ACS Combinatorial Science最新文献

{"title":"Constructing an Artificial Interface as a Bifunctional Promoter for the Li Anode and the NCM Cathode in Lithium Metal Batteries","authors":"Huayu Huang,&nbsp;Shishi Liu,&nbsp;Yuxiang Xie,&nbsp;Junke Liu,&nbsp;Chenguang Shi,&nbsp;Miaolan Sun,&nbsp;Hao Peng,&nbsp;Jian Lan,&nbsp;Ya-Ping Deng*,&nbsp;Ling Huang* and Shi-Gang Sun*,&nbsp;","doi":"10.1021/jacs.4c1101210.1021/jacs.4c11012","DOIUrl":"https://doi.org/10.1021/jacs.4c11012https://doi.org/10.1021/jacs.4c11012","url":null,"abstract":"<p >The bottleneck of Li metal batteries toward practical applications lies at inferior cyclability as well as Li dendrite issues. As a promising solution, an interface engineering strategy is proposed herein for the Li anode through constructing a hybrid artificial interface. It is assembled onto the Li anode using photocontrolled free radical polymerization (photo-CRP) of polyethylene glycol diacrylate-hexafluorobutyl methacrylate and hexafluorobutyl methacrylate-trifluoroethyl carbonate (PEGDA-HFMBA@HFMBA-FEMC or PH@HF layer). Among such hybrid interfaces, the interior layer of PEGDA-HFMBA exists as a protective shield with flexibility and fracture resistance, while the exterior layer of HFMBA-FEMC plays a role as a LiF reservoir to promote Li mass transfer and its even electrodeposition. In the meantime, some excess HFMBA and FEMC monomers further dissolve into the electrolyte as molecular additives, followed by in situ generation of a thin and robust LiF-rich cathode electrolyte interface (CEI). With the resulting Li anode, Li/NCM811 full cells showcase multifold cyclability amplification in comparison to cells using Bare-Li, covering durable cyclability with a capacity retention of 81.8% after 400 cycles. When the cutoff voltage is elevated to 4.5 V or the working temperature is elevated to 45 °C, the cells still maintain a stable operation for extending 300 cycles.</p>","PeriodicalId":14,"journal":{"name":"ACS Combinatorial Science","volume":"146 45","pages":"31137–31149 31137–31149"},"PeriodicalIF":14.4,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142608068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Efficient Fluorocarbons Capture Using Radical-Containing Covalent Triazine Frameworks","authors":"Zhiyuan Zhang,&nbsp;Shuo Zhang,&nbsp;Xiongli Liu,&nbsp;Lin Li,&nbsp;Shan Wang,&nbsp;Rufeng Yang,&nbsp;Laiyu Zhang,&nbsp;Zifeng You,&nbsp;Feng Shui,&nbsp;Shiqi Yang,&nbsp;Zhendong Yang,&nbsp;Qiao Zhao,&nbsp;Baiyan Li* and Xian-He Bu,&nbsp;","doi":"10.1021/jacs.4c1147010.1021/jacs.4c11470","DOIUrl":"https://doi.org/10.1021/jacs.4c11470https://doi.org/10.1021/jacs.4c11470","url":null,"abstract":"<p >Efficiently capturing fluorocarbons, potent greenhouse gases with high global warming potentials (GWP), remains a daunting challenge due to limited effective approaches for constructing high-performance adsorbents. To tackle this issue, we have pioneered a novel strategy of developing radical porous materials as effective adsorbents for fluorocarbon capture. The resulting radical covalent triazine framework (CTF), CTF-azo-R, shows exceptional fluorocarbon (perfluorohexane, a representative model pollutant among fluorocarbons) uptake capacity of 270 wt %, a record-high value among all porous materials reported to date. Spectral characteristics, experimental studies, and theoretical calculations indicate that the presence of stable radicals in CTF-azo-R contributes to its superior fluorocarbon capture performance. Furthermore, CTF-azo-R demonstrates exceptionally high chemical and thermal stabilities that fully meet the requirements for practical applications in diverse environments. Our work not only establishes radical CTF-azo-R as a promising candidate for fluorocarbon capture but also introduces a novel approach for constructing advanced fluorocarbon adsorbents by incorporating radical sites into porous materials. This strategy paves the way for the development of radical adsorbents, fostering advancements in both fluorocarbon capture and the broader field of adsorption and separation.