Journal of chemical technology and biotechnology最新文献

{"title":"Ultrasound-assisted improved crystallization of dimethyl sulphone","authors":"Bharat Rengarajan,&nbsp;Parag R. Gogate","doi":"10.1002/jctb.7837","DOIUrl":"https://doi.org/10.1002/jctb.7837","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> Background</h3>\u0000 \u0000 <p>The present work aims to elucidate the effect of ultrasound on the crystallization of dimethyl sulphone, a therapeutic and anti-inflammatory agent, for the first time. Cooling mode of crystallization was used, and particle size distribution (PSD) and morphology changes for different approaches were analyzed.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Results</h3>\u0000 \u0000 <p>Ultrasound-assisted cooling crystallization (UAC) showed improvements in terms of particle size and shape within a short span of sonication. The optical microscopic images revealed that the crystal shape changes from needle-shaped to spherical/rod-shaped, which is necessary to meet the desired specifications for the active pharmaceutical ingredients (API). As a result of uniform PSD, the filtration time decreased in the case of UAC compared with the conventional approach. Studies with different modes of sonication, an ultrasonic horn operating at a frequency of 20 kHz and the ultrasonic bath operating at a dual frequency of 22 and 40 kHz, resulted in a similar product yield. With the scale-up considerations, the effect of acoustic cavitation on the crystallization process was studied at a larger batch size and promising results for size reduction and morphological alterations were established.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Conclusions</h3>\u0000 \u0000 <p>The overall work demonstrated the process intensification benefits of applying ultrasound for cooling crystallization in terms of size reduction with desired morphology. © 2025 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"100 5","pages":"995-1008"},"PeriodicalIF":2.8,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143818492","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Design and economic evaluation of separation process for novel production of cyclopentyl methyl ether","authors":"Miroslav Variny,&nbsp;Lukas Hlavatý,&nbsp;Zuzana Silná,&nbsp;Tomáš Soták","doi":"10.1002/jctb.7839","DOIUrl":"https://doi.org/10.1002/jctb.7839","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>Cyclopentyl methyl ether (CPME) is a solvent with several applications and many advantages compared to similar solvents. The main problem with this solvent is its production. The current process for its production uses oil-derived cyclopentene, which is problematic from an environmental standpoint. A newer, currently unused method can produce CPME using renewable reactants; however, it also produces multiple side products, separation of which has proven to be very energy intensive.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>Using the ASPEN + V12 model of the separation process, we evaluated the energy consumption of the process for a production capacity of 100 000 t/year. This process then underwent optimization, energy integration, and several process changes which managed to lower required energy consumption by over 50%. In addition, a basic economic evaluation of the process was done, consisting of CAPEX and OPEX estimation, as well as calculation of basic economic indicators. The results of which suggest that the price of product must be 2.5× higher than the main reactant for the process to be economically feasible. Finally, a basic environmental evaluation shows that CO₂ produced by this separation train is comparable to CO₂ produced by the entire production process of comparable solvents.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>Despite the substantial savings achieved by the process optimization and heat integration, the economic and environmental assessment revealed that the process remains unfeasible, especially from an economic standpoint. This is caused by a combination of poor reactor selectivity as well as substantial amount of excess methanol required in the reactor. © 2025 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"100 5","pages":"1009-1024"},"PeriodicalIF":2.8,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143818493","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Harnessing kānuka (Kunzea ericoides) subcritical water extract for food safety and odour neutralisation: an in vitro study","authors":"Indhuja Devadass,&nbsp;Simon Swift,&nbsp;Saeid Baroutian","doi":"10.1002/jctb.7842","DOIUrl":"https://doi.org/10.1002/jctb.7842","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p><i>Kunzea ericoides</i> (kānuka) is a traditional medicinal plant with antibacterial properties due to enriched bioactive constituents. However, a limited understanding of its antimicrobial profile has constrained its applications in food safety and odour neutralisation. This study aimed to address this gap by investigating the antimicrobial activity of kānuka subcritical water extracts obtained at different extraction temperatures and times. The antibacterial efficacy of the extracts was assessed using the broth dilution method, focusing on application in food safety and odour neutralisation.