Journal of Electrochemical Science and Engineering最新文献

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Flow batteries with solid energy boosters 带固体能量助推器的液流电池
IF 2.2
Journal of Electrochemical Science and Engineering Pub Date : 2022-09-18 DOI: 10.5599/jese.1363
Y. Tolmachev, Svetlana V. Starodubceva
{"title":"Flow batteries with solid energy boosters","authors":"Y. Tolmachev, Svetlana V. Starodubceva","doi":"10.5599/jese.1363","DOIUrl":"https://doi.org/10.5599/jese.1363","url":null,"abstract":"Adding solid electroactive materials as energy boosters to flow battery tanks provides a path to electrical energy storing systems with unprecedently high specific energy and specific power, that can solve the needs of both automotive and stationary energy storage markets. This work reviews the physical and chemical principles behind this new class of flow batteries, the history of this technology, and the most promising research directions.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"33 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82432625","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Advances in processing and characterization of conversion coatings 转化涂料的制备与表征研究进展
IF 2.2
Journal of Electrochemical Science and Engineering Pub Date : 2022-09-18 DOI: 10.5599/jese.1521
J. Bajat
{"title":"Advances in processing and characterization of conversion coatings","authors":"J. Bajat","doi":"10.5599/jese.1521","DOIUrl":"https://doi.org/10.5599/jese.1521","url":null,"abstract":"The present special issue of the Journal of Electrochemical Science and Engineering presents contributions on various kinds of non-toxic conversion coatings on different metal substrates: steel, stainless steel, zinc, copper, aluminum, and the broad range of their properties and applications. Different functions require surface science and surface engineering at a molecular level and are related to the chemical, phase and morphological nature of their surfaces.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"71 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88507156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrochemical strategies for detection of Diazinon: A review 二嗪农的电化学检测方法综述
IF 2.2
Journal of Electrochemical Science and Engineering Pub Date : 2022-09-17 DOI: 10.5599/jese.1379
Azadeh Lohrasbi‐Nejad
{"title":"Electrochemical strategies for detection of Diazinon: A review","authors":"Azadeh Lohrasbi‐Nejad","doi":"10.5599/jese.1379","DOIUrl":"https://doi.org/10.5599/jese.1379","url":null,"abstract":"Diazinon or O,O-diethyl-O-(2-isopropyl-4-methyl-6-pyrimidinyl)-O,O-diethyl-O-(2- isopropyl-4-methyl-6-pyrimidinyl)- phosphorothioate, was first registered as an insecticide in the U.S. However, it was categorized in the limited group of pesticides due to high toxicity for birds, aquatic animals, and humans. Like other organophosphorus pesticides, this compound exhibits inhibitory effects on acetylcholinesterase enzyme. The inhibition of the enzyme leads to the accumulation of acetylcholine and causes the death of insects. DZN is considered a toxic compound for humans due to its high adsorption via skin and inhalation, which leads to the emergence of different symptoms of toxicity. When DZN is used for plants, the compound residues in crops enter the food chain, and hence, bring about different problems for human health. Moreover, the compound is easily washed by surface water and enters the groundwater. Its entrance into aquatic environments can negatively affect a wide range of non-targeted organisms. Thus, researchers are seeking to find fast and precise methods for the recognition of DZN. The electrochemical method for recognizing the compound in real samples is preferable to other analytical methods. Because this method can be used without spending time preparing the sample, it is simple, fast, and cost-effective. The present study is an overall review describing electrochemical-based methods for the recognition of DZN. Methods of modifying electrodes with CNT, polymers, biomolecules, and the simultaneous use of multiple methods are evaluated and compared. The influential factors contributing to the improvement of the signal response are also explained.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"28 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76306276","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
