Journal of ISASPub Date : 2024-01-31DOI: 10.59143/isas.jisas.2.3.bsvg2322
Kshama Balapure, Vinay Bhandari
{"title":"Molecular Docking Analysis for Evaluating the Efficacy of Active Components of Essential Oils against Water-Borne Multi-Virulent Bacteria and Virus","authors":"Kshama Balapure, Vinay Bhandari","doi":"10.59143/isas.jisas.2.3.bsvg2322","DOIUrl":"https://doi.org/10.59143/isas.jisas.2.3.bsvg2322","url":null,"abstract":"Traditional Indian knowledge of Ayurveda mentions a large number of essential oils that contain many active compounds such as thymol, eugenol and cinnamaldehyde etc. which contemplate nontoxic for human being and have been used mostly in the field of medicine. An application of essential oils comprising antimicrobial activities was recently described in the SWASTIIK technology (Safe Water and Sustainable Technology Initiative from Indian Knowledgebase) in conjunction with cavitation/ intense mixing for drinking water treatment. Further, it is intended to demonstrate the efficacy of SWASTIIK technology to combat multi virulent bacteria and emerging viruses such as Escherichia coli and SARS-CoV-2 (Severe Acute Respiratory Syndrome Coronavirus-2) respectively with the help of in silico computational tools. Docking study indicated eugenol and thymol were the most effective ligands against the microorganisms, although SARS-CoV-2 performed better with a low binding affinity (-7.2 kcal/mol) than multi-virulent E. coli (-4.5 kcal/mol). SWASTIIK technology for eliminating harmful microorganisms is, therefore, expected to be more effective in combating viruses, including SARS-CoV-2. Further, favorable ADMET results suggest suitability of the active components for further clinical trials study or for possible health benefits of water treated using SWASTIIK technology. In view of lack of human studies, to evaluate the effectiveness and safety of essential oils for direct intake, clinical trials with more well-designed protocols are needed.","PeriodicalId":136251,"journal":{"name":"Journal of ISAS","volume":"339 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140473267","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Journal of ISASPub Date : 2024-01-31DOI: 10.59143/isas.jisas.2.3.krgm6017
Anoop Krishnan
{"title":"Aquatic Pollution – Concerns and Abatement by Imtiyaz Qayoom, Adnan Abubakr, Anu Gopinath, Shabir.A. Dar & Keezia Khurshid","authors":"Anoop Krishnan","doi":"10.59143/isas.jisas.2.3.krgm6017","DOIUrl":"https://doi.org/10.59143/isas.jisas.2.3.krgm6017","url":null,"abstract":"","PeriodicalId":136251,"journal":{"name":"Journal of ISAS","volume":"246 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140476009","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Journal of ISASPub Date : 2024-01-31DOI: 10.59143/isas.jisas.2.3.laoi5364
Pradeep Kumar
{"title":"Modelling of CO2 Sequestration in Deep Saline Aquifer Reservoir using Surface Evolver Software","authors":"Pradeep Kumar","doi":"10.59143/isas.jisas.2.3.laoi5364","DOIUrl":"https://doi.org/10.59143/isas.jisas.2.3.laoi5364","url":null,"abstract":"A strategy to mitigate CO2 concentration in the atmosphere is injection of supercritical CO2 in porous sedimentary medium filled with saline water where CO2 gets trapped in the pores. Sequestration is resultant of two processes, drainage and imbibition in accordance with capillary law. Simulation of the pore-scale trapping has been performed on reservoir scale. A simple model reservoir consisting of 1000 tetrahedral subunits was constructed. Using Surface Evolver software, pore volueach subunit. The CO2 pressure and liquid saturation curves of the reservoir displayed hysteretic character, indicating that the evolution of the system is pathway-dependent. The simulated curves illustrate the pathway dependency of the residual gas saturation, an important parameter controlling the amount of CO2 stored in the reservoir, hence the efficiency of the CO2 storage. Our study also shows the existence of critical thresholds in terms of in/out gassing during the drainage or imbibition processes","PeriodicalId":136251,"journal":{"name":"Journal of ISAS","volume":"795 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140474382","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Journal of ISASPub Date : 2024-01-31DOI: 10.59143/isas.jisas.2.3.uoor3254
