Geochemical Perspectives Letters最新文献

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Barium isotope evidence for a magmatic fluid-dominated petrogenesis of LCT-type pegmatites 以岩浆流体为主的岩浆岩成岩作用的钡同位素证据
IF 4.9 1区 地球科学
Geochemical Perspectives Letters Pub Date : 2024-06-28 DOI: 10.7185/geochemlet.2426
G. Deng, D. Jiang, G. Li, Z. Xu, F. Huang
{"title":"Barium isotope evidence for a magmatic fluid-dominated petrogenesis of LCT-type pegmatites","authors":"G. Deng, D. Jiang, G. Li, Z. Xu, F. Huang","doi":"10.7185/geochemlet.2426","DOIUrl":"https://doi.org/10.7185/geochemlet.2426","url":null,"abstract":"Understanding the petrogenesis of granitic pegmatites associated with Li mineralisation is fundamental in constraining rare metal enrichment mechanisms. However, there is still significant controversy surrounding the central issue of the nature of pegmatite-forming liquids. Here, we report Ba isotope data for a 3000 m borehole in the Jiajika pegmatite field that hosts the largest hard rock-type Li deposit in Asia. The pegmatites exhibit markedly lower δ<sup>138/134</sup>Ba than the wall rocks and the average upper continental crust, which cannot be attributed to low degree anatexis of metasedimentary or crystal fractionation of highly evolved granitic magmas. Instead, modelling suggests that their low δ<sup>138/134</sup>Ba most likely results from substantial involvement (10–40 %) of isotopically light hydrothermal fluids exsolved from the underlying magmatic reservoirs. In the context of transcrustal magmatic system, these magmatic fluid components may be a key medium in extracting, concentrating, and transporting Li to provide a material source for mineralisation in granitic pegmatites.","PeriodicalId":12613,"journal":{"name":"Geochemical Perspectives Letters","volume":"29 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141507837","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Subduction of sedimentary carbonate in the Mariana trench 马里亚纳海沟沉积碳酸盐的俯冲作用
IF 4.9 1区 地球科学
Geochemical Perspectives Letters Pub Date : 2024-06-26 DOI: 10.7185/geochemlet.2425
S. Liu, X. Su, S. Wan, L. Zhang, S. Chen, W. Xu, H. Xu, D. Wang, D. Li, X. Peng
{"title":"Subduction of sedimentary carbonate in the Mariana trench","authors":"S. Liu, X. Su, S. Wan, L. Zhang, S. Chen, W. Xu, H. Xu, D. Wang, D. Li, X. Peng","doi":"10.7185/geochemlet.2425","DOIUrl":"https://doi.org/10.7185/geochemlet.2425","url":null,"abstract":"Calcium carbonate is a major component of shallow marine sediments but is rarely preserved in deep sea environments below the calcite compensation depth (CCD). In this study, we present evidence of sedimentary carbonate on the subducting Pacific plate of the Mariana Trench at a water depth ranging from 6675 to 10,813 m, far surpassing the local CCD of 4800 m. These deposits consist of well-preserved calcareous nannofossils, planktonic foraminifera, and siliceous radiolarians. Fossil assemblages and isotope stratigraphy analyses constrain the age of carbonate sediments to 17.6–13.5 Ma. We propose that the calcareous sediments originated from rapid deposition and burial on the seafloor above the CCD during the Miocene. Subsequently, they were transported into the hadal zone with the subduction of the Pacific Plate and exposed due to the excavation of extensive subducting-related normal faults within the subducting plate. This study implies that sedimentary carbonate may be a key component of subducting carbon at the hadal subduction zones, which has important implications for evaluating global carbon input fluxes at these zones.","PeriodicalId":12613,"journal":{"name":"Geochemical Perspectives Letters","volume":"15 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141507838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrigendum to “Sulfur solubility in a deep magma ocean and implications for the deep sulfur cycle” by Steenstra et al., 2022. 对 Steenstra 等人所著 "深岩浆海洋中的硫溶解度及其对深层硫循环的影响 "的更正,2022 年。
IF 4.9 1区 地球科学
Geochemical Perspectives Letters Pub Date : 2024-06-25 DOI: 10.7185/geochemlet.2219cor
E.S. Steenstra, O.T. Lord, S. Vitale, E.S. Bullock, S. Klemme, M. Walter
{"title":"Corrigendum to “Sulfur solubility in a deep magma ocean and implications for the deep sulfur cycle” by Steenstra et al., 2022.","authors":"E.S. Steenstra, O.T. Lord, S. Vitale, E.S. Bullock, S. Klemme, M. Walter","doi":"10.7185/geochemlet.2219cor","DOIUrl":"https://doi.org/10.7185/geochemlet.2219cor","url":null,"abstract":"Abstract not available","PeriodicalId":12613,"journal":{"name":"Geochemical Perspectives Letters","volume":"4 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141507839","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A baseline for the Sn isotopic composition of the upper continental crust 大陆上地壳锡同位素组成基线
