Journal of FluorescencePub Date : 2025-03-01Epub Date: 2024-03-08DOI: 10.1007/s10895-024-03654-4
Yu Xie, Xiaoci Lv, Zhiwei Li, Yanbo Li, Heping Li
{"title":"A Enhanced Fluorescent Probe for Simultaneous Detection and Discrimination of Hydrogen Bisulfite Anions and Glutathione.","authors":"Yu Xie, Xiaoci Lv, Zhiwei Li, Yanbo Li, Heping Li","doi":"10.1007/s10895-024-03654-4","DOIUrl":"10.1007/s10895-024-03654-4","url":null,"abstract":"<p><p>Bisulfite (HSO<sub>3</sub><sup>-</sup>) and biological thiols molecules, such as glutathione (GSH), cysteine (Cys), and homocysteine (Hcy), play important roles in organisms. Developing a fluorescent probe that can simultaneously detect and distinguish HSO<sub>3</sub><sup>-</sup> and biological thiols is of great significance. In this study, ethyl(2E,4Z)-5-chloro-2-cyano-5-(7-(diethylamino)-2-oxo-2 H-chromen-3-yl)penta-2,4-dienoate (CCO) as a novel enhanced fluorescence probe was synthesized by integrating coumarin derivatives and ethyl cyanoacetate, which can simultaneous detection and discrimination of hydrogen bisulfite anions and glutathione. The sensing mechanism was elucidated through spectral analysis and some control experiments. In weakly alkaline environments, the probe not only has good selectivity for HSO<sub>3</sub><sup>-</sup> and GSH, but also has a lower detection limits of 0.0179 µM and 0.2034 µM. The probe exhibited fuorescent turn-on for distinguishing with 296 and 28 fold the fluorescent intensity increase at 486 and 505 nm, respectively, through diferent excitation wavelengths. This provides a new method for simultaneous detection and discrimination of HSO<sub>3</sub><sup>-</sup> and biological thiol cell levels and further applications.</p>","PeriodicalId":15800,"journal":{"name":"Journal of Fluorescence","volume":" ","pages":"1797-1805"},"PeriodicalIF":2.6,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140059499","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Journal of FluorescencePub Date : 2025-03-01Epub Date: 2024-03-02DOI: 10.1007/s10895-024-03637-5
Hang Zhou, Yu Jin, Sheng Wang, Yixiang Wang, Ming Bu
{"title":"A Near-Infrared Fluorescent Probe for the Rapid Detection of Nitroxyl in Living Cells.","authors":"Hang Zhou, Yu Jin, Sheng Wang, Yixiang Wang, Ming Bu","doi":"10.1007/s10895-024-03637-5","DOIUrl":"10.1007/s10895-024-03637-5","url":null,"abstract":"<p><p>Nitroxyl (HNO) plays an important role in various physiological activities. It has the potential to be used as a treatment for certain diseases such as alcohol poisoning, acute hypertension, and atherosclerosis. However, traditional methods for detecting HNO are challenging due to its rapid polymerization and elimination into N<sub>2</sub>O. Therefore, it is crucial to establish direct and effective HNO detection methods to comprehend these physiological processes better. In this study, a new near-infrared fluorescent probe called HXM-P based on the intramolecular charge transfer (ICT) mechanism was designed and synthesized. This probe employs 2-((6-hydroxy-2,3dihydro-1 H-xanthen-4-yl)methylene)malononitrile as a fluorophore and 2-(diphenylphosphine) benzoate as a recognition group. The results showed that probe HXM-P can detect HNO with high sensitivity (1.07 × 10<sup>- 8</sup> M). A good linear correlation was observed between the fluorescence intensities at 640 nm and the concentrations of HNO in the range of 0-80 µM (R<sup>2</sup> = 0.997). Moreover, probe HXM-P exhibited a rapid response rate (within 15 s) toward HNO, and the fluorescent intensity reached a plateau within 5 min, making it easier to track the highly reactive and short-lived HNO in living systems. Additionally, HXM-P was successfully employed for imaging HNO in HepG2 cells.</p>","PeriodicalId":15800,"journal":{"name":"Journal of Fluorescence","volume":" ","pages":"1675-1683"},"PeriodicalIF":2.6,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140012721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Journal of FluorescencePub Date : 2025-03-01Epub Date: 2024-02-21DOI: 10.1007/s10895-024-03618-8
