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Alteration Mapping for Porphyry Cu Targeting in the Western Chagai Belt, Pakistan, Using ZY1-02D Spaceborne Hyperspectral Data 利用 ZY1-02D 星载高光谱数据绘制巴基斯坦西查盖矿带斑岩铜矿靶区蚀变图
IF 5.8 1区 地球科学
Economic Geology Pub Date : 2024-03-01 DOI: 10.5382/econgeo.5045
Lei Liu, Chuntao Yin, Yasir Shaheen Khalil, Jun Hong, Jilu Feng, Huishan Zhang
{"title":"Alteration Mapping for Porphyry Cu Targeting in the Western Chagai Belt, Pakistan, Using ZY1-02D Spaceborne Hyperspectral Data","authors":"Lei Liu, Chuntao Yin, Yasir Shaheen Khalil, Jun Hong, Jilu Feng, Huishan Zhang","doi":"10.5382/econgeo.5045","DOIUrl":"https://doi.org/10.5382/econgeo.5045","url":null,"abstract":"The Chagai porphyry Cu belt in Pakistan is an important metallogenic terrain extending approximately 400 km in an east-west direction. Most of the known porphyry Cu deposits, such as the world-class Reko Diq deposit and Saindak deposit, are located in the western Chagai belt. In this study, the ZY1-02D hyperspectral data acquired by a recently launched spaceborne imaging spectrometer with 166 bands within a 0.4- to 2.5-μm spectral region were used to map mineral information over 8,000 km<sup>2</sup> for exploring potential targets of porphyry Cu mineralization in the western Chagai belt. False color composite, spectral angle mapper, and wavelength position mapping methods were used in this research leading to the identification of a series of alteration minerals (including muscovite [sericite], kaolinite, alunite, epidote, chlorite, and calcite) from ZY1-02D data. The alteration mineral maps derived from ZY1-02D data match well with the known deposits and field inspections. Twenty-three new targets were identified as potential porphyry Cu mineralization targets for further exploration in the study area. Three targets, north of Saindak, Koh-i-Sultan, and Durban Chah, and six alteration sites in the southwest of Durban Chah, were inspected in the field, and Cu-Au mineralization was confirmed in all these inspected areas. As the ZY1-02D hyperspectral data covers most of the land area of the earth, this study provides new insights for mineral exploration and lithologic mapping in remote regions.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"26 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140096855","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Linking Porphyry Cu Formation to Tectonic Change in Postsubduction Settings: A Case Study from the Giant Yulong Belt, Eastern Tibet 后俯冲环境中斑岩铜矿形成与构造变化的联系:西藏东部巨型玉龙带案例研究
IF 5.8 1区 地球科学
Economic Geology Pub Date : 2024-03-01 DOI: 10.5382/econgeo.5052
Ming-Liang Huang, Xian-Wu Bi, Rui-Zhong Hu, Massimo Chiaradia, Jing-Jing Zhu, Lei-Luo Xu, Zong-Yong Yang
{"title":"Linking Porphyry Cu Formation to Tectonic Change in Postsubduction Settings: A Case Study from the Giant Yulong Belt, Eastern Tibet","authors":"Ming-Liang Huang, Xian-Wu Bi, Rui-Zhong Hu, Massimo Chiaradia, Jing-Jing Zhu, Lei-Luo Xu, Zong-Yong Yang","doi":"10.5382/econgeo.5052","DOIUrl":"https://doi.org/10.5382/econgeo.5052","url":null,"abstract":"Porphyry deposits in magmatic arcs form coincident with changes to steady-state oceanic subduction conditions, such as changes in plate convergence rate and vector or angle of subduction. However, it remains unclear whether such processes also operated during formation of postsubduction porphyry deposits. The Yulong magmatic belt in the eastern Tibetan Plateau consists of middle to late Eocene igneous rocks (~51–35 Ma) that formed during the India-Asia collision, whereas all known porphyry deposits are associated with late Eocene rocks (43–35 Ma). A synthesis of new and published geochemical data shows marked variations from the middle to late Eocene, including increasing whole-rock La/Yb, Sr/Y, and Eu<sub>N</sub>/Eu<sub>N</sub>* values, as well as zircon Eu<sub>N</sub>/Eu<sub>N</sub>* values. These geochemical