interpret phase relations involving rutile, titanite and ilmenite. In addition, we note that phase relations calculated with endmember carbonates are practically similar to those calculated for a complete ternary solid-solution model at low-to-mid temperatures (< 600 °C). In this study, we recalculated reactions in subsystem grids from previous studies across various <i>P</i>-<i>T</i>-<i>X</i><sub>CO2</sub> conditions within a consistent framework. These results are contextualized with natural assemblages and applied to constrain the field gradient of a representative contact aureole. By incorporating additional components, the grids accommodate a broader range of assemblages observed in metacarbonate rocks. Together, these expanded grids provide a robust framework for future studies of contact metamorphism in metacarbonate systems. The calculated phase equilibria were specifically applied to a contact aureole in southern Tibet, with temperature estimations derived from the phase equilibria aligning closely with a conduction model based on the timescales from diffusion speedometry.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 5","pages":"445-465"},"PeriodicalIF":3.5,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12814","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144190738","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Saskia Grund, Timm John, Johannes C. Vrijmoed, Håkon Austrheim, Torgeir B. Andersen
{"title":"A Mechanistic Look at the Amphibolitization of Mafic Crust: Insights From the Kråkeneset Gabbro Body, Western Gneiss Region, Norway","authors":"Saskia Grund, Timm John, Johannes C. Vrijmoed, Håkon Austrheim, Torgeir B. Andersen","doi":"10.1111/jmg.12809","DOIUrl":"https://doi.org/10.1111/jmg.12809","url":null,"abstract":"<p>Fluid–rock interactions play a key role in the formation, evolution and recycling of the Earth's crust. For fluids to infiltrate rocks and enable and sustain fluid-mediated mineral transformations, fluid pathways are required. In this study, we examined the potential mechanisms of formation of such pathways via detailed mineralogical, petrophysical and thermodynamic analysis of a dry, essentially ‘non-porous’ gabbro that was hydrated and transformed into an amphibolite under amphibolite-facies conditions. During a previous regional HP eclogite-facies metamorphism, the gabbro did not equilibrate and preserved almost entirely its igneous textures and magmatic minerals. Rock transformation during amphibolitization was triggered by fluid infiltration through a newly opened N–S striking fracture network. An equally spaced fracture network formed by mode I opening related to the formation of an E–W striking shear zone at the northern and southern borders of the gabbro body. The amphibolitization process allowed the fluid to pervasively infiltrate the rock from the fracture into the pristine gabbro. The essentially fully amphibolitized sample exhibits some unaffected gabbroic mineral relicts. Even though the amphibolitization process led to the formation of ~70 vol.% hydrous phases, it was accompanied by densification and related porosity formation. The modes and compositions of minerals within partly amphibolitized rocks indicate that besides the uptake of H<sub>2</sub>O, no significant mass exchanges were necessary for this transformation, at least on the thin section scale. Thermodynamic modelling and petrological data show that the transition from gabbro to amphibolite favours porosity formation. In the model, the reaction front proceeded as soon as the gabbro at the reactive interfaces of the affected minerals was sufficiently transformed. At this point, fluid was not consumed further but remained as a free fluid phase, which progressed through the newly formed pore space and advanced amphibolitization. Once the gabbro was almost entirely amphibolitized, its mineral content and mineral chemistry no longer changed, so the progress of amphibolitization progress was controlled by fluid availability. This case study shows that fluid–rock interaction leading to hydration of a rock can be efficiently maintained in almost non-permeable, dry and mafic crust and, therefore, strongly affects the petrophysical properties of the Earth's crust.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 4","pages":"385-405"},"PeriodicalIF":3.5,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12809","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143749988","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A New UHP-HP Tectono-Metamorphic Architecture for the Southern Dora-Maira Massif Nappe Stack (Western Alps) Based on Petrological and Microstructural Evidence","authors":"Chiara Groppo, Simona Ferrando, Fabrizio Tursi, Franco Rolfo","doi":"10.1111/jmg.12812","DOIUrl":"https://doi.org/10.1111/jmg.12812","url":null,"abstract":"<p>The southern Dora-Maira Massif, where coesite was first discovered 40 years ago, is among the most studied and better known example of high/ultra-high-pressure (HP/UHP) terranes. Previous to this study, the Polymetamorphic