Sokaina Saad Hemdan
{"title":"The Preferential Solvation of Methyl Red in Various Binary Aqueous Solutions: Solvatochromism, Preferential Solvation Parameters, Microheterogeneity of Solvents and Polarity Scale.","authors":"Sokaina Saad Hemdan","doi":"10.1007/s10895-024-03618-8","DOIUrl":"10.1007/s10895-024-03618-8","url":null,"abstract":"<p><p>The solvatochromic characteristics of methyl red were examined in several aqueous solutions from pure water, with methanol, ethanol, propanol, acetonitrile, and dioxane. In order to explain the preferred solvation of the probe azo dye in the binary mixed solvents, the solvent exchange model of Bosch and Roses was used to evaluate the association between the empirical solvent polarity scale (E<sub>T</sub>) values of MR and solvent composition. Non-linear solvatochromism of methyl red was noted in all aqueous mixtures containing methanol, ethanol, propanol, acetonitrile, and dioxane. In addition to calculating the local mole fraction of each solvent composition in the cybotactic area of the probe, the impact of the solvating shell composition on the preferential solvation of the solute dye was examined in terms of both solvent-solvent and solute-solvent interactions. The local mole fraction of each solvent composition in the cybotactic region of the probe was also calculated. The results indicated that the MR solvation shell was thoroughly saturated with the solvent complex S<sub>12</sub> in the following order: dioxane > ethanol > methanol > acetonitrile > propanol. Data from the binary systems were analyzed with KAT parameters using a multi-model; in aqueous methanol and ethanol solutions, the hydrogen acidity was more responsible for the spectral shift, whereas in aqueous acetonitrile and dioxane solutions, the basicity has a greater influence.</p>","PeriodicalId":15800,"journal":{"name":"Journal of Fluorescence","volume":" ","pages":"1491-1503"},"PeriodicalIF":2.6,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139912687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Journal of FluorescencePub Date : 2025-03-01Epub Date: 2024-03-08DOI: 10.1007/s10895-024-03656-2
LongYao Ma, ChaoQun Ma, GuoQing Chen, Jiao Gu, Taiqun Yang, Lei Li, Hui Gao, Yi Xiong, Yamin Wu, Chun Zhu, Yan Zhou, Anqi Hu, Kun Chen, ZhaoChen Liu
{"title":"Nitrogen and Sulfur co-doped Carbon dots as an \"on-off-on\" Fluorescent Sensor for the Detection of Hg<sup>2+</sup> and Ampicillin.","authors":"LongYao Ma, ChaoQun Ma, GuoQing Chen, Jiao Gu, Taiqun Yang, Lei Li, Hui Gao, Yi Xiong, Yamin Wu, Chun Zhu, Yan Zhou, Anqi Hu, Kun Chen, ZhaoChen Liu","doi":"10.1007/s10895-024-03656-2","DOIUrl":"10.1007/s10895-024-03656-2","url":null,"abstract":"<p><p>Herein, a fluorescent \"on-off-on\" nanosensor based on N,S-CDs was developed for highly precise and sensitive recognition of Hg<sup>2+</sup> and ampicillin (AMP). Nitrogen and sulfur co-doped carbon dots with blue fluorescence were synthesized by one-pot hydrothermal method using ammonium citrate and DL-methionine as precursors. N,S-CDs exhibited a surface abundant in -OH, -COOH, and -NH<sub>2</sub> groups, aiding in creating non-fluorescent ground state complexes when combined with Hg<sup>2+</sup>, leading to the suppression of N,S-CDs' fluorescence. Subsequent to additional AMP application, the mixed system's fluorescence was restored. Based on this N,S-CDs sensing system, the thresholds for detection for AMP and Hg<sup>2+</sup> were discovered to be 0.121 µM and 0.493 µM, respectively. Furthermore, this methodology proved effective in identifying AMP in real samples of tap and lake water, yielding satisfactory results. Consequently, in the area of bioanalysis in intricate environmental sample work, the sensing system showed tremendous promise.</p>","PeriodicalId":15800,"journal":{"name":"Journal of Fluorescence","volume":" ","pages":"1807-1817"},"PeriodicalIF":2.6,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140059505","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Journal of FluorescencePub Date : 2025-03-01Epub Date: 2024-02-06DOI: 10.1007/s10895-024-03585-0
