发布求助
文献互助 智能选刊 最新文献

Journal of Colloid Science最新文献

筛选
英文 中文
The effect of autoxidation on the wettability of a linoleic acid monolayer 自氧化对亚油酸单层润湿性的影响
Journal of Colloid Science Pub Date : 1965-06-01 DOI: 10.1016/0095-8522(65)90021-8
William H Trice
{"title":"The effect of autoxidation on the wettability of a linoleic acid monolayer","authors":"William H Trice","doi":"10.1016/0095-8522(65)90021-8","DOIUrl":"10.1016/0095-8522(65)90021-8","url":null,"abstract":"<div><p>The effect of autoxidation of a linoleic acid monolayer on the contact angle with water depended upon the conditions of oxidation and the type of surface upon which the monolayer was formed. For monolayers on a glass surface with which the carboxyl group did not react, autoxidation in air of 0.02% R.H. increased the contact angle with water from zero to 56°. However, on copper where reaction between the surface and the carboxyl group occurred, autoxidation under the same conditions decreased the contact angle from 86° to 76°. Autoxidation in air of 50% R.H. caused no change in the initial contact angle of zero with water when the monolayer was on glass. On copper, aging under these conditions caused the angle to increase from an initial value of 86° to 92°. Contact angles between methylene iodide and the monolayers were not greatly affected by autoxidation under any of the afore-mentioned conditions. Ultraviolet spectra and reductive polarography indicated that secondary oxidation of the initially formed 9- or 13-hydroperoxide of the conjugated octadecadienoic acid occurred to a much greater extent in the drier air. The hypothesis presented explains the wettability results in terms of the ability of the oxidation products to produce a solid, coherent monolayer structure, taking into account the location in the hydrocarbon chain of oxygen-containing functional groups introduced by autoxidation.</p></div>","PeriodicalId":15437,"journal":{"name":"Journal of Colloid Science","volume":"20 5","pages":"Pages 400-416"},"PeriodicalIF":0.0,"publicationDate":"1965-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0095-8522(65)90021-8","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87905197","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Rayleigh-Gans-Debye and Mie theories in the determination of spherical particle sizes 确定球形颗粒大小的瑞利-甘斯-德拜和米理论
Journal of Colloid Science Pub Date : 1965-06-01 DOI: 10.1016/0095-8522(65)90024-3
B.R Jennings, H.G Jerrard
{"title":"Rayleigh-Gans-Debye and Mie theories in the determination of spherical particle sizes","authors":"B.R Jennings,&nbsp;H.G Jerrard","doi":"10.1016/0095-8522(65)90024-3","DOIUrl":"https://doi.org/10.1016/0095-8522(65)90024-3","url":null,"abstract":"<div><p>The results of a light scattering study of four rubber latex samples using a dissymmetry technique are reported. Particle diameters found from the Rayleigh-Gans-Debye and Mie theories were in the range 1,400 to 2,000 A. In water the relative refractive index of these particles was <em>m</em> = 1.15 so that for particles of this size, the two accepted theoretical limitations for the RGD theory were exceeded. However, the results indicate that this theory can still be used to give particle sizes to within 5% for values of <em>m</em> approaching 1.15 and for diameters of up to 2,000 A.</p></div>","PeriodicalId":15437,"journal":{"name":"Journal of Colloid Science","volume":"20 5","pages":"Pages 448-452"},"PeriodicalIF":0.0,"publicationDate":"1965-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0095-8522(65)90024-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91623856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Rheology of non-Newtonian fluids: A new flow equation for pseudoplastic systems 非牛顿流体的流变学:假塑性体系的一个新的流动方程
Journal of Colloid Science Pub Date : 1965-06-01 DOI: 10.1016/0095-8522(65)90022-X
Malcolm M. Cross
