Geostandards and Geoanalytical Research最新文献

筛选
英文 中文
Strengths and Weaknesses of the Analytical Techniques Used for Measuring Low Mercury Mass Fractions (< 10 ng g-1) in Crystalline Rocks: Direct Mercury Analyser Versus Cold Vapour-Atomic Fluorescence Spectroscopy 用于测量结晶岩石中低汞质量分数(< 10 ng g-1)的分析技术的优缺点:直接汞分析仪与冷蒸汽原子荧光光谱法
IF 2.7 2区 地球科学
Geostandards and Geoanalytical Research Pub Date : 2025-04-11 DOI: 10.1111/ggr.12606
Francesco Narduzzi, Stefano Covelli, Federico Floreani, Elena Pavoni, Elisa Petranich, Sarah C. Jantzi, Mattia Pistone, Ana Černok, Marco Venier, Matteo Crosera, Luca Ziberna
{"title":"Strengths and Weaknesses of the Analytical Techniques Used for Measuring Low Mercury Mass Fractions (< 10 ng g-1) in Crystalline Rocks: Direct Mercury Analyser Versus Cold Vapour-Atomic Fluorescence Spectroscopy","authors":"Francesco Narduzzi,&nbsp;Stefano Covelli,&nbsp;Federico Floreani,&nbsp;Elena Pavoni,&nbsp;Elisa Petranich,&nbsp;Sarah C. Jantzi,&nbsp;Mattia Pistone,&nbsp;Ana Černok,&nbsp;Marco Venier,&nbsp;Matteo Crosera,&nbsp;Luca Ziberna","doi":"10.1111/ggr.12606","DOIUrl":"https://doi.org/10.1111/ggr.12606","url":null,"abstract":"<p>Elemental mercury (Hg) is routinely determined in crystalline rocks with mass fractions lower than 10 ng g<sup>-1</sup> by thermal decomposition using Direct Mercury Analyzer (DMA-80) or Lumex RA-915+ (equipped with a PYRO-915+ attachment) instruments, both based on atomic absorption spectroscopy. However, 223 analyses over the course of one year with DMA-80 and cold vapour-atomic fluorescence spectroscopy (CV-AFS) on three reference materials (RMs) and six crystalline rocks (granite, diorite, gabbro, spinel peridotite, phlogopite-rich peridotite, and sulfide-rich orthogneiss) from the exposed transcrustal section of the Ivrea-Verbano Zone and upper crustal Serie dei Laghi unit (western Alps, Italy) reveal that rock analyses using the DMA-80 are variably affected by different internal and external biases when Hg mass fractions are below 10 ng g<sup>-1</sup>. Conversely, CV-AFS analyses are more precise, providing homogenous and repeatable results, even at ultra-low Hg mass fractions (&lt; 1 pg g<sup>-1</sup>). Furthermore, CV-AFS analyses show that gabbro and spinel peridotite powders roasted for <i>analysis by DMA-80</i> still contain ~ 0.6 to ~ 1.4 ng g<sup>-1</sup> of Hg, implying inefficient release of Hg from basic/ultrabasic lithologies. Therefore, we recommend the use of CV-AFS for Hg measurements in crystalline rocks. We also propose a new Hg reference value of 3.9 ± 1.5 ng g<sup>-1</sup> for the GSJ granodiorite reference material JG-1a.</p>","PeriodicalId":12631,"journal":{"name":"Geostandards and Geoanalytical Research","volume":"49 2","pages":"295-314"},"PeriodicalIF":2.7,"publicationDate":"2025-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/ggr.12606","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143909237","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
OU-9: A Potential Reference Material with High 87Rb/86Sr and 87Sr/86Sr for Data Quality Control and Method Validation in ID-MS Rb-Sr Geochronology 高87Rb/86Sr和87Sr/86Sr标准物质OU-9在ID-MS Rb-Sr年代学数据质量控制和方法验证中的应用
IF 2.7 2区 地球科学
Geostandards and Geoanalytical Research Pub Date : 2025-04-02 DOI: 10.1111/ggr.12607
