JORDANIAN JOURNAL OF ENGINEERING AND CHEMICAL INDUSTRIES (JJECI)最新文献

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A Study effect of Substituents X on Methylenecyclopentane and 1-Methylcyclopentene System 取代基X对亚甲基环戊烷和1-甲基环戊烯体系影响的研究
JORDANIAN JOURNAL OF ENGINEERING AND CHEMICAL INDUSTRIES (JJECI) Pub Date : 2018-06-01 DOI: 10.48103/jjeci142018
G. Al-Mazaideh
{"title":"A Study effect of Substituents X on Methylenecyclopentane and 1-\u0000Methylcyclopentene System","authors":"G. Al-Mazaideh","doi":"10.48103/jjeci142018","DOIUrl":"https://doi.org/10.48103/jjeci142018","url":null,"abstract":"In this study, the geometry optimizations, orbital energies (HOMO-LUMO) and relative stabilities of methylene cyclopentane and 1-methylcyclopentene were investigated by DFT\u0000calculations. 1-methylcyclopentene was found to be more stable than methylene cyclopentane isomer with enthalpy value H=18.518 kJ/mol. Also, the effect of substituents X (F, OH,\u0000CH3, NH2, CN, NO2, CHO and CF3) also studied on the relative stabilities of these two tautomers. The results showed that the stability of both isomers is increased by all substitutes.\u0000Gibbs free energy calculations have been used to find the effect of substituents X on the system.","PeriodicalId":14808,"journal":{"name":"JORDANIAN JOURNAL OF ENGINEERING AND CHEMICAL INDUSTRIES (JJECI)","volume":"24 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84978040","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Smith predictor-based PI control of a wet granulation process 基于Smith预测的湿制粒过程PI控制
JORDANIAN JOURNAL OF ENGINEERING AND CHEMICAL INDUSTRIES (JJECI) Pub Date : 2018-06-01 DOI: 10.48103/jjeci122018
T. Shaqarin
{"title":"Smith predictor-based PI control of a wet granulation process","authors":"T. Shaqarin","doi":"10.48103/jjeci122018","DOIUrl":"https://doi.org/10.48103/jjeci122018","url":null,"abstract":"The need for prediction and reference updating in feedback control of a wet granulation process is addressed. The granulation process is often\u0000modeled as a multi-input multi-output (MIMO) linear model with dead-time. Industrial implementation of granulation process poses strict\u0000constraints on the process inputs & outputs. The presence of dead-time and the physical necessity of the input-output constraints are the key\u0000challenges of the wet granulation control. These challenges motivated the use of model predictive control (MPC) for such processes. In this\u0000work, a Smith predictor-based proportional-integral (PI) controller is designed for the dead-time compensation. Accompanied with the reference\u0000updating method to handle the physical constraints. The regulation and reference tracking control problems are assessed via closed-loop\u0000simulations of the wet granulation model. The ability of the proposed control approach of dead-time compensation and coping with input/output\u0000constraints is rigorously proved. The current approach is compared to MPC of a similar granulation process and found superior in terms of\u0000output stability, performance and reference tracking.","PeriodicalId":14808,"journal":{"name":"JORDANIAN JOURNAL OF ENGINEERING AND CHEMICAL INDUSTRIES (JJECI)","volume":"70 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80697812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption of Diazo Dye C.I. Acid Red 97 from Aqueous Solution onto Yemen Natural Clay: Equilibrium and Thermodynamic Studies 重氮染料C.I.酸红97在也门天然粘土上的吸附:平衡和热力学研究
JORDANIAN JOURNAL OF ENGINEERING AND CHEMICAL INDUSTRIES (JJECI) Pub Date : 2018-06-01 DOI: 10.48103/jjeci12018/
A. Al-Wahbi
{"title":"Adsorption of Diazo Dye C.I. Acid Red 97 from Aqueous Solution onto Yemen Natural Clay: Equilibrium and Thermodynamic Studies","authors":"A. Al-Wahbi","doi":"10.48103/jjeci12018/","DOIUrl":"https://doi.org/10.48103/jjeci12018/","url":null,"abstract":"The equilibrium adsorption of diazo dye C.I. Acid Red 97 (AR97) from aqueous solutions onto Yemen natural clay has been studied as a function of temperature and particle size range. The equilibrium data were correlated using Langmuir, Fruendlich, Temkin, Redlich-Peterson, and Sips isotherm models. Thermodynamic parameters such as standard enthalpy (ΔHº), standard entropy (ΔSº) and standard Gibbs free energy (ΔGº) were calculated. It was found that the adsorption capacity of clay for AR97 decreases with increasing temperature and particle size range. The results show that Fruendlich and Sips isotherm models best fit the experimental data over the whole concentration range. The maximum adsorption capacity for Yemen natural clay was 196.7 (mg.g-1 ). The value of ΔHº was -20.5 (kJ.g-mol−1) indicating that the adsorption of AR79 onto Yemen natural clay is characterized by physical adsorption. ΔGº values obtained were all negatives indicating a spontaneous adsorption process","PeriodicalId":14808,"journal":{"name":"JORDANIAN JOURNAL OF ENGINEERING AND CHEMICAL INDUSTRIES (JJECI)","volume":"25 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81891758","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
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