Yasmin Rostom, Ola G Hussein, Mohamed Abdelkawy, Mamdouh R Rezk, Dina A Ahmed
{"title":"A Novel Spectrofluorimetric Determination of Antazoline and Xylometazoline in their Ophthalmic Formulation; Green Approach and Evaluation.","authors":"Yasmin Rostom, Ola G Hussein, Mohamed Abdelkawy, Mamdouh R Rezk, Dina A Ahmed","doi":"10.1007/s10895-024-03585-0","DOIUrl":"10.1007/s10895-024-03585-0","url":null,"abstract":"<p><p>A green developed spectrofluorimetric method has been applied for Antazoline (ANT) and Xylometazoline (XLO) determination in both pharmaceutical formulation and pure form. The developed method is synchronous spectrofluorimetry coupled with the second derivative mathematical tool for the determination of antazoline and xylometazoline in their dosage form. The developed method depends on reacting the cited drugs with dansyl chloride, a suitable derivatizing agent, to generate highly fluorescent derivatives. The products formed were measured at emission wavelengths; 703.0 and 712.0 nm after being excited at wavelengths; 350.0 and 355.0 nm for antazoline and xylometazoline, respectively. Synchronous spectrofluorimetry coupled with second derivative mathematical tool was developed and optimized using fluorescence data manager software generating second derivative peak amplitudes at 556.5 nm for antazoline and 598.0 nm for xylometazoline. Linear responses have been represented over a wide range of concentration 0.5-12.0 µg/mL for antazoline and 0.1-10.0 µg/mL for xylometazoline, correspondingly. Method validation was successfully applied. Additionally, statistical comparison of developed method with official ones has been carried out where no significant difference was found. Evaluation of the method's greenness was proven using several assessment tools. Indeed, the method developed is found to be precise, sensitive, and discriminating to assess the cited drugs for regular analysis.</p>","PeriodicalId":15800,"journal":{"name":"Journal of Fluorescence","volume":" ","pages":"1345-1358"},"PeriodicalIF":2.6,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139692005","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Journal of FluorescencePub Date : 2025-03-01Epub Date: 2024-03-01DOI: 10.1007/s10895-024-03645-5
Weiqin Zhao, Chun Huang, Xiyu Guo, Youyu Zhu, Yuangang Li, Yingfeng Duan, Jie Gao
{"title":"A Fluorescence Biosensor Based on Carbon Quantum Dots Prepared from Pomegranate Peel and T-Hg<sup>2+</sup>-T Mismatch for Hg<sup>2+</sup> Detection.","authors":"Weiqin Zhao, Chun Huang, Xiyu Guo, Youyu Zhu, Yuangang Li, Yingfeng Duan, Jie Gao","doi":"10.1007/s10895-024-03645-5","DOIUrl":"10.1007/s10895-024-03645-5","url":null,"abstract":"<p><p>Mercury ions (Hg<sup>2+</sup>) can cause damage to human health, and thus, the study of the detection of Hg<sup>2+</sup> is extraordinarily important in daily life. This work reported a fluorescence biosensor for the detection of Hg<sup>2+</sup>. The key point of this strategy was that the fluorescence of carbon quantum dots made from pomegranate peel (P-CQDs) was quenched by hemin, and restored after G-quadruplex binding with hemin. The presence of Hg<sup>2+</sup> caused thymine (T)-rich DNA fragments to form T-Hg<sup>2+</sup>-T mismatches, and this change allowed the release of G-quadruplex. G-quadruplex could change the fluorescence of hemin/P-CQDs. P-CQDs exhibited excellent properties through characterization analysis, such as transmission electron microscope, X-ray photoelectron spectroscopy and Fourier transform infrared. This proposed fluorescence detection strategy established the linear ranges of Hg<sup>2+</sup> from 1 nM to 50 nM. In conclusion, this simple biosensor had the advantages of strong sensitivity, high selectivity, and low cost for Hg<sup>2+</sup> detection in environmental water samples.</p>","PeriodicalId":15800,"journal":{"name":"Journal of Fluorescence","volume":" ","pages":"1651-1659"},"PeriodicalIF":2.6,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139996428","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Journal of FluorescencePub Date : 2025-03-01Epub Date: 2024-02-21DOI: 10.1007/s10895-024-03616-w