variations, together with petrographic observations, indicate a transition from plagioclase-dominated to amphibole-dominated fractionation from the middle to late Eocene.Coupled changes of magma compositions and porphyry Cu metallogeny from the middle to late Eocene coincided with, or were slightly preceded by, the onset of regional uplift and crustal thickening, triggered by the India-Asia hard collision and rapid deceleration of the India-Asia convergence rate at ca. 50 to 44 Ma. Crustal thickening may have caused prolonged magma differentiation at greater depths and accumulation of dissolved H<sub>2</sub>O, both of which contributed to amphibole-dominated fractionation and generation of hydrous melt that are prospective for porphyry Cu mineralization. Our study highlights the importance of tectonic changes in the formation of the Yulong and other postsubduction porphyry Cu belts—a scenario similar to that operated in subduction-related settings such as the Andes.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"20 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140096930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
PLUME-GENERATED 90° STRESS CHANGE LINKED TO TRANSITION FROM RADIATING TO CIRCUMFERENTIAL DOLERITE DIKE SWARMS OF THE SIBERIAN TRAPS LARGE IGNEOUS PROVINCE AND TO EMPLACEMENT OF THE NORILSK-TALNAKH ORE DEPOSITS 西伯利亚陷落大火成岩带从放射状到环状辉绿岩堤群的过渡以及诺里尔斯克-塔尔纳克矿床的形成与羽状产生的 90° 应力变化有关
IF 5.8 1区 地球科学
Economic Geology Pub Date : 2024-03-01 DOI: 10.5382/econgeo.5065
R.E. Ernst, H. El Bilali, K. L. Buchan, S.M. Jowitt
{"title":"PLUME-GENERATED 90° STRESS CHANGE LINKED TO TRANSITION FROM RADIATING TO CIRCUMFERENTIAL DOLERITE DIKE SWARMS OF THE SIBERIAN TRAPS LARGE IGNEOUS PROVINCE AND TO EMPLACEMENT OF THE NORILSK-TALNAKH ORE DEPOSITS","authors":"R.E. Ernst, H. El Bilali, K. L. Buchan, S.M. Jowitt","doi":"10.5382/econgeo.5065","DOIUrl":"https://doi.org/10.5382/econgeo.5065","url":null,"abstract":"A 90° change in stress orientation has been previously proposed as the trigger for the final emplacement of the world-class Norilsk-Talnakh magmatic sulfide mineralization via the migration of accumulated sulfide melts from elsewhere within the plumbing system of the Siberian Traps large igneous province (LIP). We propose that this stress change does not require and was not triggered by a distal change in plate boundary stresses, but instead can be explained both temporally and spatially by stress changes recorded in the dike swarm patterns of the Siberian Traps LIP, namely the transition from a giant radiating dike swarm (associated with mantle plume uplift) to a giant circumferential swarm (linked to flattening of the plume head). The mantle plume stress-related changes recorded by these dike swarms, rather than distal plate boundary stress changes, were therefore most likely the trigger for the emplacement of the Norilsk-Talnakh mineralization. Other LIPs that have both giant radiating and circumferential dike swarms most likely reflect similar major and rapid changes in stress orientation, indicating that mantle plume-induced stress changes revealed by dike swarms should be considered an additional tool in magmatic sulfide exploration.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"20 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140096852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Giant Rare Earth Element Accumulation Related to Voluminous, Highly Evolved Carbonatite: A Microanalytical Study of Carbonate Minerals From the Bayan Obo Deposit, China 与体积巨大、高度演化的碳酸盐岩有关的巨型稀土元素聚集:中国巴彦奥布矿藏碳酸盐矿物显微分析研究
IF 5.8 1区 地球科学
Economic Geology Pub Date : 2024-03-01 DOI: 10.5382/econgeo.5060
Xiao-Chun Li, Hong-Rui Fan, Jian-Hui Su, David I. Groves, Kui-Feng Yang, Xin-Fu Zhao