Zhuyin Chu, Tianqi Cui, Thomas C. Meisel, Youlian Li, Chaofeng Li, Lei Xu, Yueheng Yang, Peng Peng
{"title":"OU-9: A Potential Reference Material with High 87Rb/86Sr and 87Sr/86Sr for Data Quality Control and Method Validation in ID-MS Rb-Sr Geochronology","authors":"Zhuyin Chu,&nbsp;Tianqi Cui,&nbsp;Thomas C. Meisel,&nbsp;Youlian Li,&nbsp;Chaofeng Li,&nbsp;Lei Xu,&nbsp;Yueheng Yang,&nbsp;Peng Peng","doi":"10.1111/ggr.12607","DOIUrl":"https://doi.org/10.1111/ggr.12607","url":null,"abstract":"<p>The use of ID-MS (ID-TIMS/MC-ICP-MS) techniques to characterise reference materials (RM) with high Rb/Sr and <sup>87</sup>Sr/<sup>86</sup>Sr for <i>in situ</i> LA-ICP-MS-MS Rb-Sr geochronology is highly important. However, there is a lack of well-characterised RMs with high Rb/Sr and <sup>87</sup>Sr/<sup>86</sup>Sr ratios to effectively monitor data quality for ID-TIMS/MC-ICP-MS Rb-Sr geochronology. In this study, a pegmatite RM, OU-9, was comprehensively characterised using ID-TIMS/MC-ICP-MS techniques. Measurements undertaken on OU-9 yielded mass fractions of 2494 ± 22 μg g<sup>-1</sup> for Rb, 36.05 ± 0.25 μg g<sup>-1</sup> for Sr, as well as isotope ratios of 832.4 ± 5.2 for <sup>87</sup>Rb/<sup>86</sup>Sr and 32.60 ± 0.19 for <sup>87</sup>Sr/<sup>86</sup>Sr. Despite the presence of inhomogeneity within and between RM sachets, regarding Rb-Sr isotope systematics at sampling scales of ~ 10 mg and even 0.2 g, <sup>87</sup>Rb/<sup>86</sup>Sr and <sup>87</sup>Sr/<sup>86</sup>Sr values derived from the analyses align well along the reference isochron. This alignment yields a model age of ~ 2650 Ma with an initial <sup>87</sup>Sr/<sup>86</sup>Sr of ~ 1.2. We advocate that OU-9 could serve as a potential RM for ID-TIMS/MC-ICP-MS Rb-Sr data quality control for materials characterised by high <sup>87</sup>Rb/<sup>86</sup>Sr and <sup>87</sup>Sr/<sup>86</sup>Sr ratios. The data quality of individual measurement results can be assessed based on their fit to the correlation line.</p>","PeriodicalId":12631,"journal":{"name":"Geostandards and Geoanalytical Research","volume":"49 2","pages":"425-437"},"PeriodicalIF":2.7,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143908894","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IAG Membership Information IAG会员信息
IF 2.7 2区 地球科学
Geostandards and Geoanalytical Research Pub Date : 2025-03-27 DOI: 10.1111/ggr.12563
{"title":"IAG Membership Information","authors":"","doi":"10.1111/ggr.12563","DOIUrl":"https://doi.org/10.1111/ggr.12563","url":null,"abstract":"","PeriodicalId":12631,"journal":{"name":"Geostandards and Geoanalytical Research","volume":"49 1","pages":"271"},"PeriodicalIF":2.7,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/ggr.12563","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143707310","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Short-Pulse LA-MC-ICP-MS Measurement of Sr Isotopes: Application to the Quasi “Non-Destructive” Differentiation between Saltwater and Freshwater Pearls 短脉冲LA-MC-ICP-MS测量Sr同位素:应用于咸水珍珠和淡水珍珠的准“无损”鉴别
IF 2.7 2区 地球科学
Geostandards and Geoanalytical Research Pub Date : 2025-03-16 DOI: 10.1111/ggr.12604
Xiuhong Liao, Zhaochu Hu, Dan Liu, Xianli Zeng, Lanping Feng, Wen Zhang, Jingliang Guo, Chenxi Zhang, Tao Chen