Sutanuka Roy, M. Anitha, Rajak Syed, Sukalyan Basuand, D. K. Singh
{"title":"Synergistic Extraction of Erbium(III) by n-Octyl Phenyl Phosphinic Acid (OPPA) with Oxine and 2-Methyl Oxine in Different Diluents","authors":"Sutanuka Roy, M. Anitha, Rajak Syed, Sukalyan Basuand, D. K. Singh","doi":"10.59143/isas.jisas.2.3.uoor3254","DOIUrl":"https://doi.org/10.59143/isas.jisas.2.3.uoor3254","url":null,"abstract":"The synergistic extraction of erbium (III) was investigated using n-octyl phenyl phosphinic acid (OPPA) in combination with oxine and 2-methyl oxine in different diluents. The extraction efficiencies of these synergistic extractants for erbium were measured as a function of extractant concentration, pH, temperature and diluents. The composition of extracted species determined by slope analysis method indicates the formation of [Er(HA2)3(HOX)]org complex and was also confirmed by Infrared spectroscopy. Based on the experimental data, the values of the equilibrium constants as well as synergistic coefficients have been calculated. Both the donors (oxine/2-methyl oxines) exhibited almost similar synergistic effect with OPPA. The extraction of erbium with these solvents was exothermic in nature. Diluent dependency on synergism for OPPA-oxine/2-methyl oxine system was explained in terms of regular solution theory of Hildebrand. Experimentally determined solubility parameter of ternary adduct was correlated with theoretically obtained values.","PeriodicalId":136251,"journal":{"name":"Journal of ISAS","volume":"390 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140473102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Journal of ISASPub Date : 2024-01-31DOI: 10.59143/isas.jisas.2.3.vras7769
M. Manuja, Tintu Thomas, Gijo Jose
{"title":"Temperature Assisted Ligand Conversion from 3R-MoS2 to α-MoO3 by Preserving Layered Nature","authors":"M. Manuja, Tintu Thomas, Gijo Jose","doi":"10.59143/isas.jisas.2.3.vras7769","DOIUrl":"https://doi.org/10.59143/isas.jisas.2.3.vras7769","url":null,"abstract":"All polymorphs of 2D MoS2 (1T, 2H & 3R) are layered with planes of molybdenum atoms sandwiched between two sulphur atoms (S-Mo-S layers) with intra planar covalent bonding and weak interlayer van der Waal’s interactions. Here in this work, the role of polyethylene glycol as surfactant in the formation of 3R-MoS2 is recognized. XRD and FTIR results provide structural elucidation and bonding information in the compound. More detailed crystal structure investigations and polyhedral visualizations were obtained in the Rietveld refinement procedure. The trigonal prismatic metal coordination in the 3R phase is portrayed with the ABC-ABC type layer stacking sequence. The morphology of layered 3R-MoS2 nanostructure was identified from HRTEM images and the percentage composition from FESEM mapping and EDAX analyses. Temperature dependent mass loss in the compound is monitored and the quantitative analysis confirms the complete transformation of 3R-MoS2 -MoO3 at a temperature of 398 °C. Endo and exothermic peaks in the DSC and DTA measurements help to substantiate the results. Thus the work highlights the temperature assisted conversion of sulphide (3R-MoS2 -MoO3) of molybdenum at 398°C by cleavage of S-S bonds and preserving the layered nature.","PeriodicalId":136251,"journal":{"name":"Journal of ISAS","volume":"460 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140478031","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Journal of ISASPub Date : 2024-01-31DOI: 10.59143/isas.jisas.2.3.yhoj2087
L. Ramapriya, J. Santhanalakshmi
