Polymer Engineering & Science最新文献

{"title":"Investigation of the effect of mass percentage concentration of polystyrene–toluene solution on the surface properties of the plasma‐treated polystyrene thin films","authors":"Farzad Aliabadizadeh, Vahid Siahpoush, Asal Pashabeiki Zadeh, Ataollah Eivazpour Taher","doi":"10.1002/pen.26863","DOIUrl":"https://doi.org/10.1002/pen.26863","url":null,"abstract":"Polystyrene (PS) finds diverse applications across various fields, often necessitating a hydrophilic PS surface. In this study, the PS films were prepared using PS–toluene solutions of 15, 20, and 25 mass percentage concentrations (% w/v). Here, the main focus is on the influence of concentration on the hydrophilization of the prepared PS thin films under atmospheric pressure air dielectric barrier discharge plasma treatment. The contact angle, surface energy measurements, atomic force microscopy, and Fourier‐transform infrared spectroscopy analysis were conducted to evaluate the PS surface properties. Our results demonstrate, for the first time, the significant role of concentration in altering surface properties; the lower concentration of PS films leads to the most hydrophilic surface. Fourier‐transform infrared spectroscopy analysis confirms an increase in the OH functional group on the PS surface. atomic force microscopy analysis reveals needle‐shaped surface morphology, increased roughness and an expanded effective surface area. Surface energy analysis confirms an increase in the polar sector of surface energy. Overall, the findings from this research underscore the increase in film hydrophilicity with a decrease in PS–toluene concentration.\u0000Polystyrene (PS)–toluene solutions with different concentrations were prepared.\u0000PS–toluene films were spin‐coated and were been treated with dielectric barrier discharge plasma.\u0000The contact angle, surface energy measurements, atomic force microscopy, and Fourier‐transform infrared spectroscopy analysis were conducted.\u0000PS films with lower concentration have more impact from plasma treatment.\u0000Concentration, impact the hydrophilicity and roughness of treated PS films.\u0000","PeriodicalId":134997,"journal":{"name":"Polymer Engineering & Science","volume":"91 11","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141922045","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhanced thermoregulation performance of knitted fabrics using phase change material incorporated thermoplastic polyurethane and cellulose acetate nanofibers","authors":"Çiğdem Akduman, N. Oğlakcıoğlu, A. Çay","doi":"10.1002/pen.26921","DOIUrl":"https://doi.org/10.1002/pen.26921","url":null,"abstract":"Nanofibers act as carriers in systems containing functional materials produced via electrospinning method. By this way, it is possible to transport functional materials with polymer nanofibers, besides having a large surface area compared to their volume, the encapsulation process, which includes complex preparation processes, is eliminated here, and functional materials such as phase‐change materials (PCMs) can be conveniently integrated directly into the carrier material by electrospinning method. The resulting nanofiber membrane can also be used in combination with textile fabrics. This study aims to develop PCM containing nanofibrous membrane coated knitted fabric structures with heat regulation capabilities. Two types of PCMs, hexadecane and octadecane loaded into thermoplastic polyurethane (TPU) and cellulose acetate (CA) nanofibers, directly electrospun on cotton (CO), cotton/polyester (CO/PES), cotton/acrylic (CO/PAC) knitted fabrics for thermoregulation. These nanofiber‐coated fabrics were characterized by scanning electron microscopy (SEM) and differential scanning colorimetry (DSC), and their comfort properties were evaluated by water vapor and air permeability tests and compared with a commercial microcapsule impregnated fabric. According to DSC results, PCM incorporated CA nanofibers had better heat storage capacity than TPU nanofibers and microcapsule applied fabrics. Although PCM‐loaded CA nanofibers may not block airflow as effectively as TPU nanofibers, when a proper coating is achieved air permeability can be decreased to 21.70 L/m2/s, along with a heat storage capacity of 26.38 J/g and still having permeability to water vapor (%40).