{"title":"Short-Pulse LA-MC-ICP-MS Measurement of Sr Isotopes: Application to the Quasi “Non-Destructive” Differentiation between Saltwater and Freshwater Pearls","authors":"Xiuhong Liao,&nbsp;Zhaochu Hu,&nbsp;Dan Liu,&nbsp;Xianli Zeng,&nbsp;Lanping Feng,&nbsp;Wen Zhang,&nbsp;Jingliang Guo,&nbsp;Chenxi Zhang,&nbsp;Tao Chen","doi":"10.1111/ggr.12604","DOIUrl":"https://doi.org/10.1111/ggr.12604","url":null,"abstract":"<p>A rapid, minimally destructive method for <i>in situ</i> determination of Sr isotope ratios (<sup>87</sup>Sr/<sup>86</sup>Sr) using short-pulse laser ablation multi-collector inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS) coupled with linear regression calibration is presented. The ablation lasts only one second, causing minimal surface damage (~ 7 μm depth, 60 μm diameter). A carbonate matrix reference material for Sr isotope measurement (GIC-P, containing approximately 470 μg g<sup>−1</sup> Sr), fabricated from pressed pearl nanopowder, has been developed for data quality control and validation. Analysis of GIC-P using the proposed short-pulse LA-MC-ICP-MS method yielded results consistent with thermal ionisation mass spectrometry values. This method is ideal for analysis of valuable jewellery samples, as it ensures minimal destruction, high throughput, and cost efficiency while maintaining accuracy and precision, with intermediate precision quantified at better than 0.0004 (2<i>s</i>). When applied to market samples originating from China, Japan, French Polynesia and the South Pacific, the method confirms that saltwater pearls exhibit <sup>87</sup>Sr/<sup>86</sup>Sr ratios consistent with modern seawater (~ 0.7092), whereas freshwater pearls show higher and more variable ratios (0.7102–0.7135 in this study), reflecting their growth environments in the freshwater of the middle and downstream regions of the Yangtze River, China. This distinct isotopic difference provides a reliable geochemical tool for differentiating between saltwater and freshwater pearls.</p>","PeriodicalId":12631,"journal":{"name":"Geostandards and Geoanalytical Research","volume":"49 2","pages":"369-384"},"PeriodicalIF":2.7,"publicationDate":"2025-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143909525","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Zircon S513 – A New Gem-Quality Reference Material for In Situ Microbeam U-Th-Pb, (U-Th)/He Geochronology and Hf-O Isotope Measurement 锆石S513——原位微束U-Th- pb、(U-Th)/He地质年代学和Hf-O同位素测量的新型宝石级标准物质
IF 2.7 2区 地球科学
Geostandards and Geoanalytical Research Pub Date : 2025-03-02 DOI: 10.1111/ggr.12603
Tao Luo, Liyuan Qing, Chenxi Zhang, James Crowley, Qiuli Li, Xiaoxiao Ling, Xiaoping Xia, Defeng He, Xiaodong Deng, Wen Zhang, Zhaochu Hu
{"title":"Zircon S513 – A New Gem-Quality Reference Material for In Situ Microbeam U-Th-Pb, (U-Th)/He Geochronology and Hf-O Isotope Measurement","authors":"Tao Luo,&nbsp;Liyuan Qing,&nbsp;Chenxi Zhang,&nbsp;James Crowley,&nbsp;Qiuli Li,&nbsp;Xiaoxiao Ling,&nbsp;Xiaoping Xia,&nbsp;Defeng He,&nbsp;Xiaodong Deng,&nbsp;Wen Zhang,&nbsp;Zhaochu Hu","doi":"10.1111/ggr.12603","DOIUrl":"https://doi.org/10.1111/ggr.12603","url":null,"abstract":"<p>A new gem-quality zircon reference material, S513, was developed for <i>in situ</i> microbeam U-Th-Pb, (U-Th)/He geochronology and Hf-O