Fibre ChemistryPub Date : 2024-03-25DOI: 10.1007/s10692-024-10485-3
{"title":"Methodological Challenges in Accounting for Test Conditions When Determining the Static Elastic Modulus of Advanced Aramid Structural Fibers","authors":"","doi":"10.1007/s10692-024-10485-3","DOIUrl":"https://doi.org/10.1007/s10692-024-10485-3","url":null,"abstract":"<p>To develop and implement reinforcing fibers of small diameter (less than 15 μm) and an elastic modulus exceeding 50 GPa, it is necessary to determine their mechanical properties. However, most of the conventional methods are challenging to apply to such objects due to the scale effect of the gauge length (distance between grips) on the static modulus when measuring fiber deformation by moving the grips (crosshead movement). This paper examines several advanced high-modulus fibers, including Twaron and Armos, along with introducing a model for calculating real modulus from measured values. To validate the model, experimental tests were carried out for several aramid fibers.</p>","PeriodicalId":12230,"journal":{"name":"Fibre Chemistry","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2024-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140300691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fibre ChemistryPub Date : 2024-03-23DOI: 10.1007/s10692-024-10481-7
A. E. Polyakov, M. S. Ivanov, P. G. Frasyn
{"title":"Electromechanical Device for Determining and Controlling Physical and Mechanical Parameters of Fiber Materials","authors":"A. E. Polyakov, M. S. Ivanov, P. G. Frasyn","doi":"10.1007/s10692-024-10481-7","DOIUrl":"https://doi.org/10.1007/s10692-024-10481-7","url":null,"abstract":"<p>This work focuses on upgrading a device for the determination and control of physical and mechanical parameters, including the deformation properties, of fibrous materials. The modifications involve implementing the functionality of a tensile testing machine, as well as the ability to simulate complex deformation zones within controlled electrical systems of technological equipment in laboratory conditions.</p>","PeriodicalId":12230,"journal":{"name":"Fibre Chemistry","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2024-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140200041","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fibre ChemistryPub Date : 2024-03-23DOI: 10.1007/s10692-024-10476-4
B. P. Makarov, A. Yu. Matrokhin, M. V. Shablygin, M. P. Mikhailova
{"title":"Flow of Polyoxadiazole Fiber-Forming Systems through Spinneret Capillaries under Dry-Wet Formation Conditions","authors":"B. P. Makarov, A. Yu. Matrokhin, M. V. Shablygin, M. P. Mikhailova","doi":"10.1007/s10692-024-10476-4","DOIUrl":"https://doi.org/10.1007/s10692-024-10476-4","url":null,"abstract":"<p>The article analyzes the factors involved in making polyoxadiazole fiber-forming systems through spinneret capillaries under dry-wet method conditions. The drawbacks of the wet polyoxadiazole fiber forming method were identified. A method of two-stage extrusion of solutions of polyoxadiazole fiber-forming systems, the first of which is carried out through spinneret holes into a gaseous medium and the second, in a precipitating dilute sulfuric acid bath, is proposed. A mathematical interpretation of the technological factors of polymer solution flow through spinneret capillaries, including the rate of solution flow through capillaries with different diameters and spinneret drafting, is offered.</p>","PeriodicalId":12230,"journal":{"name":"Fibre Chemistry","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2024-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140199979","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fibre ChemistryPub Date : 2024-03-23DOI: 10.1007/s10692-024-10486-2
S. M. Shebanov, V. G. Bova, M. S. Shebanov, A. V. Pavlikov, V. B. Ivanov, I. G. Kalinina, I. K. Novikov
{"title":"Microplastic Strength Increased by Using Graphene Oxide to Modify Aramid Filler","authors":"S. M. Shebanov, V. G. Bova, M. S. Shebanov, A. V. Pavlikov, V. B. Ivanov, I. G. Kalinina, I. K. Novikov","doi":"10.1007/s10692-024-10486-2","DOIUrl":"https://doi.org/10.1007/s10692-024-10486-2","url":null,"abstract":"<p>Changes in the strength of a one-dimensional elementary composite material−microplastic based on epoxide resin and complex aramid thread treated with graphene oxide are reported. The maximum increase in the strength of the microplastic was 13.36% and from 5.511 to 6.247 GPa. The graphene oxide concentration in the starting suspension for this was 0.0625 g/L.</p>","PeriodicalId":12230,"journal":{"name":"Fibre Chemistry","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2024-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140200144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fibre ChemistryPub Date : 2024-03-23DOI: 10.1007/s10692-024-10477-3
A. L. Kalabin, I. V. Koltsov
{"title":"Analytical Determination of Dependence of Full Gel Formation Time on Parameters of Fiber Making by Wet Method","authors":"A. L. Kalabin, I. V. Koltsov","doi":"10.1007/s10692-024-10477-3","DOIUrl":"https://doi.org/10.1007/s10692-024-10477-3","url":null,"abstract":"<p>The phenomenon of gel formation for the process of chemical fiber making from polymer solution was studied. An approximate algebraic equation of dependence of full gel formation time on precipitant concentration in the bath, precipitant content in the polymer solution, temperature of the solution in the bath, and radius of the polymer solution jet was derived. The dependencies obtained by modeling agree well with the results of calculations using a more comprehensive model of the gel formation process. Applicability of the derived equations for describing the gel formation phenomenon is shown.</p>","PeriodicalId":12230,"journal":{"name":"Fibre Chemistry","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2024-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140200043","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fibre ChemistryPub Date : 2024-03-23DOI: 10.1007/s10692-024-10479-1
D. A. Slobodova, R. M. Gorshkova, P. P. Gladyshev
