{"title":"A Comparative Analysis on Thermal Stability of Delithiated Nickel-Rich NCA and NCM in Pouch Cells","authors":"","doi":"10.1115/1.4062318","DOIUrl":"https://doi.org/10.1115/1.4062318","url":null,"abstract":"\u0000 As two typical nickel-rich layered oxide cathodes, LiNi0.8Co0.15Al0.05O2 (NCA) and LiNi0.8Co0.1Mn0.1O2 (NCM811) are widely applicated in commercial high energy batteries for electric vehicles. However, a comprehensive assessment of their thermal characteristics in full cell is currently lacking. In this paper, we conducted monomer level thermal runaway test on NCA|SiC pouch cell and NCM811|SiC pouch cell through ARC test. The results showed that the {T1, T2, T3} of NCA|SiC pouch cell and NCM811|SiC pouch cell are {113.8 °C, 230.4 °C, 801.4 °C } and {91.3 °C, 202.1 °C, 745 °C}, respectively. Then the thermal stability of NCA and NCM811 was tested by DSC-TG-MS. The results showed that the phase transition temperature of NCA is higher than that of NCM811. However, when NCA and NCM811 were mixed with anode electrode materials or electrolyte, NCA produced significantly more heat than NCM811. By confirming the thermal properties of NCA|SiC pouch cell and NCM811|SiC pouch cell, a deeper understanding on battery thermal runaway was achieved, which is helpful for the design of high-safety lithium-ion batteries in the future.","PeriodicalId":15579,"journal":{"name":"Journal of Electrochemical Energy Conversion and Storage","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2023-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46933008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"State of charge and state of health estimation of lithium-ion battery packs with inconsistent internal parameters using dual extended Kalman filter","authors":"","doi":"10.1115/1.4062319","DOIUrl":"https://doi.org/10.1115/1.4062319","url":null,"abstract":"\u0000 The internal battery parameters of the lithium-ion battery (LIB) energy storage system may be inconsistent due to different aging degrees during the operation, and the thermal effect can also threaten the safety of the system. In this paper, based on the second-order resistor-capacitor (2-RC) equivalent circuit model (ECM) and the dual extended Kalman filter (DEKF) algorithm, an electrical simulation model of a LIB pack with inconsistent parameters considering the thermal effect is established, in which state of charge (SOC) and state of health (SOH) are estimated using DEKF while the temperature is calculated by a thermal module. The simulation results show that the DEKF algorithm has a good effect on battery state and parameter estimation, with the root mean square error (RMSE) of voltage is lower than 0.01 V and SOC mean average error (MAE) is below 1.50 % while SOH error is 3.37 %. In addition, the thermal module can provide an accurate estimation on the inconsistent temperature rise of the battery pack, and the MAE between the model-calculated temperature and the experiment is no more than 6.60 %. This paper provides the basic data for the scale-up of the electrothermal co-simulation model of the LIB energy storage system.","PeriodicalId":15579,"journal":{"name":"Journal of Electrochemical Energy Conversion and Storage","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2023-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42665602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
You Xu, Hongxian Liu, Zhenxing Zheng, Jingxiang Yao, Kaiqing Zhou, Jiehao Li
{"title":"Comprehensive Performance Evaluation Strategy for Power Battery System based on Dynamic Weight","authors":"You Xu, Hongxian Liu, Zhenxing Zheng, Jingxiang Yao, Kaiqing Zhou, Jiehao Li","doi":"10.1115/1.4062287","DOIUrl":"https://doi.org/10.1115/1.4062287","url":null,"abstract":"\u0000 New energy vehicles are the effective solution to solve the situation of carbon neutrality with carbon peaking in China. The power battery system is the key component of new energy vehicles, and its performance is directly related to the safety and cruising range. Since the performance of the battery system is affected by factors such as electrical contact stability, voltage and current characteristics, and its own temperature, its full life cycle performance cannot be comprehensively evaluated, resulting in the inefficient prediction and protective measures. In this paper, the electrical contact stability evaluation index is proposed by studying the relationship between the electrical contact stability and the fluctuation characteristics of the reversed equilibrium potential. The parameters including electrical contact stability, polynomial-based status of charge (SoC), the status of health (SoH), the status of consistency, as well as battery system temperature constituted the performance matrix of the battery system. A comprehensive performance evaluation method of power battery system based on dynamic weight is designed with normalized classification. Finally, the cyclic charge-discharge test experiment under the vibration status were carried out to verify the effectiveness of the method. The result showed that the method can characterize various functions and provide an intuitive and detailed evaluation for the safety prediction of battery system.","PeriodicalId":15579,"journal":{"name":"Journal of Electrochemical Energy Conversion and Storage","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2023-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"63503955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Sugimoto, Zhikuan Zhu, Srikanth Gopalan, S. Basu, U. Pal