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>The extracts were effective against bacteria but not against fungal pathogens. Extracts obtained at higher temperatures were effective against <i>Staphylococcus aureus</i> (minimum bactericidal concentration (MBC) 1.2 mg mL⁻¹, &gt;160 °C) and <i>Escherichia coli</i> (MBC 7.5 mg mL⁻¹ at 220 °C). The most potent extracts, obtained between 160 and 220 °C, demonstrated bactericidal activity against foodborne pathogens, <i>Listeria monocytogenes</i>, <i>Bacillus cereus</i> and <i>Salmonella</i> Typhimurium, with an MBC 7.5 mg mL⁻¹ (&gt;160 °C), 3.75 mg mL⁻¹ (&gt;160 °C) and 1.87 mg mL⁻¹ (&gt;180 °C), respectively. The MBC against odour-causing organisms was 1.87 mg mL⁻¹ (&gt;160 °C) for <i>Kytococcus sedentarius</i> and <i>Brevibacterium linens</i>.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>The results indicated that the kānuka subcritical water extract contributed to antibacterial efficacy. Although specific bioactive concentrations were not measured in this study, the data suggest a correlation between extract composition and antibacterial activity. These findings support using kānuka extract as a potential antibacterial agent for food safety and odour control. However, further investigations are needed to understand the mechanism of action, stability of bioactive compounds and their synergistic effects with other natural extracts. These insights can broaden industrial applications. © 2025 The Author(s). <i>Journal of Chemical Technology and Biotechnology</i> published by John Wiley &amp; Sons Ltd on behalf of Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"100 5","pages":"1065-1076"},"PeriodicalIF":2.8,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/jctb.7842","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143818494","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Heterogeneous catalyst of cobalt phthalocyanine tetrasulfonamide loaded on Ca–Al hydrotalcites for oxidative desulfurization of spent sulfidic caustic","authors":"Ruiqi Huang,&nbsp;Zhaoyang Lu,&nbsp;Can Xu,&nbsp;Shuaiting Liang,&nbsp;Honglei Yuan,&nbsp;Geshan Zhang,&nbsp;Lihui Jia,&nbsp;Jun Yuan","doi":"10.1002/jctb.7840","DOIUrl":"https://doi.org/10.1002/jctb.7840","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> Background</h3>\u0000 \u0000 <p>Spent sulfidic caustic (SSC) from petrochemical and other chemical industries usually contains high concentrations of sulfur ion (S²⁻) and caustic soda (NaOH), which requires effective treatment. Here a CoPcSA/CaAl-LDHs catalyst was successfully synthesized by using a facile one-pot approach for loading cobalt phthalocyanine tetrasulfonamide (CoPcSA) on Ca–Al hydrotalcites (CaAl-LDHs). The material characterization included powder X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy and X-ray photoelectron spectroscopy.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Results</h3>\u0000 \u0000 <p>The effect of various parameters such as reaction temperature, catalyst dosage and aeration rate on the catalytic activity was investigated and optimized to be 75 °C, 1.5 mmol L⁻¹ and 2.5 L min⁻¹, respectively. CoPcSA/CaAl-LDHs shows very high catalytic efficiency for S²⁻ removal: a 95.0% S²⁻ removal can be achieved at extremely high concentration of S²⁻ (24 000 mg L⁻¹). In addition, the catalyst exhibits high stability and reusability even after 8 cycles of reuse.