Indonesian Journal of Chemistry最新文献_第8页

Simultaneous Analysis of Dopamine and Ascorbic Acid Using Polymelamine/Gold Nanoparticle-Modified Carbon Paste Electrode 使用聚丙烯酰胺/金纳米颗粒改性碳浆电极同时分析多巴胺和抗坏血酸

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Indonesian Journal of Chemistry Pub Date : 2024-02-01 DOI: 10.22146/ijc.83301

M. Harsini, Ainy Nur Farida, E. Fitriany, Denok.R. A. Paramita, A. Baktir, F. Kurniawan, S. Sakti, Yudhi Dwi Kurniawan, B. A. Widyaningrum

{"title":"Simultaneous Analysis of Dopamine and Ascorbic Acid Using Polymelamine/Gold Nanoparticle-Modified Carbon Paste Electrode","authors":"M. Harsini, Ainy Nur Farida, E. Fitriany, Denok.R. A. Paramita, A. Baktir, F. Kurniawan, S. Sakti, Yudhi Dwi Kurniawan, B. A. Widyaningrum","doi":"10.22146/ijc.83301","DOIUrl":"https://doi.org/10.22146/ijc.83301","url":null,"abstract":"Modification of electrode using polymelamine (PM) and gold nanoparticles (AuNPs) has been successfully developed via electropolymerization and electrodeposition onto carbon paste electrode (CPE) using cyclic voltammetry (CV) technique. The modified electrode (AuNPs/PM/CPE) was applied as voltammetry sensors in a simultaneous of dopamine (DA) and ascorbic acid (AA). AuNPs/PM/CPE presented an effective surface area 5 times wider than CPE and demonstrated good electrocatalytic performance in the oxidation of DA and AA in 0.1 M phosphate buffer solution (pH 3) with a scan rate of 100 mV s−1. The differential pulse voltammetry (DPV) technique was chosen as the best method for separating potential peaks of DA and AA. The linear response for determining DA and AA using the DPV technique produced a concentration range of 0.1–13 and 0.4–12 µM with coefficient linearity of 0.9999 and 0.9997, the limit of detection of 0.1405 and 0.2187 µM, the accuracy of 89.62–109.16%, and 83.63–105.08%, and the precision of 0.017–0.701% and 0.066–0.626%, respectively. In addition, this electrode was applied in a real sample of infant urine with a concentration of 1 µM by spike method and found 98.86 and 98.28% as percent recovery of DA and AA, respectively.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139827939","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Optical and Crystal Structure Properties of ZnO Nanoparticle Synthesized through Biosynthesis Method for Photocatalysis Application 通过生物合成法合成的 ZnO 纳米粒子在光催化应用中的光学和晶体结构特性

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Indonesian Journal of Chemistry Pub Date : 2024-02-01 DOI: 10.22146/ijc.84796

S. W. Suciyati, Posman Manurung, Junaidi Junaidi, Rudy Situmeang

{"title":"Optical and Crystal Structure Properties of ZnO Nanoparticle Synthesized through Biosynthesis Method for Photocatalysis Application","authors":"S. W. Suciyati, Posman Manurung, Junaidi Junaidi, Rudy Situmeang","doi":"10.22146/ijc.84796","DOIUrl":"https://doi.org/10.22146/ijc.84796","url":null,"abstract":"In this study, zinc oxide nanoparticles (ZnO NPs) were synthesized from zinc nitrate hexahydrate precursor and mango leaf extract (MLE). The purpose of this research was to investigate the crystal structure and optical properties exhibited by ZnO NPs for photocatalytic applications. ZnO NPs produced from various concentrations of sodium hydroxide (NaOH) and the addition of MLE during the synthesis stage demonstrated intriguing physical structure and optical properties. XRD characterization results revealed the attainment of a pure ZnO phase with a high crystallinity degree in all samples. Biosynthesis with MLE unveiled minor peaks corresponding to the cellulose phase. The achieved crystallite size ranged from 15–28 nm. The FTIR patterns detected in the wavenumber range of 600–4000 cm−1 indicated successful crystallization of all ZnO NPs samples. The band gap energy for each sample (ZnO-A to ZnO-E) is indicated to be in the range of 3.25, 3.25, 3.26, 3.31, and 3.17 eV, as demonstrated by the Tauc relation. The effect of MB degradation by the ZnO-E photocatalyst is revealed by the photodegradation of 96.46%.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139685076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Development of Magnetic-Silica Particles and In-house Buffers Kit for SARS-CoV-2 and CDV RNA Extraction 开发用于提取 SARS-CoV-2 和 CDV RNA 的磁性二氧化硅颗粒和内部缓冲液试剂盒

