International Journal of Chemical Kinetics最新文献

{"title":"The synergistic anti-corrosion performance and mechanism of meso-tetra(4-carboxyphenyl)porphine on steel bars in alkaline environments","authors":"Xue-qi Zhang,&nbsp;Qing-xian Yue,&nbsp;Rui Ding,&nbsp;Jie Liu","doi":"10.1002/kin.21743","DOIUrl":"https://doi.org/10.1002/kin.21743","url":null,"abstract":"<p>Corrosion protection of steel bars in alkaline concrete environments poses a common challenge in marine engineering. One approach to mitigate steel bar corrosion is the addition of corrosion inhibitors to the concrete. In alkaline environments, the passivation of rebars occurs through anodic passivation coupled with the cathodic oxygen reduction reaction (ORR). The catalysis of ORR can expedite anode passivation. To investigate the corrosion inhibition of steel bars in alkaline environments, meso-tetra(4-carboxyphenyl)porphine (TCPP), known for its ORR catalytic properties, is selected. TCPP forms adsorption films on the surface of steel bars, facilitating the formation of passivation films. TCPP primarily adsorbs onto active sites on the surface of the passivation film, where lattice iron ions have leached. The adsorbed TCPP accelerates the formation of the passivation film through ORR catalysis, inhibiting the development of passivation film defects and enhancing the integrity and protection of the passivation film. The most significant effect is observed when the concentration of TCPP is 0.5 mmol/L. The physical adsorption of TCPP is primarily determined by the negative charge centers, namely the carboxyl group O and the pyrrole N. However, due to steric hindrance caused by the unrestricted rotation of the carboxyl benzene, the pyrrole N does not play a dominant role in chemical adsorption. Instead, the active site for chemical adsorption is the carboxyl group O. The adsorption process significantly reduces the diffusion coefficient of TCPP molecules, providing a robust and stable adsorption binding. Phthalocyanine molecules without carboxyl benzene groups adopt a planar structure, allowing them to form stable adsorption configurations on the iron surface through flat adsorption. This observation provides guidance for the design of novel metal phthalocyanine molecules. Specifically, the development of metal phthalocyanine molecules with modifying groups that are coplanar with the phthalocyanine ring and possess restricted rotation can achieve flat adsorption, improve coverage rate, and enhance adsorption configuration stability.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"56 10","pages":"596-612"},"PeriodicalIF":1.5,"publicationDate":"2024-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142041538","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Kinetics of permanganate–sulfuric acid redox reaction with cetyltrimethylammonium bromide","authors":"Zoya Zaheer,&nbsp;Wafa A. Bawazir,&nbsp;Effat A. Bahaidarah,&nbsp;Shatha Abbas","doi":"10.1002/kin.21742","DOIUrl":"10.1002/kin.21742","url":null,"abstract":"<p>The permanganate–H₂SO₄ redox reaction, useful in oxidative treatments under aqueous conditions, was studied spectrophotometrically in the absence and presence of cetyltrimethylammonium bromide (CTAB). The decolorization reactions were influenced by the [MnO₄⁻], [H₂SO₄], and temperature. Permanganate reduction follows first-, and complex–order kinetics with permanganate, and H₂SO₄ concentrations, respectively. The reduction of permanganate (Mn(VII)) proceeds through a complex formation between MnO₄⁻ and H₂SO₄. The characteristic absorption peaks for MnO₄²⁻ (λ_max = 439 and 606 nm), MnO₄³⁻ (λ_max = 667 nm), and MnO₂ (λ_max = 400–418 nm) were not appeared during the redox reaction. The KMnO₄ degradation efficiency remains unaffected with sodium pyrophosphate and sodium fluoride. The results of this study demonstrated the formation of Mn(II) as the stable product in acidic reaction media. The degradation efficiency increases drastically from 15 to 100% with 2.0 × 10⁻⁴ to 16.0 × 10⁻⁴ mol/L CTAB concentration under sub-, and post-micellar reaction conditions, respectively. The thermodynamic parameters (activation energy = 98.8 and 43.2 kJ/mol), activation of enthalpy (96.3, and 39.0 kJ/mol), activation of entropy (16.2 and −149.5 J/K/mol), free energy of activation (93.1 and 83.5 kJ/mol) were calculated without and with CTAB, respectively. Hence, CTAB can be exploited for its multifunctional applications, and specifically for the catalytic role in the permanganate-assisted redox reactions in future.