{"title":"Sustainable advances in activated carbon for environmental and industrial applications","authors":"Anjas Asrani, Brijesh Prasad, Narendra Gariya, Harvinder Singh, Nitin Kumar, Kaushal Kumar, Abhijit Bhowmik, Virat Khanna, Priyaranjan Samal, Vivek John, Ajay Kumar","doi":"10.1002/ep.70176","DOIUrl":"10.1002/ep.70176","url":null,"abstract":"<p>Activated carbon (AC) has garnered widespread attention as a versatile and sustainable material for environmental remediation and industrial applications. This review offers a comprehensive and structured analysis of recent advancements in the synthesis, modification, and application of activated carbon, with an emphasis on sustainable development. The study critically evaluates fabrication techniques—including physical activation, chemical activation, hydrothermal carbonization, and microwave-assisted methods—using renewable precursors such as agricultural residues, industrial by-products, and natural biomass. Comparative insights into physical forms (powdered, granular, pellet, and membrane) and their influence on adsorption efficiency are also presented. The paper explores various chemical, physical, and microwave-assisted modification techniques aimed at enhancing surface area, porosity, and functional selectivity. It highlights the role of pore size distribution (micro-, meso-, and macropores) in adsorption dynamics and explains how surface functionalization, metal doping, and nitrogen/sulfur treatments tailor activated carbon for specific contaminants. Applications span multiple domains, including the removal of dyes, heavy metals, volatile organic compounds (VOCs), pharmaceuticals, and greenhouse gases like CO<sub>2</sub>. In addition to mapping out practical applications, the study identifies key benefits such as cost-effectiveness, resource circularity, and regenerability. It also acknowledges prevailing challenges—including environmental concerns associated with chemical activation, material variability, and scale-up limitations. The manuscript integrates emerging trends in green activation, hybrid composites, nanotechnology, and predictive modeling, providing a forward-looking roadmap for researchers and industry practitioners. By aligning technological innovation with environmental sustainability, this work establishes activated carbon as a cornerstone material for future eco-engineered solutions.</p>","PeriodicalId":11701,"journal":{"name":"Environmental Progress & Sustainable Energy","volume":"45 1","pages":""},"PeriodicalIF":2.3,"publicationDate":"2026-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146139734","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hadeer O. Refaey, Mohamed H. Abdo, Afify D. G. Al-Afify, Amal A. Othman, Rehab Mahmoud, Mahmoud A. Roshdy, Fathy M. Mohamed
{"title":"Water quality, heavy metals, and microbial assessments of Nile River water at Beni-Suef governorate, Egypt","authors":"Hadeer O. Refaey, Mohamed H. Abdo, Afify D. G. Al-Afify, Amal A. Othman, Rehab Mahmoud, Mahmoud A. Roshdy, Fathy M. Mohamed","doi":"10.1002/ep.70135","DOIUrl":"10.1002/ep.70135","url":null,"abstract":"<p>This study investigates the assessment of the water quality and microbial quality of the Nile River water within the Beni-Suef governorate in Egypt. Twenty water samples were collected seasonally from Autumn 2023 to Summer 2024. The findings showed a significant increase in nitrate, ammonium, and orthophosphate concentrations, especially in the vicinity of agricultural drainage points. Place, season, and inter-group interactions were attributed to the significant differences seen in the analysis of variance for all bacterial groups. Canadian Council of Ministers of the Environment-water quality index was used to assess each location's overall water quality. The majority of physicochemical characteristics were found to be within allowable bounds for irrigation, drinking water, and the protection of aquatic life. Extreme caution is advised in the Beni-Suef governorate's River Nile, even though the levels of water contamination are below WHO-acceptable thresholds. To preserve this essential water resource, recommendations include implementing sustainable agricultural practices, enforcing stronger regulations on polluting sources, and launching public awareness initiatives. These precautions include limiting the excessive use of organic fertilizers, establishing pollutant industries, and avoiding the use of wastewater and sewage sludge in agriculture.</p>","PeriodicalId":11701,"journal":{"name":"Environmental Progress & Sustainable Energy","volume":"45 1","pages":""},"PeriodicalIF":2.3,"publicationDate":"2026-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146136729","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Issue Information - Info for Authors","authors":"","doi":"10.1002/ep.70346","DOIUrl":"10.1002/ep.70346","url":null,"abstract":"","PeriodicalId":11701,"journal":{"name":"Environmental Progress & Sustainable Energy","volume":"45 1","pages":""},"PeriodicalIF":2.3,"publicationDate":"2026-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://aiche.onlinelibrary.wiley.com/doi/epdf/10.1002/ep.70346","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146130361","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Environmental sustainability, entropy generation, energy and exergy analysis of sanitary waste syngas-diesel blends in RCCI combustion mode","authors":"Akash Paul, Vishal Patil, Paramvir Singh, Rajsekhar Panua, Sudarshan Kumar","doi":"10.1002/ep.70116","DOIUrl":"10.1002/ep.70116","url":null,"abstract":"<p>This study addresses the dual challenge of waste management and sustainable energy by investigating the utilization of sanitary-waste-derived syngas