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Indonesian Journal of Chemistry Pub Date : 2024-02-01 DOI: 10.22146/ijc.83804

Ahadi Damar Prasetya, Muflikhah Muflikhah, W. Z. Lubis, Andon Insani, Grace Tjungirai Sulungbudi, M. Mujamilah, Uus Saepulloh

{"title":"Development of Magnetic-Silica Particles and In-house Buffers Kit for SARS-CoV-2 and CDV RNA Extraction","authors":"Ahadi Damar Prasetya, Muflikhah Muflikhah, W. Z. Lubis, Andon Insani, Grace Tjungirai Sulungbudi, M. Mujamilah, Uus Saepulloh","doi":"10.22146/ijc.83804","DOIUrl":"https://doi.org/10.22146/ijc.83804","url":null,"abstract":"Since the end of 2019, COVID-19 pandemic caused by the novel SARS-CoV-2 has become a serious problem for the world. Accurate and rapid techniques in testing and tracing are needed to control the virus spreading. Molecular diagnostics through gene amplification techniques, especially PCR, still become the gold standard for SARS-CoV-2 detection, which requires the first step of RNA extraction and purification. The limitations of commercial RNA extraction-purification kits during the pandemic caused a big problem in testing and tracing, especially for developing countries. A simple RNA extraction-purification kit based on magnetic-silica (MAGSi) beads and non-guanidine in-house buffers for RNA virus extraction-purification has been developed. Two types of MAGSi beads with different magnetic nanoparticles (MNPs) content were synthesized through a modified Stöber’s method using the sonication technique. The PCR result shows that both the MAGSi beads and the buffer can be used as a kit for RNA extraction-purification, tested for SARS-CoV-2 and Canine Distemper Virus. Further study shows that MAGSi-1 has better RNA extraction ability, and a higher concentration of RNA has been extracted. This is likely because of the smaller particle size distribution (50–1,500 nm distribution) and higher magnetization (20.2 emu/g) of MAGSi-1 compared to MAGSi-2 with 100–1,700 nm size distribution and 14.2 emu/g magnetization.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139890178","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hexahydro-1,2,3-triazine Derivatives: Synthesis, Antimicrobial Evaluation, Antibiofilm Activity and Study of Molecular Docking Against Glucosamine-6-Phosphate 六氢-1,2,3-三嗪衍生物：六氢-1,2,3-三嗪衍生物：合成、抗菌评估、抗生物膜活性以及针对葡萄糖胺-6-磷酸的分子对接研究

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Indonesian Journal of Chemistry Pub Date : 2024-02-01 DOI: 10.22146/ijc.85521

N. Ayrim, F. R. Hafedh, Yasir M. Kadhim, Abduljabbar Sabah Hussein, A. M. Abdula, Ghosoun Laftaa Mohsen, Mohammed Mahdi Sami

