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Sulfur Isotopic Composition of Sulfides and Sulfates from Rocks of Carbonatite Complexes of the Devonian Kola Alkaline Province 泥盆纪科拉碱性省碳酸盐岩群岩石中硫化物和硫酸盐的硫同位素组成
IF 0.7 4区 地球科学
Geochemistry International Pub Date : 2024-07-11 DOI: 10.1134/S0016702924700253
E. N. Kozlov, E. N. Fomina, V. N. Reutsky, M. Yu. Sidorov
{"title":"Sulfur Isotopic Composition of Sulfides and Sulfates from Rocks of Carbonatite Complexes of the Devonian Kola Alkaline Province","authors":"E. N. Kozlov,&nbsp;E. N. Fomina,&nbsp;V. N. Reutsky,&nbsp;M. Yu. Sidorov","doi":"10.1134/S0016702924700253","DOIUrl":"10.1134/S0016702924700253","url":null,"abstract":"<p>This study presents the sulfur isotopic characteristics in baryte from carbonatites of the Sallanlatva massif and sulfides (mainly pyrite and pyrrhotite) from carbonatites, phoscorites and products of their contact interaction with the host silicate rocks of most carbonatite-bearing complexes of the Devonian Kola Alkaline Province (KAP). For some complexes (Ozernaya Varaka, Kontozero), these characteristics are reported for the first time. The determined range of δ<sup>34</sup>S variations of sulfides in one complex does not exceed 4‰, but reaches 20‰ for the entire Kola Alkaline Province. This may be related to the evolution style of carbonatites and associated rocks. It is shown that the δ<sup>34</sup>S value in sulfides decreases from (1) the least evolved volcanic carbonatites of the Kontozero complex (δ<sup>34</sup>S<sub>avg.</sub> = –1.3‰) through (2) carbonatites and phoscorites of the Kovdor, Ozernaya Varaka, Sokli, and Salmagora massifs towards (3) the rocks of Seblyavr, Vuoriyarvi, and, finally, the carbonatites of Sallanlatva (δ<sup>34</sup>S<sub>avg.</sub> = –14.7‰) massifs, where sulfides differ from those of other KAP carbonatites in their exceptionally low δ<sup>34</sup>S values. The carbonatite volcanics of Kontozero are almost barren of REE mineralization; carbonatites of the second group contain accessory amounts of REE minerals; the third group is peculiar in the abundance of late carbonatites, where REE carbonates are frequently major minerals. Thus, the greater the volume of REE minerals in carbonatites of the complex, the lower the δ<sup>34</sup>S value in sulfides from its carbonatites and associated rocks. For the first time in the KAP, the sulfur isotopic composition of associated baryte–pyrite pairs was studied in the Sallanlatva carbonatites. The sulfur isotopic characteristics are shown to correspond to the final low-temperature (250–350°C) stage of carbonatite evolution in oxidized conditions, which satisfies the parameters of baryte crystallization. Since the studied samples of the Sallanlatva carbonatites are explosive breccias, the oxidized composition of fluids may indicate their phreatomagmatic nature, i.e., formation due to the interaction of intruded hot matter (melt/fluid) with meteoric waters.</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 6","pages":"561 - 573"},"PeriodicalIF":0.7,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141610182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Erratum to: Geochemical Markers of the Norilsk Ore-Bearing Intrusions: Case Study of the Maslovsky Deposit 勘误:诺里尔斯克含矿侵入体的地球化学标志:马斯洛夫斯基矿藏案例研究
IF 0.7 4区 地球科学
Geochemistry International Pub Date : 2024-07-11 DOI: 10.1134/S0016702924980015
Yu. A. Kostitsyn, N. A. Krivolutskaya, A. V. Somsikova, M. O. Anosova, I. V. Kubrakova, N. D. Tolstykh, B. I. Gongalsky, I. A. Kuzmin
{"title":"Erratum to: Geochemical Markers of the Norilsk Ore-Bearing Intrusions: Case Study of the Maslovsky Deposit","authors":"Yu. A. Kostitsyn,&nbsp;N. A. Krivolutskaya,&nbsp;A. V. Somsikova,&nbsp;M. O. Anosova,&nbsp;I. V. Kubrakova,&nbsp;N. D. Tolstykh,&nbsp;B. I. Gongalsky,&nbsp;I. A. Kuzmin","doi":"10.1134/S0016702924980015","DOIUrl":"10.1134/S0016702924980015","url":null,"abstract":"","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 6","pages":"674 - 674"},"PeriodicalIF":0.7,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142411271","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mineralogical, Geochemical and Nd Isotopic Study of the Meta-Clastic Rocks of the Paleoproterozoic Mahakoshal Basin, Central Indian Tectonic Zone: Implications for Provenance Characterization, Paleoweathering Conditions and Tectonic Setting 印度中部构造带古生代马哈科沙尔盆地元碎屑岩的矿物学、地球化学和钕同位素研究:对产状特征、古风化条件和构造背景的影响