</p>","PeriodicalId":14,"journal":{"name":"ACS Combinatorial Science","volume":"146 45","pages":"31213–31220 31213–31220"},"PeriodicalIF":14.4,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142609496","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Iterative Catalyst-Controlled Diastereoselective Matteson Homologations Enable the Selective Synthesis of Benzestrol Isomers","authors":"Samantha R. Angle,&nbsp;Hayden A. Sharma,&nbsp;Christie K. Choi,&nbsp;Kathryn E. Carlson,&nbsp;Yingwei Hou,&nbsp;Jerome C. Nwachukwu,&nbsp;Sung Hoon Kim,&nbsp;Benita S. Katzenellenbogen,&nbsp;Kendall W. Nettles,&nbsp;John A. Katzenellenbogen and Eric N. Jacobsen*,&nbsp;","doi":"10.1021/jacs.4c1285710.1021/jacs.4c12857","DOIUrl":"https://doi.org/10.1021/jacs.4c12857https://doi.org/10.1021/jacs.4c12857","url":null,"abstract":"<p >We report the development of an iterative Matteson homologation reaction with catalyst-controlled diastereoselectivity through the design of a new catalyst. This reaction was applied to the selective synthesis of each stereoisomer of benzestrol, a bioactive compound with estrogenic activity featuring three contiguous stereocenters. The different stereoisomers were assayed to determine their binding affinity for the estrogen receptor α (ERα), and the absolute configuration of the compound having uniquely high activity was determined. This research lays a framework for the catalytic synthesis and study of complete stereoisomeric sets of other bioactive molecules and chemical probes containing contiguous stereocenters.</p>","PeriodicalId":14,"journal":{"name":"ACS Combinatorial Science","volume":"146 45","pages":"30771–30777 30771–30777"},"PeriodicalIF":14.4,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142609629","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Gravitational-like Relationship of Dispersion Interactions is Exhibited by 40 Pairs of Molecules and Noble Gas Atoms","authors":"David Danovich,&nbsp;Alexandre Tkatchenko,&nbsp;Santiago Alvarez and Sason Shaik*,&nbsp;","doi":"10.1021/jacs.4c1121110.1021/jacs.4c11211","DOIUrl":"https://doi.org/10.1021/jacs.4c11211https://doi.org/10.1021/jacs.4c11211","url":null,"abstract":"<p >We present computational results of many-body dispersion (MBD) interactions for 40 pairs of molecular and atomic species: hydrocarbons, silanes, corresponding fluorinated derivatives, pairs which have multiple H---H contacts between the molecules, as well as pairs having π–π interactions, and pairs of noble gases. The calculations reveal that the MBD stabilization energy (<i>E</i>_DISP,MBD) obeys a global relationship, which is <i>gravitational-like</i>. It is proportional to the product of the masses of the two molecules (<i>M</i>₁<i>M</i>₂) and inversely proportional to the corresponding distances between the molecular centers-of-mass (<i>R</i>_COM-COM) or the H---H distances of the atoms mediating the interactions of the two molecules (<i>R</i>_H–H). This relationship reflects the interactions of instantaneous dipoles, which are formed by the ensemble of bonds/atoms in the interacting molecules. Using the D4-corrected dispersion energy (<i>E</i>_DISP,D4), which accounts for three-body interactions, we find that the <i>E</i>_DISP,MBD and <i>E</i>_DISP,D4 data sets are strongly correlated. Based on valence-bond modeling, the dispersion interactions occur primarily due to the increased contributions of the oscillating-ionic VB structures which maintain favorable electrostatic interactions; the [Sub─C⁺:H^–+H:C^–─Sub] and [Sub─C:^–+H ^–H:C⁺─Sub] structures; Sub symbolizes general residues. This augmented contribution is complemented by simultaneously diminished-weights of the destabilizing pair of structures, [Sub─C⁺:H^––H:C⁺─Sub] and [Sub─:C^– H⁺⁺H:C^–─Sub]. The local charges are propagated to the entire ensemble of bonds/atoms by partially charging the Sub residues, thus bringing about the “gravitational-like” dependence of dispersion.