IF 4.9 1区 地球科学
Geochemical Perspectives Letters Pub Date : 2024-05-30 DOI: 10.7185/geochemlet.2422
E. Kubik, F. Moynier, J.-X. She, R.L. Rudnick
{"title":"A baseline for the Sn isotopic composition of the upper continental crust","authors":"E. Kubik, F. Moynier, J.-X. She, R.L. Rudnick","doi":"10.7185/geochemlet.2422","DOIUrl":"https://doi.org/10.7185/geochemlet.2422","url":null,"abstract":"We report high precision Sn isotopic compositions, expressed as δ<sup>122/118</sup>Sn relative to the NIST3161a standard, for the fine grained matrix of 24 glacial diamictite composites. The diamictites were deposited from the Mesoarchean to the Palaeozoic and sampled from four continents (Africa, Asia, North and South America). They are relatively homogeneous in δ<sup>122/118</sup>Sn, ranging from 0.15 to 0.32 ‰ with an average δ<sup>122/118</sup>Sn value of 0.22 ± 0.14 ‰ (2 s.d., <em>n</em> = 24). The Sn isotopic composition of the diamictites is not influenced by chemical weathering, depositional age, geographic setting, atmospheric oxygen content or magmatic differentiation processes in the source region. As such, the average provides a robust estimate of the Sn isotopic composition of the bulk upper continental crust (UCC). This baseline is within the range of, but isotopically lighter than, the current depleted mantle estimate (0.37 ± 0.09 ‰; 2 s.d., <em>n</em> = 12) and bulk silicate Earth (0.38 ± 0.11 ‰; 2 s.d., <em>n</em> = 9). It also overlaps with the very few available measurements made on andesites, granites, a granodiorite and a rhyolite.","PeriodicalId":12613,"journal":{"name":"Geochemical Perspectives Letters","volume":"51 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141190530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Neoarchean marine chemical sediments as archives of Hadean silicate differentiation 新元古代海洋化学沉积物作为哈代硅酸盐分化的档案
IF 4.9 1区 地球科学
Geochemical Perspectives Letters Pub Date : 2024-05-30 DOI: 10.7185/geochemlet.2421
A.N. Wainwright, V. Debaille, J.E. Hoffmann, S. Viehmann, M. Bau
{"title":"Neoarchean marine chemical sediments as archives of Hadean silicate differentiation","authors":"A.N. Wainwright, V. Debaille, J.E. Hoffmann, S. Viehmann, M. Bau","doi":"10.7185/geochemlet.2421","DOIUrl":"https://doi.org/10.7185/geochemlet.2421","url":null,"abstract":"Planetary differentiation had a profound influence on the geochemical signature of the Earth’s silicate reservoirs. Some of the early created complementary reservoirs dissipated with time (<em>e.g.,</em> <span onclick=\"window.open('#ref3','_self')\">Bennett <em>et al.</em>, 2007</span><p>Bennett, V.C., Brandon, A.D., Nutman, A.P. (2007) Coupled <sup>142</sup>Nd-<sup>143</sup>Nd Isotopic Evidence for Hadean Mantle Dynamics. <em>Science</em> 318, 1907–1910. https://doi.org/10.1126/science.1145928</p>) and only remnants can be observed. Here, we apply the short lived isotopic system <sup>146</sup>Sm-<sup>142</sup>Nd to an alternative archive—marine chemical sediments—and show that alternating Fe- and Si-rich bands from the 2.7 billion-year-old Temagami banded iron formation (BIF), Canada, display significantly different <sup>142</sup>Nd isotopic compositions. The Fe-rich bands yield a depleted signature (expressed as deviation from the standard in μ notation) with an average μ<sup>142</sup>Nd of +7.02 ± 0.71, while the Si-rich bands display modern mantle-like signatures (average μ<sup>142</sup>Nd −2.83 ± 2.32) likely being the results of mixing between different sources. These complementary signatures reflect the dominant, locally derived source of Nd in the seawater at the time of deposition. Our results promote that layering in BIFs is a syn-depositional feature, and that BIFs are unique geochemical archives capable of recording silicate reservoirs that formed during the Hadean but were still extant during the Neoarchean.","PeriodicalId":12613,"journal":{"name":"Geochemical Perspectives Letters","volume":"21 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141190543","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Lanthanum anomalies provide constraints on macrofaunal predation at methane seeps 镧异常为甲烷渗漏区大型底栖生物捕食提供了制约因素
IF 4.9 1区 地球科学
Geochemical Perspectives Letters Pub Date : 2024-05-28 DOI: 10.7185/geochemlet.2420
X. Wang, Z. Jia, J. Peckmann, S. Kiel, J.-A. Barrat, G. Bayon, J. Li, L. Yin, T. Wei, Q. Liang, D. Feng
