International Journal of Coal Geology最新文献

{"title":"Origin and nature of pores in the Toolebuc Formation, a potential unconventional target in Australia","authors":"Xiaoxiao Mao ,&nbsp;Grant K.W. Dawson ,&nbsp;Victor Rudolph ,&nbsp;Sandra Rodrigues ,&nbsp;Suzanne D. Golding","doi":"10.1016/j.coal.2024.104497","DOIUrl":"10.1016/j.coal.2024.104497","url":null,"abstract":"<div><p>The Toolebuc Formation of Australia, a potential unconventional hydrocarbon resource, has limited studies on its pore structure and sorption characteristics. In this study, shale samples covering the lower mixed argillaceous mudstone (MAM) lithofacies, the middle interbedded calcareous mudstone and shelly thin beds (CM-STB) lithofacies, and the upper interbedded calcareous mudstone and shelly horizons (CM-SH) lithofacies of the Toolebuc Formation were collected. These samples were analysed for pore structure using a combination of scanning electron microscopy, X-ray diffraction, helium pycnometry, mercury intrusion porosimetry, and N₂ physisorption techniques. Additionally, methane sorption isotherms were measured under in-situ conditions. The results reveal that most pores are mineral-related intraparticle (intraP) and interparticle pores, with slit, equant and elongated shapes. Organic matter (OM) pores are rare. Porosity, total pore volume and BET specific surface area (SSA) are 3.25–8.26%, 1.32–3.55 cm³/100 g, and 1.26–9.65 m²/g, respectively. Pore volume is dominated by mesopores and macropores while specific surface area is dominated by fine mesopores and micropores. The porosity of the organic matter is significantly low due to the rarity of OM pores in the stage of early oil-window thermal maturity; organic matter consequently occludes pore space and also negatively impacts the average porosity. Clay by contrast is positively correlated to the average porosity. Carbonate provides intraP pores in fecal pellets, but also fills in other pore spaces as occlusion. Methane isotherms exhibit linear shapes, suggesting that a portion of the gas is stored in solution. The lower MAM lithofacies, characterised by rich clay, high porosity and BET SSA, was measured to have an in-situ methane sorption capacity of 4.32 cm³/g; the middle CM-STB lithofacies has intermediate porosity, but exhibits excellent gas generation potential and high in-situ methane sorption capacity (4.12–5.5 cm³/g). Within the CM-STB lithofacies, porosity declines with depth. The upper CM-SH lithofacies is carbonate-rich, exhibiting the lowest porosity and in-situ methane sorption capacity (2.56 cm³/g), but may act as an intraformational seal. The combination and vertical stacking pattern of the three lithofacies provided a favourable setting for gas storage.</p></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0166516224000545/pdfft?md5=cf98cdb7f41de7d62bb00c9eb59b7312&pid=1-s2.0-S0166516224000545-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140272232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"From abandoned mines to carbon sinks: Assessing the CO2 storage capacity of Austrian low-rank coal deposits","authors":"Majid Safaei-Farouji ,&nbsp;David Misch ,&nbsp;Reinhard F. Sachsenhofer ,&nbsp;Max Rauscher ,&nbsp;Nikolaos Kostoglou","doi":"10.1016/j.coal.2024.104495","DOIUrl":"10.1016/j.coal.2024.104495","url":null,"abstract":"<div><p>This study represents the first assessment of CO₂ storage potential in Austrian coal seams. Coal samples were taken from Fohnsdorf and Leoben abandoned coal mines, with particular emphasis on the Fohnsdorf coal since Leoben coal reserves were largely mined during previous coal production. Several methods were used to compare coal characteristics, including Rock-Eval pyrolysis (RE), organic petrography, and low-pressure N₂ and CO₂ sorption measurements. Both Fohnsdorf and Leoben coal samples show low sulfur and ash yields, as well as correspondingly high total organic carbon (TOC) contents. The pyrolysis T_max and vitrinite reflectance values agree with a low coal rank for both sites. According to the N₂ adsorption measurements at 77 K, low-lying mire coals from Fohnsdorf show a higher BET-specific surface area (BET-SSA) and BJH pore volume compared to raised-mire coals from Leoben. However, sapropelic shales