Basement Complex of the southern Dora-Maira Massif has been defined as a nappe stack consisting of three juxtaposed tectono-metamorphic units: the HP San Chiaffredo Unit at the bottom, the UHP Brossasco-Isasca Unit in the middle and the HP Rocca Solei Unit at the top. The origin of UHP metamorphism in the Brossasco-Isasca Unit is still controversial, due to the difficulties in reconciling the abrupt difference between the UHP conditions recorded by the Brossasco-Isasca Unit (i.e., 700°C–730°C, 4.0–4.3 GPa) and the HP conditions (i.e., ~500°C–520°C, 2.0–2.2 GPa) registered by the adjacent units. Here, we report new petrologic and microstructural evidence supporting the existence of a previously unrecognised UHP unit in the southern Dora-Maira Massif. Our data demonstrate that the tectonic unit overlying the Brossasco-Isasca Unit (i.e., the former Rocca Solei Unit), so far considered a HP unit, is actually divided in two units, one of which (the lowermost Rocca Solei Unit <i>sensu stricto</i>) experienced UHP conditions and the other (the uppermost Grimbassa Unit) reached HP conditions. The newly defined Rocca Solei Unit experienced UHP metamorphism at significantly different P–T conditions (520°C–550°C, 2.7–2.9 GPa) compared to the underlying Brossasco-Isasca Unit, but along a similar ‘cold’ T/P ratio (< 200°C/GPa), markedly lower than that defined in the neighbouring Grimbassa Unit and San Chiaffredo Unit (> 230°C/GPa). After more than 30 years of petrologic investigations, the tectono-metamorphic architecture of the southern Dora-Maira Massif is thus redefined, bridging the gap between the UHP Brossasco-Isasca Unit and the adjacent HP units and opening to new scenarios on its HP–UHP architecture. The results of this study have both regional and petrologic implications: (i) Similarities emerge in the structural position, thickness and metamorphic evolution of the new UHP Rocca Solei Unit in the southern Dora-Maira Massif and those of the Chasterain Unit recently discovered in the northern Dora-Maira Massif, suggesting a common architecture throughout the whole Dora-Maira Massif; (ii) the peculiar quartz microstructure in the metagranites described below represents an exceptional documentation of a ‘frozen’ quartz-to-coesite polymorphic reaction caught in the act and suggests that the availability of fluids was the most crucial factor controlling the progress of the reaction. The metastable persistence of quartz in H<sub>2</sub>O-undersaturated lithologies makes even more challenging the identification of UHP units that have only slightly exceeded the quartz–coesite transition and justifies why the newly defined UHP Rocca Solei Unit has remained ‘hidden’ for more than 30 years.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 4","pages":"359-383"},"PeriodicalIF":3.5,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12812","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143749309","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Robyn L. Gardner, Nathan R. Daczko, Sandra Piazolo, John Adam, Uvana Meek
{"title":"Melt–Rock Interaction Experiments Reveal Rapid Microstructural and Chemical Changes at Lower Crustal Conditions","authors":"Robyn L. Gardner, Nathan R. Daczko, Sandra Piazolo, John Adam, Uvana Meek","doi":"10.1111/jmg.12811","DOIUrl":"https://doi.org/10.1111/jmg.12811","url":null,"abstract":"<p>The reactive flow of melt through the mantle or crust triggers chemical disequilibrium, driving reactions that significantly alter the mineral assemblages and physical properties of host rocks. However, the degrees of chemical difference required to initiate these reactions and their timescale remain poorly understood. In this study, we present piston–cylinder reaction experiments simulating lower crustal conditions, where largely anhydrous lower crustal granoblastic dioritic gneiss interacts with a hydrous mafic melt, created from the same gneiss but modified by the addition of ~6-wt.% H<sub>2</sub>O. Remarkably, reactions occurred within just 12 h, producing microstructures that closely resemble those observed in natural, melt-fluxed rocks from the lower arc crust in Fiordland, New Zealand. Melt–rock interactions led to the formation of epitaxial, multilayer symplectic coronae of pargasite + plagioclase or quartz partially replacing pre-existing pyroxene grains. The protolith plagioclase and amphibole are either completely dissolved into the melt or replaced by a modified composition of the same mineral. The melt exhibits compositional variations that correlate with distance from the melt–rock reaction front. Quenched melt chemistry data demonstrate the potential for melt compositions to continuously evolve in response to both crystallisation and melt–rock interactions during reactive flow. Importantly, our findings reveal that melt–rock reactions, initiated by melt not drastically different from the solid rock (protolith), can induce significant changes in rock composition and thus physical properties in a short time. Our findings have broad implications for understanding the compositional evolution of migrating melts and the chemical and mechanical evolution of the Earth's mantle and lower crust in general.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 4","pages":"341-358"},"PeriodicalIF":3.5,"publicationDate":"2025-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12811","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143749790","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sara Nerone, Chiara Groppo, Mónica Ágreda-López, Maurizio Petrelli, Franco Rolfo