{"title":"Hexahydro-1,2,3-triazine Derivatives: Synthesis, Antimicrobial Evaluation, Antibiofilm Activity and Study of Molecular Docking Against Glucosamine-6-Phosphate","authors":"N. Ayrim, F. R. Hafedh, Yasir M. Kadhim, Abduljabbar Sabah Hussein, A. M. Abdula, Ghosoun Laftaa Mohsen, Mohammed Mahdi Sami","doi":"10.22146/ijc.85521","DOIUrl":"https://doi.org/10.22146/ijc.85521","url":null,"abstract":"The N,N',N''-trisubstituted hexahydro-1,3,5-triazine derivatives (3a–g) had been created and identified through infrared, nuclear magnetic resonance, and mass spectrometry according to their symmetric basic structure. Three molecules of diverse aromatic amines and three molecules of formaldehyde were assembled in a \"1+1+1+1+1+1\" condensation reaction to produce hexahydrotriazines. Two Gram-positive (Staphylococcus aureus, Staphylococcus epidermidis) and two Gram-negative (Klebsiella pneumonia, Pseudomonas aeruginosa) bacteria were used to evaluate the antimicrobial activity of the produced compounds. The anti-biofilm activity of 3g against S. aureus was also examined. In this investigation, glucosamine-6-phosphate synthase was employed to investigate the binding affinity of 3g within the enzyme's binding site. The results demonstrated that most of the synthesized hexahydro-1,3,5-triazine compounds have mild antimicrobial effects in comparison with the commonly used drug ampicillin, whereas the compounds 3g are potentially anti-biofilm agents. Molecular docking with the Autodock 4.2 tool was applied to study the binding affinity. It was found to hit (3g) in the active center of glucosamine-6-phosphate synthase as the target enzyme for antimicrobial agents. In silico studies reveal that the discovered hit is a promising glucosamine-6-phosphate inhibitor, as well as that the docking data matched up to the in vitro assay.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139831578","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Energy Efficiency of the Carbonate Hydroxyapatite Nanoparticle Synthesis Using Microwave Heating Treatment and Its Effect on Material Characteristics 利用微波加热处理合成碳酸盐羟基磷灰石纳米粒子的能效及其对材料特性的影响

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Indonesian Journal of Chemistry Pub Date : 2024-02-01 DOI: 10.22146/ijc.88155

Saifuddin Aziz, H. D. Pranowo, I. Ana, Yusril Yusuf

{"title":"Energy Efficiency of the Carbonate Hydroxyapatite Nanoparticle Synthesis Using Microwave Heating Treatment and Its Effect on Material Characteristics","authors":"Saifuddin Aziz, H. D. Pranowo, I. Ana, Yusril Yusuf","doi":"10.22146/ijc.88155","DOIUrl":"https://doi.org/10.22146/ijc.88155","url":null,"abstract":"This work aimed to study the energy efficiency of the synthesis process of carbonated hydroxyapatite (CHA) nanoparticles using microwave heating treatment and its effect on material characteristics. Microwaves can provide heat quickly, so it is expected to increase the efficiency of CHA synthesis through the heat provided. The CHA nanoparticles were synthesized using precipitation and heated using a microwave oven. The unheated and hydrothermal-heated precipitation methods were also conducted for comparison purposes. The microwave-heated precipitations were done at 270 W for 0.05, 0.10, and 0.15 h, while the hydrothermal-heated precipitations were done at 100 °C for 1, 2, and 3 h. The CHA materials were characterized using an infrared spectrophotometer, X-ray diffractometer, and electron microscope. The X-ray diffractogram and infrared spectra confirmed that the synthesized materials had a hydroxyapatite crystal phase with a CO32− functional group in their spectra. Microscopic images revealed that the materials were nanometer-sized grain aggregates. The heat treatment and duration increased the material characteristics, i.e., crystallinity, crystallite, and grain size. The CHA with microwave heat treatment had the highest crystallinity and crystallite size. The electrical energy calculation revealed microwave heating had better energy efficiency than hydrothermal heating.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139684554","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of Synthesis Temperature on Adsorbent Performance of Blending Anionic and Cationic Gels in Divalent Metal Ions Adsorption 合成温度对阴离子和阳离子凝胶混合吸附剂吸附二价金属离子性能的影响

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Indonesian Journal of Chemistry Pub Date : 2024-02-01 DOI: 10.22146/ijc.82104

E. O. Ningrum, Suprapto Suprapto, S. Altway, W. E. Triastuti, Afan Hamzah, Agus Surono, Lulu Sekar Taji, Erlangga Ardiansyah