and high-ash coals from Leoben show the highest BET-SSA and BJH pore volumes of all investigated samples and considerably exceed the N₂ adsorption volumes of pure coals from both locations (N₂ uptake up to 16 cm³/g; avg. for all samples 5.4 cm³/g). In contrast, the mean adsorbed CO₂ uptake measured at 273 K and ∼ 1 bar followed the order of Fohnsdorf low-lying mire coals &gt; Leoben raised-mire coals &gt; Leoben sapropelic coals and shales, ranging at ∼0.8 mmol/g, ∼0.7 mmol/g, and ∼ 0.2 mmol/g, respectively. This shows that BET-SSA and BJH equations did not allow for adequate estimation of CO₂ adsorption capacity trends in the investigated sample set. Furthermore, based on the existence of a hysteresis loop between CO₂ adsorption and desorption branches for all investigated samples, the occurrence of weak chemisorption phenomena during CO₂ adsorption is indicated. This effect helps to increase CO₂ uptake and storage safety since the chemisorption process is not fully reversible upon pressure decrease. Ultimately, the theoretical CO₂ sequestration potential of the remaining unmined Fohnsdorf coal reserves was estimated at 4.65 million tons, with an additional potential for enhanced coal bed methane production due to the gas-rich nature of Fohnsdorf coals with an estimated 1.2 billion m³ of CH₄ in place.</p></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0166516224000521/pdfft?md5=5c56313ec144f9edbe6b12d09c45dc7d&pid=1-s2.0-S0166516224000521-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140278981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A complex case of thermal maturity assessment in a terrigenous sedimentary system: The Northwestern Black Sea basin","authors":"Hamed Sanei ,&nbsp;Oskar Hagelskjær ,&nbsp;Henrik I. Petersen ,&nbsp;Arka Rudra ,&nbsp;Søren B. Nielsen ,&nbsp;François Lorant ,&nbsp;François Gelin","doi":"10.1016/j.coal.2024.104496","DOIUrl":"10.1016/j.coal.2024.104496","url":null,"abstract":"<div><p>An integrated approach combining fluorescence spectrometry, pyrolysis geochemistry, and dispersed organic matter (DOM) maceral analysis has been used to determine the thermal maturity of Oligocene source rocks in two neighboring offshore wells within the complex deep-sea system of the Northwestern Black Sea. The samples contain predominantly immature Type II kerogen, including a mixture of marine liptinite (alginite, liptodetrinite), degraded liptinite, primary vitrinite, and reworked vitrinitic macerals. The occurrence of several vitrinite reflectance (VR_o) populations in the samples is attributed to a high influx of reworked vitrinite transported to the marine basin from multiple terrestrial sources with diverse degrees of degradation. The presence of multiple VR_o populations complicates the application of VR_o for determining the thermal maturity of the organic matter. Further, the VRo measurements on the primary vitrinite population show only a subtle increasing trend with depth. A significantly improved thermal maturity resolution was obtained using the red to green quotient (R/G). R/G was measured on the autochthonous unicellular <em>Tasmanites</em>-type alginite under UV-excitation. In contrast to VR_o the results show a significant correlation between increasing R/G values with increasing depth. This indicates that the R/G quotient is a better maturity proxy for the studied low maturity marine system with a large influx of sediments. The beginning of the downward declining trend in the temporal variation of liptinite is regarded as the onset of catagenesis. This occurs at a burial depth of 2.5 km and a R/G value of 0.50, corresponding to a VR_o equivalent (VR_{o Eq}) of 0.44%. At a burial depth of 3.2 km and a R/G value of 0.57 (VR_{o Eq} = 0.57%), the onset of the oil window is marked by an increase in the amount of solid bitumen (initial oil solid bitumen). The observed alterations in maceral composition with burial depth align with the thermal maturity of the wells. However, the data suggest that the thermal evolution of the organic matter is out of sync with the surrounding formation temperature, possibly due to rapid burial induced by a high sedimentation rate.