The effect of process parameters on microstructure and corrosion behavior of AISI 4140 steel modified by pulse plasma treatment 工艺参数对脉冲等离子体改性AISI 4140钢组织和腐蚀行为的影响
IF 2.2
Journal of Electrochemical Science and Engineering Pub Date : 2022-09-14 DOI: 10.5599/jese.1259
Yıldız Yaralı Özbek, A. Demirkıran
{"title":"The effect of process parameters on microstructure and corrosion behavior of AISI 4140 steel modified by pulse plasma treatment","authors":"Yıldız Yaralı Özbek, A. Demirkıran","doi":"10.5599/jese.1259","DOIUrl":"https://doi.org/10.5599/jese.1259","url":null,"abstract":"The pulse plasma system is a surface modification method applied to steel samples. In the present study, the effect of the nozzle distance and pulse number parameters were investigated on the modification process. AISI 4140 steel was preferred as the substrate for modification. In this system, the battery capacity and voltage were constant, and, were selected as 800 mF and 3000 V, respectively. The AISI 4140 steel samples were modified by applying 5, 10, and 15 pulses with 40, 50 and 60 mm nozzle distance. The molybdenum consumable electrode was used during the process. The modified surfaces were examined by optical and scanning electron microscope (SEM) and analyzed by X-ray diffractometer (XRD). Vickers microhardness on the cross-section surface of the samples was measured under a load of 50 g for 15 s. Finally, the specimens were exposed to corrosion in 0.5 M NaCl solution. Corrosion tests were realized using the potentiodynamic polarization method. A modified layer on the steel was determined to consist of two layers, the compound layer and the diffusion layer. It was observed that the structure and thickness of the modified layer affect by pulse number and nozzle distance. New phases such as Fe2N, FeN, MoN, and γ-Fe in the modified layer have occurred. The hardness value of the treated sample has risen about 4-5 times than the untreated, depending on applied process parameters. In general, the pulse plasma treatment has improved the corrosion resistance of treated samples. It was observed that while intergranular corrosion has formed on the unmodified surface, pitting corrosion has appeared on the unmodified surfaces.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"21 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81533068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Fe3O4/GO nanocomposite modified glassy carbon electrode as a novel voltammetric sensor for determination of bisphenol A Fe3O4/GO纳米复合修饰玻碳电极作为新型伏安传感器测定双酚a
IF 2.2
Journal of Electrochemical Science and Engineering Pub Date : 2022-09-14 DOI: 10.5599/jese.1482
Fariba Beigmoradi, H. Beitollahi
{"title":"Fe3O4/GO nanocomposite modified glassy carbon electrode as a novel voltammetric sensor for determination of bisphenol A","authors":"Fariba Beigmoradi, H. Beitollahi","doi":"10.5599/jese.1482","DOIUrl":"https://doi.org/10.5599/jese.1482","url":null,"abstract":"A new voltammetric sensor is proposed for the determination of bisphenol A, using a glassy carbon electrode (GCE) modified with Fe3O4/graphene oxide (GO) nanocomposite. The modification of the electrode surface was performed by dispersion drop-casting. The electro­chemical behavior of bisphenol A was evaluated by cyclic voltammetry (CV). The oxidation peak was observed during the anodic potential scan at potentials of 0.45 V. Higher anodic peak currents (Ipa) were observed at Fe3O4/GO/GCE modified electrode than at bare GCE. The elec­trochemical determination by differential pulse voltammetry (DPV) revealed a linear response in the concentration range of 1.0×10-7 to 5.0×10-5 M, with a detection limit of 9.0×10-8 M. The proposed method was successfully applied using water samples, with good recoveries.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"45 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81547970","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Electrodeposition of polyfunctional Ni coatings from deep eutectic solvent based on choline chloride and lactic acid 基于氯化胆碱和乳酸的深共熔溶剂电沉积多功能Ni涂层
IF 2.2
Journal of Electrochemical Science and Engineering Pub Date : 2022-09-13 DOI: 10.5599/jese.1451
D. Ushchapovskiy, V. Vorobyova, G. Vasyliev, O. Linyucheva