</p>","PeriodicalId":14,"journal":{"name":"ACS Combinatorial Science","volume":"146 45","pages":"31198–31204 31198–31204"},"PeriodicalIF":14.4,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/jacs.4c11211","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142609497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Photoinduced Isomerization of [N2]2– in a Bimetallic Lutetium Complex","authors":"Mingbin Yuan,&nbsp;Andrew J. McNeece,&nbsp;Ekaterina A. Dolgopolova,&nbsp;Laura Wolfsberg,&nbsp;Eric G. Bowes,&nbsp;Enrique R. Batista*,&nbsp;Ping Yang*,&nbsp;Alexander Filatov and Benjamin L. Davis*,&nbsp;","doi":"10.1021/jacs.4c1095010.1021/jacs.4c10950","DOIUrl":"https://doi.org/10.1021/jacs.4c10950https://doi.org/10.1021/jacs.4c10950","url":null,"abstract":"<p >The first lanthanide dinitrogen photoswitch [(C₅Me₄H)₂(THF)Lu]₂(μ–η²:η²-N₂), <b>1</b>, is reported. <b>1</b> is a unique example of controlled isomerization between side-on and end-on coordination modes of [N₂]^2– in a bimetallic lutetium dinitrogen complex that results in photochromism. Near-infrared light (NIR) was used to promote this effect, as evidenced by single X-ray diffraction (XRD) connectivity and Raman data, generating the [N₂]^2– end-on bound isomer, [(C₅Me₄H)₂(THF)Lu]₂(μ–η¹:η¹-N₂), <b>2</b>. Although different ligands and coordinating solvents were studied to replicate and control the optical properties in <b>1/2</b>, only the original configuration with C₅Me₄H ligands and THF as the coordinating solvent worked. Supported by the first-principles calculations, the electronic structures along with the mechanistic details of the side-on to end-on isomerization were unraveled. Preliminary reactivity studies show that <b>2</b> formed with NIR light reacts with anthracene, generating dihydroanthracene and anthracene dimers, indicating new redox reaction pathways.</p>","PeriodicalId":14,"journal":{"name":"ACS Combinatorial Science","volume":"146 45","pages":"31074–31084 31074–31084"},"PeriodicalIF":14.4,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142609324","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Linear Paired Electrolysis Enables Redox-Neutral (3 + 2) Annulation of Benzofuran with Vinyldiazo Compounds","authors":"Lei Nie,&nbsp;Jiayi Yang,&nbsp;Zhao Liu,&nbsp;Shibo Zhou,&nbsp;Suming Chen,&nbsp;Xiaotian Qi*,&nbsp;Aiwen Lei* and Hong Yi*,&nbsp;","doi":"10.1021/jacs.4c1292510.1021/jacs.4c12925","DOIUrl":"https://doi.org/10.1021/jacs.4c12925https://doi.org/10.1021/jacs.4c12925","url":null,"abstract":"<p >Electrosynthesis has emerged as a versatile and sustainable tool in organic chemistry, offering an efficient pathway for the construction of complex molecular architectures under mild and environmentally benign conditions. Traditional electrochemical approaches, however, predominantly rely on either anodic oxidation or cathodic reduction, limiting their capacity to achieve redox-neutral transformations using a single electrode. In this work, we introduce a linear paired electrolysis strategy that circumvents these limitations, enabling a redox-neutral (3 + 2) annulation of benzofuran with vinyldiazo compounds. This method facilitates the formation of benzofuran-fused tricyclic scaffolds, which are valuable in synthetic chemistry and medicinal applications. The transformation proceeds through sequential anodic oxidation and cathodic reduction, leveraging a radical cation pathway to deliver polycyclic compounds with high selectivity. The efficiency and mechanism of this process are thoroughly validated using cyclic voltammetry and <i>in situ</i> electrochemical mass spectrometry (EC-MS) and supported by theoretical calculations, shedding light on the potential of redox-neutral electrochemical transformations.