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Reductive Approach to the Synthesis of the Molecular Lanthanide Polypnictide Complexes 还原法合成分子镧系多尼肽配合物
Vestnik RFFI Pub Date : 2019-06-25 DOI: 10.22204/2410-4639-2019-102-02-101-112
S. Konchenko
{"title":"Reductive Approach to the Synthesis of the Molecular Lanthanide Polypnictide Complexes","authors":"S. Konchenko","doi":"10.22204/2410-4639-2019-102-02-101-112","DOIUrl":"https://doi.org/10.22204/2410-4639-2019-102-02-101-112","url":null,"abstract":"In spite of the vigorous development during the last few decades, the coordination chemistry of lanthanides (Ln) is 95% still the chemistry of complexes with O- and N-donor ligands. The compounds with the Ln—E bond (E is a heavy element of the group 15th or 16th) up to now are considered as unconventional or exotic. Recently the fruitful “reductive approach” to this kind of compounds has been developed. The approach involves the performing of reactions between the strong reductants (Ln(II) complexes) and inorganic or organometallic compounds of the main group heavy elements. This paper is focused on the synthesis and structural diversity of the new family of the lanthanide compounds – polypnictide homo- and heterometallic complexes.","PeriodicalId":122949,"journal":{"name":"Vestnik RFFI","volume":"353 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134438757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Application of Complexes of Group 13 Elements in Synthetic Organic Chemistry for Activation of Carbonyl Compounds 13族元素配合物在合成有机化学中活化羰基化合物的应用
Vestnik RFFI Pub Date : 2019-06-25 DOI: 10.22204/2410-4639-2019-102-02-113-140
R. Novikov, Yu. V. Tomilov
{"title":"Application of Complexes of Group 13 Elements in Synthetic Organic Chemistry for Activation of Carbonyl Compounds","authors":"R. Novikov, Yu. V. Tomilov","doi":"10.22204/2410-4639-2019-102-02-113-140","DOIUrl":"https://doi.org/10.22204/2410-4639-2019-102-02-113-140","url":null,"abstract":"The main aspects of modern organic chemistry of the Group 13 elements – aluminum (Al), gallium (Ga), indium (In), and thallium (Tl) – are considered. Herewith, the main emphasis is placed on their use for the various carbonyl compounds activation in organic synthesis and reactions, which are specific for these elements. The 21th century marked a new era in the development of chemistry of the Group 13 elements; it is connected with the discovery of surprising and unexpected reactions and new compounds (primarily in the area of organic and coordination chemistry), defining various fields of these elements application.","PeriodicalId":122949,"journal":{"name":"Vestnik RFFI","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122594961","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Variability and Periodicity of Properties of Metal-Organic Frameworks: D.I. Mendeleev’s Periodic System in Action 金属-有机骨架性质的可变性和周期性:D.I.门捷列夫的周期系统的作用
Vestnik RFFI Pub Date : 2019-06-25 DOI: 10.22204/2410-4639-2019-102-02-74-81
L. Kustov, A. I. Kudelin, V. Isaeva
{"title":"Variability and Periodicity of Properties of Metal-Organic Frameworks: D.I. Mendeleev’s Periodic System in Action","authors":"L. Kustov, A. I. Kudelin, V. Isaeva","doi":"10.22204/2410-4639-2019-102-02-74-81","DOIUrl":"https://doi.org/10.22204/2410-4639-2019-102-02-74-81","url":null,"abstract":"This mini-review presents the analysis of the structure of metal-organic frameworks in terms of the D.I. Mendeleev’s Periodic Law. Up to date, 69,666 compounds of these coordination polymers, containing 78 elements of the Periodic Table, have been synthesized, and their structure has been established.","PeriodicalId":122949,"journal":{"name":"Vestnik RFFI","volume":"27 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123180402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nanoelements in Mendeleev’s Periodic Table. Copper Subgroup 门捷列夫元素周期表中的纳米元素。铜子群
Vestnik RFFI Pub Date : 2019-06-25 DOI: 10.22204/2410-4639-2019-102-02-46-57
A. Semenova, E. Nikelshparg, N. A. Brazhe, I. Veselova, E. Goodilin
{"title":"Nanoelements in Mendeleev’s Periodic Table. Copper Subgroup","authors":"A. Semenova, E. Nikelshparg, N. A. Brazhe, I. Veselova, E. Goodilin","doi":"10.22204/2410-4639-2019-102-02-46-57","DOIUrl":"https://doi.org/10.22204/2410-4639-2019-102-02-46-57","url":null,"abstract":"The 150th anniversary of the Mendeleev’s Periodic Table of elements requires scientists to rethink the outstanding role of this fundamental law in modern areas of chemistry, including such interdisciplinary and high-tech fields as nanochemistry and nanomaterials. The situation analysis shows that the most “nanotechnologically” popular elements belong to 1st, 2nd and partially to the 3rd periods, wherein a special practically important role is played by the noble metals because of their clear «specialization» in the development and implementation of new analytical techniques, in particular, the