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"56 10","pages":"584-595"},"PeriodicalIF":1.5,"publicationDate":"2024-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141374534","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"On non-hydrogen-atom products of thermal decomposition of benzyl radical: A theoretical investigation by the transition state theory/multi-well master equation approach","authors":"Qinghui Meng,&nbsp;Yicheng Chi,&nbsp;Lidong Zhang,&nbsp;Peng Zhang","doi":"10.1002/kin.21729","DOIUrl":"10.1002/kin.21729","url":null,"abstract":"<p>Benzyl radical (C₇H₇), one of the resonantly stabilized hydrocarbon radicals, is one of the significant precursors of polycyclic aromatic hydrocarbons in interstellar media and combustion engines. The unimolecular decomposition of benzyl radical is still incompletely understood despite of its importance and relatively small molecular size. The decomposition reactions of benzyl radical were investigated in the present study by using the ab initio transition state theory (TST) and the multi-well master equation theory. Specifically, all reaction pathways on the potential energy surface of C₇H₇ was calculated at the level of QCISD(T)/CBS. For the reactions with multireference characters, the CASPT2(9e,7o)/aug-cc-pVTZ method was used to calculate the vibrational frequencies and energies of structures along the one-dimensional reaction coordinate of the breaking bond. The high-pressure limits of rate constants for all the reactions were obtained by using the TST except those for C₇H₆ + H and C₆H₄ + CH₃ by the variational TST. The pressure-dependent rate constants were obtained by using the multi-well master equation simulations. The calculated rate constants agree well with available experimental and theoretical data in the literature. Moreover, the present results identify the composition of the non-hydrogen-atom production observed in previous experiments, which provide new insights into the reactions of aromatic compounds.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"56 10","pages":"571-583"},"PeriodicalIF":1.5,"publicationDate":"2024-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141117626","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Kinetic analysis for the interpretation of polychlorinated biphenyls removal mechanism","authors":"Arash Maghami,&nbsp;Nooshin Gholipour-Zanjani,&nbsp;Farhad Khorasheh,&nbsp;Mehdi Ardjmand","doi":"10.1002/kin.21728","DOIUrl":"10.1002/kin.21728","url":null,"abstract":"<p>Removing polychlorinated biphenyls (PCBs) from subsurface water, soils, and transformer oil is crucial to save the environment from these pollutant materials. Hydrodechlorination (HDC) of PCBs consists of numerous chemical reactions and the simple kinetic models may not provide details for the process. To gain more awareness of the reaction mechanism, in the proposed approach, the isoconversional methods of the Friedman were investigated paralleling other kinetic models of Langmuir-Hinshelwood (L-H), Eley-Rideal (E-R), pseudo-first-order, and pseudo-second-order methods. The analysis was validated by laboratory results of HDC of contaminated transformer oil in front of Pd/MWCNTs. The most reactivity was observed for biphenyls with a higher number of chlorines. Finding a suitable model, Akaike Information Criteria were applied. It was attained that Friedman model was the most suitable for monitoring of HDC of PCBs in front of catalyst. Besides, E-R reaction was appropriate to elucidate the theoretical interpretations of the adsorption and desorption of reactants and chlorinated benzene.