{"title":"Effect of Synthesis Temperature on Adsorbent Performance of Blending Anionic and Cationic Gels in Divalent Metal Ions Adsorption","authors":"E. O. Ningrum, Suprapto Suprapto, S. Altway, W. E. Triastuti, Afan Hamzah, Agus Surono, Lulu Sekar Taji, Erlangga Ardiansyah","doi":"10.22146/ijc.82104","DOIUrl":"https://doi.org/10.22146/ijc.82104","url":null,"abstract":"In this study, the anionic and cationic gels were synthesized separately using copolymerization between N-isopropylacrylamide (NIPAM) and acrylic acid or chitosan through a polymerization reaction using N,N'-methylenebisacrylamide (MBAA) as a cross-linker with various monomer concentrations and synthesis temperature. The anionic and cationic gels were blended to minimize inter-intra particle association and to improve the adsorption ability. The FTIR analysis found that the synthesis of the NIPAM-co-acrylic acid and NIPAM-co-chitosan gels was successfully carried out, indicating no presence of a vinyl group in the functional group. The result showed that the ion adsorption amount of Pb2+ ions blending gels increased significantly, almost twice compared to the adsorption before blending. The adsorption amount of Pb2+ ions increased with increasing the gel synthesis temperature. The adsorption amount follows the order of Pb2+ > Fe2+ > Ni2+. The adsorption amount of Pb2+ tends to decrease with increasing sedimentation volume. The higher the synthesis temperature, the larger the porous diameter formed. These results demonstrate that blending gel of NIPAM-co-chitosan and NIPAM-co-acrylic acid is a feasible alternative for removing heavy metal ions owing to its good adsorption performance.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139685339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Design, Synthesis of New Imidazolium-1,2,3-triazole Hybrid Derivatives as Antimicrobial Agents 作为抗菌剂的新型咪唑-1,2,3-三唑杂化衍生物的设计与合成

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Indonesian Journal of Chemistry Pub Date : 2024-02-01 DOI: 10.22146/ijc.85704

A. S. Muttaleb, N. A. Berto, Sahar Adeeb Mamoori, Z. Alaridhee, E. K. Obaid, A. Radhi

引用次数: 0

Characteristic and Performance of Ni, Pt, and Pd Monometal and Ni-Pd Bimetal onto KOH Activated Carbon for Hydrotreatment of Castor Oil 用于蓖麻油加氢处理的 KOH 活性炭上的镍、铂、钯单金属和镍钯双金属的特性和性能

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Indonesian Journal of Chemistry Pub Date : 2024-02-01 DOI: 10.22146/ijc.84640

W. Trisunaryanti, T. Triyono, I. Falah, Dwi Bagus Wicaksono, S. Sumbogo

{"title":"Characteristic and Performance of Ni, Pt, and Pd Monometal and Ni-Pd Bimetal onto KOH Activated Carbon for Hydrotreatment of Castor Oil","authors":"W. Trisunaryanti, T. Triyono, I. Falah, Dwi Bagus Wicaksono, S. Sumbogo","doi":"10.22146/ijc.84640","DOIUrl":"https://doi.org/10.22146/ijc.84640","url":null,"abstract":"The preparation of highly efficient hydrotreating catalysts has presented a significant challenge in the field of catalysis. In this study, chemically activated carbon (AC) was prepared using potassium hydroxide (KOH) as an activator and Merbau wood as a lignocellulosic source for the AC. The AC was then impregnated with mono-metallic species (nickel, platinum, and palladium) as well as a bimetallic NiPd combination. The results revealed that the optimal KOH impregnation weight ratio was determined to be 2:1, resulting in a remarkably high iodine value of 751.94 mg/g. Subsequently, AC was employed as a support material for the hydrotreating of castor oil. Among the catalysts tested, the NiPd/AC catalyst demonstrated superior performance, yielding a liquid fraction comprising 88.80 wt.%. Within this fraction, C5-C12 hydrocarbons accounted for 15.16 wt.%, alcohol compounds constituted 71.69 wt.%, while the remaining 0.87 wt.% consisted of other components. Furthermore, the NiPd/AC catalyst exhibited remarkable stability, as its performance remained largely unchanged even after being used three times consecutively. This finding suggests that coking had minimal impact on the active sites of the mentioned catalyst, indicating its robustness and potential for prolonged application.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139820445","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Antibiofilm Efficiency of CaF2/TiO2 Strontium Borate Bioactive Glass Composites against Pseudomonas aeruginosa and Gamma Radiation Effect CaF2/TiO2 硼酸锶生物活性玻璃复合材料对铜绿假单胞菌的抗生物膜效率和伽马辐射效应

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Indonesian Journal of Chemistry Pub Date : 2024-02-01 DOI: 10.22146/ijc.84412

Eman Mohamed Abou Hussein, Noha Mohamed Abou Hussien, Sabrin Ragab Mohamed Ibrahim, Mahmoud Abdelkhalek Elfaky, Tamer Dawod Abdelaziz