\u0000Phase change materials were integrated directly to the carrier material by electrospinning\u0000PCM integrated nanofiber coating reduced air permeability\u0000PCM integrated nanofiber coating did not block water vapor permeability\u0000Electrspun cellulose acetate +PCM coating had better heat storage capacity\u0000","PeriodicalId":134997,"journal":{"name":"Polymer Engineering & Science","volume":"28 19","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141924645","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Assessing rheological properties of oxidized Moringa oleifera gum and carboxymethyl chitosan‐based self‐healing hydrogel for additive manufacturing applications","authors":"Mehul Verma, Jitendra Kumar, Abhinav Ayush Pradhan, Nilotpal Majumder, Sourabh Ghosh, R. Purwar","doi":"10.1002/pen.26915","DOIUrl":"https://doi.org/10.1002/pen.26915","url":null,"abstract":"Rheology plays a vital role in pneumatic three‐dimensional (3D) printing of hydrogels. This study investigates the rheological behavior of a novel self‐healing hydrogel (O‐MOG/CMCh) formed by a Schiff base crosslinking reaction between oxidized Moringa oleifera gum (O‐MOG), a biodegradable antimicrobial polysaccharide, and carboxymethyl chitosan (CMCh), a water‐soluble biocompatible chitosan derivative. Three hydrogel formulations were designed using 5% w/v of CMCh with varied concentrations of O‐MOG (3% w/v, 4% w/v, and 5% w/v) and evaluated through rheology analyses, including frequency sweeps, amplitude sweeps, oscillatory thixotropy, and gelation kinetics. These tests revealed that the material has shear thinning, self‐healing properties, a high linear viscoelastic region (LVE), and gel formation times (tgel) of 3.23–4.57 min. The hydrogel synthesized with 5% w/v of O‐MOG composition exhibited the best characteristics for printability based on rheological assessments, and this composition was used for further printing assessment, where bi‐layered 4 × 4 and 2 × 2 grids were successfully printed using 22 G (0.41 mm) and 23 G (0.34 mm) syringes. All the constructs had a printability index value of 1 ± 0.13 and spreading ratios <6.5, demonstrating the feasibility of employing the synthesized hydrogel as an acellular matrix via additive manufacturing.\u0000Self‐healing hydrogel was prepared by mixing the precursors through a cannula.\u0000Rheology was examined using standard tests for printability assessment.\u00003D printability was achieved using two different gauze syringes.\u0000Printability parameters were recorded and analyzed for the constructs.\u0000","PeriodicalId":134997,"journal":{"name":"Polymer Engineering &amp; Science","volume":"58 51","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141928890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Experimentation, identification, and simulation of polymer swelling at extrusion die outlets","authors":"F. Rabhi, Thierry de Larochelambert, T. Barriere, David Ramel, Thibault Cousin, Mohamed Sahli","doi":"10.1002/pen.26814","DOIUrl":"https://doi.org/10.1002/pen.26814","url":null,"abstract":"The behavior of polyamide PA12 melt extrudates at die outlets is modeled to determine swelling process and rate. It is assessed as a function of imposed input parameters, process parameters, and die geometries. The modeling is carried out using Comsol Multiphysics® platform to simulate the swelling; in particular, its progression in time is investigated for different extrusion process parameters. The experimental swelling observed in extrusion lines tests is compared with the Tanner and Carreau‐Yasuda rheological models. A database is built up with all experiments carried out; the comparison between numerical and experimental results shows close agreement. A parametric analysis of the experimental and numerical swelling is performed. It confirms the important role of the die diameter on swelling rate, independently of shear rate. Increase in temperature lowers swelling rate at constant shear rates and geometric aspect ratio of the dies.\u0000Experimental and numerical study of polymer swelling at capillary die outlets.\u0000Behavior of PA12 polymer extrudate modeled to determine its swelling.\u0000Rheological models implemented to simulate the swelling phenomenon.\u0000Simulation results validated with experimental tests for two millimetric dies.\u0000Influence of die geometrical parameters investigated and justified.