International Journal of Coal Geology最新文献

{"title":"","authors":"Gregory Smith","doi":"10.1016/j.coal.2025.104756","DOIUrl":"10.1016/j.coal.2025.104756","url":null,"abstract":"","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":"304 ","pages":"Article 104756"},"PeriodicalIF":5.6,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143817710","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The role of geological fluids on the distribution of lithium in anthracite, an example from the Yangquan Mining District, Qinshui Basin, northern China","authors":"Huidi Hao ,&nbsp;Bo Jiu ,&nbsp;Wenhui Huang ,&nbsp;Chunlan Yu ,&nbsp;Zhaoguo Wang ,&nbsp;Binchao Qin ,&nbsp;Linghao Huang","doi":"10.1016/j.coal.2025.104754","DOIUrl":"10.1016/j.coal.2025.104754","url":null,"abstract":"<div><div>Coal with abundant kaolinite and illite has become an important target for the exploration of potential coal-hosted lithium deposits. The No.15 coal from the Xinjing Mine, northern China, is rich in kaolinite, illite, and NH₄-illite. This study comprehensively applied multi-scale mineral analysis and in-situ micro-regional characterization methods to analyze the lithium content distribution in clay minerals, while elucidating the genetic mechanisms of clay minerals and their interactions with geological fluids. The genesis of these minerals and their interaction with geological fluids during thermal evolution were analyzed using whole-rock and in-situ geochemical methods. Lithium is enriched in the No.15 coal (42.2 μg/g). The Li concentration in clay minerals in the No.15 coal seam follows a descending order of: cryptocrystalline kaolinite (649.9 μg/g) &gt; detrital kaolinite (366.1 μg/g) &gt; cell-filling kaolinite (94.8 μg/g) &gt; illite (16.1 μg/g) and NH₄-illite (21.1 μg/g). Cryptocrystalline and detrital kaolinite are thus the primary hosts of Li. Whole-rock and mineral geochemical data indicate detrital input as the main source of Li. The similarities in the REE distribution patterns between kaolinite in coal and Yinshan granite suggest that kaolinite, a key weathering product of acidic magmatic rocks in humid sedimentary systems, may have originated from the Yinshan Mountain granite. The presence of seawater and organic acids within coal-bearing strata collectively facilitate the illitization of kaolinite at temperatures of 120–140 °C. The negative correlation between Gd anomalies and Sr/Ba ratios indicates that the interaction between groundwater and seawater has established a geochemical barrier, which facilitates the enrichment of Li in coal.</div></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":"303 ","pages":"Article 104754"},"PeriodicalIF":5.6,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143704614","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Vitrinite reflectance patterns from the Riosa-Olloniego Sector (Carboniferous, Cantabrian Zone, NW Spain): Overburden implications","authors":"Luis Pedro Fernández ,&nbsp;Miguel Allende ,&nbsp;Ángeles G. Borrego","doi":"10.1016/j.coal.2025.104753","DOIUrl":"10.1016/j.coal.2025.104753","url":null,"abstract":"<div><div>Vitrinite reflectance is a parameter of organic matter maturity considered of paramount importance to reconstruct the history of sedimentary basins (palaeotemperature, depth of burial, unconformities, tectonic overprinting, local thermal anomalies). Although sensitive to external factors (vitrinite alteration, maceral composition, lithology) that may harm its reliability, it is still the most robust tool widely applied in sedimentary basins. In this work, vitrinite reflectance is used to study the post-sedimentary evolution of a Carboniferous (Moscovian, Asturian) succession (Riosa-Olloniego Sector, Central Asturian Coalfield) of the Cantabrian Zone foreland basin (NW Spain). Fourteen samples (coals, carbonaceous shales and channel sandstones with rip-up coaly clasts and plant fragments) from an 800-m-thick, mixed continental–marine interval and two localities, underground (coal mine) and on surface, respectively, were subjected to chemical and petrographic analyses. Attention was paid to the influence of the above-mentioned external factors. The organic matter plots in the Kerogen type III field and has a Bituminous C-B coal rank, with generally low S content. Reflectance values range from 0.79 to 1.07 Ro% with a gradient of ∼0.3 Ro%/km for both mine and surface samples, which plot along similar trends but with the latter yielding comparatively lower values. Palaeotemperatures calculated from vitrinite reflectance using the most general models yielded palaeogeothermal gradients of 23–36 °C/km and maximum burial depths of ∼3.9–5.2 km, depending on the model. It was concluded that the vitrinite reflectance was mainly governed by sedimentary burial, with differences between mine and surface values reflecting variable tectonic overburden under a neighbouring nappe (Aramo Nappe).