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Synthesis and Performance of N-(Benzoyl) Stearic Acid Hydrazide N-(苯甲酰)硬脂酸肼的合成及性能研究
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/514386
Yan-Hua Cai, Shunhua Li
{"title":"Synthesis and Performance of N-(Benzoyl) Stearic Acid Hydrazide","authors":"Yan-Hua Cai, Shunhua Li","doi":"10.1155/2012/514386","DOIUrl":"https://doi.org/10.1155/2012/514386","url":null,"abstract":"N-(benzoyl) stearic acid hydrazide was synthesized from benzoyl hydrazine and stearyl chloride which was deprived from stearic acid via acylation. The structure of the compound had been characterized by FT-IR, 1H NMR, at the same time, the structure of N-(benzoyl) stearic acid hydrazide was optimized by the semiempirical method PM3. The influence of the reaction ratio, reaction time and reaction temperature to the yield of N-(benzoyl) stearic acid hydrazide was investigated by orthogonal experiment, and the optimized reaction condition was molar ratio of benzoyl hydrazine: stearyl chloride 1:1, reaction time 6 h, reaction temperature 70°C, and the yield was 92.9%. The TGA thermal analysis of N-(benzoyl) stearic acid hydrazide showed that thermal stability of N-(benzoyl) stearic acid hydrazide was affected by heating rate, and the N-(benzoyl) stearic acid hydrazide enhanced the tensile strength, modulus and elongation at break of Poly(L-lactic acid)(PLLA).","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/514386","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64328914","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Investigation of Friedel-Crafts Alkylation in the Presence of Supported Sulfonic Acid on Silica Gel 负载型磺酸存在下硅胶上Friedel-Crafts烷基化反应的研究
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/610579
A. Kiasat, M. Karimi-Cheshmeali, R. Soleymani, H. Rajabzadeh
{"title":"Investigation of Friedel-Crafts Alkylation in the Presence of Supported Sulfonic Acid on Silica Gel","authors":"A. Kiasat, M. Karimi-Cheshmeali, R. Soleymani, H. Rajabzadeh","doi":"10.1155/2012/610579","DOIUrl":"https://doi.org/10.1155/2012/610579","url":null,"abstract":"From the Reaction between cellulose and chloro sulfonic acid was prepared sulfuric acid cellulose composition as a new solid acid. The solid acid supported on silica gel and then as an effective catalyst in Friedel-Crafts alkylation of alcohols and aromatic compounds was used. The reaction progress was controlled using thin layer chromatography and the reaction products were analyzed using IR spectroscopy devise. The results show this new catalyst is effective in the friedel crafts alkylation and C-C bond formation was done in short time with very good yields.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/610579","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64337233","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Synthesis, Thermal Properties and Nucleating Effect of N, N, N, N'-Tetra(benzoyl) Ethylene Diamine Tetraacetic Acid Dihydrazide as Nucleating Agent of Poly(L-lactic acid) 聚l -乳酸成核剂N, N, N, N'-四(苯甲酰)乙二胺四乙酸二肼的合成、热性能及成核效应
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/645635
Yan-Hua Cai
{"title":"Synthesis, Thermal Properties and Nucleating Effect of N, N, N, N'-Tetra(benzoyl) Ethylene Diamine Tetraacetic Acid Dihydrazide as Nucleating Agent of Poly(L-lactic acid)","authors":"Yan-Hua Cai","doi":"10.1155/2012/645635","DOIUrl":"https://doi.org/10.1155/2012/645635","url":null,"abstract":"N, N, N, N'-Tetra(benzoyl) ethylene diamine tetraacetic acid dihydrazide as nucleating agent of Poly(L-lactic acid) (PLLA) was synthesized from benzoyl hydrazine and tetraacetic acid by acylation and ammoniation. and the structure of this novel tetraamide compound had been characterized by FT-IR. The thermal stability of N, N, N, N'-Tetra(benzoyl) ethylene diamine tetraacetic acid dihydrazide was investigated by TGA thermal analyzer. The result showed good thermal stability of N, N, N, N'-Tetra(benzoyl) ethylene diamine tetraacetic acid dihydrazide under 170 °C. N, N, N, N'-Tetra(benzoyl) ethylene diamine tetraacetic acid dihydrazide modified PLLA sample was prepared by a melt-mixing technique. With incorporation of 0.5% N, N, N, N'-Tetra(benzoyl) ethylene diamine tetraacetic acid dihydrazide, Non-isothermal crystallization behavior at different cooling rate showed the crystallization peak of PLLA became sharper and shift to higher temperature, and indicated that the presence of N, N, N, N'-Tetra(benzoyl) ethylene diamine tetraacetic acid dihydrazide accelerated the overall PLLA crystallization.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/645635","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64340515","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Recycling of Different Available Organic Wastes through Vermicomposting 利用蚯蚓堆肥回收不同的有机废物
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/945762
S. Karmakar, K. Brahmachari, A. Gangopadhyay, S. R. Choudhury