IF 0.8 4区 地球科学
Geochemistry International Pub Date : 2024-07-10 DOI: 10.1134/s0016702924700472
Kamaal Parvez, M. E. A. Mondal, Iftikhar Ahmad, Waliur Rahaman, Anil D. Shukla, Wamiq Mohammed Khan
{"title":"Mineralogical, Geochemical and Nd Isotopic Study of the Meta-Clastic Rocks of the Paleoproterozoic Mahakoshal Basin, Central Indian Tectonic Zone: Implications for Provenance Characterization, Paleoweathering Conditions and Tectonic Setting","authors":"Kamaal Parvez, M. E. A. Mondal, Iftikhar Ahmad, Waliur Rahaman, Anil D. Shukla, Wamiq Mohammed Khan","doi":"10.1134/s0016702924700472","DOIUrl":"https://doi.org/10.1134/s0016702924700472","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>The present study focuses on the petrographic studies, XRD patterns, whole-rock geochemical data and Nd isotopic data of the clastic rocks of the Paleoproterozoic Mahakoshal Basin which includes meta-argillites, meta-greywackes and quartzites to characterize their provenance, tectonic setting, weathering intensity, and paleoclimate condition. Geochemically, the rock samples of meta-argillite and meta-greywacke in the bivariate plot Log Na<sub>2</sub>O/K<sub>2</sub>O vs. Log SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> are classified as litharenite and greywacke. The samples of quartzite fall in the fields from the sublitharenite to quartzarenite. The weathering indices such as CIA, <span>(alpha _{{{text{Ca}}}}^{{{text{Al}}}})</span>, <span>(alpha _{{{text{Na}}}}^{{{text{Al}}}})</span>, <span>(alpha _{{text{K}}}^{{{text{Al}}}})</span>, <span>(alpha _{{{text{Sr}}}}^{{{text{Al}}}})</span>, <span>(alpha _{{{text{Ba}}}}^{{{text{Al}}}})</span> and Th/U suggest that the clastic rocks have undergone moderate to intense chemical weathering and show K-metasomatism. Chondrite normalized REE patterns, discriminant diagrams of La–Th–Sc and Ni–V–10*Th and various transition elements ratio such as Cr/Th, Th/Co, Th/Sc, and La/Sc support the mixing of the mafic, intermediate and felsic sources. The Eu anomaly is highly variable and ranges from 0.29 to 1.08 and supports that the sediments have been derived from the heterogeneous source. T<sub>CHUR</sub> model ages are consistent with 1.98–2.92 Ga possible provenance. εNd(t) and <i>f</i>(Sm/Nd) values overlap with the arc and the Archean crust signatures indicating that the sediments are derived from a Paleoproterozoic arc and older Archean crust (TTG gneisses and Archean granite). The opening of the Mahakoshal Basin is characterized by the retreating accretionary orogen and the closure of the basin is due to switching retreating accretionary orogen into advancing accretionary orogen which is contemporaneous to the assembly of the Columbia Supercontinent (∼1.8 Ga).</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"38 1","pages":""},"PeriodicalIF":0.8,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141586094","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Studying the Influence of Soil Characteristics on Selenium Distribution in Bas-Chellif Soils Algeria and Predicting Speciation Patterns 研究阿尔及利亚下切利夫土壤中土壤特性对硒分布的影响并预测其种类模式
IF 0.7 4区 地球科学
Geochemistry International Pub Date : 2024-07-10 DOI: 10.1134/S0016702924700460
M. Ait Mechedal, H. Laoufi, K. Ouamer-ali, K. Djili, Y. Daoud, D. B. Sims
{"title":"Studying the Influence of Soil Characteristics on Selenium Distribution in Bas-Chellif Soils Algeria and Predicting Speciation Patterns","authors":"M. Ait Mechedal,&nbsp;H. Laoufi,&nbsp;K. Ouamer-ali,&nbsp;K. Djili,&nbsp;Y. Daoud,&nbsp;D. B. Sims","doi":"10.1134/S0016702924700460","DOIUrl":"10.1134/S0016702924700460","url":null,"abstract":"<p>Knowledge of the geochemistry of selenium (Se) is crucial for understanding its behavior in the environment. While numerous studies have explored selenium geochemistry, there is a notable inadequacy, especially in extreme soil conditions such as saline soils, which are widespread globally. This study focuses