isotope measurement. The well-cut gem-quality zircon weighed 51.3 carats. Its U, Th, Pb and Hf mass fractions were 924 ± 64.6 μg g<sup>−1</sup> (2<i>s</i>), 89.6 ± 3.92 μg g<sup>−1</sup> (2<i>s</i>), 119 ± 5.20 μg g<sup>−1</sup> (2<i>s</i>) and 8259 ± 244 μg g<sup>−1</sup> (2<i>s</i>), respectively. Imaging results from LA-ICP-ToF-MS analysis showed homogeneous distribution of elements in S513. The Th-corrected weighted mean <sup>206</sup>Pb/<sup>238</sup>U, <sup>207</sup>Pb/<sup>235</sup>U and <sup>207</sup>Pb/<sup>206</sup>Pb ratios of S513 zircon from eight ID-TIMS analyses are 0.090955 ± 0.000019 (2<i>s</i>, MSWD = 0.22, <i>n</i> = 8), 0.73873 ± 0.00023 (2<i>s</i>, MSWD = 0.19, <i>n</i> = 8) and 0.058934 ± 0.000008 (2<i>s</i>, MSWD = 0.35, <i>n</i> = 8), respectively. The Th-corrected weighted mean <sup>206</sup>Pb/<sup>238</sup>U age obtained from chemical abrasion-isotope dilution-thermal ionisation mass spectrometry is 561.18 ± 0.63 Ma (<i>n</i> = 8, 95% conf., MSWD = 0.9), which is recommended as the best age estimate of S513. The weighted mean <sup>206</sup>Pb/<sup>238</sup>U ages obtained from <i>in situ</i> microbeam analysis (i.e., LA-ICP-MS and SIMS) were 560.8 ± 5.8/10.2 Ma (2<i>s</i>, <i>n</i> = 260) and 562.4 ± 7.2/13.4 Ma (2<i>s</i>, <i>n</i> = 198). The measured weighted mean <sup>208</sup>Pb/<sup>232</sup>Th age of S513 from LA analyses was 561.3 ± 3.3/11.7 Ma (2<i>s</i>, <i>n</i> = 86). The U-Pb and Th-Pb ages of S513 obtained with <i>in situ</i> methods showed good agreement with the CA-ID-TIMS results, respectively. The obtained (U-Th)/He age of S513 from thirty-seven aliquots analysed with U-Th isotope dilution method was 420.3 ± 7.6 Ma (2<i>s</i>, MSWD = 0.72). The recommended reference value of Hf isotope ratio was 0.281606 ± 0.000010 (2<i>s</i>, MSWD = 1.4, <i>n</i> = 12) according to the mean <sup>176</sup>Hf/<sup>177</sup>Hf ratio acquired with solution MC-ICP-MS analysis. All the LA analyses yielded a mean <sup>176</sup>Hf/<sup>177</sup>Hf ratio of 0.281605 ± 0.000008 (2<i>s</i>, MSWD = 0.53, <i>n</i> = 310), which was consistent with the reference value. Laser fluorination analyses yielded mean δ<sup>18</sup>O values of S513 were 11.71 ± 0.11‰ (2<i>s</i>, MSWD = 0.25, <i>n</i> = 5). The results obtained with multiple analytical methods show that zircon S513 is homogeneous to 8% (1<i>s</i>) or better for contents of Y, Nb, Ce, Gd, heavy REE, Ta, U, Th, Pb and Hf. Additionally, the homogeneity is observed at 0.12‰ (2<i>s</i>) for U-Pb ages, 1.8% (2<i>s</i>) for (U-Th)/He ages, 0.0036% (2<i>s</i>) for Hf isotopes, and 0.11‰ (2<i>s</i>) for O isotope ratios. Zircon S513 is proposed as a new potential primary calibration or quality control reference material for microbeam U-Th-Pb geochronology and Hf-O isotope measurement.</p>","PeriodicalId":12631,"journal":{"name":"Geostandards and Geoanalytical Research","volume":"49 2","pages":"403-423"},"PeriodicalIF":2.7,"publicationDate":"2025-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143909383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of a New Certified Copper Isotopic Reference Material (GBW04624) and its Application to Copper Isotope Measurements in Geological Samples 新型铜同位素标准物质(GBW04624)的研制及其在地质样品中铜同位素测量中的应用
IF 2.7 2区 地球科学