{"title":"Recycling of Different Available Organic Wastes through Vermicomposting","authors":"S. Karmakar, K. Brahmachari, A. Gangopadhyay, S. R. Choudhury","doi":"10.1155/2012/945762","DOIUrl":"https://doi.org/10.1155/2012/945762","url":null,"abstract":"Generation of organic wastes has been increased in an unprecedented rate in India with rapid population expansion, leading to disposal problems. These organic wastes can be converted into valuable wealth by applying vermicomposting technology. Vermicompost which provides macro and micro nutrients to the plants, also reduces pollution by providing a valuable substitute for chemical fertilizers. Present paper deals with vermicomposting of organic wastes from seven different sources and evaluation of nutrient in those vermicomposts following chemical analyses. These seven sources include coconut coir, water hyacinth, mixed materials, cabbage, banana pseudostem, cow dung, and rice husk. Three composting species of earthworms e.g. Eisenia. fetida, Eudrilus. eugeniae, and Perionyx excavatus were chosen for the experiment. Chemical analysis of vermicomposts under study clearly showed that the vermicompost from water hyacinth contained maximum amount of organic C, total N, and total K though the phosphorous content was maximum in vermicompost from mixed materials. Lowest nutrient content was observed in vermicompost of coconut coir. Vermicomposts from mixed materials, cabbage, banana pseudostem were at per in their chemical properties. It can be concluded that among the seven sources, vermicompost from water hyacinth is best for its nutrient value.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/945762","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64369952","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
Effect of Temperature on the Critical Micelle Concentration and Micellization Thermodynamic of Nonionic Surfactants: Polyoxyethylene Sorbitan Fatty Acid Esters 温度对非离子表面活性剂聚氧乙烯山梨糖脂肪酸酯临界胶束浓度和胶束热力学的影响
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/961739
E. Mohajeri, G. D. Noudeh
{"title":"Effect of Temperature on the Critical Micelle Concentration and Micellization Thermodynamic of Nonionic Surfactants: Polyoxyethylene Sorbitan Fatty Acid Esters","authors":"E. Mohajeri, G. D. Noudeh","doi":"10.1155/2012/961739","DOIUrl":"https://doi.org/10.1155/2012/961739","url":null,"abstract":"In this study, non-ionic surfactants, polyoxyethylene sorbitan fatty acid esters (polysorbate) are chosen to examine the temperature effect on the CMC over a wide temperature range. The enthalpy and entropy of micelle formation are evaluated according to the phase separation model. The surface tension of solutions was determined by means of Du Nouys ring. The CMC values were taken from the sharp breaks in the surface tension vs. logarithms of surfactant concentration plots. As the surfactants' chain length increases the CMC at a constant temperature decreases, which is directly related to the decrease of hydrophilicity of the molecules. For each surfactant, as the system temperature increases, the CMC initially decreases and then increases, owing to the smaller probability of hydrogen bond formation at higher temperatures. The onset of micellization tends to occur at higher concentrations as the temperature increases. To evaluate the enthalpy of micellization, the CMCs are first correlated by a polynomial equation. It is found that ∆Gom decreases monotonically as the temperature increases over the whole temperature range. Both ∆Hom and ∆Som appear to be decrease monotonically with an increase in temperature. The compensation temperature was found to be 42 oC by linear regression over the whole temperature range and for all three surfactant systems together.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/961739","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64371509","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 118
Synthesis, Characterization and Antimicrobial Activity of Imidazole Derivatives Based on 2-chloro-7-methyl-3-formylquinoline 2-氯-7-甲基-3-甲酰基喹啉类咪唑衍生物的合成、表征及抗菌活性研究
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/164235
R. Parab, B. Dixit
{"title":"Synthesis, Characterization and Antimicrobial Activity of Imidazole Derivatives Based on 2-chloro-7-methyl-3-formylquinoline","authors":"R. Parab, B. Dixit","doi":"10.1155/2012/164235","DOIUrl":"https://doi.org/10.1155/2012/164235","url":null,"abstract":"A series of oxazole and thereof imidazole derivatives were prepared from 2-chloro-7-methyl-3-formyl quinoline. The structures of all synthesized compounds were elucidated by elemental, IR, 1HNMR, 13CNMR spectra. Supplementary to these, they were assayed in vitro for their antimicrobial activity; it was revealed that some synthesized derivatives were exhibiting competent biological activity against both gram negative and gram positive bacterial species and fungal microorganisms.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/164235","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64297729","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
An Efficient One-Pot Synthesis of 1,8-Dioxodecahydroacridines Using Silica-Supported Polyphosphoric Acid (PPA-SiO2) under Solvent-Free Conditions 无溶剂条件下二氧化硅负载多磷酸(PPA-SiO2)一锅高效合成1,8-二氧十二氢吖啶化合物