{"title":"Giant Rare Earth Element Accumulation Related to Voluminous, Highly Evolved Carbonatite: A Microanalytical Study of Carbonate Minerals From the Bayan Obo Deposit, China","authors":"Xiao-Chun Li, Hong-Rui Fan, Jian-Hui Su, David I. Groves, Kui-Feng Yang, Xin-Fu Zhao","doi":"10.5382/econgeo.5060","DOIUrl":"https://doi.org/10.5382/econgeo.5060","url":null,"abstract":"The giant Bayan Obo deposit in China represents the largest rare earth element (REE) resource in the world, but the mechanisms for its highly anomalous REE enrichment have long been controversial. The central debate concerns the nature and origin of the ore-hosting dolomite. In this study, a texturally constrained microanalytical study of carbonate minerals from the Bayan Obo ore-hosting dolomite is presented to resolve this controversy.The dolomite rocks contain two major components: the early-stage coarse-grained dolomite (CD) and the late-stage fine-grained dolomite (FD). The CD dolomite grains have C-O isotope ratios (δ<sup>13</sup>C<sub>Vienna-PeeDee Belemnite (V-PDB)</sub>: –4.8 to –3.3‰; δ<sup>18</sup>O<sub>Vienna-standard mean ocean water (V-SMOW)</sub>: 7.1 to 11.9‰) plotting in or adjacent to the primary igneous carbonatite field, with a narrow range of low <sup>87</sup>Sr/<sup>86</sup>Sr ratios (0.70262–0.70327). The mantle-like C-O and Sr isotopes indicate that the coarse-grained dolomite rocks are magmatic in origin. Dolomite grains from the FD have experienced extensive hydrothermal alteration related to both REE mineralization and post-ore metamorphism of the Bayan Obo deposit. The domains of primary unaltered dolomite have high SrO and MnO contents that clearly distinguish them from sedimentary carbonates. The <sup>87</sup>Sr/<sup>86</sup>Sr ratios of unaltered dolomite domains range from 0.70271 to 0.70473, with the majority lower than 0.7035, contrasting with higher <sup>87</sup>Sr/<sup>86</sup>Sr ratios of Mesoproterozoic sedimentary carbonates globally. Thus, the primary unaltered fine-grained dolomite, the precursor to the FD, is also proposed to be a carbonatite.Compared with dolomite grains from the CD, most of the unaltered dolomite domains within the FD are more enriched in FeO and MnO and have higher δ<sup>13</sup>C<sub>V-PDB</sub> (-4.9 to 0.3 ‰) and δ<sup>18</sup>O<sub>V-SMOW</sub> (9.4 to 17.1 ‰) values. In addition, the FD contains abundant REE- and volatile-rich hydrothermal minerals and Fe-Mg carbonates, which are rare in the CD. The geochemical and mineralogical data in conjunction indicate that the melts forming the late-stage FD were much more evolved than those forming the early-stage CD. It is noteworthy that the unaltered dolomite domains within the FD have a wider range of <sup>87</sup>Sr/<sup>86</sup>Sr ratios than those within the CD, which implies that the CD and FD, at least a proportion of them, are unlikely to have crystallized from the same progenitor magmas. Some FD was possibly the product of fractionation of less-evolved carbonatitic magma that generated the CD, whereas other FD crystallized from new pulses of magmas that were highly fractionated at depth.When compared with other carbonatite complexes, the Bayan Obo carbonatite suite is notable for having a large surface area (~48 km<sup>2</sup> in outcrop) and containing an anomalously large proportion of highly evolved components. The voluminous ","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"22 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140096921","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
San Albino, Nicaragua: A Low-Angle, Thrust-Controlled Orogenic Gold Deposit 尼加拉瓜圣阿尔比诺:低角度、受推力控制的造山运动金矿藏
IF 5.8 1区 地球科学
Economic Geology Pub Date : 2024-03-01 DOI: 10.5382/econgeo.5042
Rael D. Lipson, Richard J. Goldfarb, Ben M. Frieman, John Payne