{"title":"Rheology of non-Newtonian fluids: A new flow equation for pseudoplastic systems","authors":"Malcolm M. Cross","doi":"10.1016/0095-8522(65)90022-X","DOIUrl":"10.1016/0095-8522(65)90022-X","url":null,"abstract":"<div><p>On the assumption that pseudoplastic flow is associated with the formation and rupture of structural linkages a new flow equation is derived. The equation takes the form <span><span><span><math><mtext>ƞ = ƞ</mtext><msub><mi></mi><mn>∞</mn></msub><mtext> + </mtext><mtext>ƞ</mtext><msub><mi></mi><mn>0</mn></msub><mtext> − ƞ</mtext><msub><mi></mi><mn>∞</mn></msub><mtext>1 + αD</mtext><msup><mi></mi><mn><mtext>2</mtext><mtext>3</mtext></mn></msup><mtext>,</mtext></math></span></span></span> where <em>D</em> = rate of shear, <em>η</em><sub>0</sub> = limiting viscosity at zero rate of shear, <em>η</em><sub>∞</sub> = limiting viscosity at infinite rate of shear, and α is a constant associated with the rupture of linkages.</p><p>Graphical methods for evaluating the three constants <em>η</em><sub>0</sub> , <em>η</em><sub>∞</sub> , and α are presented.</p><p>Experimental data are presented on a wide range of pseudoplastic systems, ranging from suspensions to optically clear solutions, in both aqueous and nonaqueous media. In all cases the results conform to the equation with a high degree of accuracy over a wide range of shear rates.</p></div>","PeriodicalId":15437,"journal":{"name":"Journal of Colloid Science","volume":"20 5","pages":"Pages 417-437"},"PeriodicalIF":0.0,"publicationDate":"1965-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0095-8522(65)90022-X","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85431952","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1624
Counter for emulsion photomicrographs 用于乳胶显微照片的计数器
Journal of Colloid Science Pub Date : 1965-06-01 DOI: 10.1016/0095-8522(65)90027-9
P Narasimham, Mohammad Yaseen, P.S Kolhatkar, J.S Aggarwal
{"title":"Counter for emulsion photomicrographs","authors":"P Narasimham,&nbsp;Mohammad Yaseen,&nbsp;P.S Kolhatkar,&nbsp;J.S Aggarwal","doi":"10.1016/0095-8522(65)90027-9","DOIUrl":"10.1016/0095-8522(65)90027-9","url":null,"abstract":"","PeriodicalId":15437,"journal":{"name":"Journal of Colloid Science","volume":"20 5","pages":"Pages 473-475"},"PeriodicalIF":0.0,"publicationDate":"1965-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0095-8522(65)90027-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88099094","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Manipulation of insoluble films at an oil/water interface 油/水界面上不溶膜的处理
Journal of Colloid Science Pub Date : 1965-06-01 DOI: 10.1016/0095-8522(65)90020-6
L Blight, C.W.N Cumper, V Kyte
{"title":"Manipulation of insoluble films at an oil/water interface","authors":"L Blight,&nbsp;C.W.N Cumper,&nbsp;V Kyte","doi":"10.1016/0095-8522(65)90020-6","DOIUrl":"10.1016/0095-8522(65)90020-6","url":null,"abstract":"<div><p>An apparatus is described for compressing and expanding insoluble monolayers, or films, present at an oil/water interface. Typical results for polymethylmethacrylate and pepsin monolayers at a petroleum ether/water interface are described.</p></div>","PeriodicalId":15437,"journal":{"name":"Journal of Colloid Science","volume":"20 5","pages":"Pages 393-399"},"PeriodicalIF":0.0,"publicationDate":"1965-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0095-8522(65)90020-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82402974","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 16
Editors' note 编者注
Journal of Colloid Science Pub Date : 1965-06-01 DOI: 10.1016/0095-8522(65)90029-2
Milton Kerker, A.C Zettlemoyer
{"title":"Editors' note","authors":"Milton Kerker,&nbsp;A.C Zettlemoyer","doi":"10.1016/0095-8522(65)90029-2","DOIUrl":"https://doi.org/10.1016/0095-8522(65)90029-2","url":null,"abstract":"","PeriodicalId":15437,"journal":{"name":"Journal of Colloid Science","volume":"20 5","pages":"Page i"},"PeriodicalIF":0.0,"publicationDate":"1965-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0095-8522(65)90029-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91623855","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An improved mass-transport cell for measuring electrophoretic mobilities 一种用于测量电泳迁移率的改进的质量传递细胞
Journal of Colloid Science Pub Date : 1965-06-01 DOI: 10.1016/0095-8522(65)90023-1
Richard P Long , Sydney Ross