on characterizing the geochemistry of selenium in saline soils, with a specific focus on the El Hamadna perimeter in Bas-Cheliff, Algeria. This location was chosen due to its diverse salinity levels and selenium content. Utilizing Phreeqc software, the study examines selenium’s chemical speciation. In the arid soils of this region, predicted selenium (IV) concentrations range from 0.19 to 3.05 mg kg<sup>–1</sup>, and selenium (VI) concentrations range from 0.54 to 5.58 mg kg<sup>–1</sup>. A significant negative correlation was observed between total selenium and Se(VI) concentrations with pH, whereas Se(IV) showed a positive and significant correlation with pH. No correlation was found between selenium concentrations and the salinity gradient in the studied soils. Non-significant correlations were observed between selenium levels and CaCO<sub>3</sub>, clay, and organic matter in the soils, suggesting that these soil properties do not influence the distribution of selenium concentrations in the examined soils. Only the pH and the presence of the main form MgSeO<sub>3</sub> control the representation of selenium in the soil profile.</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 8","pages":"897 - 907"},"PeriodicalIF":0.7,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141586138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
REE Distribution in the Water and Bottom Sediments of Small Lakes within the Ukok Plateau and the Ulagan Depression (Russian Altai) 乌科克高原和乌拉干洼地(俄罗斯阿尔泰)小湖泊水体和湖底沉积物中的稀土元素分布
IF 0.7 4区 地球科学
Geochemistry International Pub Date : 2024-05-29 DOI: 10.1134/S001670292470037X
V. D. Strakhovenko, E. A. Ovdina, G. I. Malov, V. I. Malov
{"title":"REE Distribution in the Water and Bottom Sediments of Small Lakes within the Ukok Plateau and the Ulagan Depression (Russian Altai)","authors":"V. D. Strakhovenko,&nbsp;E. A. Ovdina,&nbsp;G. I. Malov,&nbsp;V. I. Malov","doi":"10.1134/S001670292470037X","DOIUrl":"10.1134/S001670292470037X","url":null,"abstract":"<p>The contemporary scientific investigations delves into the mechanisms of migration, distribution, and fractionation of rare earth elements and yttrium (REE + Y) in aqueous environments characterized by humid and arid sedimentogenesis. This particular facet has been employed to solve numerous fundamental inquiries pertaining to lithology and paleolimnology. The manner in which REE + Y behave in water bodies within the cryolithozone remains largely unexplored. By evaluating the concentration levels and distribution patterns of REE + Y in the waters and sediments of the lakes situated in the Ukok Plateau and the Ulagan depression, under the prevailing conditions of cryolithogenesis as the primary geochemical process transforming rocks, soils, and sediments, we were able to augment the existing comprehension of nival sedimentation. In all the lakes examined, the content of REE + Y in the water exhibits a similar magnitude as that of small lakes in other landscape zones of the southern Western Siberia, while the content level of REE + Y is greater in the bottom sediments. The concentrations, distribution and fractionation of REE + Y vary from lake to lake and are determined by several factors: the chemical properties of REE + Y in solutions, the intensity of transformation of host rocks and the mineral forms of the REE + Y in the rocks (minerals). The concentrations, distribution and fractionation of REE + Y in bottom sediments vary slightly from lake to lake except for the contents of Eu, Y, La. The content of Eu, Y, La in the bottom sediment of the lake is influenced by a combination of factors, including their concentrations in the water, the redox conditions of diagenesis, and the mineral composition of the bottom sediment, particularly the amount of accessory minerals.</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 7","pages":"772 - 791"},"PeriodicalIF":0.7,"publicationDate":"2024-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141192614","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Timing and Genesis of Late Paleoproterozoic Molybdenum Mineralization in the East Qinling Molybdenum Belt, China: Constraints from the Zhaiwa Deposit 中国东秦岭钼矿带晚古生代钼矿化的时间和成因:寨洼矿藏的制约因素