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Conclusion</h3>\u0000 \u0000 <p>CoPcSA/CaAl-LDHs exhibits outstanding catalytic activity and stability, showing impressive potential in practical application. © 2025 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"100 5","pages":"1057-1064"},"PeriodicalIF":2.8,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143818665","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Influence of C/N ratio on the efficacy of the continuous flow double-sludge AOA process with double cathode microbial fuel cell","authors":"Licheng Zhang,&nbsp;Xiao Chen,&nbsp;Chi Zhang,&nbsp;Jinchi Zhou","doi":"10.1002/jctb.7833","DOIUrl":"https://doi.org/10.1002/jctb.7833","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> Background</h3>\u0000 \u0000 <p>The continuous flow double-sludge anaerobic/aerobic/anoxic process is a good choice for removing nitrogen (N) and phosphorus (P) simultaneously, although these are difficult to remove efficiently. Microbial fuel cells (MFCs) can extract energy from wastewater and use electrons to remove pollutants. This study proposes a novel integration of MFCs with the continuous flow double-sludge AOA process, investigating the system's performance across different carbon (C)/N ratios (2, 3.5, 5 and 6.5) in terms of pollutant removal, electricity generation and microbial community structure.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Result</h3>\u0000 \u0000 <p>When the influent C/N ratio was 3.5, the average removal rates of chemical oxygen demand, ammonium (NH₄⁺)-N, and phosphate (PO₄³⁻)-P were 92.01%, 79.68% and 92.91%, respectively, and the average simultaneous nitrification and denitrification (SND) and SND P removal (SNDPR) rates of nitrogen oxide (NO_x⁻)-N were 53.30% and 42.09%, respectively. The diversity and abundance of microbial community were at a good level, and the relative abundance of <i>Dechloromonas</i>, <i>Pseudomonas</i> and <i>Candidatus_Competibacter</i> reached 4.16%, 2.16% and 4.61%, respectively, at C/N = 3.5.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Conclusions</h3>\u0000 \u0000 <p>Significant differences in pollutant removal were observed under different C/N conditions, with electron acceptors emerging as the biggest factor affecting power generation. According to the microbiological results, the combination of lower C/N ratios and higher PO₄³⁻-P contributed to the enrichment of key functional microorganisms. © 2025 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"100 5","pages":"978-994"},"PeriodicalIF":2.8,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143818786","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A comprehensive review on progression and innovations in microwave assisted extraction technology for essential oils","authors":"Irsha Dhotre","doi":"10.1002/jctb.7823","DOIUrl":"https://doi.org/10.1002/jctb.7823","url":null,"abstract":"<p>This Review Paper provides a comprehensive analysis of extraction methods for essential oils, focusing particularly on the innovative Microwave Assisted Extraction (MAE) technology. Essential oils, derived from various plant parts, are highly valued for their aromatic and therapeutic properties, finding applications in industries such as perfumery, aromatherapy, cosmetics, and food flavoring. Traditional extraction methods often face challenges, including prolonged extraction times, excessive solvent usage, and the risk of degrading sensitive compounds. In contrast, MAE has emerged as a superior alternative, offering significant advantages such as expedited extraction processes, reduced solvent consumption, and enhanced preservation of volatile compounds. This study highlights key findings, including the optimal parameters for MAE, such as microwave power, extraction time, and solvent-to-raw material ratios, which collectively influence the yield and quality of essential oils. Notably, findings of this survey, indicates that MAE can achieve up to a 40% increase in essential oil yield compared to conventional methods. The review also discusses the evolution of MAE techniques, from initial simple heating methods to advanced systems incorporating infrared temperature sensors and magnetic stirrers, which improve precision and efficiency. By elucidating these advancements, this paper underscores the transformative impact of MAE on the extraction of essential oils, paving the way for future research and development in this field. © 2025 Society of Chemical Industry (SCI).</p>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"100 5","pages":"894-907"},"PeriodicalIF":2.8,"publicationDate":"2025-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143818616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fermentation and leaching of the organic fraction of municipal solid waste to improve methane production","authors":"Hamilton G. Mosquera-Toscano,&nbsp;Idania Valdez-Vazquez,&nbsp;Iván Moreno-Andrade,&nbsp;Oscar González-Barceló","doi":"10.1002/jctb.7832","DOIUrl":"https://doi.org/10.1002/jctb.7832","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> Background</h3>\u0000 \u0000 <p>The anaerobic digestion of soluble substances extracted from the organic fraction of municipal solid waste (OFMSW) results in an enhanced rate and production of methane. However, the influence of substrate fermentation and subsequent leaching on methane output has yet to be investigated. This research aimed to examine the impact of combined fermentation and leaching processes over time on the degree of solubilization, fermentation by-products and, subsequently, the production of methane from fermented leachates and bagasses.