</p></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0166516224000533/pdfft?md5=c25dfaa5878aa022d98e07e9e6b20c57&pid=1-s2.0-S0166516224000533-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140205789","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Solid bitumen as an indicator of petroleum migration, thermal maturity, and contact metamorphism: A case study in the Barrandian Basin (Silurian - Devonian), Czech Republic","authors":"Václav Suchý ,&nbsp;Ivana Sýkorová ,&nbsp;Jiří Zachariáš ,&nbsp;Kateřina Pachnerová Brabcová ,&nbsp;Petr Dobeš ,&nbsp;Martina Havelcová ,&nbsp;Ivan Rozkošný ,&nbsp;Qingyong Luo ,&nbsp;Weixun Cao ,&nbsp;Jin Wu ,&nbsp;Petra Mácová ,&nbsp;Alberto Viani ,&nbsp;Ivo Svetlik ,&nbsp;Daniel Maxa","doi":"10.1016/j.coal.2024.104493","DOIUrl":"10.1016/j.coal.2024.104493","url":null,"abstract":"<div><p>Silurian and Devonian marine shales and limestones of the Barrandian Basin host abundant black solid, non-fluorescing bitumens that fill tectonic fractures and veins, and occlude fossil moulds and diagenetic concretions. Solid bitumen, interpreted as thermally degraded petroleum, entered the rocks during several successive episodes of fracture-bound petroleum migration that occurred during deeper burial of the strata. Regional distribution of bitumen reflectance values that range between ∼0.9–2.3% R_r, correlate with variations of its FT-IR and Raman spectroscopic characteristics and aromatic hydrocarbon composition, and collectively evidence the maturity trend increasing across the basin from the southwest to the northeast. The reflectance of chitinozoans and graptolites (∼0.8–1.9% R_r) in the country rocks and homogenization temperatures of hydrocarbon fluid inclusions document palaeotemperatures ranging between ∼90–150 °C, characteristic of the oil window zone grading into the gas/condensate zone. Although in a basin-wide perspective the averaged values of solid bitumen and zooclast optical reflectance converge and indicate the same northeastern-increasing regional diagenetic trend, solid bitumen reflectance values vary considerably at individual localities and even within some bitumen samples. The wide scatter of optical reflectance values and the heterogeneity of optical properties, which were attributed to the presence of multiple source rocks in the basin, the variable lithology of bitumen host rocks, or other variables, hamper the use of solid bitumen as a simple alternative to zooclast/vitrinite reflectance palaeothermometers in a given basin. On the other hand, the highly anisotropic domain and the mesophase “coking” textures of the solid bitumen that were recognized in the NE part of the basin provide unique evidence on an anomalous, hitherto unrecognized, geologically short-lasting thermal event that affected the Palaeozoic rocks. A line of indirect evidence suggests that the coking of the bitumen was caused by a cryptic intrusion, possibly a concealed branch of the Central Bohemian Pluton, which intruded into the strata during the Variscan orogeny. More rarely occurring semi-solid, vividly yellow fluorescing waxy bitumen, that postdates solid bitumen in some fractures and voids, does not reveal a regional thermal maturation trend. It precipitated from relict waxy oils that migrated through the strata during a post-Neogene uplift of the Barrandian region.</p></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140205786","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Novel insights about petroleum systems from source and reservoir rock characterization, Cretaceous Deposits, Babouri-Figuil Basin, Northern Cameroon","authors":"W. Gaspard Owona Manga ,&nbsp;Javin J. Hatcherian ,&nbsp;Paul C. Hackley ,&nbsp;Moise Bessong ,&nbsp;Carole L. Bapowa ,&nbsp;Henri E. Pougue ,&nbsp;Arsène Meying","doi":"10.1016/j.coal.2024.104491","DOIUrl":"10.1016/j.coal.2024.104491","url":null,"abstract":"<div><p>The Babouri-Figuil Basin (BFB) is a frontier basin for petroleum in Cameroon. It belongs to the series of Cretaceous rift basins of the West and Central Rift System (WCARS), the origin of which is related to the opening of the South Atlantic. Within the same rift system, commercial hydrocarbon accumulations have been discovered in Chad, Sudan, Niger and, more recently, in Nigeria (Gongola Basin). The study of the geology of the BFB just recently received