{"title":"Multi-Stage Growth of Kyanite in Migmatites Interpreted by Integrating Forward Thermodynamic Modelling and Trace Element Signature","authors":"Sara Nerone, Chiara Groppo, Mónica Ágreda-López, Maurizio Petrelli, Franco Rolfo","doi":"10.1111/jmg.12810","DOIUrl":"https://doi.org/10.1111/jmg.12810","url":null,"abstract":"<p>Trace element zoning in kyanite can retain information about its growth history, particularly in anatectic metapelites. There, kyanite can grow (i) at sub-solidus conditions through metamorphic reactions involving other aluminous phases as reactants, (ii) through muscovite dehydration melting reactions, and (iii) during cooling and melt crystallisation either through back-reactions between melt and solid phases (e.g., garnet) or crystallising directly from the melt. Thermodynamic modelling successfully reproduces these reactions, allowing a more robust interpretation of the observed features based on predicted reactants and products. In this study, we interpret the kyanite trace element zoning (particularly of Cr, V, and partly of Fe) observed through cathodoluminescence and quantified through LA-ICP-MS maps, using the forward thermodynamic modelling approach. The studied samples are biotite + kyanite + garnet migmatites from the Lower-Greater Himalayan Sequence of eastern Nepal, which experienced muscovite and incipient biotite dehydration melting. Three main generations of kyanite revealed by trace element zoning have been identified (i.e., Ky1, Ky2, and Ky3), consistent with the three main kyanite-producing reactions predicted by forward thermodynamic modelling, also applying a melt reintegration approach. Ky1 (i.e., sub-solidus kyanite) integrated only minimum amounts of Cr, V and Fe. Ky2 (i.e., peritectic kyanite) incorporates Cr and V released from muscovite during its dehydration melting reaction. Ky3 (i.e., back-reaction overgrowth or magmatic kyanite) is particularly developed in samples where melt segregation has been absent or limited and incorporates lower amounts of Cr and V than Ky2, but is enriched in Fe. The major implications of this study concern the interpretation of the melt segregation processes in anatectic rocks and our understanding of the Cr and V partitioning between minerals and melt. Further methodological considerations are also provided, which could help guide similar studies in the future.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 4","pages":"315-339"},"PeriodicalIF":3.5,"publicationDate":"2025-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12810","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143749968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Diane Skipton, Natasha Wodicka, Owen Weller, Simon Jackson, Marc St-Onge, Benoit Saumur, Duane Petts
{"title":"Polyphase Metamorphism of the Northern Rae Craton (Baffin Island, Arctic Canada) and Trace Element Behaviour in Monazite: Insights From Phase Equilibria Modelling and Geochronology","authors":"Diane Skipton, Natasha Wodicka, Owen Weller, Simon Jackson, Marc St-Onge, Benoit Saumur, Duane Petts","doi":"10.1111/jmg.12808","DOIUrl":"https://doi.org/10.1111/jmg.12808","url":null,"abstract":"<p>Integrated field mapping, phase equilibria modelling and in situ U–Pb monazite geochronology from the northern margin of the Rae craton on Baffin Island document three metamorphic events during the Neoarchean to the middle Paleoproterozoic. The Qimivvik area comprises Neoarchean tonalitic gneiss structurally juxtaposed over Neoarchean metasedimentary rocks along the Paleoproterozoic Qimivvik thrust and associated shear zone. High-grade metamorphism at ca. 2.56–2.50 Ga supports a footprint for cryptic late Neoarchean metamorphism over a distance of ∼600 km along the northwestern Rae margin from southern Boothia Peninsula to northern Baffin Island. Thermal peak mineral assemblages in the Qimivvik area equilibrated at ca. 1.9 Ga at conditions of ~710°C–790°C and 4.3–5.5 kbar. The dominant Paleoproterozoic foliation is defined by peak metamorphic phases and is reoriented by folds related to the Qimivvik thrust. Peak metamorphism and associated deformation, including the Qimivvik thrust, are interpreted as a manifestation of the Ellesmere-Inglefield belt of Ellesmere Island and West Greenland, which links with the ca. 1.9 Ga Thelon orogen of western Canada. Partial melting also occurred at ca. 1.8 Ga, possibly resulting from decompression of the Churchill domain following the collisional-accretionary events related to the late stages of amalgamation of Laurentia and