{"title":"Electrodeposition of polyfunctional Ni coatings from deep eutectic solvent based on choline chloride and lactic acid","authors":"D. Ushchapovskiy, V. Vorobyova, G. Vasyliev, O. Linyucheva","doi":"10.5599/jese.1451","DOIUrl":"https://doi.org/10.5599/jese.1451","url":null,"abstract":"The process of electrodeposition of nickel coatings from electrolytes based on a deep eutectic solvent (DES) mixture of choline chloride and lactic acid with a molar ratio of 1:3 was studied. The physicochemical properties and characteristics of DES, namely, con­ductivity, FT-IR and NMR analysis were determined. FT-IR results confirmed that H-bonds occurring between two components in DES were the main force leading to the eutectic formation. Electrochemical techniques were used to characterize the deposition process and scanning electron microscopy was used to study the deposit morphology. Based on polarization measurements, it has been found that at NiCl2·6H2O content of 1.14 M and a temperature of 75 °C, the limiting current density of nickel electrodeposition was near 2 A dm-2. The polarization of the cathodic nickel deposition varied within -0.63 to 1.1 V at current density of 0.25 A dm-2 It has been shown that an increase of water content in the electrolyte does not significantly affect the current efficiency of the nickel electrodeposition process, which was in a range 85-93 %. However, the increase in water content contributes to the increase of heterogeneity and crystal grains size distribution of galvanic deposits. The established values of the Wagner number indicate the predominance of the primary current density distribution in the process of electrodeposition of nickel coatings. Galvanic coatings possess a highly developed nanostructured surface, exhibit increased capillary properties, and can be used as electrode materials for the process of electrolysis of water.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"11 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86987171","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Influence of operating temperature on the activation efficiency of Li-ion cells with xLi2MnO3-(1-x)LiMn0.5Ni0.5O2 electrodes 工作温度对xLi2MnO3-(1-x)LiMn0.5Ni0.5O2电极活化锂离子电池效率的影响
IF 2.2
Journal of Electrochemical Science and Engineering Pub Date : 2022-09-12 DOI: 10.5599/jese.1458
R. Nazario-Naveda, S. Rojas-Flores, Moisés Gallozzo-Cardenas, L. Juárez-Cortijo, L. Angelats-Silva
{"title":"Influence of operating temperature on the activation efficiency of Li-ion cells with xLi2MnO3-(1-x)LiMn0.5Ni0.5O2 electrodes","authors":"R. Nazario-Naveda, S. Rojas-Flores, Moisés Gallozzo-Cardenas, L. Juárez-Cortijo, L. Angelats-Silva","doi":"10.5599/jese.1458","DOIUrl":"https://doi.org/10.5599/jese.1458","url":null,"abstract":"In this study, the effect of operating temperature at 55 °C on xLi2MnO3-(1-x)LiMn0.5Ni0.5O2 electrodes during the charge/discharge process at different current densities was investigated. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used for structural and morphological analysis of the fabricated cathode materials, while charge-discharge curves and differential capacity were used to study the electrochemical behavior. Results confirm the formation of the structures with two phases associated with the components of the layered material. It was found that at 55 °C, a capacity higher than 357 mAh g-1 could be achieved at a voltage of 2.5-4.8 V vs. Li/Li+, which was larger than the capacity achieved at room temperature. At 55 °C, a change in valence could be observed during charging and discharging due to the change in the position of the peaks associated with Mn and Ni, highlighting cathodic material with x = 0.5 as the material that retains the layered structure at this temperature. This work confirms the good performance of electrodes made with this material at elevated temperatures and gives a better understanding of its electrochemical behavior.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"2 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79256492","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Chemical vapor deposited graphene-based quasi-solid-state ultrathin and flexible sodium-ion supercapacitor 化学气相沉积石墨烯基准固态超薄柔性钠离子超级电容器
IF 2.2
Journal of Electrochemical Science and Engineering Pub Date : 2022-09-09 DOI: 10.5599/jese.1411
Mohammed Saquib Khan, Preeti Shakya, N. Bhardwaj, Deependra Jhankal, A. Sharma, M. K. Banerjee, K. Sachdev
