{"title":"Synthesis and characterization of highly substituted pyrazoles using silicaphosphoric acid nanoparticles as a recoverable heterogeneous solid acid catalys","authors":"","doi":"10.56042/ijct.v30i4.66505","DOIUrl":"https://doi.org/10.56042/ijct.v30i4.66505","url":null,"abstract":"Highly substituted pyrazoles have been prepared by condensing 1,3-diketones and various hydrazine derivatives using silica-phosphoric acid nanoparticles (nano-SPA). This nano solid catalyst has been prepared by the reaction of nano silica chloride with dry phosphoric acid. This green methodology has advantages such as short reaction times, simple work-up, high efficiency, reusability of the catalyst and no use of any solvents.","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"1 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70701638","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Multiphase pyrolysis of waste expanded polystyrene and in-situ hydrogenation of pyrolysis oil on silica-alumina supported nickel catalyst for the production of fuel range paraffinic and aromatic hydrocarbons","authors":"A. Verma, H. Pramanik","doi":"10.56042/ijct.v30i4.66513","DOIUrl":"https://doi.org/10.56042/ijct.v30i4.66513","url":null,"abstract":"In this work, thermal and catalytic pyrolysis of waste expanded polystyrene (WEPS) have been investigated in a laboratory designed semi-batch reactor in the temperature range of 400-700℃ and heating rate of 15 ℃/min to produce gasoline range lower paraffins and valuable aromatics i.e., benzene, toluene and ethylbenzene (BTE). Three different type of reactor arrangements i.e., liquid phase/A-type, vapour phase/B-type and multiphase/AB-type have been used to conduct the catalytic pyrolysis of WEPS using nickel on silica-alumina catalyst. The thermal pyrolysis of WEPS produced highest liquid yield of 94.37 wt.% at a temperature of 650℃ and heating rate of 15 ℃/min, whereas, liquid phase/A-type, vapour phase/B-type and multiphase/AB-type catalytic pyrolysis produced highest liquid yield of 88.54 wt.%, 83.21 wt.%, and 81.15 wt.%, respectively, at the same heating rate of 15 o C/min and at the temperature of 600℃, 550℃, and 550℃, respectively. The pyrolysis oil obtained from thermal pyrolysis mainly contains styrene monomer of 84.74 wt.% and very less BTE content of 11.38 wt.%. Among, the all types of catalytic pyrolysis, AB-type/multiphase pyrolysis produced pyrolysis oil with highest amount of BTE content of 28.56 wt.%. Furthermore, the pyrolysis oil obtained from A-type, B-type and AB-type catalytic pyrolysis contains low styrene content of 69.94 wt.%, 65.67 wt.% and 55.55 wt.%, respectively, as compared to thermal pyrolysis (84.74 wt.%).","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"6 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70701645","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Removal of lead (II) ion from industrial wastewater by activated carbon prepared from Vitex negundo using batch adsorption studies","authors":"","doi":"10.56042/ijct.v30i3.70662","DOIUrl":"https://doi.org/10.56042/ijct.v30i3.70662","url":null,"abstract":"","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"1 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70701884","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Electrochemical oxidation of textile effluents and further treatment by coupled system electrooxidation using Prosopis cineraria","authors":"","doi":"10.56042/ijct.v30i2.69010","DOIUrl":"https://doi.org/10.56042/ijct.v30i2.69010","url":null,"abstract":"","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"43 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70701919","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Performance test of dual fuel engine using octagonal with algae biodiesel","authors":"","doi":"10.56042/ijct.v30i2.69766","DOIUrl":"https://doi.org/10.56042/ijct.v30i2.69766","url":null,"abstract":"","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"1 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70701989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of high temperature resistant ZrO2-SiO2 composite aerogels via supercritical fluid deposition","authors":"","doi":"10.56042/ijct.v30i2.68707","DOIUrl":"https://doi.org/10.56042/ijct.v30i2.68707","url":null,"abstract":"","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"38 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70702049","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Experimental investigations of the production of methyl acetate in batch catalytic distillation process in the presence of Indion 180","authors":"","doi":"10.56042/ijct.v30i5.5208","DOIUrl":"https://doi.org/10.56042/ijct.v30i5.5208","url":null,"abstract":"As a novel study, esterification of acetic acid with methanol has been studied in a simple batch reactive distillation apparatus to produce methyl acetate as main product and water as byproduct. Novel solid catalyst named Indion 180 has been used in this esterification process. The product methyl acetate can be distilled out in two ways namely sequential and simultaneous reactive distillation. In the simple distillation batch process, first the reaction is carried out till the equilibrium with total reflux of vapours, and then distillation is carried out where the vapours are condensed and collected separately with zero reflux. In the second case, simultaneous reaction and distillation processes are carried out. During these experiments, the dynamics of bubble point temperature of the reboiler is recorded and analyzed. From the experimental results it is found that the maximum purity of methyl acetate in instantaneous distillate of reaction followed by distillation and simultaneous reaction and distillation are 0.847 and 0.782, respectively, as analyzed by gas chromatography. From these studies it is found that a batch distillation apparatus itself can be used in certain way to produce the desired product for the case of methyl acetate production by monitoring the temperature regime of the reboiler.","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"9 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135446279","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Evaluation of Punica granatum extract as an environmentally safe corrosion inhibitor for carbon steel in a solution of 1 M sulfuric acid","authors":"","doi":"10.56042/ijct.v30i3.70544","DOIUrl":"https://doi.org/10.56042/ijct.v30i3.70544","url":null,"abstract":"","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"1 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70701816","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Impact of titania phase structure and surface reactivity on the photocatalytic degradation of various dyes and textile wastewater","authors":"","doi":"10.56042/ijct.v30i1.59399","DOIUrl":"https://doi.org/10.56042/ijct.v30i1.59399","url":null,"abstract":"","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"139 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70701429","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Stability indicating HPLC method for the simultaneous analysis of Gatifloxacin and Loteprednol in eyedrop formulation using design of experiment approach","authors":"","doi":"10.56042/ijct.v30i2.66233","DOIUrl":"https://doi.org/10.56042/ijct.v30i2.66233","url":null,"abstract":"","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"1 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70701779","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}