IF 0.7 4区 地球科学
Geochemistry International Pub Date : 2024-05-29 DOI: 10.1134/S0016702924700381
Bing Yu, Qingdong Zeng, Shuai Gao, Jianling Xue, Xiaofei Zhang
{"title":"The Timing and Genesis of Late Paleoproterozoic Molybdenum Mineralization in the East Qinling Molybdenum Belt, China: Constraints from the Zhaiwa Deposit","authors":"Bing Yu,&nbsp;Qingdong Zeng,&nbsp;Shuai Gao,&nbsp;Jianling Xue,&nbsp;Xiaofei Zhang","doi":"10.1134/S0016702924700381","DOIUrl":"10.1134/S0016702924700381","url":null,"abstract":"<p>The East Qinling Molybdenum Belt (EQMB), which is located on the southern margin of the North China Craton (NCC), is the largest Mo province in the world. This belt hosts a significant number of Mesozoic magmatic-hydrothermal Mo deposits and a small portion of pre-Mesozoic Mo deposits. Understanding the mineralization timing and mechanism of the unique pre-Mesozoic Mo deposits is essential to comprehend the evolution of the EQMB, the pre-Mesozoic Mo enrichment, and the Mesozoic Mo mineralization event. The recently discovered Zhaiwa deposit is a porphyry Mo deposit located in the Xiong’er Terrane of the EQMB. In this study, five molybdenite samples from the Mo-bearing quartz veins were analyzed for Re-Os isotopes composition. These samples yield an isochron age of 1794 ± 45 Ma, which represents the age of mineralization. The mineralization is mostly hosted within the biotite-amphibole plagiogneiss and granite porphyry. LA-ICP-MS U-Pb data of zircons constrain the crystallization age of the granite porphyry to be at 1791 ± 16 Ma. The close spatial and temporal association suggests that the granite porphyry is the causative rocks of the Mo mineralization. The δ<sup>34</sup>S values of pyrite vary from 5.3 to 6.8‰, suggesting that the S was mainly derived from magmatic source. The intrusion of magmas and associated Mo mineralization are contemporaneous to the regional Xiong’er volcanism that occurred during the late Paleoproterozoic. The Xiong’er volcanism was triggered by partial melting of lithospheric mantle in an extensional setting. The results of our study provide robust evidence for a late Paleoproterozoic Mo metallogenic event along the southern margin of the NCC. Future exploration should also consider the potential of late Paleoproterozoic porphyry Mo mineralization existing in the EQMB, which is closely associated with the Xiong’er volcanism.</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 7","pages":"733 - 747"},"PeriodicalIF":0.7,"publicationDate":"2024-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141198398","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Geochemistry of the Bottom Sediments of Lake Peyungda, Tunguska Nature Reserve, and Paleoclimatic Reconstructions of the Arctic Territories of Eastern Siberia 通古斯卡自然保护区佩永达湖湖底沉积物的地球化学与东西伯利亚北极地区的古气候重建
IF 0.7 4区 地球科学
Geochemistry International Pub Date : 2024-05-23 DOI: 10.1134/S0016702924700216
V. S. Novikov, A. V. Darin, V. V. Babich, F. A. Darin, D. Yu. Rogozin
{"title":"Geochemistry of the Bottom Sediments of Lake Peyungda, Tunguska Nature Reserve, and Paleoclimatic Reconstructions of the Arctic Territories of Eastern Siberia","authors":"V. S. Novikov,&nbsp;A. V. Darin,&nbsp;V. V. Babich,&nbsp;F. A. Darin,&nbsp;D. Yu. Rogozin","doi":"10.1134/S0016702924700216","DOIUrl":"10.1134/S0016702924700216","url":null,"abstract":"<p>Lake Peyungda contains annually layered bottom sediments (varves), which make it possible to build a reliable age model for the entire depth of the core. An age model was refined over the last century based on the presence of a layer of anomalous thickness associated with the fall of the Tunguska cosmic body (TCB) in June 1908. The results of scanning µXRF-SI (elemental analysis along core depth) were used for comparison with regional average annual weather observation data over the time span of 1895–2000 to create a transfer function: average annual temperature as a function of the elemental composition of the dated layer of bottom sediment. Approximation of the obtained function to the depth of core sampling made it possible to reconstruct changes in regional temperature over the time interval of the last millennium with an annual time resolution. Comparison of the obtained reconstruction with literature data on reconstructions for the Arctic region over the past 1000 years shows the presence of general trends and extremes, which confirms the reliability of the obtained results.