Current Green Chemistry最新文献

Organic Electrosynthesis: A Promising Green Tool in Solving Key Steps for the Total Synthesis of Complex Natural Products 有机电合成：解决复杂天然产物全合成关键步骤的前景广阔的绿色工具

IF 2.2

Current Green Chemistry Pub Date : 2023-12-20 DOI: 10.2174/0122133461270888231128050236

Ayan Bandyopadhyay, Rajib Sarkar

{"title":"Organic Electrosynthesis: A Promising Green Tool in Solving Key Steps for the Total Synthesis of Complex Natural Products","authors":"Ayan Bandyopadhyay, Rajib Sarkar","doi":"10.2174/0122133461270888231128050236","DOIUrl":"https://doi.org/10.2174/0122133461270888231128050236","url":null,"abstract":"Electro-organic synthesis, an atom-efficient, sustainable, mild process, permits an ecofriendly and elegant green path to synthesize structurally complex, still valuable molecules, avoiding the use of conventional harsh oxidizing and reducing agents and long-route reaction protocols. Being one of the oldest forms of reaction setups in a laboratory, it deals with fundamental redox chemistry through the direct application of electrical potential. Here flow of electrons acts as an oxidizing agent at the anode at the same time reducing agent at the cathode, depending upon the requirement of the reaction. Simultaneously, it minimizes the generation of reagent waste during the reaction. However, electrifying organic synthesis plays more than preventing the waste footprint. This technology provides an alternative roadmap through nonclassical bond disconnections to access desired target molecules by cutting down a number of steps with the formation of apparently looking difficult bonds with excellent regio-, chemo-and stereoselectivity. Hence, it emerges as an alternative and attractive technique for the contemporary synthetic communities. Consequently, in recent years, multiple milestones have been achieved in the electro-organic synthesis of fascinating natural products through oxidative C-C bond formation, C-H/N-H functionalization, very rare oxidative N-N dimerization, RCDA dimerization, etc. Thus, synthesis of extremely complex natural products through finding new electro-synthetic route as a key methodology have become one of the alluring synthetic targets to synthetic chemists because of their versatile utilities in medicine, agriculture, food, and cosmetic industry. This review presents advances in electrochemistry in the total synthesis of 20 complex natural products reported since 2013. Enabling synthetic steps are analyzed alongside innate advantages as well as future prospects are speculated.","PeriodicalId":10856,"journal":{"name":"Current Green Chemistry","volume":"34 S1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2023-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139168409","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Eco-friendly Synthesis of Copper Nanoparticles: An Overview of the Epoch-making Role of Natural Resources, Applications, and Recent Developments 纳米铜的生态友好合成:自然资源的划时代作用、应用和最新进展综述

Current Green Chemistry Pub Date : 2023-11-10 DOI: 10.2174/0122133461279579231103055412

Sameea Ahmed Khan, Rajesh Sharma

{"title":"Eco-friendly Synthesis of Copper Nanoparticles: An Overview of the Epoch-making Role of Natural Resources, Applications, and Recent Developments","authors":"Sameea Ahmed Khan, Rajesh Sharma","doi":"10.2174/0122133461279579231103055412","DOIUrl":"https://doi.org/10.2174/0122133461279579231103055412","url":null,"abstract":"Abstract: Green synthesized metal nanoparticles offer a broad spectrum of applications. They also offer unmatched significance because they are eco-friendly, cost-effective, and less toxic to human beings. Copper nanoparticles, when synthesized using green protocols, exhibit enriched properties and are substantially used in the preparation of nanofluids, medicine, conductive agents, etc. In this review, we have highlighted how the side effects of synthetic compounds have paved the way to look for greener alternatives in the field of nanomedicine. Green fabrication, characterization, and activities of copper nanoparticles using different biological sources have been extensively studied and reported. The biological sources have been broadly classified into two categories, plant-based and microbial-based. Natural resources are a reservoir of flavonoids, polyphenols, saponins, etc. They act as reducing and stabilizing agents for nanoparticles. Bio-synthesized metal nanoparticles have presented themselves as anti-microbial agents, bioreductors, cytotoxic agents, bioremediators, etc. This review has described the effective utilization of natural resources for synthesizing copper nanoparticles. It also emphasizes the recent developments in this field covering the diverse applications of the same.","PeriodicalId":10856,"journal":{"name":"Current Green Chemistry","volume":"102 42","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135136670","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Pharmaceuticals in the Water: Emerging Concerns and Innovative Remediation Solutions 水中的药物:新出现的问题和创新的补救解决方案

Current Green Chemistry Pub Date : 2023-10-23 DOI: 10.2174/0122133461272526231012064151