Nayana K, Sunitha A P
{"title":"Unveiling the Radiative Electron-Hole Recombination of MoS<sub>2</sub> Nanostructures at Extreme pH Conditions.","authors":"Nayana K, Sunitha A P","doi":"10.1007/s10895-024-03616-w","DOIUrl":"10.1007/s10895-024-03616-w","url":null,"abstract":"<p><p>Nanostructures of MoS<sub>2</sub> are in wide research for optoelectronic, energy and biological applications. Opto-electronic and biological applications requires the tuning of photoluminescence properties of MoS<sub>2</sub> nanostructures. In this article, nanosized MoS<sub>2</sub> is hydrothermally synthesized, and photoluminescence at extreme pH conditions (pH 1 and 13) is examined. As the photoluminescence gives a key to probe the radiative electron-hole recombination, here, photoluminescence emissions are used as an indicator to suggest the pattern of electron-hole recombination in the material at extreme pH conditions. Raman spectroscopy, dynamic light scattering, Scanning electron microscopic image and energy dispersive x-ray analysis are done for material confirmation. At pH 1 and 13 as-synthesized nanostructured MoS<sub>2</sub> exhibited both upconversion and downconversion photoluminescence. The intensity of photoluminescence is varied with respect to pH. Excitation-dependent photoluminescence mechanisms and preliminary understanding on the ratio of quantum yields and life span of excited state of as-synthesized nanostructured MoS<sub>2</sub> are unveiled here.</p>","PeriodicalId":15800,"journal":{"name":"Journal of Fluorescence","volume":" ","pages":"1467-1474"},"PeriodicalIF":2.6,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139912688","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A Phenanthroimidazole-Based Luminophore for Selective and Specific Identification of Sarin Simulant, Diethylchlorophosphate.","authors":"Tuhina Sultana, Manas Mahato, Najmin Tohora, Sabbir Ahamed, Arpita Maiti, Sudhir Kumar Das","doi":"10.1007/s10895-024-03631-x","DOIUrl":"10.1007/s10895-024-03631-x","url":null,"abstract":"<p><p>The simplicity of synthesis, significant toxicity of organophosphorus-containing nerve agents, and ease of use of their in-terrorism attacks highlight the necessity to create efficient probes and precise methods for detecting these chemicals. This study developed luminogenic probe 4-(1 H-phenanthrene imidazole-2-yl) benzaldehyde, PB for selectively recognizing lethal chemical sarin mimicking diethylchlorophosphate (DCP) with µM detection limit. Following the addition of DCP to the PB solution, the fluorescence changed from bluish-cyan to green simultaneously; after the insertion of triethylamine (TEA) into the PB-DCP phosphorylated solution, the fluorescence of the original one came back, and it occurred five times. A paper strip-based test kit and dip-stick experiments have been executed to demonstrate the practical applicability of our sensor PB and instant, on-site recognition of the target analyte DCP. An experiment has been investigated using a smartphone and red-green-blue (RGB) color analysis, which offers a novel way for the fast, on-site visual detection and quantification of DCP in actual samples. It also reduces equipment costs, speeds up detection times, and substantially simplifies the operation procedure.