</div></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":"304 ","pages":"Article 104753"},"PeriodicalIF":5.6,"publicationDate":"2025-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143726003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enrichment of Al-Li-Ga-Nb(Ta)-Zr(Hf) in the Permo-Carboniferous coal-bearing sequences of the Jungar Coalfield, northern China","authors":"Yuan Wang ,&nbsp;Jing Li ,&nbsp;Daohua Wang ,&nbsp;Xin Luo ,&nbsp;Wei Yuan ,&nbsp;Hongguang Cai ,&nbsp;Han Zhang ,&nbsp;Xiangdong Feng ,&nbsp;Shuai Guo ,&nbsp;Wenhua Li ,&nbsp;Xinguo Zhuang ,&nbsp;Van Long Hoang","doi":"10.1016/j.coal.2025.104752","DOIUrl":"10.1016/j.coal.2025.104752","url":null,"abstract":"<div><div>Coal-hosted critical metal deposits have emerged as a viable alternative to conventional critical metal resources and have garnered significant attention in recent years. Notable enrichments of critical metal assemblages, including aluminum, gallium, lithium, and rare earth elements and yttrium (REY) have been identified in several Permo-Carboniferous coal measures within the Jungar Coalfield and across other coalfields in the Ordos Basin, northern China. Using a number of analytical techniques such as X-ray diffraction analysis (XRD), scanning electron microscopy (SEM-EDX), the TIMA-X integrated mineral analyzer, X-ray fluorescence spectroscopy (XRF), inductively coupled plasma-mass spectrometry (ICP-MS), and LA-ICP-MS, this study systematically investigates the mineralogical and geochemical characteristics of three economically significant coal seams (Nos. 3, 6 upper, and 6 coal) in the Laosangou exploration area of the northern Jungar Coalfield. The study focuses on the modes of occurrence, enrichment mechanisms, and economic potential of critical metal assemblages within the coal deposits.</div><div>Compared to the average for world hard coals, Al-Ga-Li-Nb(Ta)-Zr(Hf) assemblages are generally enriched in the No. 3 coal of the Shanxi Formation and Nos. 6 upper and 6 coals of the Taiyuan Formation, and exhibit much higher values in the lower portion of the No. 6 coal adjacent to or within the tonsteins. Aluminum, Ga, and Li in the studied coals are primarily hosted in kaolinite and/or boehmite, while Nb, Ta, Zr, and Hf primarily occur in zircon and/or anatase embedded within kaolinite. The critical metals in the studied coals all demonstrate promising economic potential and could potentially be extracted from the coal-combustion fly ashes.</div><div>The enrichment of the Al-Li-Ga-Nb(Ta)-Zr(Hf) assemblages in these coals is attributed to contributions from both terrestrial sediment sources and pyroclastic materials, as well as hydrothermal fluid injections. The sediment provenance of the studied coals includes inputs mainly from the Yinshan Oldland, northern Trans North China Orogens (TNCO), and bauxite-rich weathering crusts of the Benxi Formation, which served as initial sources of Al, Li, Ga, and other critical metals. Additionally, the intermediate-felsic alkaline volcanic ash enriched in Li, Ga, Nb, Ta, Zr, and Hf along with the injection of acid groundwater or low-temperature hydrothermal fluids further facilitated the enrichment of these critical metals.</div></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":"303 ","pages":"Article 104752"},"PeriodicalIF":5.6,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143678267","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Tracing highly oxidized events and its response to peat dynamic from the northwest Kapuas coastal wetlands, Indonesia","authors":"Aulia Agus Patria ,&nbsp;Stephen P. Obrochta ,&nbsp;Ferian Anggara","doi":"10.1016/j.coal.2025.104751","DOIUrl":"10.1016/j.coal.2025.104751","url":null,"abstract":"<div><div>Peat deposits are highly sensitive to environmental changes and are well-suited to palaeobotanical investigations. Therefore, we assess the integration between organic petrology, palynology, and microcharcoal distributions to provide a robust interpretation on peatland dynamic and paleoenvironmental reconstruction. In addition, we propose a peat characterization using a quantitative color coordinate (CIELAB) to reduce biases while characterizing peat via qualitative comparisons to the Munsell soil color chart. This study was conducted in low-lying mires in the northwest Kapuas coastal plain, West