{"title":"Photocatalytic Studies on Zinc Oxide Nanoparticles Doped with Selenium and Silicon Dioxides for Photodegradation of Lasix Drug","authors":"L. Ramapriya, J. Santhanalakshmi","doi":"10.59143/isas.jisas.2.3.yhoj2087","DOIUrl":"https://doi.org/10.59143/isas.jisas.2.3.yhoj2087","url":null,"abstract":"Metal oxide nanoparticles have taken a broad area of intense research because of their unique properties and application in diversified fields. Zinc oxide (ZnO) nanoparticles show varied morphologies and significant activities especially after doped with different metals. In this work, ZnO nanoparticles, Selenium dioxide (SeO2) doped Zinc oxide nanoparticles and Silicon dioxide (SiO2) doped Zinc oxide nanoparticles are synthesised by sol-gel method. The dopant effect on ZnO for band gap energy, crystal size and morphology are investigated by analysing the UV-DRS, powder X-ray diffraction and FESEM measurements respectively. The photocatalytic activities of these synthesised nanoparticles are compared by subjecting them into degradation of drug Lasix (furosemide) under UV and Solar irradiation sources. The progress of drug degradation is studied by measuring absorbance versus time interval at constant wavelength (325 nm) of the drug. The rate coefficient values found in this oxidative (H2O2) and reductive (NaBH4) catalytic degradation process of the drug is found efficient in solar irradiations. The results of characterisation studies and the order of photocatalytic activities of the nanoparticles are discussed.","PeriodicalId":136251,"journal":{"name":"Journal of ISAS","volume":"57 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140478782","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Journal of ISASPub Date : 2024-01-31DOI: 10.59143/isas.jisas.2.3.mudx2303
Usman Lawal Usman, S. Ellumalai, S. Anandh, Venkatesan Madha Suresh
{"title":"Chitosan-based Biogenic Nanoparticles for Wastewater Remediation: Synthesis, Characterization, and Applications - A Review","authors":"Usman Lawal Usman, S. Ellumalai, S. Anandh, Venkatesan Madha Suresh","doi":"10.59143/isas.jisas.2.3.mudx2303","DOIUrl":"https://doi.org/10.59143/isas.jisas.2.3.mudx2303","url":null,"abstract":"Wastewater pollution has been a global concern, necessitating the development of efficient and sustainable treatment technologies. Biogenic nanoparticles have emerged as a potential solution owing to their low cost, eco-friendliness, and high remediation efficiency. Among these nanoparticles, chitosan-based nanoparticles have gained significant attention for the treatment of wastewater. Chitosan, a biodegradable polysaccharide derived from chitin, possesses unique physicochemical properties that make it a suitable candidate for nanoparticle synthesis. The present review focuses on the synthesis, characterization, and applications of chitosan-based biogenic nanoparticles for wastewater remediation. Various synthesis methods, such as chemical cross-linking, precipitation, biosynthesis, solvent evaporation, and emulsion techniques are discussed. The characterization of chitosan nanoparticles using techniques such as transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and, Fourier-transform infrared spectroscopy (FTIR) among others were also highlighted to provide insights into their structural and chemical properties. Additionally, the applications of chitosan-based nanoparticles in wastewater remediation, including the adsorption of heavy metals, organic dyes, and pharmaceuticals, are discussed. Finally, the review concludes with a discussion of the prospects and potential research directions in employing chitosan-based nanoparticles for wastewater remediation","PeriodicalId":136251,"journal":{"name":"Journal of ISAS","volume":"342 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140471056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Journal of ISASPub Date : 2023-07-31DOI: 10.59143/isas.jisas.2.1.xgqp4076
K. Dimya, M. Potangale
{"title":"Removal of Ni (II) ions from aqueous solution using chitosan and activated carbon: isotherms and kinetics","authors":"K. Dimya, M. Potangale","doi":"10.59143/isas.jisas.2.1.xgqp4076","DOIUrl":"https://doi.org/10.59143/isas.jisas.2.1.xgqp4076","url":null,"abstract":"The present study deals with adsorption of Ni (II) ions from aqueous solution using chitosan (CHI) and activated carbon (ACC) as adsorbents. Several parameters such as pH, contact time, adsorbent dosage, concentration of adsorbate and radiation dose were varied to achieve an optimized adsorption of the metal ions. It was concluded that maximum removal of Ni (II) ions (92.2%) using CHI was observed at pH 3, dosage 1 g and contact time 240 min. Maximum removal of Ni (II) ions (82.3%) was achieved