{"title":"CHROMIUM POISONING MITIGATION STRATEGY IN STRONTIUM DOPED LANTHANUM MANGANITE BASED AIR ELECTRODES IN SOLID OXIDE FUEL CELLS","authors":"M. Sugimoto, Zhikuan Zhu, Srikanth Gopalan, S. Basu, U. Pal","doi":"10.1115/1.4062192","DOIUrl":"https://doi.org/10.1115/1.4062192","url":null,"abstract":"\u0000 Chromium poisoning of the air electrode remains an obstacle to the long-term performance of solid oxide fuel cells (SOFCs). In Sr-doped LaMnO3 (LSM) air electrodes, the poisoning process results in two types of deposits, chromium oxide (Cr2O3), and Mn, Cr spinel (MnCr2O4). The former forms electrochemically and the latter forms via a chemical reaction. By applying a small anodic reverse bias, Cr2O3 deposits can be removed because their formation is electrochemical in nature. However, MnCr2O4 deposits remain because their formation is chemical, rather than electrochemical, in nature. In-situ chemical decomposition of the Mn, Cr spinel was investigated as an alternate removal method as thermodynamics supports its decomposition into constituent oxides below ~540°C in pure oxygen. The spinel decomposition process was characterized using TGA and XRD analyses. The experimentally determined rate of spinel decomposition was undetectable (very slow) with isolated MnCr2O4 powders. The addition of 10 mole% gadolinia doped ceria (GDC) and silver powders significantly increased the rate of decomposition. However, the rate is limited by the diffusion of oxygen through the decomposed oxide layer. Although one strategy may be the addition of GDC and silver to the LSM air electrode to enhance spinel decomposition, the more effective mitigation strategy would be to prevent the formation of MnCr2O4 spinel in the first place through the removal of the reactants: Cr2O3 via electrochemical cleaning and mobile Mn ions in the zirconia electrolyte by incorporating a diffusion barrier layer such as GDC between the air electrode and electrolyte.","PeriodicalId":15579,"journal":{"name":"Journal of Electrochemical Energy Conversion and Storage","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2023-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43098804","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Special Section on 2D Materials for Electrochemical Energy Storage and Conversion","authors":"Leela Mohana Reddy Arava, D. Datta, W. Chiu","doi":"10.1115/1.4062186","DOIUrl":"https://doi.org/10.1115/1.4062186","url":null,"abstract":"","PeriodicalId":15579,"journal":{"name":"Journal of Electrochemical Energy Conversion and Storage","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2023-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"63503885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jinjing Du, Y. Guo, Meng Zhou, Ya-ru Cui, Bin Wang, Qian Li, Jun Zhu, Dandan Zhao
{"title":"Effect of SiO2 coating on microstructure and electrochemical properties of LiNi0.5Mn1.5O4 cathode material","authors":"Jinjing Du, Y. Guo, Meng Zhou, Ya-ru Cui, Bin Wang, Qian Li, Jun Zhu, Dandan Zhao","doi":"10.1115/1.4062161","DOIUrl":"https://doi.org/10.1115/1.4062161","url":null,"abstract":"We present a simple method for producing SiO2 modified LNMO cathode materials. Manganese carbonate was directly mixed with nickel nitrate and lithium hydroxide, and a spherical structure LNMO cathode material was prepared by two-step calcination, then ethyl orthosilicate and LNMO powder were simply mixed in solid and liquid phase to prepare SiO2-coated LNMO material. The effect of SiO2 coating on the structure of LNMO was studied by XRD, SEM, TEM, TG-DSC. An amorphous SiO2 coating layer developed on the surface of the LNMO particles in the modification, and this could alleviate the strike of HF caused by electrolyte decomposition as well as the development of a solid electrolyte interphase. The electrochemical performance of the coated material was as follows: when the amount of SiO2 was 0wt%, 1wt%, 2wt% and 3wt%, the initial discharge capacity of the sample was 98.2, 84.1, 101.3 and 89.8mAh·g−1, respectively. After 50 charge-discharge cycles, the capacity retention rates are 92.7%, 66.8%, 97.9% and 93.8%, respectively. The cyclic stability of the samples can be significantly improved when the SiO2 coating amount is 2wt% and 3wt%, indicating that SiO2 coating can not only improve the discharge specific capacity of the material, but also improve its cyclic stability.","PeriodicalId":15579,"journal":{"name":"Journal of Electrochemical Energy Conversion and Storage","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2023-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47448738","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Exhaust gas composition of lignin reactions in molten carbonate salt of Direct Carbon Fuel Cell (DCFC) using Factsage","authors":"U. L. Compaore, O. Savadogo, K. Oishi","doi":"10.1115/1.4062162","DOIUrl":"https://doi.org/10.1115/1.4062162","url":null,"abstract":"\u0000 The most studied Molten Carbonate-Direct Carbon Fuel Cel (MC-LFC) or Molten Carbonate Direct Carbon Fuel Cell (MC-DCFC) prototypes are those which are fed by fossil fuel. Substituting these fossilized fuels in the MC-DCFC operation with lignin, which is a bio-based carbon, may make this system more efficient, clean, and sustainable. The manipulation module (Mixture) and the computational module (Equilib) of the Factsage package were used to simulate two systems that can represent the anodic compartment of a direct carbon fuel cell based on MC-DCFC. The first system includes lignin and a mixture of molten carbonate (Li2CO3-Na2CO3-Cs2CO3). The second system uses the same first electrolyte system but with the