{"title":"Lanthanum anomalies provide constraints on macrofaunal predation at methane seeps","authors":"X. Wang, Z. Jia, J. Peckmann, S. Kiel, J.-A. Barrat, G. Bayon, J. Li, L. Yin, T. Wei, Q. Liang, D. Feng","doi":"10.7185/geochemlet.2420","DOIUrl":"https://doi.org/10.7185/geochemlet.2420","url":null,"abstract":"The feeding habits and predation behaviour of organisms can exert significant control on the dynamics of local food webs. Yet, little is known about the effects of predation on the material and trophic transfer dynamics in chemosynthesis-based ecosystems. Here, we investigated the rare earth element (REE) composition of soft tissues and hardparts for thiotrophy-dependent vesicomyid clams (<em>Archivesica marissinica</em>), aerobic methanotrophy-dependent bathymodiolin mussels (<em>Gigantidas haimaensis</em>), in addition to turrid gastropods (<em>Phymorhynchus buccinoides</em>) and parasitic scale worms (<em>Branchipolynoe pettiboneae</em>) from the Haima seeps of the South China Sea; the latter two species are predators feeding on mussels. Our goal was to determine if the specific, microbially-derived, light REE enrichment characteristics of seep mussels can be transferred to the biomass of their predators. The vesicomyid clams were found to exhibit light REE patterns similar to that of seawater. In contrast, the bathymodiolin mussels, turrid gastropods, and scale worms revealed pronounced lanthanum (La) enrichment, agreeing with substantial transfer of La within the local food web. The observed enrichment of La in seep dwelling predators represents an independent method for monitoring the dynamics within seep ecosystems and potentially for assessing faunal interactions in ancient chemosynthesis-based ecosystems.","PeriodicalId":12613,"journal":{"name":"Geochemical Perspectives Letters","volume":"21 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141169446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correlative microspectroscopy of biogenic fabrics in Proterozoic silicified stromatolites 新生代硅化叠层石中生物结构的相关微谱分析
IF 4.9 1区 地球科学
Geochemical Perspectives Letters Pub Date : 2024-05-13 DOI: 10.7185/geochemlet.2419
K. Hickman-Lewis, B. Cavalazzi, W. Montgomery
{"title":"Correlative microspectroscopy of biogenic fabrics in Proterozoic silicified stromatolites","authors":"K. Hickman-Lewis, B. Cavalazzi, W. Montgomery","doi":"10.7185/geochemlet.2419","DOIUrl":"https://doi.org/10.7185/geochemlet.2419","url":null,"abstract":"Questions surrounding the biogenicity of ancient stromatolites have perplexed geobiologists for decades. Abiotic processes can produce superficially stromatolite-like structures; moreover, stromatolites frequently fail to preserve organic materials and cellular traces of their microbial architects. Using spatially correlated optical and electron microscopy coupled with Raman and FTIR microspectroscopy, we show that silicified stromatolites from the Tonian Skillogalee Dolomite (Flinders Ranges, South Australia) contain exceptionally well preserved microbial mat fragments and microbially induced sedimentary structures. These organic-rich layers exhibit mat-like laminations with low degrees of inheritance and reflect interactions between microbial communities and their environments, <em>i.e.</em> growth, sediment trapping and binding, and reactions to early diagenesis, and are inconsistent with abiotic formation. Although accounting for a minor proportion of the volume of the stromatolites, these kerogenous relics are demonstrably syngenetic and comprise aromatic and aliphatic organic materials, likely preserved due to early and rapid silicification. Constraining the origins of such lamination-scale features can elucidate relationships between morphogenesis and diagenesis and may assist in the resolution of controversies surrounding stromatolite biogenicity in deep time.","PeriodicalId":12613,"journal":{"name":"Geochemical Perspectives Letters","volume":"67 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140929504","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Variable δ11B signatures reflect dynamic evolution of the Mariana serpentinite forearc 不同的δ11B特征反映了马里亚纳蛇绿岩前弧的动态演化
IF 4.9 1区 地球科学
Geochemical Perspectives Letters Pub Date : 2024-05-03 DOI: 10.7185/geochemlet.2416
E. Cannaò, B. Debret