{"title":"Antibiofilm Efficiency of CaF2/TiO2 Strontium Borate Bioactive Glass Composites against Pseudomonas aeruginosa and Gamma Radiation Effect","authors":"Eman Mohamed Abou Hussein, Noha Mohamed Abou Hussien, Sabrin Ragab Mohamed Ibrahim, Mahmoud Abdelkhalek Elfaky, Tamer Dawod Abdelaziz","doi":"10.22146/ijc.84412","DOIUrl":"https://doi.org/10.22146/ijc.84412","url":null,"abstract":"Microbial drug resistance has emerged as one of the most fundamental health threats. The current work aims to assess the antibacterial and antibiofilm potential of strontium borate bio-glasses (BBGs). Three CaF2/TiO2 strontium borate compositions have been prepared through melting annealing methods. The XRD pattern displays the amorphous nature of the glassy samples. The primary structural components of the borate, the trigonal BO3 and tetrahedral BO4 group, can be observed in FTIR spectra. Sharpness and shifting peaks to longer wavenumbers were evident after 40 kGy of gamma radiation. In contrast, density and molar volume (Vm) reveal an obvious change after irradiation. The agar diffusion technique was conducted as a preliminary screening of the antibacterial activity against Pseudomonas aeruginosa. The studied samples possessed no antimicrobial activity toward this strain; however, samples with 2% CaF2 strontium borate (T1) and 5% TiO2 strontium borate (T3) had higher biofilm inhibition potential (inhibition percentages of 75.17 and 65.77%, respectively). The gamma irradiation procedure had an unexpected detrimental effect on the bio-glass antibiofilm activity, making it unsuitable for use in sterilization procedures. Collectively, BBGs could be further investigated as possible antibacterial agents against biofilm-producing resistant strains.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139825371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Simultaneous Analysis of Dopamine and Ascorbic Acid Using Polymelamine/Gold Nanoparticle-Modified Carbon Paste Electrode 使用聚丙烯酰胺/金纳米颗粒改性碳浆电极同时分析多巴胺和抗坏血酸

IF 0.9

Indonesian Journal of Chemistry Pub Date : 2024-02-01 DOI: 10.22146/ijc.83301

M. Harsini, Ainy Nur Farida, E. Fitriany, Denok.R. A. Paramita, A. Baktir, F. Kurniawan, S. Sakti, Yudhi Dwi Kurniawan, B. A. Widyaningrum

{"title":"Simultaneous Analysis of Dopamine and Ascorbic Acid Using Polymelamine/Gold Nanoparticle-Modified Carbon Paste Electrode","authors":"M. Harsini, Ainy Nur Farida, E. Fitriany, Denok.R. A. Paramita, A. Baktir, F. Kurniawan, S. Sakti, Yudhi Dwi Kurniawan, B. A. Widyaningrum","doi":"10.22146/ijc.83301","DOIUrl":"https://doi.org/10.22146/ijc.83301","url":null,"abstract":"Modification of electrode using polymelamine (PM) and gold nanoparticles (AuNPs) has been successfully developed via electropolymerization and electrodeposition onto carbon paste electrode (CPE) using cyclic voltammetry (CV) technique. The modified electrode (AuNPs/PM/CPE) was applied as voltammetry sensors in a simultaneous of dopamine (DA) and ascorbic acid (AA). AuNPs/PM/CPE presented an effective surface area 5 times wider than CPE and demonstrated good electrocatalytic performance in the oxidation of DA and AA in 0.1 M phosphate buffer solution (pH 3) with a scan rate of 100 mV s−1. The differential pulse voltammetry (DPV) technique was chosen as the best method for separating potential peaks of DA and AA. The linear response for determining DA and AA using the DPV technique produced a concentration range of 0.1–13 and 0.4–12 µM with coefficient linearity of 0.9999 and 0.9997, the limit of detection of 0.1405 and 0.2187 µM, the accuracy of 89.62–109.16%, and 83.63–105.08%, and the precision of 0.017–0.701% and 0.066–0.626%, respectively. In addition, this electrode was applied in a real sample of infant urine with a concentration of 1 µM by spike method and found 98.86 and 98.28% as percent recovery of DA and AA, respectively.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139888223","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0