in a dual-fuel Reactivity-Controlled Compression Ignition (RCCI) engine. Sanitary waste, co-gasified with CO<sub>2</sub>, produces hydrogen-rich syngas, offering a novel route for both waste valorization and partial diesel displacement. The engine was operated under varying load conditions using different diesel-syngas injection strategies (DS2–DS10), with syngas port-injected and diesel directly injected. A combined energy and exergy analysis was performed to evaluate combustion behavior, emission characteristics, entropy generation, and the sustainability index. The results revealed that the DS2 blend (2 ms syngas injection) delivered the most balanced performance, achieving only a 4.1% reduction in exergy efficiency compared to diesel while limiting exergy destruction and entropy generation. Higher syngas fractions such as DS10 degraded performance, leading to an 18.45% drop in exergy efficiency and a 36.26% increase in entropy generation. Compared to diesel, DS2 showed minor losses in BTE (4.68%) and exhaust energy (3.72%) but enabled a net improvement in environmental sustainability metrics. The novelty of this work lies in demonstrating the viability of sanitary-waste syngas as a co-fuel in RCCI mode, supported by integrated thermodynamic and sustainability assessments, extending beyond conventional biomass syngas applications by addressing the energy-exergy trade-offs of hydrogen-rich waste-derived fuels.</p>","PeriodicalId":11701,"journal":{"name":"Environmental Progress & Sustainable Energy","volume":"45 1","pages":""},"PeriodicalIF":2.3,"publicationDate":"2026-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146136873","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Upgrading waste polyethylene into superhydrophilic aerogel membrane for efficient oily emulsion wastewater treatment","authors":"Xuejie Yue, Liping Gan, Jicheng Xu, Dongya Yang, Tao Zhang, Fengxian Qiu","doi":"10.1002/ep.70098","DOIUrl":"10.1002/ep.70098","url":null,"abstract":"<p>Removing oil from oily emulsion wastewater is critically required prior to their downstream processing. However, the commonly used superhydrophilic separation membranes suffer from a complex hydrophilic modification process, high cost, and low efficiency. Herein, a cost-effective superhydrophilic aerogel membrane was presented via phase transfer and low-temperature plasma strategy using waste polyethylene as a building block. This plasma strategy involves directly and swiftly introducing oxygen functional groups with high surface energy onto the membrane surface, avoiding classical and sophisticated wet chemistry such as graft polymerization or physical modification. Such a direct plasma strategy renders the intrinsically hydrophobic polyethylene-based aerogel membrane stable and robust superhydrophilicity in harsh environments and excellent underwater anti-oil adhesion properties, thus achieving excellent gravity-driven oil-in-water emulsions separation with high flux (1940 L m<sup>−2</sup> h<sup>−1</sup>) and high separation efficiency (98.9%). Additionally, this directly hydrophilized aerogel membrane presents favorable reusability, thereby maintaining satisfactory separation flux and efficiency even after 10 cycles of separation. Overall, this work provides a general and efficient avenue to surface engineer polyethylene-based aerogel membrane for rapid separation of oil-in-water emulsion wastewater.</p>","PeriodicalId":11701,"journal":{"name":"Environmental Progress & Sustainable Energy","volume":"45 1","pages":""},"PeriodicalIF":2.3,"publicationDate":"2026-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146136175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Reduction of eggshell protein for adsorbing metals in water","authors":"Dun-Sheng Yang, Shyi-Tien Chen","doi":"10.1002/ep.70161","DOIUrl":"10.1002/ep.70161","url":null,"abstract":"<p>Eggshell (ES) membranes are rich in proteins consisting of many disulfide bonds and are reducible by various reductants to thiol ligands if adequately treated. This study adopted factorial experiments and response surface design to verify the most critical factors and determine the optimal conditions in eggshell reduction operations. Also, isothermal and kinetic adsorption models were used to demonstrate the metal adsorptive characteristics of the non-reduced and optimally reduced eggshells that adsorbed silver, copper, and chromium in water. Analysis-wise, metals in water were treated by aqua regia digestion and analyzed through inductively coupled plasma atomic emission spectroscopy (ICP-AES). Results revealed that thioglycol (i.e., 2-mercaptoethanol) and reaction time were the two most critical eggshell-modifying factors. Results of the response surface experiments indicated that the optimal eggshell reduction conditions were at the initial reductant concentration and reaction time equal to 9.75 M and 1.9 h, respectively. As for the isothermal metal adsorption using the modified eggshells, it fit the Langmuir model the best with the maximum adsorption capacities (<i>q</i><sub>m</sub>) of silver, copper, and chromium equal to 1.35, 2.09, and 2.39 mmole/g-ES, respectively. Data revealed that the reduced eggshells could completely adsorb silver, copper, and chromium within five hours and adsorbed around 6 and 2.6 times more copper and silver than the unreduced eggshells. These results demonstrate the much better uses of the reduced eggshells than plain eggshells for water metal purification.