Kalimantan, Indonesia. Five types of peat were identified: sapric muck, sapric shorts, sapric wood, coarse hemic, and fine hemic. The quantitative color coordinate analysis successfully recognizes the peat physical properties but is not directly related to the peat type. Higher values of the red-green chromaticity index (a*) indicate a greater preservation of plant material. Conversely, lower values represent charcoal or an oxidized layer of organic matter. Higher contents of inertinite or oxidized organic matter are comparable to the microcharcoal abundance, showing the presence of severe fires. At least eight fire events were reported, with decreasing intensity towards top of the core. Variation in microcharcoal abundances led to a degree of preservation changes, nutrient status and paleovegetation shift in the studied area. Four phases of peat dynamics were identified: initiation, early ombrogenous, late ombrogenous, and topogenous phases. In general, past vegetation shows an alternation community of mixed-riparian forest and open vegetation to present day mangrove low-lying topogenous mire. Our findings refer to the vulnerability of vegetation changes and peat dynamics concerning on highly oxidized events related to the fire intensity as an important driver in the northwest coastal wetlands of Kalimantan Island.</div></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":"303 ","pages":"Article 104751"},"PeriodicalIF":5.6,"publicationDate":"2025-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143643156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Elastic anisotropy and deformation characteristics of Pennsylvania anthracite","authors":"Bodhisatwa Hazra ,&nbsp;Hem Bahadur Motra ,&nbsp;James C. Hower ,&nbsp;Maria Mastalerz ,&nbsp;Chinmay Sethi ,&nbsp;Harold Schobert","doi":"10.1016/j.coal.2025.104740","DOIUrl":"10.1016/j.coal.2025.104740","url":null,"abstract":"<div><div>The mechanical behavior and elastic anisotropy of coal under stress are critical to understanding its structural integrity and performance in subsurface environments. Despite its significance, limited research has systematically analysed the elastic anisotropic responses of coals under such conditions. This study investigates the elastic anisotropy of three anthracite-rank coals, Primrose, Lattimer, and Mt. Carmel, subjected to conventional triaxial loading. P-wave (V_P) and S-wave (V_S) velocities, along with Thomsen parameters (ε and γ), were evaluated to elucidate the effects of increasing vertical stress on the structural integrity and anisotropy of each coal type. The results reveal that the Primrose coal exhibits the highest structural integrity, maintaining elevated V_P and V_S values and stable Thomsen parameters under stress due to its dense microstructure, higher inertinite content, and low porosity, which resist stress-induced microcracking. In contrast, the Lattimer coal demonstrates a significant reduction in VP and ε beyond 45 MPa, indicating greater susceptibility to microstructural damage and a trend towards isotropy as stress increases. The Mt. Carmel coal shows intermediate behavior, with moderate decreases in VP and ε but relatively stable γ values, reflecting a balanced resistance to structural degradation. S-wave anisotropy, as evidenced by shear wave splitting, remains most prominent in the Primrose coal, suggesting its superior ability to retain directional properties and resist stress-induced deformation. Principal component analysis highlights the role of rank, inertinite-to-vitrinite ratio, and aromaticity in influencing the mechanical responses of the coals, with Primrose coal consistently segregating as the most robust and anisotropically stable sample. These findings underscore the critical influence of compositional and microstructural differences on coal's anisotropic behavior under conventional-triaxial loading. They provide valuable insights for applications in subsurface energy extraction and storage, where understanding the mechanical and anisotropic properties of coal is essential for optimizing performance and mitigating risks.