considerable attention, mainly because of its presumed hydrocarbon potential. In the pursuit of researching possible petroleum systems in the BFB, the current study provides a first look into the characterization of source and reservoir rock and its integration into a 2D lithostratigraphic model. The study was solely based on outcrop samples. Black shale and massive claystone are good to excellent hydrocarbon source rocks [e.g., up to 38 wt% total organic carbon (TOC), up to 943 mg/g hydrogen index, up to 85 m thickness, up to 20–30 km lateral extension], with moderate to high values of extractable organic matter (e.g., &gt;10,000 ppm). Calcareous claystone, on the other hand, are poor source rocks [e.g., &lt;0.20 wt% TOC]. The samples are thermally immature, except for those located close to volcanic intrusion at Golombe that have reached the threshold for oil generation (Tmax &gt;435 °C, production index &gt;0.1). The petrographic analysis of sandstone revealed that they are fine-grained to coarse-grained, poorly to moderately sorted, texturally and compositionally immature to submature, subarkosic to arkosic arenites. The main diagenetic processes that affected sandstones are as follows: moderate to intense compaction characterized by the development of long, concavo-convex, and sutured contacts between grains; cementation through calcite, iron oxide, and quartz cements; alteration of mica and feldspar grains; partial to complete dissolution of feldspar, mica, amphibole grains, and calcite cement; and the replacement of feldspar and mica grains by clay minerals. Alteration and dissolution increase the porosity of sandstone through the creation of secondary pores. However, mechanical compaction through the development of a pseudomatrix and cementation as pore-filling materials have significantly reduced the quality of sandstone beds as conventional petroleum reservoirs. Hence, the best reservoir-quality sandstones in the basin are generally located in the upper portion of the basin in terms of its lithostratigraphic model. They are the cleanest sandstones with the smallest amount of cement and the lowest ductile grain content (pseudomatrix), with a thickness that varies from 3 m to 120 m and a lateral extension of 20 km. The lithostratigraphic model of the basin is characterized by an extensive lacustrine environment that provided a thick sequence of organic-rich formations; sand deposited as extensive reservoirs sandwiched between shale/claystone beds; the development of stratigraphic ","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140142226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Evaluating the impact of artificial maturation on the petrophysical and geochemical properties of unconventional shale formations by integrating dielectric and NMR measurements","authors":"Amjed Hassan ,&nbsp;Mahmoud Elsayed ,&nbsp;Ali Oshaish ,&nbsp;Salah Al-Ofi ,&nbsp;Ammar El-Husseiny ,&nbsp;Israa S. Abu-Mahfouz ,&nbsp;Mohamed Mahmoud ,&nbsp;Mohamed Abouelresh ,&nbsp;Hussein Attia","doi":"10.1016/j.coal.2024.104492","DOIUrl":"10.1016/j.coal.2024.104492","url":null,"abstract":"<div><p>This paper addresses challenges in characterizing unconventional shale reservoirs. For the first time, the nuclear magnetic resonance (NMR) and dielectric responses are integrated to characterize intact, saturated, and kerogen-rich subsurface shale samples at various maturation stages. The NMR and dielectric were measured separately using independent pieces of equipment, and all NMR and dielectric measurements were carried out at surface conditions. A comprehensive assessment is provided to address the changes induced by maturation through combined geochemical and petrophysical analyses. Shale samples from the Upper Cretaceous sequence of Jordan were characterized using Rock-Eval analysis, before and after maturation treatments. The total organic carbon (TOC) was decreased from 17.4 to 13.8 and 11.3 wt% and the pyrolyzed sulfur content was decreased from 3.32 to 0.25 and 0.15 3.18%, after maturing the samples at 250 °C for 1 and 5 days, respectively. The study employed NMR to track changes in pore structure via <em>T</em>_<em>2</em> relaxation time and measured dielectric properties and conductivity dispersion across