</p>","PeriodicalId":14,"journal":{"name":"ACS Combinatorial Science","volume":"146 45","pages":"31330–31338 31330–31338"},"PeriodicalIF":14.4,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142609553","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Fully Saturated Covalent Organic Framework","authors":"Junyu Ren,&nbsp;Chunqing Ji,&nbsp;Bowen Du,&nbsp;Qixing Liu,&nbsp;Kexin Yu,&nbsp;Dohyun Ahn,&nbsp;Zhenyu Zhang,&nbsp;Yingxiang Ye,&nbsp;Christian R. Göb and Dan Zhao*,&nbsp;","doi":"10.1021/jacs.4c1325610.1021/jacs.4c13256","DOIUrl":"https://doi.org/10.1021/jacs.4c13256https://doi.org/10.1021/jacs.4c13256","url":null,"abstract":"<p >We report the design and synthesis of the first aliphatic covalent organic framework (COF), NUS-119, and its subsequent conversion to NUS-120, marking the first fully saturated COF. NUS-119 is built by imine-linkages exhibiting high crystallinity and porosity, achieved by using a Lewis acid as a reaction modulator to circumvent compatibility issues between the Brønsted acid and the strong basic monomer. The structure was successfully solved using 3D microelectron diffraction (microED) techniques. NUS-119 and NUS-120 demonstrated remarkable catalytic performance in base-catalyzed Knoevenagel condensation reactions, exhibiting high conversion rates, excellent size selectivity, and good recyclability. This work advances the understanding of COF materials and paves the way for future research and applications.</p>","PeriodicalId":14,"journal":{"name":"ACS Combinatorial Science","volume":"146 45","pages":"30784–30789 30784–30789"},"PeriodicalIF":14.4,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142609628","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Coassembling Mesoporous Zeolitic Imidazolate Frameworks by Directed Reticular Chemistry","authors":"Min Liu,&nbsp;Mehrdad Asgari,&nbsp;Katrina Bergmann,&nbsp;Kayla Shenassa,&nbsp;Graham King,&nbsp;Adam F. G. Leontowich,&nbsp;David Fairen-Jimenez and Zachary M. Hudson*,&nbsp;","doi":"10.1021/jacs.4c1238510.1021/jacs.4c12385","DOIUrl":"https://doi.org/10.1021/jacs.4c12385https://doi.org/10.1021/jacs.4c12385","url":null,"abstract":"<p >Conventional microporous zeolitic imidazolate frameworks (ZIFs) face limitations in mass transfer and pore accessibility when dealing with large guest molecules. Here, we describe a technique for the synthesis of mesoporous ZIFs (MesoZIFs) using a strategy we term directed reticular chemistry. MesoZIF-8 was prepared through solvent evaporation-induced coassembly of polystyrene-<i>block</i>-poly(ethylene oxide) (PS-<i>b</i>-PEO), ZIF-8 building blocks, and acetic acid (AcOH), followed by amine-facilitated crystallization of ZIF-8 in the interstices of PS-<i>b</i>-PEO micelles. AcOH prevents the fast coordination of ZIF-8 building blocks, avoiding phase separation during coassembly. The employed amine plays a crucial role in neutralizing the crystallization environment and further deprotonating the 2-methlyimizale linker to coordinate with zinc ions. Ink bottle-shaped mesopores with tunable mesopore sizes were created by adjusting the molecular weight of PS-<i>b</i>-PEO. Compared to microporous ZIF-8, MesoZIF-8 exhibited enhanced performance in Knoevenagel condensation reactions involving large reactants and hydrogen storage capacity. With this study, we establish an efficient approach for synthesizing MesoZIFs with highly accessible mesopores to enhance ZIF performance in targeted applications.