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Results</h3>\u0000 \u0000 <p>The degree of solubilization observed in the non-leaching experiment was recorded at 12.7%, while the experiment utilizing daily leaching resulted in a solubilization of 22%. The fermented leachate collected at 24 h yielded 457 ± 75 NL CH₄ kg⁻¹ <i>VS</i>, which was 1.6 times greater than the methane production from the raw leachate of the OFMSW. In contrast, the fermented bagasse produced after 96 h demonstrated enhanced digestibility, resulting in 264 ± 26 NL CH₄ kg⁻¹ <i>VS</i>, or 1.5 times the methane production of the raw fermented bagasse of the OFMSW. The overall energy recoverable from the raw leachate and bagasse of the OFMSW amounts to 1103.6 kJ kg⁻¹ OFMSW. In contrast, the implementation of the fermentation-leaching method yields a total of 2482.6 kJ kg⁻¹ OFMSW.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Conclusions</h3>\u0000 \u0000 <p>By employing fermentation and subsequently leaching the OFMSW, a greater quantity of particulate substrate was solubilized, leading to an improved recovery of fermentation by-products. Moreover, both methane production and energy recovery experienced an increase, which can be attributed to the soluble substances extracted from the fermented leachate and the enhanced digestibility of the fermented bagasse. © 2025 The Author(s). <i>Journal of Chemical Technology and Biotechnology</i> published by John Wiley &amp; Sons Ltd on behalf of Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"100 5","pages":"967-977"},"PeriodicalIF":2.8,"publicationDate":"2025-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/jctb.7832","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143818799","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Efficiency of adsorption of PSNPs using spontaneous magnetic biochar prepared from pyrolysis of municipal sludge and industrial red mud solid waste","authors":"Dongsheng Feng,&nbsp;Junming Yi,&nbsp;Yuxin Liu,&nbsp;Jiangzhe Fu,&nbsp;Ruihui Gong,&nbsp;Huidong Li","doi":"10.1002/jctb.7819","DOIUrl":"https://doi.org/10.1002/jctb.7819","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>The environmental problems caused by microplastics are becoming increasingly serious with the widespread use of plastic products. This study utilized lignin-modified preparation of spontaneous magnetic sludge-based biochar (LC@SRBC) to remove Polystyrene nanoplastics (PSNPs).</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULT</h3>\u0000 \u0000 <p>The quasi-second-order adsorption kinetics model, and the SIPs adsorption isothermal model exhibited excellent agreement with the experimental data, the Theoretical saturation adsorption capacity of 406.68 mg/g was found at the 500 °C-pyrolyzed LC@SRBC. The effects of different factors on the efficiency of PSNPs removal by adsorbents were analyzed in detail, and the final PSNPs removal rate reached 97.87% in 30 min. We believe that the electrostatic effect is the main factors affecting the removal effect of PSNPs. With the increase of pH value, the potential difference between PSNPs and the surface of adsorbent increases, and the electrostatic repulsion is strengthened, which leads to a significant decrease in the adsorption capacity. Furthermore, the presence of metal nanoparticles on the LC@SRBC surface promoted the formation of metal-O-PSNPs and oxygen-containing functional groups, which enhanced its adsorption capacity for PSNPs. Meanwhile, the spontaneous magnetism of the adsorbent is utilized for solid–liquid separation, avoiding the influence of filtration on the experimental effect.