frequencies from 10 MHz to 1 GHz using a wideband open-ended coaxial probe. After the maturation treatments, the dielectric constant of saturated shale samples doubled, and the conductivity increased by over three times. These changes in dielectric properties can be attributed to increased fluid-rock interfacial polarization and the formation of new pore spaces during maturation. NMR findings also indicated the emergence of a new pore system within the organic matter and the development of new fractures, resulting in a 6 to 12% increase in total porosity. The results obtained indicate that maturation-induced microstructural changes have a more significant influence on the dielectric responses than alterations on total organic carbon.</p></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140142230","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Depositional conditions, wildfires, maturity, and hydrocarbon potential evaluation of Central Carpathian Paleogene Basin based on integrative approach from Orava Basin","authors":"Dorota Staneczek ,&nbsp;Dariusz Więcław ,&nbsp;Leszek Marynowski","doi":"10.1016/j.coal.2024.104490","DOIUrl":"10.1016/j.coal.2024.104490","url":null,"abstract":"<div><p>Central Carpathian Paleogene Basin (CCPB, Central Western Carpathians) comprises mainly Oligocene clastic autochthonous age-equivalents of the widely known Menilite shale formation from the Outer Carpathians. However, little is known about the paleoenvironment and its subsequent changes during the basin's evolution. Furthermore, the available hydrocarbon potential data are based on anachronous methods and are not investigated on the sub-basin level. Gas chromatography-mass spectrometry (GC–MS) analyses supported by Rock-Eval data along with petrographic measurements enabled us to identify and document the paleoenvironmental evolution of the Orava sub-basin (NW remnant of CCPB). Thermal maturity based on vitrinite reflectance, 22S/(22S + 22R) homohopane ratio and 20S/(20S + 20R) sterane ratio increases from N to S and from Upper to Lower Oligocene. In the least mature samples ββ-hopanes, hopenes, and oleanenes are present, whereas in the most mature deposits less thermally stable compounds dissapeared. This maturation trend is shown also by the Rock-Eval data. Terrestrial organic matter input is documented by the predominance of III- and II/III-type of kerogen and the occurrence of several biomarkers, such as 3,3,7-trimethyl-1,2,3,4-tetrahydrochrysene, cadalene, retene, and perylene. The significant contribution of polycyclic aromatic hydrocarbons (PAHs) may be linked with wildfire-related land degradation and following runoff to the basin. Based on the measured fusinite reflectance values the wildfire types could range from hotter crown fires to colder surface fires. Depositional conditions in Lower Oligocene units are characterized by intermittent euxinia, as derived from small (&lt;5 μm) pyrite framboid diameters and the presence of isorenieratane. Subsequently, a change of conditions to oxic/dysoxic in younger units is observed, and the input of terrestrial organic matter increased.</p></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140142222","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Burial and thermal history modeling of basins in convergent oblique-slip mobile zones: A case study of the Ardmore Basin, southern Oklahoma","authors":"Ian A. Cox,&nbsp;Jack C. Pashin","doi":"10.1016/j.coal.2024.104486","DOIUrl":"10.1016/j.coal.2024.104486","url":null,"abstract":"<div><p>The burial and thermal history of sedimentary basins within oblique-slip mobile zones are unique and multifaceted, with irregular periods of subsidence that are closely related to compressional and shear stress. Modern basin modeling techniques can constrain the timing of tectonic events and thermal history as well as determine rates and magnitudes of basin subsidence, which in turn, helps guide exploration for hydrocarbons. The work presented here is the first modern basin modeling effort in the Ardmore Basin in southern Oklahoma. The study uses 12 one-dimensional burial history models to evaluate the thermal maturity of the Late Devonian (Famennian)–Early Mississippian (Tournaisian) Woodford Shale and the Early–Late