{"title":"San Albino, Nicaragua: A Low-Angle, Thrust-Controlled Orogenic Gold Deposit","authors":"Rael D. Lipson, Richard J. Goldfarb, Ben M. Frieman, John Payne","doi":"10.5382/econgeo.5042","DOIUrl":"https://doi.org/10.5382/econgeo.5042","url":null,"abstract":"The San Albino deposit is an orogenic gold occurrence hosted by a low-angle thrust that is the site of a new open-pit mine in northern Nicaragua. The deposit is hosted in greenschist facies rocks of the Jurassic metasedimentary Neuvo Segovia Formation. The schist was uplifted and exposed during arc accretion and Cretaceous thin-skin deformation, forming the NE-striking Colon fold-and-thrust belt. Deformation included emplacement of the 119 to 113 Ma NE-trending Dipilto batholith into the regionally metamorphosed clastic rocks about 5 km northwest of the San Albino deposit. Mineralization is dominated by three laminated quartz vein systems (i.e., San Albino, Naranjo, Arras) that broadly follow shallowly dipping (approx. 30°) carbonaceous shears roughly concordant to schistosity along the limbs of a doubly plunging antiform. The three main parallel shears are each separated by about 90 m and individually reach a maximum thickness of about 8 m. Maximum thickness of ore zones is where post-ore local folding and reverse motion along the shallow shears has duplicated the laminated low-angle gold-bearing veins (D<sub>2</sub> and early D<sub>3</sub>). Additional gold was added to the veins, with abundant sulfides, during a subsequent brecciation event of the early formed quartz veins that accompanied progressive thrusting (late D<sub>3</sub>). This predated boudinage of the veins during continued compression and thrust loading (D<sub>4</sub>); high gold grades are particularly notable along pyrite- and arsenopyrite-bearing stylolites formed during D<sub>4</sub> pressure solution. The D<sub>2</sub> to D<sub>3</sub> gold event is likely coeval with Albian uplift of the Dipilto batholith and with back thrusting in the schist aided by the stress inhomogeneities provided by the igneous complex.Low-angle thrust-controlled orogenic gold deposits may represent world-class exploration targets because of their large linear footprints, although they are traditionally looked at as less favorable exploration targets relative to gold systems developed more commonly along high-angle reverse faults. Our case study of the San Albino deposit shows that although low-angle deposits are not inherently misoriented for failure like the more common subvertical reverse fault-related deposits, they may be sites of significant pressure buildup due to hydrothermal mineral precipitation during initial water-rock interaction or slight temperature decreases along the low-angle flow path. Resulting fluid cycling may lead to thick laminated vein development, such as seen at San Albino, where especially high-grade zones may be associated with local steepening and/or dilational zones within the broader, low-angle vein-hosting shear system.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"71 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140135939","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Silver Behavior During Magmatic and Magmatic-Hydrothermal Evolution of a Highly Evolved Reduced Granitic System Related to the Giant Shuangjianzishan Ag-Pb-Zn-(Sn) Epithermal Deposit, Northeast China 中国东北双剑子山银铅锌(锡)热液巨型矿床相关高度演化的还原花岗岩系岩浆和岩浆-热液演化过程中的银行为
IF 5.8 1区 地球科学
Economic Geology Pub Date : 2024-01-01 DOI: 10.5382/econgeo.5031
Kaixuan Hui, Bertrand Rottier, Kezhang Qin, Zoltan Zajacz, Alexandra Tsay, Junxing Zhao, Shen Gao, Ruizhe Shi
{"title":"Silver Behavior During Magmatic and Magmatic-Hydrothermal Evolution of a Highly Evolved Reduced Granitic System Related to the Giant Shuangjianzishan Ag-Pb-Zn-(Sn) Epithermal Deposit, Northeast China","authors":"Kaixuan Hui, Bertrand Rottier, Kezhang Qin, Zoltan Zajacz, Alexandra Tsay, Junxing Zhao, Shen Gao, Ruizhe Shi","doi":"10.5382/econgeo.5031","DOIUrl":"https://doi.org/10.5382/econgeo.5031","url":null,"abstract":"Magmatic-related epithermal silver-rich polymetallic deposits are among the most important sources of Ag in the world, and they are found associated with magmatic systems with striking differences. Most of the