{"title":"Chemical vapor deposited graphene-based quasi-solid-state ultrathin and flexible sodium-ion supercapacitor","authors":"Mohammed Saquib Khan, Preeti Shakya, N. Bhardwaj, Deependra Jhankal, A. Sharma, M. K. Banerjee, K. Sachdev","doi":"10.5599/jese.1411","DOIUrl":"https://doi.org/10.5599/jese.1411","url":null,"abstract":"Flexible electronic devices find wide application in wearable electronics and foldable gadgets. This article reports chemical vapor deposited (CVD) few-layers graphene for a solid-state flexible supercapacitor device. Raman spectroscopy analysis reveals up to five layers in the graphene samples. Polyvinyl alcohol-Na2SO4 hydrogel membrane is used as a gel polymer electrolyte (GPE). 50 nm thick silver (Ag) deposited on polyethylene tere­phthalate (PET) through E-beam deposition served as the flexible current collector for the device. Galvanostatic charge-discharge (GCD) executed on the fabricated device to ana­lyze its electrochemical performance yielded a specific areal capacitance of 15.3 mF cm-2 at 0.05 mA cm-2 current density. The obtained power density of the fabricated device is 0.53 µWh cm-2 at a power density of 25 µW cm-2.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"29 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90096367","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
An electrochemical sensor for detection of vanillin in food samples using CuFe2O4 nanoparticles/ionic liquids modified carbon paste electrode CuFe2O4纳米颗粒/离子液体修饰碳糊电极用于食品中香兰素的电化学传感器
IF 2.2
Journal of Electrochemical Science and Engineering Pub Date : 2022-09-08 DOI: 10.5599/jese.1395
Afsaneh Hajializadeh
{"title":"An electrochemical sensor for detection of vanillin in food samples using CuFe2O4 nanoparticles/ionic liquids modified carbon paste electrode","authors":"Afsaneh Hajializadeh","doi":"10.5599/jese.1395","DOIUrl":"https://doi.org/10.5599/jese.1395","url":null,"abstract":"A highly selective electrochemical sensor modified with CuFe2O4 nanoparticles and the ionic liquid was constructed for the detection of vanillin. The sensor could recognize vanillin from its analogs and possible coexistent substances. The response peak current and vanillin concen­tration showed a good linear relationship in the range of 0.01 - 300.0 μM, with a sensitivity of 0.0923 μA μM-1. The detection limit was 0.008 μM (S/N = 3). Besides, the reproducibility and stability measurements were also evaluated. It was applied to the determination of vanillin in real samples with satisfactory results.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"125 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90567616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Applications of biopolymer coatings in biomedical engineering 生物聚合物涂层在生物医学工程中的应用
IF 2.2
Journal of Electrochemical Science and Engineering Pub Date : 2022-09-07 DOI: 10.5599/jese.1460
Jashanpreet Sing, Simranjit Singh, R. Gill
{"title":"Applications of biopolymer coatings in biomedical engineering","authors":"Jashanpreet Sing, Simranjit Singh, R. Gill","doi":"10.5599/jese.1460","DOIUrl":"https://doi.org/10.5599/jese.1460","url":null,"abstract":"In this paper, a comprehensive overview of recent developments in the many different types of biopolymer coatings used in biomedical applications is presented. Biopolymer coatings have tremendous promise in various biological applications due to their adaptability. Polymer coatings may be used to improve surface qualities to fulfill certain criteria or to include extra capabilities for various biomedical applications. This analysis focuses mostly on certain polymers for usage in coating applications as well as a variety of polymer coatings that provide enhanced functionalization. The most recent findings from relevant research have been presented on using polymer coatings on nanoparticles for biological applications. Moreover, the latest research on biopolymer coatings for im­proved tissue engineering and drug delivery on various substrates and nanoparticles has been reported. Additionally, the most recent scientific breakthroughs have been compiled.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"11 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2022-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77464035","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 17
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