using ACC at pH 2, dosage 2.5 g for 120 min. The percentage removal of Ni (II) ions increases slightly after irradiation with Co-60. The adsorbents were characterized before and after irradiation and adsorption using FTIR and SEM techniques which clearly indicated the occurrence of adsorption of metal ions. Harkin-Jura and Jovanovic isotherms study indicated multilayer adsorption. The adsorption process follows pseudo-second-order kinetics.","PeriodicalId":136251,"journal":{"name":"Journal of ISAS","volume":"279 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122087101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Journal of ISASPub Date : 2023-07-31DOI: 10.59143/isas.jisas.2.1/epyi9445
S. O. Chetti, G. L. Kadam, S. Ghumatkar
{"title":"Cypermethrin insecticide in viscera of suspected snake bite case: A Forensic case study","authors":"S. O. Chetti, G. L. Kadam, S. Ghumatkar","doi":"10.59143/isas.jisas.2.1/epyi9445","DOIUrl":"https://doi.org/10.59143/isas.jisas.2.1/epyi9445","url":null,"abstract":"The present paper reports the use of analytical techniques in identifying the reason of the death of a suspect. After the death of an individual, a post-mortem examination was conducted. As part of the investigation, the viscera (I) and (II) were sent to the Mini Forensic Science Laboratory in Solapur. The Medical Officer, in their report, mentioned that no injuries or defensive marks were found on the body, except for a small prick mark or bite mark with clotted blood observed on the right foot, between the small toe and adjacent fingers. Upon cleaning the area, it was noticed that one spot was more prominent, while the other spot was faint. Since there were no eyewitnesses present at the crime scene, the police recorded in their inquest that the death might be a result of a snake bite. No formal complaint was registered at that time. However, the viscera samples were preserved for further examination and a final opinion. In the analysis of the viscera, techniques such as Thin-Layer Chromatography (TLC) and Gas Chromatography-Mass Spectrometry (GC-MS) were employed. The results of the analysis revealed that the cause of death was cypermethrin poisoning, as indicated by the presence of cypermethrin in the viscera samples","PeriodicalId":136251,"journal":{"name":"Journal of ISAS","volume":"71 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122931121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Journal of ISASPub Date : 2023-07-31DOI: 10.59143/isas.jisas.2.1.wfjr9779
N. Gokarn, K. Kiran
{"title":"Role of Lubricants in Industry: A Review","authors":"N. Gokarn, K. Kiran","doi":"10.59143/isas.jisas.2.1.wfjr9779","DOIUrl":"https://doi.org/10.59143/isas.jisas.2.1.wfjr9779","url":null,"abstract":"Lubricants are available in our daily lives for functioning as coolants, to dissipate heat and lubricate different surfaces which can be either in solid, liquid or gaseous forms. It reduces friction by the formation of thin film between two surfaces in contact and by improving efficiency and reducing wear. For any system to work efficiently and effectively appropriate lubricant is needed. Fresh lubricating oil needs to meet specifications of Original Equipment Manufacturers (OEMs). Applying lubricant regularly on tool increases life on usage and durability but a situation comes when the oil starts degrading may be due to depletion of additives or tool break down. Degraded oil is tested by using different physicochemical properties and also by employing different sophisticated analytical techniques like infrared spectroscopy (FTIR), Gas chromatography (GC), Inductively coupled plasma atomic emission spectroscopy (ICPAES), etc. In this article, we shall discuss some basics of lubrication, different lubrication regimes and various kinds of lubricants used for various industrial and automotive applications. Some case studies of oil and also their representative formulations, testing and interpretation of results is being presented for understanding of various lubricants.","PeriodicalId":136251,"journal":{"name":"Journal of ISAS","volume":"46 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122427314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}