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>In summary, the present study found that the preparation of adsorbent materials from the resource utilization of red mud solid wastes is effective for the removal of polystyrene from water. © 2025 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"100 4","pages":"778-791"},"PeriodicalIF":2.8,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143717089","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Degradation and ecotoxicity of favipiravir and oseltamivir in the presence of microplastics during ozonation and catalytic ozonation of synthetic municipal wastewater effluents","authors":"Serdar Dogruel,&nbsp;Nasim Chavoshi,&nbsp;Nilay Bilgin-Saritas,&nbsp;Alireza Khataee,&nbsp;Emel Topuz,&nbsp;Elif Pehlivanoglu","doi":"10.1002/jctb.7831","DOIUrl":"https://doi.org/10.1002/jctb.7831","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> Background</h3>\u0000 \u0000 <p>Favipiravir (FAV) and oseltamivir (OSE) are antiviral agents developed against influenza and they were repurposed against SARS-CoV-2 during the COVID-19 pandemic. This study evaluated the potential of ozonation and catalytic ozonation as tertiary treatment approaches for removing FAV and OSE from municipal wastewaters, both in the presence and absence of microplastics (MPs), while comparing the ecotoxicity of untreated and treated secondary effluents to predict the ecotoxicological effects of these technologies during municipal wastewater treatment.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Results</h3>\u0000 \u0000 <p>At an initial antiviral concentration of 50 μg L⁻¹, ozonation at pH 7 with a specific ozone dose of 0.6 mg O₃ (mg DOC)⁻¹ yielded FAV and OSE removals of 84 and 64%, respectively, while the presence of catalyst or MPs decreased the degradation rate by 30–40%. Raising the pH to 10 had minimal impact on FAV abatement, but improved OSE reduction by 21%. Acute toxicity tests using <i>Vibrio fischeri</i> demonstrated that simultaneous ozonation of the analytes led to the accumulation of transformation products (TPs) of FAV and OSE, with their combined effect almost equal to that of the original compounds. Reproduction toxicity tests indicated that TPs of antiviral drugs generated during ozonation were less toxic to <i>Enchytraeus crypticus</i> than the parent chemicals.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Conclusion</h3>\u0000 \u0000 <p>Ozonation proved to be a viable option for upgrading existing wastewater treatment facilities, serving as a complementary treatment to minimize the release of antivirals from municipal secondary effluents and reduce their inhibitory effect on earthworm reproduction, thereby enhancing the reuse potential of treated wastewater for irrigation. © 2025 The Author(s). <i>Journal of Chemical Technology and Biotechnology</i> published by John Wiley &amp; Sons Ltd on behalf of Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"100 5","pages":"955-966"},"PeriodicalIF":2.8,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/jctb.7831","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143818817","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Tailored chemical processes: opportunities and challenges in shaping a sustainable future","authors":"Eduardo Sánchez-Ramírez","doi":"10.1002/jctb.7835","DOIUrl":"https://doi.org/10.1002/jctb.7835","url":null,"abstract":"<p>The chemical industry is at a critical juncture, where traditional mass production is increasingly being challenged by the need for more flexible, efficient and sustainable approaches. This perspective article explores the viability of tailored chemical production as a future model for the industry, focusing on the opportunities and challenges inherent in moving towards a more personalized, customer-driven production paradigm. Tailored chemical processes have the potential to revolutionize how we meet rapidly evolving societal demands, adapt to shifting political landscapes such as the 2030 and 2050 sustainability agendas, and leverage technological advances in digitalization and automation. By critically analyzing the economic and environmental aspects, as well as the implications of advanced technologies such as process intensification, modular reactors and artificial intelligence, this article aims to provide a comprehensive view of whether a future of tailored chemical production is both viable and desirable. We also discuss the importance of aligning these processes with the principles of the circular economy and propose concrete steps the industry should take—including fostering collaboration between academia, industry, and government—to transition successfully towards this promising future. This perspective seeks to inspire a deeper consideration of the role that personalized chemical production can play in advancing sustainability, adaptability and resilience in the chemical sector. © 2025 Society of Chemical Industry (SCI).</p>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"100 5","pages":"887-893"},"PeriodicalIF":2.8,"publicationDate":"2025-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143818467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}