</p>","PeriodicalId":14,"journal":{"name":"ACS Combinatorial Science","volume":"146 45","pages":"31295–31306 31295–31306"},"PeriodicalIF":14.4,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142609632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Denitrogenative Ring-Contraction of Pyridines to a Cyclopentadienyl Skeleton at a Dititanium Hydride Framework","authors":"Xiaoxi Zhou,&nbsp;Qingde Zhuo,&nbsp;Takanori Shima*,&nbsp;Xiaohui Kang* and Zhaomin Hou*,&nbsp;","doi":"10.1021/jacs.4c1343910.1021/jacs.4c13439","DOIUrl":"https://doi.org/10.1021/jacs.4c13439https://doi.org/10.1021/jacs.4c13439","url":null,"abstract":"<p >Selective removal of the nitrogen atom from an aromatic <i>N</i>-heterocycle, such as pyridine, is of significant interest and importance, yet it remains highly challenging. Here, we report an unprecedented denitrogenative ring-contraction reaction of pyridines at a dititanium hydride framework, yielding cyclopentadienyl and nitride species under mild conditions. The reaction of pyridine with a dititanium tetrahydride complex (<b>1</b>) bearing rigid acridane-based PNP-pincer ligands at room temperature produced a cyclopentadienyl/nitride complex (<b>2</b>), in which the two Ti atoms are bridged by a nitride atom and one Ti atom is bonded to a cyclopentadienyl group formed by pyridine denitrogenation and ring-contraction. The reactions of 2-, 3-, and 4-methylpyridines with <b>1</b> under similar conditions yielded the same product (<b>3</b>), a methylcyclopentadienyl-ligated analog of <b>2</b>. When 2,4- or 3,5-dimethylpyridine reacted with <b>1</b> at 60 °C, the 1,3-dimethylcyclopentadienyl-ligated analog (<b>5</b>) formed almost quantitatively. The mechanistic details have been elucidated by isolation of key intermediates and density functional theory calculations. It was revealed that the reaction proceeded via coordination of the N atom of a pyridine unit to a Ti atom in <b>1</b> followed by H₂ release, C═N reduction, two C–N bond cleavage (ring-opening and denitrogenation), and C–C coupling (ring closing). The involvement of C–H activation in an isopropyl group of a PNP ligand at the later stages of the reaction significantly contributed to the stabilization of the denitrogenative ring-contraction product. This work not only provides unprecedented mechanistic insights into denitrogenation of aromatic <i>N</i>-heterocycles but also represents a novel example of skeletal editing of aromatic <i>N</i>-heterocycles.</p>","PeriodicalId":14,"journal":{"name":"ACS Combinatorial Science","volume":"146 45","pages":"31348–31355 31348–31355"},"PeriodicalIF":14.4,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142609633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Inductively Coupled Plasma-Mass Spectrometry (ICP-MS): An Emerging Tool in Radiopharmaceutical Science","authors":"Karel D. Klika,&nbsp;Jianlin Han,&nbsp;Marvin S. Busse,&nbsp;Vadim A. Soloshonok,&nbsp;Ramin Javahershenas,&nbsp;Frank Vanhaecke* and Ata Makarem*,&nbsp;","doi":"10.1021/jacs.4c1225410.1021/jacs.4c12254","DOIUrl":"https://doi.org/10.1021/jacs.4c12254https://doi.org/10.1021/jacs.4c12254","url":null,"abstract":"<p >Although radioactive experiments are necessary in radiopharmaceutical drug discovery and theranostic cancer research, they are expensive, require special facilities, and face certain restrictions. Thus, finding techniques not involving radioactivity is highly beneficial for minimizing these disadvantages in such research. In this regard, methods using inductively coupled plasma-mass spectrometry (ICP-MS) have emerged as viable alternatives to traditional radioactive approaches. Despite its potential, practical applications of ICP-MS in radiopharmaceutical cancer research have only emerged in recent years. This Perspective focuses on the development and implementation of nonradioactive ICP-MS-based assays in radiopharmaceutical research and aims to inspire future research efforts in this area.</p>","PeriodicalId":14,"journal":{"name":"ACS Combinatorial Science","volume":"146 45","pages":"30717–30727 30717–30727"},"PeriodicalIF":14.4,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/jacs.4c12254","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142609660","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}