surface-enhanced Raman spectroscopy (SERS). There is an obvious need to develop and introduce fundamentally new, unique approaches and tools for the analysis of functioning living tissue structures. And SERS is precisely such a method, which implements multiplex, nonivasive spatially- and time-resolved control of chromoproteins at the extremely low concentrations in small volumes of samples of biological objects (tissues, cells, cell structures / organelles), and is an important innovative method of practical biomedical diagnostics.","PeriodicalId":122949,"journal":{"name":"Vestnik RFFI","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130881869","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Elements of the Fifth Group of the Periodic System of D.I. Mendeleev – the Elements of Life 门捷列夫的周期系统的第五族元素——生命的元素
Vestnik RFFI Pub Date : 2019-06-25 DOI: 10.22204/2410-4639-2019-102-02-26-45
A. Gazizov, Y. M. Sadykova, E. Gibadullina, A. Burilov, L. Kibardina, I. R. Knyazeva, A. Trifonov, O. Sinyashin
{"title":"Elements of the Fifth Group of the Periodic System of D.I. Mendeleev – the Elements of Life","authors":"A. Gazizov, Y. M. Sadykova, E. Gibadullina, A. Burilov, L. Kibardina, I. R. Knyazeva, A. Trifonov, O. Sinyashin","doi":"10.22204/2410-4639-2019-102-02-26-45","DOIUrl":"https://doi.org/10.22204/2410-4639-2019-102-02-26-45","url":null,"abstract":"In the popular science review, dedicated to the 150th anniversary of the first publication of the Periodic Table of chemical elements by D.I. Mendeleev, the elements of the 5th (main) Group (namely nitrogen, phosphorus, arsenic, antimony, and bismuth) are considered. The history of these elements discovery and some their properties are shortly described. The elements of the fifth group are also called “the elements of life”, which is linked with both the development of living organisms themselves and their compounds importance for human life. The review confirms this thesis in a popular-science form, using the available literature data on the role of chemical compounds of Group 5th elements in the development of living nature as well as in the progress of human civilization.","PeriodicalId":122949,"journal":{"name":"Vestnik RFFI","volume":"18 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134368902","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analytical Chemistry of the 21st Century: New Face of the Science 21世纪的分析化学:科学的新面貌
Vestnik RFFI Pub Date : 2019-04-24 DOI: 10.22204/2410-4639-2019-101-01-120-128
Y. Zolotov
{"title":"Analytical Chemistry of the 21st Century: New Face of the Science","authors":"Y. Zolotov","doi":"10.22204/2410-4639-2019-101-01-120-128","DOIUrl":"https://doi.org/10.22204/2410-4639-2019-101-01-120-128","url":null,"abstract":"The paper constitutes a review of the analytical chemistry general state, changes in its development trends, as well as substantial rise of both its tasks volume and complexity and its potential. The place that the analytical chemistry takes among other sciences is briefly considered, and its instrumentation improvement is noted. Author focuses on the russian scientists’ advances in this sphere, particularly those whose investigation were supported by the Russian Foundation for Basic Research. Examples of the new analytical methods creation, the original analytical approaches development and the important applied tasks solution in spheres of medicine, environmental protection and the food and medicines quality and safety control are given. Author attempts to forecast the analytical chemistry development prospects for the next 10–15 years.","PeriodicalId":122949,"journal":{"name":"Vestnik RFFI","volume":"62 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114954947","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Russian Contribution to the Periodic System 俄罗斯对周期制的贡献
Vestnik RFFI Pub Date : 2019-04-24 DOI: 10.22204/2410-4639-2019-101-01-54-69
Elena A. Baum, V. Lunin
{"title":"Russian Contribution to the Periodic System","authors":"Elena A. Baum, V. Lunin","doi":"10.22204/2410-4639-2019-101-01-54-69","DOIUrl":"https://doi.org/10.22204/2410-4639-2019-101-01-54-69","url":null,"abstract":"For 50 years, scientists around the world have been searching for the relationship between the mass of atoms and the properties of elements, until the Russian scientist D.I. Mendeleev, having created the Periodic Table and formulated the Periodic Law, did complete this search. The discoveries of new chemical elements predicted by D.I. Mendeleev had soon followed and confirmed the fundamental importance of his Periodic law as the basic law of natural sciences. The works on the synthesis of transuranium and superheavy elements with serial numbers 113-118, been carried out by the scientists of the Joint Institute for Nuclear Research (Dubna, Russia) during the past 50 years, are the indisputable evidence of the validity of the Law of Periodicity of chemical elements and the proof of the Russian science triumph.","PeriodicalId":122949,"journal":{"name":"Vestnik RFFI","volume":"18 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132476080","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Mendeleev’s Periodic Table and Marine Biomolecules 门捷列夫元素周期表与海洋生物分子
