Green Chemistry Letters and Reviews最新文献

{"title":"Green synthesis of zero-valent iron nanoparticles using <i>Flos Sophorae Immaturus</i> extract for the transformation of ginsenoside Rb1 to 25-OH derivatives","authors":"Yusheng Xiao, Yanyan Chang, Bo Li, Na Li, Mengya Zhao, Huanxi Zhao, Yang Xiu","doi":"10.1080/17518253.2026.2621487","DOIUrl":"https://doi.org/10.1080/17518253.2026.2621487","url":null,"abstract":"In this study, zero-valent iron nanoparticles (nZVI) were green synthesized through a one-pot thermal method using Flos Sophorae Immaturus (FSI) extract, and subsequently used for the heterogeneous transformation of ginsenoside Rb1 to prepare 25-OH ginsenoside derivatives. Detailed characterization of the synthesized FSI-nZVI revealed aggregated spherical nanoparticles with a size distribution ranging from 30 to 60 nm and multiple functional groups encapsulated on the surface. HPLC-MS analysis indicated that polyphenolic compounds such as rutin in the extract were involved in the green synthesis of FSI-nZVI and were responsible for these functional groups. In the transformation of ginsenoside Rb1 catalyzed by FSI-nZVI, the intermediate 20(S/R)-Rg3 and the final product 20(S/R)−25-OH-Rg3 were obtained via deglycosylation at the C20 position and hydration at the C24(25) double bond of Rb1. The transformation pathways were established as Rb1→20(S/R)-Rg3→20(S/R)−25-OH-Rg3 based on time-course experiments. Under optimized conditions, FSI-nZVI achieved a complete transformation of Rb1 to 25-OH-Rg3 epimers with 100% selectivity within 2 h, demonstrating superior transformation efficiency and selectivity compared to five commercial solid acid catalysts. This study provides a promising method for the green synthesis of efficient catalyst nZVI using biomass, and also facilitates the preparation of 25-OH rare ginsenosides with high efficiency and selectivity.","PeriodicalId":12768,"journal":{"name":"Green Chemistry Letters and Reviews","volume":"19 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147381663","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sustainable RP-UPLC analysis of Nirogacestat for desmoid tumors using quality-by-design and green analytical chemistry","authors":"V. Mohan Goud, Sarad Pawar Naik Bukke, Praveen Kumar Kusuma, Bayapa Reddy Narapureddy, Chandrashekar Thalluri","doi":"10.1080/17518253.2025.2595722","DOIUrl":"https://doi.org/10.1080/17518253.2025.2595722","url":null,"abstract":"Quality-by-Design (QbD) and Green Analytical Chemistry (GAC) are used to develop a sustainable RP-UPLC method for detecting Nirogacestat hydrobromide (NGS) in bulk and pharmaceutical formulations. The FDA-approved NGS for desmoid tumors necessitates reliable, environmentally friendly analytical techniques. QbD principles were applied to optimize NGS peak shape and resolution using Design Expert software, taking into account flow rate, temperature, and mobile phase. An ACQUITY UPLC HSS C18 Column utilized a mobile phase of 0.1% (v/v) TFA in water and methanol (71:29) at 0.29 mL/min and 27°C, with detection wavelength of 318.0 nm and a retention time of 1.761 min. The method was highly precise, with %RSD of 0.3 and 0.7 and a recovery rate of 100.26%. The LOD and LOQ were 0.34 and 1.04 μg/mL, respectively. A greenness rating was generated using ComplexMoGAPI, AGREE, the ChlorTox Scale, and the Analytical Eco-Scale, with method validation as per ICH Q2, and stability studies identified a degradation product, affirming the method's reliability. The method is simple, cost-effective, and supports quality control, aligning with GAC and QbD principles. It enhances sustainable pharmaceutical analysis by optimizing performance and minimizing environmental impact. The Efficient Valid Green (EVG) & RGBfast model framework emphasizes regulatory flexibility and quick analysis, setting a benchmark for future advancements.Abbreviations: AGREE: Analytical Greenness; AMV: analytical method validation; AQbD: analytical quality-by-design; AR: Analytical Reagent; ATP: analytical target profile; BAGI: Blue Applicability Grade Index; CAT: Critical analytical attributes; EVG: Efficient Valid Green; GAC: green analytical chemistry; LOD: limit of detection; LOQ: limit of quantitation; NGS: Nirogacestat; NTP: Number of Theoretical Plates, PRESS: predicted residual sums of