Smriti Ojha, Shivendra Mani Tripathi, Pratik Kumar Vishwakarma, Sudhanshu Mishra

{"title":"Pharmaceuticals in the Water: Emerging Concerns and Innovative Remediation Solutions","authors":"Smriti Ojha, Shivendra Mani Tripathi, Pratik Kumar Vishwakarma, Sudhanshu Mishra","doi":"10.2174/0122133461272526231012064151","DOIUrl":"https://doi.org/10.2174/0122133461272526231012064151","url":null,"abstract":"Abstract: Pharmaceutical contamination, resulting from the discharge of active pharmaceutical ingredients (APIs) and other related compounds into the water, has become a growing concern due to its potential adverse effects on ecosystems and human health. This review article aims to examine the many facets of pharmaceutical contamination and highlight the most recent developments in its remediation. The effects of pharmaceuticals, sources, and pathways of pharmaceutical contamination, as well as the difficulties in detecting and evaluating its toxicities, have been included in the present manuscript. Nowadays various remediation strategies are employed to mitigate pharmaceutical contamination in water. Conventional wastewater treatment techniques, including activated sludge processes and membrane filtration, are effective in removing a portion of the pharmaceutical compounds. However, advanced oxidation processes such as ozonation and photocatalysis have shown promising results in enhancing the degradation of recalcitrant APIs. Nanotechnology-based approaches, such as the use of nanoparticles for adsorption and degradation, and bioremediation methods utilizing microbial degradation, enzymatic processes, and phytoremediation, offer potential future directions for efficient and sustainable remediation. This review describes the most recent developments, current status, and potential research directions with the future prospects of pharmaceutical pollutants.","PeriodicalId":10856,"journal":{"name":"Current Green Chemistry","volume":"51 5","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135414682","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Eco-friendly Synthesis of Indole Conjugated Chromeno[B]Pyridines as Anti-cancer agents and their Molecular Modelling Studies 吲哚共轭色氨酸吡啶的生态合成及其分子模拟研究

Current Green Chemistry Pub Date : 2023-10-20 DOI: 10.2174/0122133461267868231018100148

Anjali Jha, V R Krishnam Raju

引用次数: 0

Ultrasound-Assisted Catalyst-Free Knoevenagel Condensation of Carbonyl Compounds with C – H Acids in Water 羰基化合物与C - H酸在水中无催化剂Knoevenagel缩合

Current Green Chemistry Pub Date : 2023-10-11 DOI: 10.2174/0122133461268098231004072803

Goutam Brahmachari, Indrajit Karmakar, Mullicka Mandal, Bhagirath Mandal

引用次数: 0

Organocatalysis for the Chemical Fixation of Carbon Dioxide to Synthesise N-Heterocycles 二氧化碳化学固定合成n -杂环的有机催化

Current Green Chemistry Pub Date : 2023-10-04 DOI: 10.2174/0122133461255437230930182648

Henrique Esteves, Nathália Evelyn Morais Costa, Vinicius Kalil Tomazett, Jorge Luiz Sônego Milani, Rafael Pavão das Chagas, Ângelo de Fátima

引用次数: 0

Biochar, Clay, Zeolites, and Microorganism-Based Methods for Remediation of Heavy Metals 生物炭、粘土、沸石和微生物为基础的重金属修复方法

Current Green Chemistry Pub Date : 2023-09-15 DOI: 10.2174/2213346110666230915140448

Yukti Monga, Shivangi Sharma, Shivendra Singh, Ashu Gupta

引用次数: 0

Solvent-Free Approaches towards the Synthesis of Therapeutically Important Heterocycles 无溶剂方法合成具有重要治疗意义的杂环化合物

Current Green Chemistry Pub Date : 2023-09-15 DOI: 10.2174/2213346110666230915163034

Ambarish Priyadarshan, Garima Tripathi, Anil Kumar Singh, Sanchiyata Rajkhowa, Abhijeet Kumar, Vinod K. Tiwari

引用次数: 0

Agricultural and Veterinary Pesticides Residues in Human Food 人类食物中的农业和兽医农药残留

IF 2.2

Current Green Chemistry Pub Date : 2023-09-01 DOI: 10.2174/2213346110666230607150014

Latifa Khattabi, Moussa Mokhtari, M. Bouhenna, Ahmed Fellak, Mohamed Abu-Mustapha, Saleh Akkal, Feriel Sellam

{"title":"Agricultural and Veterinary Pesticides Residues in Human Food","authors":"Latifa Khattabi, Moussa Mokhtari, M. Bouhenna, Ahmed Fellak, Mohamed Abu-Mustapha, Saleh Akkal, Feriel Sellam","doi":"10.2174/2213346110666230607150014","DOIUrl":"https://doi.org/10.2174/2213346110666230607150014","url":null,"abstract":"\u0000\u0000Expanding utilization of pesticides can provoke serious issues due to their biomagnification and persistent nature. Eventual contamination of fresh daily-consumed food by pesticide\u0000constitutes a human food security problem.\u0000\u0000\u0000\u0000The present investigation planned to check out whether the most hazardous pesticides could be\u0000found in a varied collection of wheat, vegetables and fruit, on the other hand, we attempted to know if\u0000some banned and no more commercialized pesticides could be even detected. Effectively, we have chosen\u0000to analyze wheat, potato, tomato, apple, peach and grape, so, after the extraction procedure of pesticides,\u0000we used gas chromatography-mass spectrometry (GC-MS) to identify some hazardous compounds (organochlorines and organophosphorus). These compounds were used as standards to generate calibration\u0000curves and estimate precisely their concentration in the tested samples using selected ion monitoring\u0000(SIM) mode.\u0000\u0000\u0000\u0000The results have shown the presence of an important quantity of pesticides that are no more used\u0000(banned) for decades for agriculture purposes but they are still used as veterinary drugs, such as lindane\u0000(0.2 ppm grape, 0.32 ppm tomato) and fenchlorphos (0.5 ppm grape).\u0000\u0000\u0000\u0000This survey should be routinely executed by scientists and concerned authorities to control\u0000pesticides circulation with their exact amounts in food and other environmental matrices as well as eventual contamination with another toxic element.\u0000","PeriodicalId":10856,"journal":{"name":"Current Green Chemistry","volume":" ","pages":""},"PeriodicalIF":2.2,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48550354","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Acknowledgements to Reviewers 审稿人致谢

Current Green Chemistry Pub Date : 2023-09-01 DOI: 10.2174/221334611002230621163020

引用次数: 0