</div></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":"303 ","pages":"Article 104740"},"PeriodicalIF":5.6,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143609970","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Origin of chemical structure and pore heterogeneity of over-matured organic matter in the Paleozoic marine shales, China","authors":"Yingzhu Wang ,&nbsp;Jijin Yang","doi":"10.1016/j.coal.2025.104742","DOIUrl":"10.1016/j.coal.2025.104742","url":null,"abstract":"<div><div>Organic matter (OM) pores play a leading role in gas storage for many shale formations, and understanding their development mechanism is critical to evaluating the mechanisms of shale gas enrichment. However, an insufficient knowledge of OM compositional and structural complexity makes the origin of pore heterogeneity still unclear. This study correlates high-resolution scanning electron microscopy (SEM) and Raman microscopy to investigate the association of OM molecular structure and pore development in the Cambrian Niutitang shales and Silurian Longmaxi shales, south China. Results show that pyrobitumen, the predominant OM maceral, can be divided into two types (PB1 and PB2) which have differences in petrographic characteristics, Raman parameters, and pore distribution. In the shales with good gas preservation, the pore-filling PB2 shows a lower degree of aromaticity, a higher apparent transformation ratio (15 %–40 %), and larger pore size (peak of 80–90 nm) than that of the less porous PB1. In the poorly-preserved shales, different pyrobitumen exhibit homogeneous molecular structure and smaller pore size (peak of 30–40 nm). The poor development of OM-hosted pores in the Niutitang shale is related to the increased OM graphitization at a Ro &gt; 3.5 %. The heterogeneity of OM structure and porosity in different Longmaxi shales would be originally impacted by a distinction in the degree of oil expulsion under different preservation condition. In the well-preserved shales, a higher retention of aliphatic-rich oil may lead to the more porous and less aromatic pyrobitumen, and thus a higher current gas content. The study provides new insights into the OM chemical controls on nanoscale pore heterogeneity, which is significant for shale gas exploration.</div></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":"303 ","pages":"Article 104742"},"PeriodicalIF":5.6,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143576864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Restoring the original hydrocarbon-generating potential of deep source rocks: A critical review and a novel method using the Songliao Basin, China, as a case study","authors":"Daming Niu ,&nbsp;Tianyi Li ,&nbsp;Yueyue Bai ,&nbsp;Pingchang Sun ,&nbsp;Hongliang Dang ,&nbsp;Yilin Li ,&nbsp;Lianxin Tao ,&nbsp;Xingxuan Lei ,&nbsp;Sicheng Li ,&nbsp;Lixiang Gui ,&nbsp;Chunlong Liu","doi":"10.1016/j.coal.2025.104741","DOIUrl":"10.1016/j.coal.2025.104741","url":null,"abstract":"<div><div>Deep source rocks are typically in a high-to-overmature stage, characterized by lower than original values of total organic carbon. Thus, resource evaluation is significantly influenced by the accuracy of the measured data and the restoration methods of original (pre-thermal maturation) values. Therefore, reliable data for assessing petroleum and natural gas resources generated during the burial process are urgently needed. This study first critically reviews commonly used methods for restoring the original TOC (TOC_o) and hydrocarbon-generating potential (HGP). The principles, advantages, and disadvantages of each method are discussed, and a novel workflow for evaluating the resource is proposed. The workflow involves four steps: (1) selecting a fit for-the-purpose method for original TOC and HGP restoration; (2) establishing original restoration coefficients by weighted TOC and HGP restoration formulas; (3) assessing the remaining resource potential through hydrocarbon generation and expulsion; and (4) validating the assessment results. Using the Permian source rocks in the Songliao Basin as an example, this workflow restores the total remaining resource amount (65.3 × 10⁹ t). Predicted results indicate that high-value areas with remaining resource potential are near the Heyupao Sag (57.7 × 10⁸ t), Chaoyanggou Terrace (73.5 × 10⁸ t), and Binxian-Wangfu Sag (39.0 × 10⁸ t). The advantages of this workflow include: (1) overcoming the limitations of the original TOC and HGP restoration method by selecting the most suitable restoration model; (2) directly identifying the original TOC spatial distribution using recovery coefficient, which overcomes the heterogeneity in the spatial distribution of organic matter types; and (3) accurately verifying the remaining resource potential presence based on tectonic and thermal evolution. The proposed workflow significantly improves the credibility of resource evaluations and is likely applicable to other deep and ultradeep buried source rocks worldwide.