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"56 9","pages":"560-567"},"PeriodicalIF":1.5,"publicationDate":"2024-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141121192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Reactivity and detailed reaction mechanism of quasi-tetrahedral o-azophenylboronic acid","authors":"Azusa Kuroda,&nbsp;Yota Suzuki,&nbsp;Yoshihisa Shintani,&nbsp;Tomoaki Sugaya,&nbsp;Koji Ishihara","doi":"10.1002/kin.21726","DOIUrl":"10.1002/kin.21726","url":null,"abstract":"<p>Quasi-tetrahedral <i>o</i>-azophenylboronic acid (azoB-ROH), which contains the protic solvent ROH, is a key species in the colorimetric sensing of saccharides by <i>o</i>-azophenylboronic acid (azoB). In this study, we compared the reactivity of azoB-ROH with that of trigonal azoB and tetrahedral <i>o</i>-azophenylboronate (azoB-OH⁻), and clarified the reaction mechanism of azoB-ROH with <i>cis</i>-1,2-cyclopentanediol and D-glucose. Analysis of the kinetics of the reactions of azoB with <i>cis</i>-1,2-cyclopentanediol and D-glucose in DMSO:water = 1:9 and azoB with <i>cis</i>-1,2-cyclopentanediol in tetrahydrofuran containing a small amount of methanol revealed that there was not much difference in the reactivity of azoB-H₂O and azoB-OH⁻, although the reactivity of azoB was higher than that of azoB-MeOH, that is, the reaction mechanism of azoB-H₂O was essentially the same as that of azoB-OH⁻.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"56 9","pages":"549-559"},"PeriodicalIF":1.5,"publicationDate":"2024-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140838861","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Autoignition enhancement of methane by admixture of low fraction of acetaldehyde: Simulations and RCM experiments in stoichiometric and rich mixtures","authors":"Seyed B. Nourani Najafi,&nbsp;Sander Gersen,&nbsp;Hamid Hashemi,&nbsp;Peter Glarborg,&nbsp;Anatoli V. Mokhov,&nbsp;Howard B. Levinsky","doi":"10.1002/kin.21727","DOIUrl":"10.1002/kin.21727","url":null,"abstract":"<p>The effect of small fractions of acetaldehyde (CH₃CHO) on the ignition delay time of methane (CH₄) was examined at high pressure. Measurements are reported for the ignition delay time obtained in a rapid compression machine (RCM) at a compression pressure (<i>P</i>_c) of ∼60 bar and temperatures after compression (<i>T</i>_c) in the range 750–900 K for fuel-air equivalence ratios <i>ϕ</i> in the range 1–4. The results show that mixtures of 2%–5% CH₃CHO in CH₄ ignite under conditions at which pure methane does not ignite experimentally. The efficiency of acetaldehyde as a promoter seems to be comparable to that of other oxygenated fuels like alcohols and ethers. For comparison with the experimental results, ignition delay times are computed using an updated reaction mechanism and two mechanisms from the literature for CH₃CHO oxidation. For most conditions, the simulations using the current mechanism agree with the measurements to within a factor of two. The ignition profile shows a pre-ignition temperature rise and two-stage ignition similar to that previously observed in low fractions of dimethyl ether in ammonia; both phenomena are captured by the simulations. Analysis of simulations at constant volume indicates that CH₃CHO is oxidized much more rapidly than CH₄, producing reactive species that initiate the oxidation of CH₄ and generates heat that accelerates oxidation toward ignition. The low-temperature chain-branching reactions of CH₃CHO are important in the early oxidation of the fuel mixture. Additional simulations were performed for equivalence ratios of <i>ϕ</i> = 1 and 4, at a compression pressure (<i>P</i>_c) of 100 bar and <i>T</i>_c = 750–1000 K. The simulations indicate that CH₃CHO has a strong ignition-enhancing effect on CH₄, with small fractions reducing the ignition delay time by up to a factor of 100, depending on the temperature, as compared to pure CH₄.