time, they are associated either with I-type oxidized (magnetite-series granite) intermediate to evolved intrusions or with S-type/A-type reduced (ilmenite-series granite) highly evolved intrusions. To better understand these associations, the Ag evolution has been tracked during the magmatic differentiation and the magmatic-hydrothermal transition stage of A-type highly evolved porphyritic granites associated with the giant Shuangjianzishan Ag-Pb-Zn-(Sn) epithermal deposit, the largest known Ag deposit of Asia (145 million tonnes at 128.5 g/t Ag and 2.2 wt % Pb + Zn) located in the largest known metallogenic province for Ag in China (the southern Great Xing’an Range). At the Shuangjianzishan deposit, the porphyritic granite complex consists of three temporally distinct intrusions—a coarse-grained monzogranite porphyry, a fine-grained syenogranite porphyry, and a fine-grained syenogranite—having crystallized at ~2 kbar and ~750°C and recording a continuous magmatic differentiation trend. The silicate melt that generated the last highly differentiated intrusion (fine-grained syenogranite) is interpreted as the source of the mineralizing fluids forming the Shuangjianzishan Ag-Pb-Zn-(Sn) epithermal deposit, as it is the only intrusive unit that reached fluid saturation, as indicated by cotrapped fluid and melt inclusions in quartz phenocrysts and by the occurrences of unidirectional solidification textures (USTs). Silver evolution in the different porphyritic granite facies was reconstructed with laser ablation-inductively coupled plasma-mass spectrometry analyses of quartz-hosted silicate melt inclusions, amphibole-hosted magmatic sulfide inclusions, and chemical modeling. The silicate melt forming the porphyritic granite complex was sulfide saturated during the first crystallization stage, as shown by the occurrence of Ag-rich monosulfide solid solution (MSS) inclusions hosted in amphibole phenocrysts from the coarse-grained monzogranite porphyry and from mafic microgranular enclaves hosted in the coarse-grained monzogranite porphyry. However, these Ag-rich MSSs had only a minimal impact on the Ag budget of the magmatic system, as shown by the increase of the Ag concentration (~100–1,000 ppb) in quartz-hosted silicate melt inclusions during the further evolution of the system until fluid exsolution was reached. These results combined with mass balance modeling suggest that Ag and Sn are efficiently transferred to the evolving residual melt during crystallization and crystal-melt segregation. The results of this study indicate that highly Ag endowed epithermal polymetallic deposits can be formed from the exsolution of Ag-rich mineralizing fluids from relatively low volume, highly evolved, reduced melts, similar to those responsible for the fo","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"20 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139752511","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tin Mineralization in the Triassic Chacaltaya District (Cordillera Real, Bolivia) Traced by In Situ Chemical and δ18O-δ11B Compositions of Tourmaline 通过电气石的原位化学成分和δ18O-δ11B成分追踪三叠纪查卡尔塔亚地区(玻利维亚雷阿尔山脉)的锡矿化情况
IF 5.8 1区 地球科学
Economic Geology Pub Date : 2023-12-18 DOI: 10.5382/econgeo.5051
L. Torró, Matthieu Harlaux, Angela Castro-Morante, Jean Vallance, Lorenzo Tavazzani, A. Bouvier, T. Bovay, Cyril Chelle-Michou, Thierry P. A. Sempere, Joan Carles Melgarejo