Geostandards and Geoanalytical Research Pub Date : 2025-02-26 DOI: 10.1111/ggr.12600
Panshu Song, Zeqi Liu, Jun Wang, Yuanjing Zhou, Tongxiang Ren, Hai Lu, Tao Zhou
{"title":"Development of a New Certified Copper Isotopic Reference Material (GBW04624) and its Application to Copper Isotope Measurements in Geological Samples","authors":"Panshu Song,&nbsp;Zeqi Liu,&nbsp;Jun Wang,&nbsp;Yuanjing Zhou,&nbsp;Tongxiang Ren,&nbsp;Hai Lu,&nbsp;Tao Zhou","doi":"10.1111/ggr.12600","DOIUrl":"https://doi.org/10.1111/ggr.12600","url":null,"abstract":"<p>To meet the demand of reliable copper isotopic data in various scientific research, a new copper isotopic reference material GBW04624 with high purity (99.9996%), sufficient homogeneity and stability was developed in this study. A copper isotope amount ratio of <i>n</i>(<sup>65</sup>Cu)/<i>n</i>(<sup>63</sup>Cu) = 0.44559 ± 0.00018 (<i>U</i>, <i>k</i> = 2) in GBW04624 was obtained by calibrated mass spectrometry involving two mass bias correction strategies. The uncertainty of property values was evaluated and traceability to the International System of Units (SI) was established. Copper isotope ratios in geological reference materials GBW07105 and BCR-2 were determined relative to both GBW04624 and the internationally recognised copper isotopic reference material NIST SRM 976. The conversion between δ<sup>65</sup>Cu values relative to NIST SRM 976 and GBW04624 was achieved by applying a δ<sup>65</sup>Cu<sub>GBW04624–NIST SRM 976</sub> value of 0.252 ± 0.015‰ (<i>U</i>, <i>k</i> = 2).</p>","PeriodicalId":12631,"journal":{"name":"Geostandards and Geoanalytical Research","volume":"49 2","pages":"357-368"},"PeriodicalIF":2.7,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143909515","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
GGR Handbook of Rock and Mineral Analysis Chapter 6 (Part 2) Principles and Practice of X-Ray Fluorescence Spectrometry – 2: Wavelength Dispersive and Energy Dispersive Instrumentation 岩石和矿物分析GGR手册第6章(第2部分)x射线荧光光谱法的原理和实践- 2:波长色散和能量色散仪器
IF 2.7 2区 地球科学
Geostandards and Geoanalytical Research Pub Date : 2025-02-19 DOI: 10.1111/ggr.12597
Kenneth E. Turner, Elizabeth Webber
{"title":"GGR Handbook of Rock and Mineral Analysis Chapter 6 (Part 2) Principles and Practice of X-Ray Fluorescence Spectrometry – 2: Wavelength Dispersive and Energy Dispersive Instrumentation","authors":"Kenneth E. Turner,&nbsp;Elizabeth Webber","doi":"10.1111/ggr.12597","DOIUrl":"https://doi.org/10.1111/ggr.12597","url":null,"abstract":"<p>This chapter (Principles and Practice of X-Ray Fluorescence Spectrometry – 2: Wavelength Dispersive and Energy Dispersive Instrumentation) is a contribution to the <i>Geostandards and Geoanalytical Research Handbook of Rock and Mineral Analysis</i> – an online textbook that is a fully revised and updated edition of <i>A Handbook of Silicate Rock Analysis</i> (P. J. Potts, 1987, Blackie, Glasgow).