\u0000","PeriodicalId":134997,"journal":{"name":"Polymer Engineering &amp; Science","volume":"28 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141646216","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Anisotropic polymer components with desired elastic properties manufactured through fused filament fabrication additive manufacturing","authors":"Alireza Bagheri Bami, F. Honarvar, Reza Teimouri","doi":"10.1002/pen.26842","DOIUrl":"https://doi.org/10.1002/pen.26842","url":null,"abstract":"Fused filament fabrication (FFF) is a popular additive manufacturing (AM) process, primarily used for fabricating polymer components. Optimizing the mechanical properties of FFF components, such as their elastic moduli, is crucial in many applications. This study focuses on adjusting the elastic properties of polymer components manufactured through FFF process by selecting appropriate process parameters. The elastic constants of the anisotropic FFF components are measured by using ultrasonic testing (UT). Response surface methodology (RSM) is employed to determine the optimal settings for these parameters to achieve the desired elastic properties. The effects of layer thickness, printing speed, and raster angle on Young's modulus are explored. Analysis of variance (ANOVA) is used to identify the contributions of each process factor on the output responses. According to ANOVA results, the optimal conditions identified are: a printing speed of 2040 mm/min, a layer thickness of 0.2 mm, and a raster angle of 29°. These conditions collectively achieved the maximum Young's modulus. The differences between the predicted and measured moduli for all responses are less than 5%. The structural factors influencing the results are examined by analyzing the fracture surfaces of the tensile testing (TT) specimens with field emission scanning electron microscopy. Additional measurements of other properties, including ultrasound velocity and wave attenuation, are conducted on the samples. The findings indicate that optimizing the parameters by setting them to their minimum values does not only improve the maximum elastic modulus in specific directions but also reduces attenuation. It is concluded that the desired elastic modulus for a component can be achieved by properly adjusting the process parameters.\u0000Optimizing AM parameters to achieve the desired elastic properties of FFF samples.\u0000Examining the effects of each AM parameter by utilizing ANOVA and RSM methods.\u0000Measuring the anisotropic elastic properties of AM samples by UT.\u0000Verifying UT results through TT and measuring attenuation.\u0000","PeriodicalId":134997,"journal":{"name":"Polymer Engineering &amp; Science","volume":"48 14","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141650764","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Morphology, viscoelastic properties and the mechanical performance of highly toughened polyamide 6/acrylonitrile–butadiene–styrene/polylactic acid ternary blends","authors":"A. Foroozan, Y. Jahani","doi":"10.1002/pen.26855","DOIUrl":"https://doi.org/10.1002/pen.26855","url":null,"abstract":"In this research, the morphology, rheology, and mechanical performance of polyamide 6/polylactic acid/acrylonitrile–butadiene–styrene (PA6/ABS/PLA) ternary blends were studied. The optimum ABS percentage in PA6/ABS binary blend to achieve highly toughened blend was determined around 35 wt.%. The spreading coefficient (Sij) predictions showed that each of PLA and ABS can form separate phase in the PA6 matrix. The evaluation of the interfacial interactions in the ternary blends revealed a higher tendency of PLA to interact with PA6 chains (Sij:−1.20) rather than ABS (Sij:−0.20) which is in comply with higher work of adhesion of PLA/PA6 than PLA/ABS and PA6/ABS. By adding PLA to the binary blends of PA6/ABS, it was found that the ABS domain size decreased due to rheological change. The localization of each component in the ternary blends observed in SEM analysis was in agreement with spreading coefficient predictions. Morphological evaluations revealed higher interfacial interactions between PA6 and PLA in the blends with up to 20 wt.% PLA. The optimized blend ratio of ternary blends showed higher complex viscosity at low shear rates and higher values than the mixing rule prediction. The optimum flexural modulus of 2 GPa and impact resistance of 47 kJ/m2 were achieved at 20 wt.% PLA in PA6/ABS/PLA ternary blend.\u0000The optimum PA6/ABS blend ratio to achieve high toughness was determined.\u0000The phase localization in the blends predicted via Spreading Coefficient.\u0000The interaction of PA6 and ABS enhanced by the addition of PLA in the blends.\u0000The mechanical properties of blends are correlated with rheological behavior.\u0000The flexural modulus of blends was higher than Halpin–Tsai model predictions.