squares, RSD: Relative standard deviation; SHE: Safety, Health, and Environmental, TUV: Tunable ultraviolet","PeriodicalId":12768,"journal":{"name":"Green Chemistry Letters and Reviews","volume":"18 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147882246","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"State-of-the-art mean centering of ratio spectra and HPLC methodologies for comprehensive analysis of some dry eyes drugs: investigation of white and green practices","authors":"Maha A. Alwaili, Fahad M. Alminderej, Bandar R. Alsehli, Hassan A. Rudayni, Ahmed A. Allam, Sayed M. Saleh, Mahmoud A. Mohamed","doi":"10.1080/17518253.2025.2473487","DOIUrl":"https://doi.org/10.1080/17518253.2025.2473487","url":null,"abstract":"White and green chemistry contribute significantly to improving the sustainability of the chemical industry. Based on green and white metrics, ten sustainability tools have been developed. Several tools were used to evaluate how environmentally friendly, innovative as well as forthright RP-HPLC and mean centering of ratio spectra (MCR) techniques were used to simultaneously analyze and separate sodium hyaluronate (SDH) and benzalkonium chloride (BNZ) in eye drops. An HPLC study utilizing 0.07 M sodium sulfate adjusted to pH 3.0 and Ethanol (90:10, v/v) with 205 nm UV detection used an isocratic approach. The experiment used a Partisil Hichrom SCX column (150 mm × 4.6 mm, 5 μm), 20 μL injection volume, and a 0.8 mL/min flow rate. The column oven was set at 25°C for each sequence. With the aid of the MCR spectral method, the overlapping of the medications' spectral parameters was efficiently resolved. This technique enabled SDH and BNZ to distinguish at 222.1 and 215 nm wavelengths. HPLC and MCR calibration curves revealed a correlation coefficient exceeding 0.999 for all medications between 10–200 μg/mL and 5–30 μg/mL. The approach produces good recovery results with 98% to 102%. The proposed approach has been validated following ICH principles.","PeriodicalId":12768,"journal":{"name":"Green Chemistry Letters and Reviews","volume":"18 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.tandfonline.com/doi/pdf/10.1080/17518253.2025.2473487?needAccess=true","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147330932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Endowing deep eutectic solvent with neutral and ionizable perfluoroalkyl substances extracting capability: experimental study and ab initio molecular dynamics simulation","authors":"Chen Fan, Yuwei Shan, Linru Cheng, Yaqi Yin","doi":"10.1080/17518253.2024.2438066","DOIUrl":"https://doi.org/10.1080/17518253.2024.2438066","url":null,"abstract":"The simultaneous separation of neutral and ionizable perfluoroalkyl substances (PFASs) is challenging. The traditional solvents used for this purpose are toxic and harmful. Deep eutectic solvents (DESs) as sustainable alternatives to toxic reagents have received considerable attention in current research. In this work, an array of complementary experimental (liquid–liquid equilibrium experiments) and computational (ab initio molecular dynamics, AIMD) techniques were utilized to explore the distinct distribution behaviors, complicated interaction network, and corresponding mechanisms from multidimensional temporal and spatial perspectives. The proposed bromophenylcyanide-based eutectic solvent systems exhibited good separation and extraction performance for both neutral and ionizable PFASs. The presence of a cyano group adjacent to bromine leads to increased polarization of the C–Br bond, resulting in increased strength of the Br···F contact, which provides selectivity to some extent. For fatty acids, their disruptive effect on eutectic systems is greater because of the relatively strong aggregation that affects DES structuring. For PFASs, different categories of target monomers are confined in the DES cavities and interact with the surrounding solvent through abundant interaction sites (such as electrostatic attraction, N-H···F-C, O-H···F-C, O-H···O-H, and C≡N···O-H hydrogen bonds) without significantly disrupting the solvent structural properties by reducing the molecular mobility.","PeriodicalId":12768,"journal":{"name":"Green Chemistry Letters and Reviews","volume":"18 