{"title":"8 Electrochemical Fluoroalkylation","authors":"Z. Ruan, Z. Huang, K. Kuciński","doi":"10.1055/sos-sd-236-00149","DOIUrl":"https://doi.org/10.1055/sos-sd-236-00149","url":null,"abstract":"This chapter reviews electrochemical fluoroalkylations. Reactions covered include trifluoromethylation, difluoromethylation, monofluoromethylation, and perfluoroalkylation as well as polyfluoroalkylation through direct electrolysis and indirect electrolysis.","PeriodicalId":128112,"journal":{"name":"Electrochemistry in Organic Synthesis","volume":"2002 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131799288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"5 Metal-Catalyzed C—H Activation","authors":"Yunzhe Xing, P. Fang, Z.-H. Wang, T. Mei","doi":"10.1055/sos-sd-236-00108","DOIUrl":"https://doi.org/10.1055/sos-sd-236-00108","url":null,"abstract":"Synthetic organic electrochemistry is currently experiencing a renaissance, the merger of electrochemistry with transition-metal-catalyzed C—H activation would provide not only an environmentally friendly approach, but also offer new opportunities that conventional transition-metal catalysis may not have achieved. In this chapter, we summarize the recent progress made in catalytic C—H activation reactions using organometallic electrochemistry, including C—C, C—O, C—N, C—halogen, and C—P bond-forming reactions.","PeriodicalId":128112,"journal":{"name":"Electrochemistry in Organic Synthesis","volume":"88 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128627615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"14 Electrochemistry in Natural Product Synthesis","authors":"K. Lam, M. Leech, A. Lennox","doi":"10.1055/sos-sd-236-00280","DOIUrl":"https://doi.org/10.1055/sos-sd-236-00280","url":null,"abstract":"The multistep synthesis of natural products has historically served as a useful and informative platform for showcasing the best, state-of-the-art synthetic methodologies and technologies. Over the last several decades, electrochemistry has proved itself to be a useful tool for conducting redox reactions. This is primarily due to its unique ability to selectively apply any oxidizing or reducing potential to a sufficiently conductive reaction solution. Electrochemical redox reactions are readily scaled and can be more sustainable than competing strategies based on conventional redox reagents. In this chapter, we summarize the examples where electrochemistry has been used in the synthesis of natural products. The chapter is organized by the reaction type of the electrochemical step and covers both oxidative and reductive reaction modes.","PeriodicalId":128112,"journal":{"name":"Electrochemistry in Organic Synthesis","volume":"6 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125495530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"9 Anodic Arylation Reactions","authors":"M. Selt, S. R. Waldvogel","doi":"10.1055/sos-sd-236-00167","DOIUrl":"https://doi.org/10.1055/sos-sd-236-00167","url":null,"abstract":"The arylation of organic compounds is a tremendously important tool in organic synthesis, since substituted (het)arenes are essential moieties in many applications ranging from organic intermediates to natural products, pharmaceuticals, and materials. Therefore, an effective, sustainable, and economic synthetic accesses to such compounds is of great demand. This chapter covers the arylation of carbon and heteroatom compounds via an electrooxidative pathway. Direct dehydrogenative methods without the application of a metal catalyst as well as constant-current electrolyses are emphasized. The electrochemical synthesis of biaryl compounds, arylalkanes and arylalkenes, as well as arylated nitrogen, oxygen, and sulfur compounds are described in detail. Additionally, the synthesis of heterocycles through anodic arylation reactions is discussed.","PeriodicalId":128112,"journal":{"name":"Electrochemistry in Organic Synthesis","volume":"8 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130333277","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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