Mississippian (Tournaisian–Serpukhovian) Caney Shale hydrocarbon source rocks. All models display a similar tectonic evolution with subsidence during and following Cambrian Iapetan rifting, tectonic stability during a Silurian–Late Mississippian passive margin phase, Pennsylvanian synorogenic subsidence, Permian post-orogenic subsidence, Late Permian–Early Cretaceous regional uplift and unroofing, and Early Cretaceous–Paleogene subsidence of the Gulf of Mexico Basin. Episodic Pennsylvanian subsidence appears to have been synchronous with sequential uplift of the Wichita Uplift and the Arbuckle Uplift in response to major left-lateral transpression. Rapid and high magnitude Late Mississippian–Permian subsidence (&gt;250 m/m.y.; 820 ft/m.y. in basin synclines) suggests the Ardmore Basin functioned episodically as an elevator basin, which is typical of sedimentary basins in oblique-slip mobile zones. The Devonian–Mississippian shale section has a broad range of thermal maturity (vitrinite reflectance, 0.40–2.00% R_o), which is strongly dependent on structural position. Isoreflectance lines are subhorizontal and cross-cut structure, indicating post-kinematic thermal maturation in which strata are thermally immature in uplifts and thermally overmature in the deepest synclines. The post-kinematic pattern is a product of a rapid, early phase of synkinematic thermal maturation that has been obscured by a prolonged period of post-kinematic thermal maturation. Variations in basal heat flow, structural history, and general variability of hydrocarbon source rock organic composition, particularly at low thermal maturity levels, have resulted in a modest degree of scatter in the vitrinite reflectance-depth data.</p></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140142208","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Paleovegetation and environment during deposition of the Late Oligocene sub-bituminous coal in the Bobov Dol Basin (SW Bulgaria) as deduced from petrographic and geochemical characteristics","authors":"Alexander Zdravkov ,&nbsp;Achim Bechtel ,&nbsp;Doris Groβ ,&nbsp;Ivan Kojić ,&nbsp;Ksenija Stojanović ,&nbsp;Dragana Životić","doi":"10.1016/j.coal.2024.104489","DOIUrl":"https://doi.org/10.1016/j.coal.2024.104489","url":null,"abstract":"<div><p>Coal and carbonaceous shale samples were taken from the Late Oligocene Bobov Dol Basin, SW Bulgaria. Seams I^a, I, II^a+b, III, IV and V from the coal-bearing Bobov Dol Fm. were sampled to provide insights into the peat forming vegetation and depositional environment based on detailed organic petrological and geochemical study.</p><p>The petrographic composition indicates that both coals and carbonaceous shales contain predominantly terrestrial organic matter with abundant huminite macerals and locally enriched liptinite macerals. Inertinite is rare or absent. Good tissue preservation in seams I, IV and V indicates deposition under wet sedimentary environment, whereas predominance of detrohuminite and lower Tissue Preservation Index (TPI) in seams I^a, II^a+b and III are linked to enhanced humification of the plant remains due to changes in the hydrological regime. The low percent of inertinite and the overall high Gelification Index (GI), however, argue for peat formation under wetter climatic settings, whereas low to moderate ash yields of coal samples indicate organic matter deposition in oligo- to mesotrophic topogenous mires. Reconstructed evolution of the environmental settings during peat formation denotes differences which might be caused by changes in the hydrological regime and tectonic activity.</p><p>The biomarker composition shows prevalence of gymnosperm-derived sesqui- and diterpenoids, followed by lower concentration of <em>n</em>-alkanes (apart from the carbonaceous shale samples from seam I^a), whereas angiosperm-derived non-hopanoid triterpenoids, acyclic isoprenoids, steroids and hopanoids, are generally present in minor amounts. Diterpenoid composition indicates dominant contribution from <em>Cupressaceae and Pinaceae</em> conifers. Minor amounts of predominantly lupane-type non-hopanoid triterpenoids denote limited development of angiosperm vegetation, presumably mostly related to <em>Betulaceae</em> family. Relative abundance of mid-chain (<em>n</em>-C₂₁_–₂₅) <em>n</em>-alkanes, associated with elevated proxy ratio (Paq) furthermore, suggest possible contribution from aquatic macrophytes to peat formation. Very low hopane concentrations and low/moderate ββ/(ββ + αβ) hopane ratios imply minor aerobic bacterial activity under mild acidic conditions. The presence of inorganic carbon suggests that environmental acidity might be controlled by the occasional input of neutral to slightly alkaline ground waters. Moderate sulfur contents and the occurrence of hopenes denote anaerobic bacterial activity after organic matter burial.