{"title":"Tin Mineralization in the Triassic Chacaltaya District (Cordillera Real, Bolivia) Traced by In Situ Chemical and δ18O-δ11B Compositions of Tourmaline","authors":"L. Torró, Matthieu Harlaux, Angela Castro-Morante, Jean Vallance, Lorenzo Tavazzani, A. Bouvier, T. Bovay, Cyril Chelle-Michou, Thierry P. A. Sempere, Joan Carles Melgarejo","doi":"10.5382/econgeo.5051","DOIUrl":"https://doi.org/10.5382/econgeo.5051","url":null,"abstract":"\u0000 We present a petrographic and geochemical study of tourmaline from the Triassic Chacaltaya Sn-polymetallic district in the Cordillera Real of Bolivia. Tourmaline is associated with greisens, breccias, and veins, which occur around the Triassic Chacaltaya peraluminous granitic stock hosted by Silurian metasedimentary rocks. Three main petrographic types of hydrothermal tourmaline have been identified: pre-ore greisen-related (Tur-1), syn-ore breccia-related (Tur-2), and syn-ore vein-related (Tur-3). The three types of tourmaline belong to the alkali group and have Fe-rich compositions mostly close to the schorl end member. Overlapping Fe/(Fe + Mg) ratios suggest broadly similar compositions of the hydrothermal fluids during the deposition of tourmaline. The most notable differences in minor and trace element contents include relative enrichment in Zn and Li in Tur-1 and relative enrichment in Ca, Sc, V, Cr, Sr, Sn, Y, Cs, Be, and Zr in Tur-3, with Tur-2 showing intermediate compositions between those of Tur-1 and Tur-3. The progressive enrichment in Sn from Tur-1 (avg = 14 ppm) through Tur-2 (avg = 311 ppm) and Tur-3 (avg = 476 ppm) indicates an increase of Sn concentrations in the hydrothermal system coinciding with cassiterite deposition in breccias and veins. The transition from high Li and Zn contents in Tur-1 to elevated Ca, Sr, V, and Cr contents in Tur-3 is interpreted as reflecting interaction between a hydrothermal fluid of magmatic origin and the metasedimentary country rocks. Strong and relatively steady positive Eu anomalies in all tourmaline types suggest dominantly reduced hydrothermal conditions. In situ δ18O and δ11B analyses of greisen-related Tur-1 reveal crystallization in isotopic equilibrium with magmatic water derived from a peraluminous S-type granite. In contrast, higher δ18O values of breccia-related Tur-2 and vein-related Tur-3 indicate crystallization in isotopic equilibrium with a fluid of metamorphic origin or a magmatic fluid that variably interacted with the metasedimentary host rocks. Geochemical modeling reproduces interactions between a fluid of magmatic origin and the host metasedimentary rocks at moderate water/rock ratios between 0.1 and 0.5. We conclude that cassiterite mineralization in the Chacaltaya district was formed primarily through interaction between B-Sn–rich magmatic fluids and the metasedimentary country rocks.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":" 28","pages":""},"PeriodicalIF":5.8,"publicationDate":"2023-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138963442","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nature and Origin of a Massive Sulfide Occurrence in the Karrat Group: Evidence for Paleoproterozoic VMS Mineralization in Central West Greenland 卡拉特群大规模硫化物矿床的性质和起源:格陵兰岛中西部古生代 VMS 矿化的证据
IF 5.8 1区 地球科学
Economic Geology Pub Date : 2023-12-18 DOI: 10.5382/econgeo.5036
Y. M. DeWolfe, J. Kolb, E. Sørensen, D. Rosa, P. Guarnieri
{"title":"Nature and Origin of a Massive Sulfide Occurrence in the Karrat Group: Evidence for Paleoproterozoic VMS Mineralization in Central West Greenland","authors":"Y. M. DeWolfe, J. Kolb, E. Sørensen, D. Rosa, P. Guarnieri","doi":"10.5382/econgeo.5036","DOIUrl":"https://doi.org/10.5382/econgeo.5036","url":null,"abstract":"\u0000 Mafic volcanic rocks of the Kangilleq Formation of the Paleoproterozoic Karrat Group host volcanogenic massive sulfide (VMS) mineralization in the area of central Kangiusap Kuua, central West Greenland. The mafic volcanic rocks display evidence of subaqueous, effusive eruption and redeposition by mass debris flows generated along fault scarps on the sea floor. A zone of semiconformable quartz alteration and disconformable chlorite alteration within hydrothermal breccias and mafic tuff breccias near the top of the volcanic sequence is interpreted to reflect a synvolcanic hydrothermal system. Conformable, massive to semimassive, and discordant, stringer-style sulfide mineralization is hosted within the quartz- and chlorite-altered volcanic rocks. The massive to semimassive sulfide mineralization is ~10 m thick and crops out along strike for ~2,000 m. The stringer zone is ≤10 m thick with individual sulfide stringers ranging in width from 5 to 90 cm. All sulfide zones are dominated by coarse pyrrhotite and pyrite, with trace amounts of sphalerite and chalcopyrite.