Vestnik RFFI Pub Date : 2019-04-24 DOI: 10.22204/2410-4639-2019-101-01-105-119
V. Stonik, T. Makarieva
{"title":"Mendeleev’s Periodic Table and Marine Biomolecules","authors":"V. Stonik, T. Makarieva","doi":"10.22204/2410-4639-2019-101-01-105-119","DOIUrl":"https://doi.org/10.22204/2410-4639-2019-101-01-105-119","url":null,"abstract":"The mini-review highlights the involvement of some elements of Mendeleev Periodic Table into marine biogenic compounds and these elements participation in the marine organisms’ metabolism. Some metals accumulation by marine invertebrates and the metal complexation by highly structurally diverse secondary metabolites are discussed. In addition, examples of the covalent bonds formation in marine bioorganic molecules with a number of non-metals are considered.","PeriodicalId":122949,"journal":{"name":"Vestnik RFFI","volume":"283 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122105243","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
UNESCO Leading Role in the Celebration of the International Year of the Periodic Table of Chemical Elements (IYPT-2019) 教科文组织在庆祝化学元素周期表国际年(IYPT-2019)中的主导作用
Vestnik RFFI Pub Date : 2019-04-24 DOI: 10.22204/2410-4639-2019-101-01-43-53
N. Tsivadze
{"title":"UNESCO Leading Role in the Celebration of the International Year of the Periodic Table of Chemical Elements (IYPT-2019)","authors":"N. Tsivadze","doi":"10.22204/2410-4639-2019-101-01-43-53","DOIUrl":"https://doi.org/10.22204/2410-4639-2019-101-01-43-53","url":null,"abstract":"In accordance with United Nations General Assembly resolution, the year 2019 was proclaimed the International Year of the Periodic Table of Chemical Elements, and the United Nations Educational, Scientific and Cultural Organization (UNESCO) was designated as the lead organization for its implementation. At the present day, the UNESCO is the largest UN specialized agency with broad competence in providing interstate collaboration in the area of science, capable of playing a unique role for promotion of peace and sustainable development. The establishment of UN observances stimulates interest in the activities and programs of the organization in these areas, and also contributes to the intensification of activities at the international level. The proclamation of 2019 as the International Year of the Periodic Table is a recognition of the important role of the basic sciences, in particular, achievements in the field of chemistry and physics, in addressing the numerous development challenges that the world is currently facing in implementing the United Nations “2030 Agenda for Sustainable Development”. The International Year under the auspices of UNESCO provides an opportunity to mobilize all interested parties around the topic of science for peace and development – from government officials to media representatives and schoolchildren.","PeriodicalId":122949,"journal":{"name":"Vestnik RFFI","volume":"69 4","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"113988129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and Study of the New Superheavy Elements of D.I. Mendeleev Periodic Table of the Elements 门捷列夫元素周期表中新超重元素的合成与研究
Vestnik RFFI Pub Date : 2019-04-24 DOI: 10.22204/2410-4639-2019-101-01-87-104
Y. Oganessian
{"title":"Synthesis and Study of the New Superheavy Elements of D.I. Mendeleev Periodic Table of the Elements","authors":"Y. Oganessian","doi":"10.22204/2410-4639-2019-101-01-87-104","DOIUrl":"https://doi.org/10.22204/2410-4639-2019-101-01-87-104","url":null,"abstract":"In the sixties of the XX century, the possibility of existence of the region of increased stability of superheavy nuclei in the vicinity of Z | 114 and N | 184 was proved. For the first time a successful synthesis of superheavy elements was carried out in the Flerov Laboratory of Nuclear Reactions of the Joint Institute for Nuclear Research (JINR). Superheavy elements of D.I. Mendeleev Periodic Table of the Elements with atomic numbers 114–118 were synthesized in the fusion reactions of the nuclei of the transuranic elements with calcium-48 nuclei. The article deals with the choice of reactions for the synthesis of new elements, methods of studying their nuclear-physical and chemical properties. The experimental complex “Factory of superheavy elements” created in JINR and prospects of further research development are described.","PeriodicalId":122949,"journal":{"name":"Vestnik RFFI","volume":"9 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125278736","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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