Technical Fiber Based on Flax Cellulose as Tire Cord Precursor

IF 0.5 4区 工程技术 Q4 CHEMISTRY, MULTIDISCIPLINARY
Ya.V. Golubev, I. S. Makarov, M. I. Vinogradov, L. K. Golova, A. G. Smyslov
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引用次数: 0

Abstract

Eco-unfriendliness of viscose process − the main producer of tire cord from wood cellulose − does not meet the growing need for creation of “green” tires. Alongside viscose cord fiber, production of a new cord fiber, Lyocell, from wood cellulose by eco-clean NMMO process is developing. Technical fibers were obtained from high-molecular flax cellulose by the method of its solid-phase dissolution in N-methylmorpholine-N-oxide. Comparative studies of the structure and mechanical and thermal properties of flax fibers and industrial cord fibers showed correspondence of their properties and that the stiffness of the flax fiber is almost 30 % higher than that of the cord fiber. Flax fibers are resistant to cyclic deformative actions and their deformation at high temperature is less than that of commercial samples. Water losses by the samples in the process of thermal studies at temperatures up to 170 °C have a reverse nature, which is confirmed by the stability of the mechanical properties of the samples under equilibrium conditions after thermal action. The obtained data set indicates sufficiently high fatigue strength of flax fibers and makes it possible to use them as cord fiber at par with cord fiber from wood cellulose.

Abstract Image

基于亚麻纤维素的工业纤维作为轮胎帘子线原丝
以木材纤维素为原料的轮胎帘子线的主要生产商--粘胶工艺的生态不友好性无法满足生产 "绿色 "轮胎日益增长的需求。除粘胶帘子线纤维外,利用生态清洁的 NMMO 工艺从木纤维素中生产新型帘子线纤维 Lyocell 的技术也在不断发展。通过在 N-甲基吗啉-N-氧化物中固相溶解的方法,从高分子亚麻纤维素中获得了工业纤维。对亚麻纤维和工业帘子线纤维的结构、机械性能和热性能进行的比较研究表明,它们的性能是一致的,亚麻纤维的刚度比帘子线纤维高出近 30%。亚麻纤维可抵抗循环变形作用,其在高温下的变形小于商业样品。在温度高达 170 °C 的热研究过程中,样品的水分损失具有反向性质,这一点可以从热作用后平衡条件下样品机械性能的稳定性得到证实。所获得的数据表明亚麻纤维具有足够高的疲劳强度,因此可以将其用作帘子线纤维,与从木材纤维素中提取的帘子线纤维相媲美。
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来源期刊
Fibre Chemistry
Fibre Chemistry 工程技术-材料科学:纺织
CiteScore
0.70
自引率
60.00%
发文量
70
审稿时长
6-12 weeks
期刊介绍: Fibre Chemistry publishes original research and review articles in the field of man-made fibre production and application. The journal offers scientific and technical articles on the following aspects: chemistry, technology, machinery and economics of man-made production; the initial monomers and polymers; the properties of man-made fibres and their processing in various industry branches (textiles, rubber, composites, etc).
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