\u0000","PeriodicalId":134997,"journal":{"name":"Polymer Engineering &amp; Science","volume":"52 5","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141650156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Graphene oxide‐enhanced polyethersulfone/polysulfone forward osmosis membranes for Suez Canal water desalination","authors":"Mai A. Hassan, Gehad Hamdy, F. A. Taher, Sahar S. Ali, R. Sabry","doi":"10.1002/pen.26819","DOIUrl":"https://doi.org/10.1002/pen.26819","url":null,"abstract":"Forward osmosis (FO) has emerged as a highly promising and energy‐efficient technology for seawater desalination. This study investigates the enhancement of polyethersulfone/polysulfone FO membranes by incorporating graphene oxide (GO) for seawater desalination. The effects of different GO concentrations on membrane properties and FO desalination performance were examined. Among the tested membranes, the one with 0.04 wt% GO exhibited optimal hydrophilicity, as indicated by a lower contact angle (53.93° ± 5.61°), higher porosity (69.86 ± 0.66), and a minimal structure parameter (312.33 μm). The GO.04 membrane demonstrated significantly improved water flux (Jw) of 106 L/m2 h and low reverse salt flux (Js) of 0.69 g/m2 h. Compared to the GO0 membrane without GO, the water flux was 103% higher without compromising salt selectivity (Js/Jw = 0.0065 g/L) when using distilled water as the feed solution (FS) and 1 M NaCl as the draw solution. However, over a threshold of 0.09%, GO concentration on membrane surfaces and pores can impede water flow, reducing porosity and increasing resistance to membrane transport. The GO.04 membranes also exhibited high water flux (113, 94.28, and 84.64 L/m2 h) when brackish water with different NaCl concentrations (5000, 10,000, and 15,000 mg/L) was used as the FS. Moreover, under real seawater conditions from the Suez Canal, the GO.04 FO membrane showed a significantly higher water flux of 94.3 L/m2 h. These findings provide valuable insights into the desalination of actual seawater from the Suez Canal, offering significant potential for the advancement of water treatment and resource management practices.","PeriodicalId":134997,"journal":{"name":"Polymer Engineering &amp; Science","volume":"5 32","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141337094","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Dielectric properties of polypropylene blended with copolymers of varying ethylene contents","authors":"S. Kamarudin, K. Y. Lau, Noor Azlinda Ahmad, Nur Azalia Azrin, Kuan Yong Ching, A. B. A. Ghani, N. A. Arifin","doi":"10.1002/pen.26815","DOIUrl":"https://doi.org/10.1002/pen.26815","url":null,"abstract":"Polypropylene (PP) has recently been actively investigated as a potential power cable insulation substitute for crosslinked polyethylene (XLPE). This is mainly due to PP's higher thermal withstand capability over XLPE. Notably, PP has much higher stiffness than XLPE and therefore needs to be modified with tougher materials to reduce its overall stiffness while maintaining its desirable dielectric properties. To date, many investigations have been conducted on the mechanical and dielectric effects of PP blended with various copolymers. Nevertheless, systematic investigations on the dielectric effects of PP blended with ethylene‐based copolymers having different ethylene contents are less explored. The current work therefore reports on the impact of different ethylene contents of ethylene‐based copolymers on the breakdown performances of PP. The findings reveal that PP blended with a copolymer having a low ethylene content (68.7 wt%) results in at least 11% higher breakdown performance than PP containing a copolymer having a high ethylene content (77.0 wt%). Specifically, PP containing 10 wt% of copolymers having 68.7 wt% of ethylene content results in comparable breakdown performance to XLPE (325 kV mm−1). These results suggest that ethylene‐based copolymers with an appropriately low ethylene content can be blended with PP to achieve desirable breakdown properties.\u0000PP is blended with copolymers of varying amounts and ethylene contents.\u0000PP blended with low amounts of copolymers has good breakdown strength.\u0000PP blended with low ethylene level copolymers has favorable breakdown strength.\u0000PP blended with copolymers of low ethylene contents is desirable.\u0000The breakdown mechanisms are related with the structure and permittivity.