</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 5","pages":"520 - 528"},"PeriodicalIF":0.7,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141132704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Melt Sources and Formation Parameters of the Khokhol−Repyevka Granitoid Batholith in the Volga−Don Orogen, East European Craton 东欧克拉通伏尔加河-顿河造山带霍霍尔-列皮耶夫卡花岗岩岩体的熔融源和形成参数
IF 0.7 4区 地球科学
Geochemistry International Pub Date : 2024-05-23 DOI: 10.1134/S001670292470023X
M. E. Petrakova, A. B. Kuznetsov, Sh. K. Baltybaev, V. M. Savatenkov, R. A. Terentiev, K. A. Savko
{"title":"Melt Sources and Formation Parameters of the Khokhol−Repyevka Granitoid Batholith in the Volga−Don Orogen, East European Craton","authors":"M. E. Petrakova,&nbsp;A. B. Kuznetsov,&nbsp;Sh. K. Baltybaev,&nbsp;V. M. Savatenkov,&nbsp;R. A. Terentiev,&nbsp;K. A. Savko","doi":"10.1134/S001670292470023X","DOIUrl":"10.1134/S001670292470023X","url":null,"abstract":"<p>The paper discusses the melt sources and formation parameters of the Khokhol-Repyevka granitoid batholith that compose the Don terrane of the Volga–Don orogen in the East European craton. The batholith consists of three granitoid types: Pavlovsk granitoids (quartz monzonites–granites, mostly without pyroxenes), Potudan granitoids (quartz monzogabbro–granodiorites containing pyroxene), and hybrid ones (quartz monzodiorites, monzonites, and quartz monzonites). These three types of rocks occur together and have a similar age of 2050–2080 Ma, similar geochemical characteristics (high contents of Ba, Sr, and highly fractionated REE patterns with Gd<sub>N</sub>/Yb<sub>N</sub> = 2–11), but differ in petrographic and isotopic geochemical parameters. The initial isotope characteristics of the sources of the Pavlovsk-type rocks are ε<sub>Nd</sub>(t) = +0.2 to ‒3.7 and Sr<sub><i>i</i></sub> = 0.70335, those of the Potudan type are ε<sub>Nd</sub>(t) = –1.7 to –3.8, Sr<sub><i>i</i></sub> = 0.70381–0.70910, and the hybrid rocks have ε<sub>Nd</sub>(t) = –8.8, Sr<sub><i>i</i></sub> = 0.70596. In addition to granitoids, the batholith was found out to host two types of leucogranite dikes. One of them is characterized by ε<sub>Nd</sub>(t) = –3.8 and fractionated HREE patterns (Gd<sub>N</sub>/Yb<sub>N</sub> = 2.1–3.8) and could be formed as a result of the deep differentiation of Pavlovsk-type magma. The other type has ε<sub>Nd</sub>(t) = –7.8 and less fractionated HREE patterns (Gd<sub>N</sub>/Yb<sub>N</sub> = 1.1–1.6), which likely resulted from the melting of a crustal source at shallow depths. The Rb–Sr isotope-geochemical characteristics of rocks of the Pavlovsk and Potudan types indicate that their melts were derived from different sources. Therefore the melts of the Khokhol–Repyevka batholith were derived from at least three sources: (1) lower (or buried oceanic) crust of predominantly mafic composition and/or enriched mantle, which was metasomatized in the Proterozoic, whose involvement is reflected in the composition of the Pavlovsk granitoids; (2) an enriched mantle source, which was likely subcontinental lithospheric mantle (SCLM) that had been metasomatized during an earlier stage of the geological development of the region, specific of the Potudan-type monzonitoids; and (3) Archean crust consisting mostly of TTG gneisses and metasediments, which underwent melting and participated in the formation of some of the leucogranite dikes and hybrid rocks. The results of thermodynamic modeling indicate that the mixing of two melts contrasting in composition (Potudan-type mafic and Pavlovsk-type intermediate–felsic) could form only some of the hybrid rocks. The others could be formed by mafic melt contaminated with anatectic melts derived from the Archean crust of the Kursk block.</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 5","pages":"466 - 492"},"PeriodicalIF":0.7,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141141090","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Geochemical Surface–Water Modification of the Khibiny Mountains since the Launching of a New Mining Enterprise 新采矿企业成立后基比尼山脉地表水地球化学变化情况