supercontinent Nuna. Quantitative trace element maps (acquired using LA-ICP-MS) of monazite reveal distinct trace element signatures associated with each of three growth stages. Ca. 2.5 Ga monazite exhibits complex intragrain compositional zoning, has elevated Y and heavy rare earth elements (HREEs) relative to ca. 1.9 Ga monazite and has higher Th/U overall than both ca. 1.9 Ga and ca. 1.8 Ga monazite. These signatures suggest that ca. 2.5 Ga monazite growth was concomitant with partial melting and preceded the majority of garnet growth. The ca. 1.9 Ga monazite grains are comparatively less zoned and have lower Y + HREE contents than both ca. 2.5 Ga and 1.8 Ga monazite, consistent with the ca. 1.9 Ga monazite forming after most garnet growth. Elevated Y + HREE in the ca. 1.8 Ga monazite imply that it formed after retrograde resorption of garnet rims. In our samples, Y + HREE generally exhibit stronger correlations with monazite age and/or petrographic context than Eu/Eu* and Th/U. As some compositional overlap exists between monazite of different ages and petrographic contexts, quantitative limits (‘cut-offs’) based on trace element concentrations or ratios (e.g., Th/U, Eu/Eu*, La<sub>CN</sub>/Yb<sub>CN</sub>) are unreliable for distinguishing between monazite populations. In addition to providing important constraints on the early tectonic evolution of northeastern Laurentia, our study offers new insights into trace element behaviour in a key accessory mineral during three metamorphic events occurring over a ~700 Ma time period.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 3","pages":"287-314"},"PeriodicalIF":3.5,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12808","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143530437","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Plate Interface Shear Zone in the Sanbagawa Metamorphic Belt, Constrained by RSCM Thermometry, U–Pb Zircon Dating and Phase Equilibria Modelling in the Sarutagawa Region, Central Shikoku, Japan","authors":"Samuele Papeschi, Kenta Kawaguchi, Keishi Okazaki, Yasutaka Hayasaka, Takehiro Hirose","doi":"10.1111/jmg.12807","DOIUrl":"https://doi.org/10.1111/jmg.12807","url":null,"abstract":"<p>Exhumed high-P/low-T complexes are of paramount importance to directly access rocks that experienced subduction zone processes. However, the original tectono-metamorphic fabrics are often partially obliterated by exhumation and later deformation, hindering our understanding of the processes occurring at depth. We show an example of how multiple field- and lab-based analytical techniques may be used to extract information of the pristine fabrics of polydeformed metamorphic rocks. We investigated a natural cross section through the chlorite, garnet and albite-biotite zones of the exhumed Shirataki Unit in the Sanbagawa metamorphic belt, exposed in the Sarutagawa (Saruta River) area of the Central Shikoku, coupling structural-petrographic analysis with Raman Spectroscopy on Carbonaceous Material (RSCM) thermometry, phase equilibrium modelling and U–Pb zircon dating. RSCM thermometry reveals a progressive temperature increase from 350°C–400°C to 500°C–550°C over an ~400 m distance, characterized by condensed metamorphic isograds in the garnet zone. Phase equilibrium modelling indicates slightly decreasing metamorphic pressures through the transect from 0.6–0.9 GPa at low-T to 0.4–0.7 GPa at high-T with preserved blueschist-facies parageneses, documented for the first time in the area, restricted to the ~400°C–450°C range. Hence, rocks developed close to the Sanbagawa subduction gradient are juxtaposed with rocks that experienced significant retrograde heating during exhumation. Moreover, we found that competent lithologies such as quartzite and basic schist along the transect preserve trenchward-directed deformation structures that are obliterated by orogen-parallel stretching in the surrounding, incompetent pelitic schists. U–Pb dating shows progressively older youngest detrital zircon ages and syn-depositional peaks from 79–76 and ~88–80 Ma in the chlorite zone to ~92 and ~100 Ma in the garnet zone, respectively, indicating that the lower grade units were subducted at a later stage and that, hence, different metamorphic grades in the area correspond to different protolith ages. The data discussed above is consistent with the former presence of a regional shear zone that, although partially obliterated by younger deformation, contributed to the exhumation of higher-T rocks of the albite-biotite and oligoclase-biotite zones over subducting rocks of the chlorite and garnet zones, likely exploiting the subduction interface. These results offer a framework to investigate the geological record of subduction in the polyphase metamorphic rocks of the Sanbagawa belt.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 3","pages":"257-285"},"PeriodicalIF":3.5,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12807","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143530245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}