</p><p>Chapter 6, Part 2 (from Section 2 of the handbook devoted to techniques for the determination of major and trace elements) deals with XRF wavelength dispersive and energy dispersive spectrometry. Dealing first with WD-XRF, Part 2 discusses its instrumentation, spectrum analysis and routine operating conditions. The following sections on ED-XRF discuss its detectors and their characteristics,  the associated (pulse-processing) electronics, and X-ray interaction with these detectors. Consideration is then given to procedures for ED-XRF spectra analysis, as well as its analysis of silicate rock and mineral materials under routine operating conditions. Further sections cover total reflection XRF (TRXRF) and field portable (PXRF) instrumentation, and statistical procedures relevant to XRF analysis. The chapter also includes a comparison of the WD and ED spectrometer types and of their analytical performance, with emphasis on silicate rock analysis.</p>","PeriodicalId":12631,"journal":{"name":"Geostandards and Geoanalytical Research","volume":"49 1","pages":"51-130"},"PeriodicalIF":2.7,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143707661","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Determination of Thallium Isotope Ratios in Ten Geological Reference Materials, and of Thallium Isotopic Fractionation Effects Related to Sample Digestion by Dry Ashing 10种地质标准物质中铊同位素比值的测定及其与干灰化溶出有关的铊同位素分馏效应
IF 2.7 2区 地球科学
Geostandards and Geoanalytical Research Pub Date : 2025-02-17 DOI: 10.1111/ggr.12599
Feiyu Dong, Zhaoyang Wang, Lu Yin, Jie Li
{"title":"Determination of Thallium Isotope Ratios in Ten Geological Reference Materials, and of Thallium Isotopic Fractionation Effects Related to Sample Digestion by Dry Ashing","authors":"Feiyu Dong,&nbsp;Zhaoyang Wang,&nbsp;Lu Yin,&nbsp;Jie Li","doi":"10.1111/ggr.12599","DOIUrl":"https://doi.org/10.1111/ggr.12599","url":null,"abstract":"<p>We report for the first time Tl isotope ratios for ten geological reference materials (RMs), namely SGR-1b (from the USGS), and GBW07302, GBW07303a, GBW07401a, GBW03104, GBW07103, GBW07109, GBW07110, GBW07111 and GBW07113 (from China). The principal matrix characteristics of these materials range from sediments to igneous rocks, including stream sediment, soil, shale, granite, nepheline syenite, trachyte, granodiorite and rhyolite. Analytically, the procedure we developed includes a sample digestion step, a simplified single-stage anion exchange matrix separation step and measurements by MC-ICP-MS. For sample digestion we compared a dry ashing-based process with an acid digestion method under high-pressure conditions. We observed that the RMs with high organic content (e.g., SGR-1b = ~ 25%) showed very high values of loss on ignition (LOI) (~ 40%) during dry ashing. Moreover, Tl isotopic measurement results were heavier after dry ashing than after application of the high-pressure bomb method. We infer that the combustion conditions in case of large amounts of organic matter are probably the cause of Tl isotopic fractionation effects (preferential evaporation of <sup>203</sup>Tl). We thus recommend the high-pressure bomb method for the sample digestion step. We validated our entire measurement procedure by applying it to well-documented RMs, including GSP-2 (granodiorite), Nod-A-1 (Marine sediment), Nod-P-1 (Marine sediment) and SCo-1 (shale). Our measurement results were in agreement with literature values.</p>","PeriodicalId":12631,"journal":{"name":"Geostandards and Geoanalytical Research","volume":"49 2","pages":"329-341"},"PeriodicalIF":2.7,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143909479","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In Situ Boron Isotope Determination in Amphibole by LA-MC-ICP-MS: Matrix Effects and New Potential Reference Materials LA-MC-ICP-MS原位测定角闪洞中硼同位素:基质效应和新的潜在标准物质