\u0000","PeriodicalId":134997,"journal":{"name":"Polymer Engineering &amp; Science","volume":"84 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141338232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"3D‐printed PLA/PMMA polymer composites: A consolidated feasible characteristic investigation for dental applications","authors":"Arunkumar Thirugnanasamabandam, Ramasamy Nallamuthu, Malavika Renjit, Constance L. Gnanasagaran","doi":"10.1002/pen.26829","DOIUrl":"https://doi.org/10.1002/pen.26829","url":null,"abstract":"This research article focused on the blending of poly(lactic acid)/poly(methyl methacrylate) (PLA/PMMA) polymer materials to overcome PLA's inherent weaknesses, such as low glass transition temperature, brittleness, and lack of melt strength. Consolidated feasible characteristic investigations, such as mechanical, thermal, and aging behavior, were carried out for PLA/PMMA blended polymer materials. Initially, the miscibility of PLA/PMMA blend filaments was prepared at various blend ratios (91/9, 82/18, and 73/27) and samples were printed by fused deposition modeling (FDM). Differential scanning calorimetry (DSC) and Fourier infrared spectroscopy (FTIR) analysis have been utilized to evaluate the glass transition temperature (Tg) and intermolecular interaction, respectively, on blended polymer materials. Experimental tensile, compression, and flexural strength testing were performed on neat polymers and blended polymer composites. Compared to neat PLA materials, blended composites had 13.24% and 19.07% higher flexural and compression strengths. Besides, the interfacial interaction of neat and blended polymers has been done using dynamic mechanical analysis (DMA). Furthermore, Tg, storage modulus, and aging behavior of blended polymer materials have significantly improved over neat PLA materials. Altogether, the development of PMMA/PLA blends as sustainable biomaterials for dental applications aligns with environmental concerns and the need for biocompatible materials in dentistry.\u0000Blending of PLA and PMMA helps mitigate the inherent constraints of PLA.\u0000Blended composites exhibited greater compressive and flexural strengths.\u0000Better glass transition temperature and intermolecular interaction.\u0000Excellent thermal stability and water aging imply viable dental biomaterials.\u0000","PeriodicalId":134997,"journal":{"name":"Polymer Engineering &amp; Science","volume":"8 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141337488","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Discrete molecular weight strategy modulates hydrogen bonding‐induced crystallization and chain orientation for melt‐spun high‐strength polyamide fibers","authors":"Jinling Wang, Senlong Yu, Jialiang Zhou, Chengyao Liang, Weilei Huang, Zexu Hu, Ziye Chen, H. Xiang, Meifang Zhu","doi":"10.1002/pen.26832","DOIUrl":"https://doi.org/10.1002/pen.26832","url":null,"abstract":"Hydrogen bonding is the prerequisite for polyamide fibers to have better stress–strain behavior. It affects the crystal structure of polyamide fibers, such as orientation and periodic arrangement. To illustrate the effect of intermolecular hydrogen bonding on fiber orientation structure and macroscopic mechanical properties, this work uses conventional polyamide resin doped with high molecular weight components to construct polymer compounds with discrete distribution characteristics. By analyzing the changes in intermolecular hydrogen bonds, melt rheological properties, non‐isothermal crystallization behaviors, the impact of hydrogen bonds on the crystal structure and orientation structure and thus on the fiber strength was clarified. The doping of high molecular weight components can make the compound form more hydrogen bonds and inhibit the relaxation of molecular chains through entanglement, thereby promoting melt non‐isothermal crystallization process and increasing complex viscosity η* and storage mode G'. 1D and 2D wide‐angle and small‐angle X‐ray scattering show that doping components reduce crystal size of α1(200) and α2(002, 202) planes from 4.19 to 3.47 nm and 5.88 to 4.96 nm, resulting in a denser long‐period structure. Through the strategy of this work, polyamide 6 fibers' tensile strength is effectively improved by18%, and the mechanical properties are significantly improved.\u0000High‐strength polyamide compound fibers were prepared.\u0000Discretely distributed compounds are achieved.\u0000Discretely distributed molecular weight enabled hydrogen bonding regulation.\u0000Hydrogen bonding‐induced compound fiber crystal structure.\u0000Multiple external fields induced crystallization and orientation structures.\u0000","PeriodicalId":134997,"journal":{"name":"Polymer Engineering &amp; Science","volume":"33 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141344242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}