{"title":"An improved mass-transport cell for measuring electrophoretic mobilities","authors":"Richard P Long ,&nbsp;Sydney Ross","doi":"10.1016/0095-8522(65)90023-1","DOIUrl":"10.1016/0095-8522(65)90023-1","url":null,"abstract":"<div><p>A new design is presented of an improved mass-transport cell for the measurement of electrophoretic mobilities of concentrated suspensions of particles. The results obtained with three different suspensions are compared with those from a Burton cell (moving-boundary method) and found to give good agreements. The advantages and disadvantages of the new cell are pointed out.</p></div>","PeriodicalId":15437,"journal":{"name":"Journal of Colloid Science","volume":"20 5","pages":"Pages 438-447"},"PeriodicalIF":0.0,"publicationDate":"1965-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0095-8522(65)90023-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"23844573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 33
Optical interference in curved soap films 弯曲肥皂膜中的光学干涉
Journal of Colloid Science Pub Date : 1965-06-01 DOI: 10.1016/0095-8522(65)90025-5
H. M. Princen, S. G. Mason
{"title":"Optical interference in curved soap films","authors":"H. M. Princen, S. G. Mason","doi":"10.1016/0095-8522(65)90025-5","DOIUrl":"https://doi.org/10.1016/0095-8522(65)90025-5","url":null,"abstract":"","PeriodicalId":15437,"journal":{"name":"Journal of Colloid Science","volume":"4 1","pages":"453-463"},"PeriodicalIF":0.0,"publicationDate":"1965-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76907794","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Rayleigh-Gans-Debye and Mie theories in the determination of spherical particle sizes 确定球形颗粒大小的瑞利-甘斯-德拜和米理论
Journal of Colloid Science Pub Date : 1965-06-01 DOI: 10.1016/0095-8522(65)90024-3
B. Jennings, H. Jerrard
{"title":"Rayleigh-Gans-Debye and Mie theories in the determination of spherical particle sizes","authors":"B. Jennings, H. Jerrard","doi":"10.1016/0095-8522(65)90024-3","DOIUrl":"https://doi.org/10.1016/0095-8522(65)90024-3","url":null,"abstract":"","PeriodicalId":15437,"journal":{"name":"Journal of Colloid Science","volume":"20 1","pages":"448-452"},"PeriodicalIF":0.0,"publicationDate":"1965-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86922079","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Effect of urea, guanidinium chloride, and dioxane on the c.m.c. of branched-chain nonionic detergents 尿素、氯化胍和二氧六环对支链非离子洗涤剂cmc的影响
Journal of Colloid Science Pub Date : 1965-06-01 DOI: 10.1016/0095-8522(65)90026-7
M.J Schick, A.H Gilbert
{"title":"Effect of urea, guanidinium chloride, and dioxane on the c.m.c. of branched-chain nonionic detergents","authors":"M.J Schick,&nbsp;A.H Gilbert","doi":"10.1016/0095-8522(65)90026-7","DOIUrl":"10.1016/0095-8522(65)90026-7","url":null,"abstract":"<div><p>The effect of urea on the c.m.c. of polyoxyethylene straight-chain alkanols has been reported in a previous investigation. The observed increments in c.m.c. values have been attributed to increased hydration of the ethylene oxide chain caused by a reduction of the cooperative structure of water. On the basis of analogous results obtained in this investigation with polyoxyethylene branched-chain nonylphenols, the possibility of channel compound formation in these highly concentrated urea solutions has been excluded. Comparable increments in c.m.c. values have also been observed with guanidinium chloride and dioxane at lower concentration levels than with urea. The former presents additional evidence for attributing these changes to increased hydration of the ethylene oxide chain caused by a reduction of the cooperative structure of water.</p></div>","PeriodicalId":15437,"journal":{"name":"Journal of Colloid Science","volume":"20 5","pages":"Pages 464-472"},"PeriodicalIF":0.0,"publicationDate":"1965-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0095-8522(65)90026-7","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88663343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 67
首页 上一页 下一页 尾页
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整，为了账户安全，请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们：info@booksci.cn Book学术提供免费学术资源搜索服务，方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号：481959085
Book学术官方微信