IF 2.7 2区 地球科学
Geostandards and Geoanalytical Research Pub Date : 2025-02-17 DOI: 10.1111/ggr.12601
Enrico Cannaò, Gianluca Sessa, Samuele Agostini, Massimo Tiepolo
{"title":"In Situ Boron Isotope Determination in Amphibole by LA-MC-ICP-MS: Matrix Effects and New Potential Reference Materials","authors":"Enrico Cannaò,&nbsp;Gianluca Sessa,&nbsp;Samuele Agostini,&nbsp;Massimo Tiepolo","doi":"10.1111/ggr.12601","DOIUrl":"https://doi.org/10.1111/ggr.12601","url":null,"abstract":"<p>The B isotope systematics (δ<sup>11</sup>B) in amphibole offer insights into fluid- and melt-dominated processes in the crust-mantle system. We developed an analytical strategy for <i>in situ</i> B isotope determination in amphibole using LA- MC-ICP-MS on material with a B fraction of a few μg g<sup>−1</sup> using 10<sup>13</sup> Ω resistors. Sources of error deriving from matrix effects were evaluated. Two Ca-amphiboles, one from Pargas, Finland (PRG), and another from the Finero Complex (S. Alps, FIN), were characterised as potential reference materials. PRG has a B mass fraction of 6.75 ± 1.10 μg g<sup>−1</sup> and a δ<sup>11</sup>B value of -16.58 ± 0.06‰, while FIN has 3.27 ± 0.68 μg g<sup>−1</sup> of B and a δ<sup>11</sup>B value of -5.90 ± 0.09‰. A standard-sample-standard bracketing method, using USGS BHVO-2G basaltic glass as the bracketing ‘standard’ (calibrator), provided accurate and reproducible <i>in situ</i> δ<sup>11</sup>B measurements with 2<i>s</i> of ± 2.86‰ (<i>n</i> = 87) for PRG and ± 3.96‰ for FIN (<i>n</i> = 70). These Ca-amphiboles are suitable reference materials to assess accuracy during <i>in situ</i> B isotope determination with LA-MC-ICP-MS. The potential of <i>in situ</i> B isotope determination in Ca-amphibole as a geochemical tool to investigate petrogenetic processes of a well-characterised amphibole-bearing gabbro from the Adamello batholith (C. Alps) has been tested successfully.</p>","PeriodicalId":12631,"journal":{"name":"Geostandards and Geoanalytical Research","volume":"49 2","pages":"343-356"},"PeriodicalIF":2.7,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/ggr.12601","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143909480","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Obituary Dr. Klaus Peter Jochum 克劳斯·彼得·约赫姆医生的讣告
IF 2.7 2区 地球科学
Geostandards and Geoanalytical Research Pub Date : 2025-02-17 DOI: 10.1111/ggr.12602
Thomas C. Meisel, Dorrit Jacob, Ulrike Weis, Regina Mertz-Kraus, Jacinta Enzweiler, Anastassia Borisova, Edward A. Williams
{"title":"Obituary Dr. Klaus Peter Jochum","authors":"Thomas C. Meisel,&nbsp;Dorrit Jacob,&nbsp;Ulrike Weis,&nbsp;Regina Mertz-Kraus,&nbsp;Jacinta Enzweiler,&nbsp;Anastassia Borisova,&nbsp;Edward A. Williams","doi":"10.1111/ggr.12602","DOIUrl":"https://doi.org/10.1111/ggr.12602","url":null,"abstract":"","PeriodicalId":12631,"journal":{"name":"Geostandards and Geoanalytical Research","volume":"49 1","pages":"5-6"},"PeriodicalIF":2.7,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143707258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信