</p>","PeriodicalId":15800,"journal":{"name":"Journal of Fluorescence","volume":" ","pages":"1625-1636"},"PeriodicalIF":2.6,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139990241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A Simple Method for Synthesizing Nitrogen-Doped Carbon Quantum Dots for Fluorescent \"Turn off\" Mercury (II) Ion Sensing.","authors":"Prafulla Kumar Behera, Deepak Sahu, Bigyan Ranjan Jali, Aruna Kumar Barick, Sarat Kumar Swain, Priyaranjan Mohapatra","doi":"10.1007/s10895-024-03649-1","DOIUrl":"10.1007/s10895-024-03649-1","url":null,"abstract":"<p><p>Here, straightforward and environmentally friendly fluorescent nitrogen doped carbon quantum dots (N-CQDs) with a high blue fluorescence emission at 455 nm are used for ultrasensitive Hg<sup>2+</sup> ion detection. Folic acid and urea are used as carbon sources in the carbonization process. Two broad absorption bands at around 280 and 370 nm from UV-Vis spectrum and characteristic absorption peaks from infrared spectrum confirms the successful synthesis of the N-CQDs. Energy dispersive X-Ray analysis confirmed the elemental composition of the N-CQDs. Transmission electron microscopy showed the homogeneous globular morphology of the N-CQDs with an average particle size of 65 nm. Zeta potential measurement established the stability and surface charge of N-CQDs. Dynamic light scattering measurement showed the average size of N-CQDs. With the addition of Hg<sup>2+</sup> ion to N-CQDs, the blue fluorescence emission is quenched. Moreover, the N-CQDs can be applied to real water sample such as pond water, river water, and tap water. The detection limit is approximately calculated to be 12 nM and linear range is 0-30 parts per billion.</p>","PeriodicalId":15800,"journal":{"name":"Journal of Fluorescence","volume":" ","pages":"1685-1694"},"PeriodicalIF":2.6,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140012722","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Journal of FluorescencePub Date : 2025-03-01Epub Date: 2024-02-21DOI: 10.1007/s10895-023-03556-x
V N Reena, G S Bhagyasree, T Shilpa, R Aswati Nair, B Nithyaja
{"title":"Multifaceted Applications of DNA-Capped Silver Nanoparticles in Photonics, Photocatalysis, Antibacterial Activity, Cytotoxicity, and Bioimaging.","authors":"V N Reena, G S Bhagyasree, T Shilpa, R Aswati Nair, B Nithyaja","doi":"10.1007/s10895-023-03556-x","DOIUrl":"10.1007/s10895-023-03556-x","url":null,"abstract":"<p><p>Deoxyribonucleic acid (DNA) capped silver nanoparticles are exceptional nanomaterials, featuring precise size and shape control enabled by DNA as a capping agent. DNA stabilizes these nanoparticles' role leading to uniform structures for diverse applications. These nanoparticles are excellent in photonics and medical applications, enhancing fluorescence and medical imaging. In this study, we explore the multifaceted applications of DNA-capped silver nanoparticles, delving into their optical, photocatalytic, antibacterial, cytotoxic, and bioimaging properties. Employing UV-visible absorption spectroscopy and scanning electron microscopy, we provide an analysis of confirmation of silver nanoparticles. The investigation demonstrates substantial photocatalytic efficacy, photodegradation of methylene blue is higher than rhodamine 6G. The presence of silver nanoparticles enhances the fluorescence of rhodamine 6G doped sol-gel glasses. Furthermore, our findings illustrate significant antibacterial effects, encompassing both Gram-positive and Gram-negative bacteria, with DNA-capped silver nanoparticles exhibiting antibacterial activity. Cytotoxicity assessments on HeLa cells reveal concentration-dependent effects, with an LC<sub>50</sub> value of 47 µL. Additionally, the in vitro experiments with HeLa cells suggest the promising utility of DNA-capped silver nanoparticles for bioimaging applications. This comprehensive analysis highlights the multifunctionality and potential of DNA-capped silver nanoparticles, offering promising avenues for further exploration and innovation within various scientific domains, particularly in the realm of nanomaterial research.</p>","PeriodicalId":15800,"journal":{"name":"Journal of Fluorescence","volume":" ","pages":"1475-1489"},"PeriodicalIF":2.6,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139912685","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}