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"56 9","pages":"534-548"},"PeriodicalIF":1.5,"publicationDate":"2024-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/kin.21727","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140671246","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Urease stabilization in urea–urease–H+ system and its influence on the clock reaction dynamics","authors":"Dan Yang,&nbsp;Hua Zhang,&nbsp;Fengyi Cao,&nbsp;Sijia Chang,&nbsp;Guihao Tan,&nbsp;Lin Ji","doi":"10.1002/kin.21725","DOIUrl":"10.1002/kin.21725","url":null,"abstract":"<p>The inherent autocatalytic kinetics of the urea–urease–H⁺ system positions it as a promising candidate for the design of dynamic materials with time-domain programmable functions. Nevertheless, the stability of the enzyme can markedly influence the temporal evolution dynamics of the system and curtail its widespread applicability. This work employs several kinds of enzyme stabilization methods, including chemical cross-linking, physical coating, solvent stabilization, and solvent-physical coating co-modification, to systematically explore the impact of enzyme stabilization on clock reaction dynamics. Extensive experimental tests and analysis indicate that solvent and chemical cross-linking stabilization methods can better preserve clock dynamics with sensitive switching ability. Nevertheless, due to significant pH changes in the reacting system, the reusability of the enzyme is better retained in the physical coating and solvent-physical coating co-modification methods.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"56 9","pages":"522-533"},"PeriodicalIF":1.5,"publicationDate":"2024-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140591283","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Evaluation of reaction rate of thermogravimetric analysis data using periodic sinc function interpolation","authors":"Alireza Aghili,&nbsp;Amir Hossein Shabani","doi":"10.1002/kin.21724","DOIUrl":"10.1002/kin.21724","url":null,"abstract":"<p>The periodic sinc function interpolation offers a compelling solution to address the issue of noise in the analysis of thermogravimetric analysis (TGA) data, thereby enhancing the outcomes of differential techniques such as the Friedman isoconversional method. In this study, we introduce a novel approach that leverages the periodic sinc function interpolation to directly obtain smooth reaction rates from TGA data, eliminating the reliance on numerical differentiation methods. The efficacy of this method has been confirmed through its application to noisy experimental data derived from the thermal decomposition of various polymers, showcasing its robustness. Readers are provided with the corresponding code for Gnu Octave, serving as a free alternative to MATLAB. Additionally, the activation energies calculated from the experimental data using both the Friedman method and periodic sinc function interpolation closely align with those determined by the integral Vyazovkin method, emphasizing the validity and reliability of this new approach.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"56 9","pages":"513-521"},"PeriodicalIF":1.5,"publicationDate":"2024-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140591281","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Reaction path identification and validation from molecular dynamics simulations of hydrocarbon pyrolysis","authors":"Felix Schmalz,&nbsp;Wassja A. Kopp,&nbsp;Eirini Goudeli,&nbsp;Kai Leonhard","doi":"10.1002/kin.21719","DOIUrl":"10.1002/kin.21719","url":null,"abstract":"<p>Creation of complex chemical mechanisms for hydrocarbon pyrolysis and combustion is challenging due to the large number of species and reactions involved. Reactive molecular dynamics (RMD) enables the simulation of thousands of reactions and the discovery of previously unknown components of the reaction network. However, due to the inherent imprecision of reactive force fields, it is necessary to verify RMD-obtained reaction paths using more accurate methods such as Density Functional Theory (DFT). We demonstrate a method for identification and confirmation of reaction pathways from RMD that supplement an established mechanism, using the example of benzene formation from <i>n</i>-heptane and <i>iso</i>-octane pyrolysis. We