{"title":"Thermodynamics of Sorption Processes in Sorbents Based on Pectic Polysaccharides","authors":"D. A. Slobodova, R. M. Gorshkova, P. P. Gladyshev","doi":"10.1007/s10692-024-10479-1","DOIUrl":"https://doi.org/10.1007/s10692-024-10479-1","url":null,"abstract":"<p>The sorption mechanism of cadmium ions is studied using isolated fractions of microgel and pectic substances from pomelo albedo, beet pulp, and sunflower calathides. The sorption capacity of pectic polysaccharides, degree of sorbent affinity for the sorbate, and their binding strength are evaluated. The sorption process is found to obey the Langmuir equation. The thermodynamic parameters of the sorption processes at temperatures from 298.15 to 318.15 K are evaluated. The sorption process is found to have an exothermic mixed character.</p>","PeriodicalId":12230,"journal":{"name":"Fibre Chemistry","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2024-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140200152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fibre ChemistryPub Date : 2024-03-23DOI: 10.1007/s10692-024-10478-2
V. P. Galitsyn, S. I. Shkurenko, A. V. Sokolov, P. M. Pakhomov
{"title":"Relationship of Strength of Fibers Obtained from Ultrahigh-Molecular-Weight Polyethylene Gel with Different Multiplicity of Orientation Stretching with their Breaking Elongation","authors":"V. P. Galitsyn, S. I. Shkurenko, A. V. Sokolov, P. M. Pakhomov","doi":"10.1007/s10692-024-10478-2","DOIUrl":"https://doi.org/10.1007/s10692-024-10478-2","url":null,"abstract":"<p>The object of the study were samples of fibers obtained from ultrahigh-molecular-weight polyethylene (UHMWP) gel with different multiplicity of stretching (λ) with a scatter (dispersion) of mechanical properties. It is shown that the dependence of strength (σ<sub>b</sub>) on breaking elongation (ε) of the studied samples is expressed by the equation σ<sub>b</sub> = σ<sub>b0</sub> + <i>K</i>·ε and appears as a series of variously inclined straight lines specific for each λ value, which converge upon extrapolation to ε = 0 to a single point (pole), the ordinate of which coincides with the strength of unoriented fiber (σ<sub>b0</sub>). With increase of λ the straight lines representing the course of the relationships σ<sub>b</sub>(ε) shift toward low ε values. The decrease of ε is compensated abundantly by increase of angular coefficient <i>K</i>, which determines the degree of effect of ε on σ<sub>b</sub>.</p>","PeriodicalId":12230,"journal":{"name":"Fibre Chemistry","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2024-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140200047","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fibre ChemistryPub Date : 2023-12-28DOI: 10.1007/s10692-023-10474-y
{"title":"Effect of Air Temperature and Humidity on Electromechanical Properties of Elastic Graphite-Based Fiber Composites","authors":"","doi":"10.1007/s10692-023-10474-y","DOIUrl":"https://doi.org/10.1007/s10692-023-10474-y","url":null,"abstract":"<p>In this work, we demonstrate the possibility of obtaining elastic electrically conductive composites by aerosol application of graphite and polytetrafluoroethylene dispersions in an organic solvent on fiber materials made of natural and synthetic polymers. We observe a manyfold change of electrical resistance, as well as deformation and strain sensitivity parameters of the obtained fiber electrically conductive composites due to elongation and elastic contraction of filaments in the deformation range of 15–30 %. Laboratory prototypes of strain sensors manufactured from electrically conductive composites based on a knit fabric with a minimal electrical resistance hysteresis (less than 4 %) were tested under cyclic deformation.</p>","PeriodicalId":12230,"journal":{"name":"Fibre Chemistry","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2023-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139055613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fibre ChemistryPub Date : 2023-12-27DOI: 10.1007/s10692-023-10471-1
A. V. Kuznetsov, A. V. Genis, V. G. Oros
{"title":"Effect of Absorptive Fibrous Composite Material Structure on its Protective Properties","authors":"A. V. Kuznetsov, A. V. Genis, V. G. Oros","doi":"10.1007/s10692-023-10471-1","DOIUrl":"https://doi.org/10.1007/s10692-023-10471-1","url":null,"abstract":"<p>Various methods for modifying fibrous composite materials for application in respiratory protective devices are discussed. The main advantages and disadvantages of absorptive materials prepared by various methods for modifying composites are enumerated. The most effective activated carbons used in respiratory protective devices and samples of absorptive materials filled by them are compared by testing. The effects of the properties of the filler and the structure of the absorptive fibrous composite materials on its characteristics are studied.</p>","PeriodicalId":12230,"journal":{"name":"Fibre Chemistry","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139055688","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fibre ChemistryPub Date : 2023-12-27DOI: 10.1007/s10692-023-10473-z
{"title":"Modified Needle-Punched Nonwoven Based on Blend of Polymer Fibers","authors":"","doi":"10.1007/s10692-023-10473-z","DOIUrl":"https://doi.org/10.1007/s10692-023-10473-z","url":null,"abstract":"<p>The influence of the speed of processing on a special equipment and the content of polypropylene fibers on tensile strength and porosity of modified nonwovens has been studied. The technology of processing needle-punched nowoven fabrics made from blend of fibers with different melting points on a roller calender and a special equipment has been analyzed. At fixed temperatures of the roller in the special equipment the speed of processing affects the tensile strength, but the tensile strength of the modified materials does not depend on the processing speed significantly.</p>","PeriodicalId":12230,"journal":{"name":"Fibre Chemistry","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139055691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}