IF 0.7 4区 地球科学
Geochemistry International Pub Date : 2024-05-23 DOI: 10.1134/S0016702924700204
V. A. Dauvalter, S. S. Sandimirov, D. B. Denisov, M. V. Dauvalter, Z. I. Slukovskii
{"title":"Geochemical Surface–Water Modification of the Khibiny Mountains since the Launching of a New Mining Enterprise","authors":"V. A. Dauvalter,&nbsp;S. S. Sandimirov,&nbsp;D. B. Denisov,&nbsp;M. V. Dauvalter,&nbsp;Z. I. Slukovskii","doi":"10.1134/S0016702924700204","DOIUrl":"10.1134/S0016702924700204","url":null,"abstract":"<p>The paper assesses the chemical transformation of surface waters in the southeastern part of the Khibiny Mountainous Massif after launching the Oleniy Ruchey apatite–nepheline ore deposit in 2012. The influence of the Oleniy Ruchey Mine was reflected in an increase in water mineralization (by an order of magnitude) and in a change in the basic ion ratios in water objects receiving runoff from mines, rock, and tailing dumps compared to the watercourses unaffected by the mining enterprise’s activities. Natural hydrocarbonate–sodium water with a mineralization of 10 mg/L was transformed into the nitrate–sodium or sulfate–calcium water. The content of nitrogen group compounds in the Lake Komarinoe water, which receives wastewater from the tailing dumps over the ten-year history of the mining and processing plant, has increased by two orders of magnitude, and the nitrate became basic ion. The concentrations of other basic ions and mineralization in this lake increased by an order of magnitude, as the content of trace elements (Sr, F, Mo), which belong to the main rock-forming minerals of apatite–nepheline deposits. Compared to the background water bodies, the mine wastewaters have the elevated mineralization (up to 260 mg/L), pH value (up to 10), and a modified chemical composition. They are characterized by a hydrocarbonate–sodium composition with a large proportion of nitrates and sulfates. Mine wastewaters have elevated contents of nutrient compounds, organic matter, and some trace elements (Al, Fe, Sr, Cu, Mn, Zn, and Cr). It has been established that the geochemical modifications in the quality of surface water are locally developed, being typical of water bodies receiving wastewater from a mining enterprise, in contrast to metallurgical plants, the atmospheric emissions of which caused pollution over tens and hundreds km.</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 5","pages":"529 - 546"},"PeriodicalIF":0.7,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141136931","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural Ordering of Feldspars as an Indicator of the Temperature of Mineral-Forming Processes 长石的结构有序性是矿物形成过程温度的指标
IF 0.7 4区 地球科学
Geochemistry International Pub Date : 2024-05-23 DOI: 10.1134/S0016702924700228
A. R. Kotelnikov, T. I. Shchekina, N. I. Suk, Z. A. Kotelnikova, T. V. Antonovskaya
{"title":"Structural Ordering of Feldspars as an Indicator of the Temperature of Mineral-Forming Processes","authors":"A. R. Kotelnikov,&nbsp;T. I. Shchekina,&nbsp;N. I. Suk,&nbsp;Z. A. Kotelnikova,&nbsp;T. V. Antonovskaya","doi":"10.1134/S0016702924700228","DOIUrl":"10.1134/S0016702924700228","url":null,"abstract":"<p>The processes of albite ordering were experimentally studied in the temperature range of 500–150°C at a pressure of 0.5–1 kbar in alkaline solutions of sodium hydroxide with excess silica. Our original experimental and literature data on the ordering of albite and sodic plagioclase were used to derive dependences for evaluating the temperature based on the degree of feldspar structural ordering. Temperatures were determined for plagioclase-bearing mineral assemblages of rocks from various greenschist-facies metamorphic complexes.</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 5","pages":"493 - 499"},"PeriodicalIF":0.7,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141130984","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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