establish a validation workflow to extract reaction geometries from RMD and optimize transition states using the Nudged-Elastic-Band method on semi-empirical and quantum mechanical levels of theory. Our findings demonstrate that the widely recognized ReaxFF parameterization, CHO2016, can identify known pathways from a established soot formation mechanism while also indicating new ones. We also show that CHO2016 underestimates hydrogen migration barriers by up to <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mn>40</mn>\u0000 <mspace></mspace>\u0000 <msup>\u0000 <mrow>\u0000 <mi>kcal</mi>\u0000 <mspace></mspace>\u0000 <mi>mol</mi>\u0000 </mrow>\u0000 <mrow>\u0000 <mo>−</mo>\u0000 <mn>1</mn>\u0000 </mrow>\u0000 </msup>\u0000 </mrow>\u0000 <annotation>$40,{rm {kcal,mol}}^{-1}$</annotation>\u0000 </semantics></math> as compared to DFT and can lower activation barriers significantly for spin-forbidden reactions. This highlights the necessity for validation or potentially even reparametrization of CHO2016.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"56 9","pages":"501-512"},"PeriodicalIF":1.5,"publicationDate":"2024-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/kin.21719","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140591635","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"UV photolysis of oxalyl chloride: ClCO radical decomposition and direct \u0000 \u0000 \u0000 \u0000 Cl\u0000 2\u0000 \u0000 \u0000 \u0000 ${rm Cl}_2 {rm }$\u0000 formation pathways","authors":"Michael Stuhr,&nbsp;Sebastian Hesse,&nbsp;Nancy Faßheber,&nbsp;Marcel Wohler,&nbsp;Mithun Pal,&nbsp;Yasuyuki Sakai,&nbsp;Patrick Hemberger,&nbsp;Gernot Friedrichs","doi":"10.1002/kin.21723","DOIUrl":"10.1002/kin.21723","url":null,"abstract":"<p>Oxalyl chloride, <span></span><math>\u0000 <semantics>\u0000 <msub>\u0000 <mtext>(ClCO)</mtext>\u0000 <mn>2</mn>\u0000 </msub>\u0000 <annotation>$text{(ClCO)}_2$</annotation>\u0000 </semantics></math>, is widely used as a photolytic source of Cl atoms in reaction kinetics studies. <span></span><math>\u0000 <semantics>\u0000 <msub>\u0000 <mtext>(ClCO)</mtext>\u0000 <mn>2</mn>\u0000 </msub>\u0000 <annotation>$text{(ClCO)}_2$</annotation>\u0000 </semantics></math> photolysis is typically assumed to produce Cl atoms with an overall yield of 2 via three-body dissociation, <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <msub>\u0000 <mtext>(ClCO)</mtext>\u0000 <mn>2</mn>\u0000 </msub>\u0000 <mo>+</mo>\u0000 <mi>h</mi>\u0000 <mi>ν</mi>\u0000 <mo>→</mo>\u0000 <mtext>Cl</mtext>\u0000 <mo>+</mo>\u0000 <mtext>CO</mtext>\u0000 <mo>+</mo>\u0000 <msup>\u0000 <mtext>ClCO</mtext>\u0000 <mo>∗</mo>\u0000 </msup>\u0000 </mrow>\u0000 <annotation>$text{(ClCO)}_2 + hnu rightarrow text{Cl} + text{CO} + text{ClCO}^*$</annotation>\u0000 </semantics></math>, followed by fast subsequent ClCO unimolecular decomposition of either the energetically excited <span></span><math>\u0000 <semantics>\u0000 <msup>\u0000 <mi>ClCO</mi>\u0000 <mo>∗</mo>\u0000 </msup>\u0000 <annotation>${rm ClCO}^*$</annotation>\u0000 </semantics></math> fragment, <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <msup>\u0000 <mtext>ClCO</mtext>\u0000 <mo>∗</mo>\u0000 </msup>\u0000 <mo>→</mo>\u0000 <mtext>Cl</mtext>\u0000 <mo>+</mo>\u0000 <mtext>CO</mtext>\u0000 </mrow>\u0000 <annotation>$text{ClCO}^* rightarrow text{Cl} + text{CO}$</annotation>\u0000 </semantics></math>, or the thermalized ClCO radical, <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mtext>ClCO</mtext>\u0000 <mo>+</mo>\u0000 <mi>M</mi>\u0000 <mo>→</mo>\u0000 <mtext>Cl</mtext>\u0000 <mo>+</mo>\u0000 <mtext>CO</mtext>\u0000 <mo>+</mo>\u0000 <mi>M</mi>\u0000 </mrow>\u0000 <annotation>$text{ClCO} + text{M} rightarrow text{Cl} + text{CO} + text{M}$</annotation>\u0000 </semantics></math>. However, a study","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"56 8","pages":"482-498"},"PeriodicalIF":1.5,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/kin.21723","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140591279","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}