{"title":"Variable δ11B signatures reflect dynamic evolution of the Mariana serpentinite forearc","authors":"E. Cannaò, B. Debret","doi":"10.7185/geochemlet.2416","DOIUrl":"https://doi.org/10.7185/geochemlet.2416","url":null,"abstract":"This study aims to uncover the evolving dynamics of element mobility in serpentinised ultramafic clasts within the Asùt Tesoru mud volcano in the Mariana forearc. By employing <em>in situ</em> analysis of trace elements and boron isotopes (δ<sup>11</sup>B), our findings document a progressive <sup>11</sup>B depletion from lizardite- to antigorite-bearing serpentinites, accompanied by a reduction in the incompatible element inventory in some samples. This pattern aligns with either a chemical evolution linked to phase transitions along the slab interface of shallow forearc serpentinites dragged down to depth, or interaction with shallow <em>vs.</em> deep slab fluids. Our results support a scenario of complex fluid and mechanical mixing along the plate interface in the Mariana subduction system, with major implications for the B recycling in convergent margins.","PeriodicalId":12613,"journal":{"name":"Geochemical Perspectives Letters","volume":"36 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140835451","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A two stage impact melting process in an impact glass strewn field from the Atacama Desert 阿塔卡马沙漠撞击玻璃散落区的两阶段撞击熔化过程
IF 4.9 1区 地球科学
Geochemical Perspectives Letters Pub Date : 2024-05-03 DOI: 10.7185/geochemlet.2418
P. Rochette, G. Di Vincenzo, J. Gattacceca, J.A. Barrat, B. Devouard, L. Folco, A. Musolino, Y. Quesnel
{"title":"A two stage impact melting process in an impact glass strewn field from the Atacama Desert","authors":"P. Rochette, G. Di Vincenzo, J. Gattacceca, J.A. Barrat, B. Devouard, L. Folco, A. Musolino, Y. Quesnel","doi":"10.7185/geochemlet.2418","DOIUrl":"https://doi.org/10.7185/geochemlet.2418","url":null,"abstract":"A new type of silica-rich glass has been discovered associated with the known impact glass strewn field of the Atacama Desert. Based on petrography, chemical composition and indistinguishable <sup>40</sup>Ar/<sup>39</sup>Ar formation ages at <em>circa</em> 6.6 Ma, we infer that these two glasses were produced by the same impact event, which gave rise to two successive compositionally different melt batches in close succession. The first one is a silica-rich melt derived from a mixture of quartz sand and weathered magmatic rocks. It is reduced and devoid of extraterrestrial contamination. The second one, much more abundant and which corresponds to the normal glass, is oxidised, highly contaminated by the iron type impactor and derived from an underlying unweathered dacitic rock. This scheme sheds a new light on the first second of the interaction between the Earth surface and a large metallic asteroid.","PeriodicalId":12613,"journal":{"name":"Geochemical Perspectives Letters","volume":"12 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140835697","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Direct precipitation of siderite in ferruginous environments 铁矿环境中菱铁矿的直接沉淀
IF 4.9 1区 地球科学
Geochemical Perspectives Letters Pub Date : 2024-04-30 DOI: 10.7185/geochemlet.2414
A. Grengs, G. Ledesma, Y. Xiong, S. Katsev, S.W. Poulton, E.D. Swanner, C. Wittkop
{"title":"Direct precipitation of siderite in ferruginous environments","authors":"A. Grengs, G. Ledesma, Y. Xiong, S. Katsev, S.W. Poulton, E.D. Swanner, C. Wittkop","doi":"10.7185/geochemlet.2414","DOIUrl":"https://doi.org/10.7185/geochemlet.2414","url":null,"abstract":"Siderite (FeCO<sub>3</sub>) is often assumed to precipitate from dissimilatory reduction of Fe-(oxyhydr)oxides, but geochemical and mineralogical analyses from ferruginous (anoxic, Fe-rich) Canyon Lake, USA, suggest Fe-carbonate represents a direct early precipitate unrelated to substantial oxide burial. X-ray absorption near edge structure (XANES) spectroscopy of sediment trap materials and an anoxic sediment core indicated a mixture of Fe(II) and Fe(III) in water column particulates and ferruginous surface sediments, while all Mn phases were reduced. About 60 cm below the sediment–water interface, Fe-Mn carbonates were detected by X-ray diffraction and XANES, while Fe extended X-ray absorption fine structure (EXAFS) spectra were best fit with combinations of a biogenic Fe-oxyhydroxide (“Bio Fe”), greigite, and siderite. Sediment Fe speciation indicates a large pool of reduced Fe with a minor component of oxides. Although we found no evidence of significant carbonate phases above or below the 60 cm horizon, equilibrium modelling indicates siderite supersaturation throughout surface sediment porewater, with pH as the primary control on supersaturation. We conclude that delivery of wildfire ash to sediments increased pH, initiating siderite precipitation from ferruginous porewater.","PeriodicalId":12613,"journal":{"name":"Geochemical Perspectives Letters","volume":"36 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140835689","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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