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147333271","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Life cycle assessment and biodegradability of biodiesel produced using different alcohols and heterogeneous catalysts","authors":"Ieva Gaide, Andrius Grigas, Violeta Makareviciene, Egle Sendzikiene","doi":"10.1080/17518253.2024.2394503","DOIUrl":"https://doi.org/10.1080/17518253.2024.2394503","url":null,"abstract":"The synthesis of fatty acid methyl (RME) and fatty acid butyl esters (RME) using heterogeneous catalysts (dolomite, eggshells, snail shells) is attractive as more and more legislations about global...","PeriodicalId":12768,"journal":{"name":"Green Chemistry Letters and Reviews","volume":"6 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142209859","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sustainable ballistic solutions for recycling silkworm cocoon waste into high-performance bulletproof materials","authors":"Sutha Loidueanchai, Varinrumpai Seithtanabutara, Apichart Artnaseaw","doi":"10.1080/17518253.2024.2385929","DOIUrl":"https://doi.org/10.1080/17518253.2024.2385929","url":null,"abstract":"This study aims to develop a method for producing ballistic panels meeting NIJ Level IIIA standards by integrating silkworm cocoon waste (SCW) as reinforcement and utilizing bias fabric through col...","PeriodicalId":12768,"journal":{"name":"Green Chemistry Letters and Reviews","volume":"14 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141945027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Retraction","authors":"","doi":"10.1080/17518253.2024.2379172","DOIUrl":"https://doi.org/10.1080/17518253.2024.2379172","url":null,"abstract":"Published in Green Chemistry Letters and Reviews (Vol. 17, No. 1, 2024)","PeriodicalId":12768,"journal":{"name":"Green Chemistry Letters and Reviews","volume":"17 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141772519","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhanced light absorption and charge carrier’s separation in g-C3N4-based double Z-scheme heterostructure photocatalyst for efficient degradation of navy-blue dye","authors":"Wali Muhammad, Abbas Khan, Sajjad Hussain, Hammad Khan, Rasha A. Abumousa, Mohamed Bououdina, Iltaf Khan, Sikandar Iqbal, Muhammad Humayun","doi":"10.1080/17518253.2024.2381591","DOIUrl":"https://doi.org/10.1080/17518253.2024.2381591","url":null,"abstract":"Effective wastewater treatment is essential due to the dye environmental threats. Photocatalysis offers an eco-friendly dye degradation solution. Herein, we report a double Z-scheme photocatalyst, ...","PeriodicalId":12768,"journal":{"name":"Green Chemistry Letters and Reviews","volume":"20 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141772520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Green synthesis of polymeric surfactants from recycling of plastic waste for applications on steel protection in the petroleum industry","authors":"Reda Abdel-Hameed, Ghadah Aleid, Hanan Ragab, Hussin Alshafey, Enas Aljuhani, Saedah Al-Mhyawi","doi":"10.1080/17518253.2024.2379442","DOIUrl":"https://doi.org/10.1080/17518253.2024.2379442","url":null,"abstract":"Green synthesis of four novel nonionic polymeric surfactants: from the recycled product of poly (ethylene terephthalate) plastic waste for application in corrosion protection of carbon steel. In th...","PeriodicalId":12768,"journal":{"name":"Green Chemistry Letters and Reviews","volume":"45 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2024-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141740691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Development of phase change eco-composite materials from eggshell waste","authors":"Wafa Ben Aribia, Abdelwaheb Trigui, Naif Khalaf Alshammari, Makki Abdelmoleh","doi":"10.1080/17518253.2024.2380060","DOIUrl":"https://doi.org/10.1080/17518253.2024.2380060","url":null,"abstract":"The consumption of eggshell powder (ES) as an affluent source of calcium carbonate (CaCO3) can efficiently solve both ecological and financial interest. The use of eggshell waste in eco-composite m...","PeriodicalId":12768,"journal":{"name":"Green Chemistry Letters and Reviews","volume":"33 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2024-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141717509","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}