addition of CO2 gas. The results show the formation of mixed gases in the anodic compartment which are composed of H2, CO, CO2, CH4 and H2O. The relative concentration of each of the species of this mixed gas has an impact on the efficiency of the MC-DCFC. How the relative concentration of these gases in this electrolyte can impact the performance parameters of the MC-DCFC is systematically analysed. If the operating conditions of the fuel cell are optimized to get a gas composition of mainly of CO2 with low amounts of H2, CO, CH4, H2O in the anode compartment of the MC-DCFC, This will help to improve the conversion efficiency of lignin fuel in the MC-DCFC.","PeriodicalId":15579,"journal":{"name":"Journal of Electrochemical Energy Conversion and Storage","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2023-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41812672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Modified Silicon Anode for Improved Low Temperature Performance of Lithium-ion Batteries","authors":"Jason A. Mennel, D. Chidambaram","doi":"10.1115/1.4062163","DOIUrl":"https://doi.org/10.1115/1.4062163","url":null,"abstract":"\u0000 The shift away from fossil fuels for modern day energy requirements has resulted in a higher demand for electric vehicles and has led to a critical role for lithium-ion batteries. Next generation higher capacity electrode materials are needed to meet the demands of future electric vehicles. Lithium-ion batteries function optimally around room temperature (23°C), but discharge capacity diminishes rapidly below 0°C and significantly affects population living in colder climates. Higher capacity electrode materials such as silicon need to be paired with new electrolytes that favor ideal low temperature performance. This work pairs a typical nickel rich lithium cathode with a modified silicon anode and a ternary carbonate/ester electrolyte to demonstrate improved discharge capacity at sub zero temperature.","PeriodicalId":15579,"journal":{"name":"Journal of Electrochemical Energy Conversion and Storage","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2023-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49274028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hengjie Shen, Minghai Li, Yan Wang, Hewu Wang, Xuning Feng, Juan Wang
{"title":"Effect of Liquid Cooling Structure of Confluence Channel on Thermal Performance of Lithium-Ion Batteries","authors":"Hengjie Shen, Minghai Li, Yan Wang, Hewu Wang, Xuning Feng, Juan Wang","doi":"10.1115/1.4062080","DOIUrl":"https://doi.org/10.1115/1.4062080","url":null,"abstract":"\u0000 In this study, based on the liquid cooling method, A confluence channel structure is proposed, and the heat generation model in the discharge process of three-dimensional battery module is established. The effects of channel structure, inlet mass flow rate and coolant flow direction on the heat generation of battery module were studied by control variable method. Simulation results show that the confluence channel structure ( e ) shows good cooling effect on the battery temperature when controlling the 5 C discharge of the battery module. In addition, compared with the straight channel under the same working condition. In the discharge process of battery module, Average temperature amplitude in battery module decreased by 17.3 %, the inlet and outlet pressure is reduced by 16.47 %, and the maximum temperature amplitude is reduced by 20.3 %. Effectively improve temperature uniformity and reduce pressure drop. The problem of uneven temperature distribution caused by uneven velocity distribution of coolant in traditional straight channel is improved. At the same time, the design of the confluence structure accelerates the heat transfer of the channel plate and provides a new idea for the design of the cooling channel.","PeriodicalId":15579,"journal":{"name":"Journal of Electrochemical Energy Conversion and Storage","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2023-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45048777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Improved Performance of Silicon Anodes Using Copper Nanoparticles as Additive","authors":"Gabrielle Bachand, Jason Mennel, Dev Chidambaram","doi":"10.1115/1.4056841","DOIUrl":"https://doi.org/10.1115/1.4056841","url":null,"abstract":"Abstract Nanoscale copper has been successfully integrated into a silicon-based anode via a cost-effective, one-step process. The additive was found to improve the overall electrical conductivity and charge/discharge cycling performance of the anode. Analysis of the new material shows that copper particles are homogeneously interspersed into the silicon active layer. The formation of Cu3Si during the annealing step of the fabrication process was also confirmed using X-ray diffraction and is thought to contribute to the structural stability of the anode during cycling. Despite the inclusion of only small quantities of the additive (approximately 3%), anodes with the added copper show significantly higher initial discharge capacity values (957 mAg−1) compared to anodes without copper (309 mAg−1), and they continue to outperform the latter after 100 charge/discharge cycles. Results also show a significant decrease in the resistance of anodes with the additive, a contributing factor in the improvement of the electrochemical performance.","PeriodicalId":15579,"journal":{"name":"Journal of Electrochemical Energy Conversion and Storage","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136007376","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}