</div></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":"303 ","pages":"Article 104741"},"PeriodicalIF":5.6,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143609971","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Rare earth resource in fly ashes from coal power plants of China: Based on machine learning model and unit-based estimation","authors":"Chang Liu ,&nbsp;Yi Yang ,&nbsp;Long Chen ,&nbsp;Jiayuan Wu ,&nbsp;Yuan Sun ,&nbsp;Mingzhe Han ,&nbsp;Xingpan Guo ,&nbsp;Maoyong He ,&nbsp;Zhangdong Jin","doi":"10.1016/j.coal.2025.104743","DOIUrl":"10.1016/j.coal.2025.104743","url":null,"abstract":"<div><div>Coal fly ashes (CFAs) are an alternative resource of rare earth elements and yttrium (REY). China is the largest producer of CFAs in the world and is likely to hold substantial reserves of CFA-REY resources, while nationwide research on REY resource in Chinese CFAs is lacking. In this work, CFA samples were collected from 118 coal - fired power plants (CFPPs), including eight subjected to long-term monitoring. Based on this, a machine-learned (ML) REY concentration predictive model was developed with a deviation of 16 %, which showed REY concentration and the proportion of air-dried-basis ash yield in coal, and CFPP boiler type were the three governing factors regulating REY concentrations in CFAs. Using this ML model and a unit-based database of Chinese CFPPs, REY concentrations in CFAs from 1062 additional CFPPs were predicted, who accounted for 89.2 % of national coal consumption. Promising CFA-REY resources were defined as those containing ≥300 mg/kg REY in CFA, and were concentrated in North (Inner Mongolia, Shanxi, and Hebei Provinces), East (Shandong, Jiangsu, Zhejiang, and Anhui Provinces), South (Guangdong Province) and Southwest (Guizhou Province) China. Moreover, using a unit-based estimation model, the total amount of rare earth oxides from unutilized CFAs with REY recovery potential in China is estimated to be about 74,300 tons/y, which would meet six months of global demand and have a gross value of US $ 4.2 billion.</div></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":"303 ","pages":"Article 104743"},"PeriodicalIF":5.6,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143576862","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Implications of solid bitumen association with low- to medium-temperature hydrothermal minerals in hydrocarbon reservoirs of Southwest China: Insights from organic petrology and sulfur isotopes","authors":"Wen Sun ,&nbsp;Ningning Zhong ,&nbsp;Yongli Lu ,&nbsp;Dahua Li ,&nbsp;Qingyong Luo ,&nbsp;Lipeng Yao ,&nbsp;Yanan Yang ,&nbsp;Chunfang Cai ,&nbsp;Zilong Fang","doi":"10.1016/j.coal.2025.104739","DOIUrl":"10.1016/j.coal.2025.104739","url":null,"abstract":"<div><div>Solid bitumen in Southwest China often coexists with metal deposits, indicating a genetic link between organic matter and ore formation. However, this linkage remains underexplored. This study investigated the relationship between sulfur origin and organic matter maturity through sulfur isotopes of metal sulfides. Organic petrology revealed that solid bitumen associated with minerals exhibited stronger optical anisotropy (ΔBRo &gt;3.32 %) and higher S/C atomic ratios (0.029–0.033) than non-associated bitumen (0.005–0.021). Fluid inclusion analysis showed that ore-stage calcite inclusions have higher homogenization temperatures than those in paleo-oil reservoirs, indicating that ore-forming processes accelerated hydrocarbon thermal evolution. Solid bitumen-mineral associations were classified into Mississippi Valley-type (MVT), stratiform mercury, and disseminated gold deposits. Sulfur isotope compositions identified three sulfur sources: bacterial sulfate reduction (BSR), thermochemical sulfate reduction (TSR), and thermal decomposition of sulfur-containing organic matter (TDS). In the Lanping-Simao Basin, δ³⁴S_CDT values below 0 ‰ suggest sulfur derived from BSR, with hydrocarbons contributing reduced sulfur. In the Xuefeng Mountains Uplift, δ³⁴S_CDT values exceeding 20 ‰ indicate TSR-driven sulfur, with metallogeny enhancing hydrocarbon accumulation and mineralization. In the Kangdian Axis, δ³⁴S_CDT values under 20 ‰ suggest sulfur from TSR and TDS, with mineralization causing oil cracking and reservoir destruction. The findings demonstrate that metallogeny accelerates organic matter maturation, reshapes reservoirs, and drives oil cracking. Simultaneously, organic-inorganic interactions govern metal sulfide formation and precipitation, underscoring their critical role in ore genesis.</div></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":"303 ","pages":"Article 104739"},"PeriodicalIF":5.6,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143576865","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}