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/214231
F. Moeinpour, A. Khojastehnezhad
{"title":"An Efficient One-Pot Synthesis of 1,8-Dioxodecahydroacridines Using Silica-Supported Polyphosphoric Acid (PPA-SiO2) under Solvent-Free Conditions","authors":"F. Moeinpour, A. Khojastehnezhad","doi":"10.1155/2012/214231","DOIUrl":"https://doi.org/10.1155/2012/214231","url":null,"abstract":"Silica gel–supported polyphosphoric acid (PPA-SiO2) was found to be an efficient catalyst for the synthesis of 1,8-dioxodecahydroacridines via one-pot three-component condensation of aryl aldehydes, dimedone, and ammonium acetate or 4-methyl aniline in high yields, easy workup procedure and short period of times. The catalyst was separated by simple filtration and used in the reaction three times without any significant loss of its activity.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/214231","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64302745","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 20
Densities, Viscosities, Refractive Indices and Sound Speeds of Acetophenone with Methylacetate at Different Temperatures 苯乙酮与乙酸甲酯在不同温度下的密度、粘度、折射率和声速
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/237068
K. Saravanakumar, R. Baskaran, T. Kubendran
{"title":"Densities, Viscosities, Refractive Indices and Sound Speeds of Acetophenone with Methylacetate at Different Temperatures","authors":"K. Saravanakumar, R. Baskaran, T. Kubendran","doi":"10.1155/2012/237068","DOIUrl":"https://doi.org/10.1155/2012/237068","url":null,"abstract":"Densities, viscosities, refractive indices and ultrasonic velocities of the binary mixtures of Acetophenone with Methyl acetate were measured over the entire mole fractions at (303.15, 313.15 and 323.15) K. From these experimental results, excess molar volumes VE, viscosity deviation ∆η, refractive index deviation ∆nD, deviations in isentropic compressibility ∆Ks and excess intermolecular free length ∆Lf are calculated. The viscosity values were fitted to the models of Krishnan-Laddha and McAllister. The thermo physical properties under study were fit to the Jouyban - Acree model. The excess values were correlated using Redlich-Kister polynomial equation to obtain their coefficients and standard deviations. It was found that in all cases, the data obtained fitted with the values correlated by the corresponding models very well. The results are interpreted in terms of molecular interactions occurring in the solution.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/237068","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64304097","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
Ab Initio and DFT Studies of Conformational Properties of Heteroatom Containing Ketene Analogues and Their Comparison with the Related Cyclic Analogues 含烯酮类似物杂原子构象性质的从头算和DFT研究及其与相关环类似物的比较
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/380109
S. Z. Sayyed-alangi, M. T. Baei
{"title":"Ab Initio and DFT Studies of Conformational Properties of Heteroatom Containing Ketene Analogues and Their Comparison with the Related Cyclic Analogues","authors":"S. Z. Sayyed-alangi, M. T. Baei","doi":"10.1155/2012/380109","DOIUrl":"https://doi.org/10.1155/2012/380109","url":null,"abstract":"Minimum-energy and transition state geometries of 3-thioxoprop-2-enethial, 3-thioxoacrylaldehyde, 3-oxoprop-2-enethial, 3-selenoxoprop-2-enethial, 3-thioxoprop-2-eneselenal, 3-selenoxoprop-2-eneselenal, 3-oxoacrylaldehyde, 3-selenoxoacrylaldehyde and 3-oxoprop-2-eneselenal were calculated using HF, B3LYP and MP2 levels of theory and 6-31","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/380109","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64317441","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Synthesis, Spectral and Thermal Behavior of Some New Four Coordinated Complexes 新型四配位配合物的合成、光谱和热行为
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/952926
M. Montazerozohori, S. Khani, S. Joohari, S. A. Musavi
{"title":"Synthesis, Spectral and Thermal Behavior of Some New Four Coordinated Complexes","authors":"M. Montazerozohori, S. Khani, S. Joohari, S. A. Musavi","doi":"10.1155/2012/952926","DOIUrl":"https://doi.org/10.1155/2012/952926","url":null,"abstract":"A new symmetric bidentate Schiff base N, N′ bis(4-fluorobenzal-dehydene)-1,2-diaminoethane(L) and its complexes with general formula MLX2 (M= Zn(II), Cd(II) and Hg(II) and X=chloride, bromide, iodide, thiocyanate and azide) have been prepared. The ligand and complexes have been established by microanalysis, electronic, FT-IR, 1H and 13C NMR spectra, and by molar conductivity measurements. All compounds are non-electrolytes in chloroform or DMSO-d6. The thermal behavior of the complexes shows weight loss by decomposition of the anions and ligand segments in the subsequent steps. Some activation thermodynamic parameters such as E*, ∆H*, ∆S* and ∆G* were calculated from thermal analysis.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/952926","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64370410","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
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