</p><p>Low maturity of the organic matter and limited hydrocarbon generation potential is indicated by the low huminite reflectance, hopane (C₃₁ 22S/(22S + 22R)) and sterane (αααC₂₉ 20S/(20S + 20R)) isomerization ratios, as well as Rock-Eval parameters, T_max and Production Index (PI).</","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0166516224000466/pdfft?md5=58097d7fb199eb77d4664ea947499359&pid=1-s2.0-S0166516224000466-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140113386","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Depositional environmental controls on mechanical stratigraphy of Barakar Shales in Rajmahal Basin, India","authors":"Chinmay Sethi ,&nbsp;Bodhisatwa Hazra ,&nbsp;Mehdi Ostadhassan ,&nbsp;Hem Bahadur Motra ,&nbsp;Arpan Dutta ,&nbsp;J.K. Pandey ,&nbsp;Santosh Kumar","doi":"10.1016/j.coal.2024.104477","DOIUrl":"10.1016/j.coal.2024.104477","url":null,"abstract":"<div><p>Understanding mechanical behaviour of shale is essential for efficient shale gas extraction, which can vary in different depositional settings. The impact of sedimentary environment on shale characteristics, such as mineralogical composition, total organic carbon content (TOC), and petrophysical properties, has been extensively researched. However, its influence on shale mechanical properties, especially in defining mechanical stratigraphy for targeting specific fracturing intervals, remains less explored. In this study, the influence of depositional environment on the mechanical properties of shale samples from the Rajmahal Basin is evaluated. Tensile strength of the samples was measured by the Brazilian splitting tensile strength and the brittleness index was calculated as a measure of mechanical properties. In addition, inductively coupled plasma optical emission spectroscopy (ICP-OES), X-ray fluorescence spectroscopy (XRF), Rock-Eval 6, and X-ray diffraction (XRD) analysis were carried out to assess geochemical characteristics of the samples from different perspectives. The results revealed that such geochemical variations that are generally controlled by the depositional environment, would impact the mechanical properties of the samples. Based on major and trace elements proxies, the depositional environment was determined to be passive continental margin, with hot and humid paleoclimatic conditions and freshwater anoxic settings. Tensile strength and brittleness index of the shale samples was observed to vary between 0.93 and 4.12 MPa and 0.71 to 3.40, respectively, while samples with the TOC exceeding 15 wt% had a strong negative correlation with tensile strength, as reasonably expected, due to weakening impact of the sedimentary organic matter on the shale matrix. Tensile strength and brittleness index correlated positively with clay mineral content, particularly their type, but negatively with the quartz content. Furthermore, samples abundant in biogenic silica exhibited reduced brittleness compared to those with lithogenic silica. Nevertheless, the variation in mechanical properties with burial depth was not substantial, and the examination of stress-strain curves indicated an overall brittle nature of the layer where the samples were retrieved from. Overall, achieving more robust conclusions regarding mechanical stratigraphy within the studied section of the Rajmahal Basin, would necessitate additional vertical sampling.</p></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S016651622400034X/pdfft?md5=bd21868cdd4fd641dff8cbd837f24e75&pid=1-s2.0-S016651622400034X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140069814","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}