\u0000 The pillow lavas are subalkaline with geochemical characteristics typical of modern transitional to tholeiitic mid-ocean ridge or back-arc basin basalt. Trace element and Nd isotope data suggest that these lavas erupted in an epicratonic, back-arc basin. Characteristics of the host rocks indicate a period of localized rifting, volcanism, and VMS formation during genesis of the Karrat Group, which is dominated by siliciclastic rocks.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":" 8","pages":""},"PeriodicalIF":5.8,"publicationDate":"2023-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138963669","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Geology and Structure of the Río Blanco Cu-Mo Porphyry Deposit, Central Chile 智利中部 Río Blanco 铜-钼斑岩矿藏的地质与结构
IF 5.8 1区 地球科学
Economic Geology Pub Date : 2023-12-18 DOI: 10.5382/econgeo.5043
J. Skarmeta, Fernando Ortiz, Marco Solé
{"title":"Geology and Structure of the Río Blanco Cu-Mo Porphyry Deposit, Central Chile","authors":"J. Skarmeta, Fernando Ortiz, Marco Solé","doi":"10.5382/econgeo.5043","DOIUrl":"https://doi.org/10.5382/econgeo.5043","url":null,"abstract":"The Río Blanco-Los Bronces deposit is the largest Cu-Mo porphyry deposit in the world in terms of contained Cu metal. It is the product of protracted superposed magmatic and hydrothermal activity associated with multiple intrusive and brecciation events, with simultaneous regional uplift, erosion and unroofing, and decompression. Magmatism resulted in three major mineralization-alteration stages. The premineralization stage occurred during the emplacement of the San Francisco batholith, resulting in late magmatic and early hydrothermal events. The synmineralization stage corresponds to the main hydrothermal events associated with the Río Blanco-Los Bronces porphyry and breccia complexes, which were related to three intrusion phases, widespread brecciation, and an epithermal-style advanced argillic alteration. Late-stage magmatism, followed by hydrothermal activity, was associated with the emplacement of subvolcanic rhyolite complexes and late-stage porphyry intrusions. The synmineralization intrusions are associated with high-grade breccia bodies that have well-defined alteration-zonation patterns. Compilation and analysis of the historical Río Blanco structural data sets from the different mines, tunnels, and pits have allowed the assignment of all mapped structures to four hierarchical orders based on their continuity, crosscutting relationships, and infill compositions. The larger structures (orders 0 and 1) have along-strike continuity, correlate between drifts and/or mine levels, whereas smaller structures (orders 2 and 3) were grouped according to their dimensions and distributions within the larger-order structure-defined panels. All orders 0 and 1 structures were modeled in three dimensions, while orders 2 and 3 were in two dimensions. The structures mapped at Río Blanco have an intimate relationship with the pre- to the late-stage geologic evolution of magmatism and mineralization. The regional- and to a lesser extent district-scale structural evolution was related to premineralization basin-opening and subsequent tectonic inversion, whereas at the camp scale, syn- to late mineralization intrusions and related hydrothermal features were superimposed on this inherited structural architecture.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"38 ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2023-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139176234","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Superimposed Gold Mineralization Events in the Tuanshanbei Orogenic Gold Deposit, Central Jiangnan Orogen, South China 华南江南造山带中部团山北造山带金矿床的叠加金矿化事件