</p>","PeriodicalId":11701,"journal":{"name":"Environmental Progress & Sustainable Energy","volume":"45 1","pages":""},"PeriodicalIF":2.3,"publicationDate":"2026-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146136402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Optimizing the injector nozzle geometry to improve biodiesel-fueled CI engine's performance: An experimental approach","authors":"S. Jaichandar, D. Samuelraj, D. Yogaraj","doi":"10.1002/ep.70111","DOIUrl":"10.1002/ep.70111","url":null,"abstract":"<p>In this experimental analysis, the impacts of altering the injection nozzle geometry on the performance parameters of a compression ignition (CI) engine were explored. The injection nozzle geometry of the standard engine with three holes of 0.24 mm diameter was replaced by a 6-hole injector having 0.20 mm diameter. The modified engine was tested by a blend of 20 volume per cent of jatropha biodiesel (JOME20) in diesel. Considering the small size of the injector orifice, the injection pressure was raised to 240 bar from the standard pressure, and the injection timing was adjusted to 21° before Top Dead Center (bTDC) from the normal. The test findings revealed that the modified engine showed an enhancement in “Brake Specific Fuel Consumption (BSFC)” and “Brake Thermal Efficiency (BTE).” Notable improvements in the decrease of emissions have been observed. However, the enhanced fuel-air mixing and high combustion temperature increased the oxides of nitrogen (NOx) emissions. The modification of the injection nozzle geometry showed improvements in BSFC, BTE, and a reduction in emissions, but with a trade-off of increased NOx emissions, highlighting the need for further optimization.</p>","PeriodicalId":11701,"journal":{"name":"Environmental Progress & Sustainable Energy","volume":"45 1","pages":""},"PeriodicalIF":2.3,"publicationDate":"2026-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146136501","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Study on preparation of porous water treatment fillers from fly ash by foaming","authors":"Ting Xia, Shuhao Xia, Jiliang Bi, Zhiheng Zhang, Ruyan Zhang, Ruiqing Wang","doi":"10.1002/ep.70108","DOIUrl":"10.1002/ep.70108","url":null,"abstract":"<p>Fly ash is one of the most troublesome industrial solid wastes in China, and the large amounts stockpiled in many regions urgently need value-added utilization. Owing to its honeycomb structure and high surface area, fly ash shows potential as a water treatment material. However, the commonly used ceramic-particle preparation process suffers from high energy consumption and low porosity. This study explored the process optimization of foamed fly ash filler, aiming to develop a non-sintered, porous substrate for water treatment. The results showed that using a certain power plant's fly ash as the raw material, with a ratio of 70% fly ash, 30% cement, and a 60% water to cement ratio, animal protein was used as the foaming agent; the foamed fly ash filler had the best performance. Its apparent density was 762.8 kg/m<sup>3</sup>, specific surface area was 8.75 m<sup>2</sup>/g, 1-hour water absorption rate was 37.25%, and the combined crushing and wear rate was 4.23%. In nitrogen and phosphorus adsorption tests, the non-sintered filler achieved removal rates of 66.58% for phosphorus and 52.59% for ammonia nitrogen, outperforming the commonly used substrates of sintered ceramic particles and natural quartz sand. The non-sintering route can promote large-scale resource utilization of fly ash and deliver environmental benefits by reducing waste and energy use.</p>","PeriodicalId":11701,"journal":{"name":"Environmental Progress & Sustainable Energy","volume":"45 1","pages":""},"PeriodicalIF":2.3,"publicationDate":"2026-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146140053","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Thermoeconomic and environmental co-optimization of diesel combined heat and power systems via compression ratio tuning: Parametric study for residential application","authors":"Behrad Alizadeh Kharkeshi","doi":"10.1002/ep.70172","DOIUrl":"10.1002/ep.70172","url":null,"abstract":"<p>This study addresses key research gaps in diesel engine-based combined heat and power (CHP) systems by presenting the very first overall Energy, Exergy, Economic, and Environmental (4E) investigation of compression ratio optimization. Unlike previous research, this research uniquely demonstrates that optimization of the in-built compression ratio in diesel-CHP systems can alone result in significant efficiency, economic, and environmental improvements. This novel 4E analysis and optimization approach opens up a new design pathway via quantification of multi-objective trade-offs of compression ratio modulation, thereby advancing CHP system design beyond peripheral retrofits. It has been demonstrated that raising the compression ratio (14:25) elevates engine power output by 44% and recoverable heat, to as much as 89.5% CHP efficiency. These advantages are realized, however, at severe costs: 6.8% more exergy destruction and 10.3% less carbon emission savings (CDER). To mitigate these trade-offs, a novel multi-objective genetic algorithm framework was developed with normalized objectives. Optimization returns cr = 20.11 as the Pareto-optimal solution, trading off 89.13% CHP efficiency, 0.2469 $/kWh energy cost, moderated exergy destruction (44.7 kJ/kg), and sustainable CDER (0.2389). Above all, the Pareto frontier delineates actionable design regimes: sustainability-focused applications favor cr = 14–18.89 (high emission reduction), while efficiency-focused systems operate at cr = 20.11–25 (peak <i>η</i><sub>CHP</sub>).</p>","PeriodicalId":11701,"journal":{"name":"Environmental Progress & Sustainable Energy","volume":"45 1","pages":""},"PeriodicalIF":2.3,"publicationDate":"2026-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146136129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}