1区 地球科学
Economic Geology Pub Date : 2023-11-06 DOI: 10.5382/econgeo.5034
Cheng Wang, Yong-Jun Shao, Richard Goldfarb, Shi-Min Tan, Ji Sun, Chao Zhou, Han Zheng, Qing-Quan Liu, Yi-Qu Xiong
{"title":"Superimposed Gold Mineralization Events in the Tuanshanbei Orogenic Gold Deposit, Central Jiangnan Orogen, South China","authors":"Cheng Wang, Yong-Jun Shao, Richard Goldfarb, Shi-Min Tan, Ji Sun, Chao Zhou, Han Zheng, Qing-Quan Liu, Yi-Qu Xiong","doi":"10.5382/econgeo.5034","DOIUrl":"https://doi.org/10.5382/econgeo.5034","url":null,"abstract":"Abstract The Jiangnan orogen, one of the largest gold-producing areas in China, has experienced multiple orogenic events with complex structural overprinting that is marked by multiple stages of magmatism, deformation, metamorphism, and orogenic gold mineralization. Different orogenic events have been recognized in the Neoproterozoic, mid-Paleozoic, Triassic, and Early Cretaceous, reflecting collisions and intracontinental orogenic episodes. The age of gold deposition in the Jiangnan orogen, however, has been poorly constrained owing to the absence of suitable dating minerals. Field studies in the orogen indicate the Tuanshanbei gold deposit includes two generations of auriferous quartz-ankerite-pyrite-arsenopyrite veins (Q2 and Q3), with the latter of the two notable for containing more abundant ankerite and base metal sulfides. The Q2 veins were formed throughout the near S-N–directed shortening associated with D1 deformation and along resulting subhorizontal to low-angle-dipping EW- to WNW-striking transpressive faults. The Q3 veins, containing about 70% of the total gold resource, were primarily localized in moderately to steeply dipping NW-striking tensional/tensional shear faults and moderately dipping NE- to NNE-striking transpressive faults that were products of NW-SE–directed shortening during D2 deformation. Both vein generations are temporally younger than the 437.2 ± 4.2 Ma Tuanshanbei granodiorite host, and both are crosscut by postgold ca. 225 Ma diabase dikes. Hydrothermal monazite coexists with native gold and gold-bearing metal sulfides in the Q2 and Q3 veins. The Q2 monazite yielded a Tera-Wasserburg lower intercept age of 415.1 ± 2.1 Ma, consistent within error with an ankerite Sm-Nd isochron age of 410 ± 15 Ma and a laser ablation-inductively coupled plasma-mass spectrometry hydrothermal zircon 206Pb/238U age of 411.2 ± 4.0 Ma. The Q3 monazite yielded a Tera-Wasserburg lower intercept age of 234.3 ± 1.1 Ma. These new ages suggest that the Early Devonian gold event was overprinted by hydrothermal activity along the same structural system almost 200 m.y. later such that the gold resource must be a product of two temporally distinct events. Geologic and structural evidence, coupled with existing published geochemical data, suggests both ore-forming events were related to crustal metamorphism typical of most orogenic gold deposits. Fluids would have been derived from Neoproterozoic metasedimentary basement rocks, most likely from metamorphic devolatilization of the Neoproterozoic Cangxiyan Group greenschist-amphibolite facies metasediments. There is no evidence suggesting any type of magmatic contribution to the ore-forming process at either time. The data are best interpreted to suggest that various parts of the basement were metamorphosed near the greenschist-amphibolite boundary at different times, but during both times, the gold-bearing metamorphic fluids eventually migrated into the same structural conduits.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"233 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135685058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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