Complex Metals最新文献

Theoretical calculations on layered perovskites: implications for photocatalysis 层状钙钛矿的理论计算:光催化的意义

Complex Metals Pub Date : 2014-12-31 DOI: 10.1080/2164232x.2014.921386

Xiang Liu, K. Sohlberg

引用次数: 0

Stability constants and complex formation equilibria between iron, calcium, and zinc metal ions with vitamin B9 and glycine 铁、钙、锌金属离子与维生素B9和甘氨酸之间的稳定常数和络合形成平衡

Complex Metals Pub Date : 2014-09-05 DOI: 10.1080/2164232X.2014.941115

A. Fazary, A. Ramadan

引用次数: 16

Synthesis, spectral characterization and biological activity studies of transition metal complexes of Schiff base ligand containing indole moiety 含吲哚席夫碱配体过渡金属配合物的合成、光谱表征及生物活性研究

Complex Metals Pub Date : 2014-03-27 DOI: 10.1080/2164232X.2014.889580

Fazlur Rahaman, B. Mruthyunjayaswamy

{"title":"Synthesis, spectral characterization and biological activity studies of transition metal complexes of Schiff base ligand containing indole moiety","authors":"Fazlur Rahaman, B. Mruthyunjayaswamy","doi":"10.1080/2164232X.2014.889580","DOIUrl":"https://doi.org/10.1080/2164232X.2014.889580","url":null,"abstract":"A new series of transition metal complexes of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II), with a tridentate (oxygen nitrogen nitrogen) ligand 3,5-dimethyl-N′-[(1E)-1′-pyridin-2′-ylethylidene]-1H-indole-2-carbohydrazide (L) have been synthesized and characterized on the basis of analytical, magnetic susceptibility, infra red, nuclear magnetic resonance, fast atom bombardment-mass, electron paramagnetic resonance spectral studies, X-ray powder diffraction and UV-visible spectral data. Based on analytical and molar conductance data, the complexes may be formulated as [M(L)2]·(H2O)n, where M˭ Co, Cu and Ni and [M(L)Cl2].(H2O)n, where M=Zn, Cd and Hg. The spectral studies revealed that, an octahedral geometry for Co(II), Ni(II) and Cu(II) complexes, whereas square pyramidal geometry for Zn(II), Cd(II) and Hg(II) complexes. The ligand and its Co(II) complex have been characterized by X-ray powder diffraction studies. The ligand and its complexes were tested for their antibacterial activity against Escherichia coli & Staphyloccocus aureus and antifungal activity against Aspergillus niger & Candida albicans.","PeriodicalId":10590,"journal":{"name":"Complex Metals","volume":"17 1","pages":"88 - 95"},"PeriodicalIF":0.0,"publicationDate":"2014-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82106419","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 32

Synthesis, characterization, fluorescence and biological studies of Mn(II), Fe(III) and Zn(II) complexes of Schiff bases derived from Isatin and 3-substituted-4-amino-5-mercapto-1,2,4-triazoles Isatin和3-取代-4-氨基-5-巯基-1,2,4-三唑衍生的Schiff碱Mn(II)、Fe(III)和Zn(II)配合物的合成、表征、荧光和生物学研究

Complex Metals Pub Date : 2014-03-25 DOI: 10.1080/2164232X.2014.884939

S. Patil, M. Manjunatha, A. Kulkarni, P. S. Badami

引用次数: 20

Synthesis and characterization of mononuclear copper(II) complex of tetradentate N2S2 donor set and the study of DNA and bovine serum albumin binding 四齿N2S2供体单核铜(II)配合物的合成、表征及DNA与牛血清白蛋白结合的研究

Complex Metals Pub Date : 2014-03-18 DOI: 10.1080/2164232X.2014.887448

S. Sarkar, B. Das

引用次数: 5

Synthesis, characterization and biological profile of metal and azo-metal complexes of embelin 栓塞金属及偶氮金属配合物的合成、表征及生物学特性

Complex Metals Pub Date : 2014-03-18 DOI: 10.1080/2164232X.2014.886963

R. Aravindhan, T. Sreelatha, P. Perumal, A. Gnanamani

{"title":"Synthesis, characterization and biological profile of metal and azo-metal complexes of embelin","authors":"R. Aravindhan, T. Sreelatha, P. Perumal, A. Gnanamani","doi":"10.1080/2164232X.2014.886963","DOIUrl":"https://doi.org/10.1080/2164232X.2014.886963","url":null,"abstract":"The present study emphasizes synthesis and bioprofiling of embelin, embelin-metal (EM) and embelin-azo-metal (EAM) complexes in detail. EM complexes were prepared using pure embelin and d-block transition elements, namely Mn, Fe, Co, Ni, Cu, and Zn. Similarly, EAM complexes were synthesized using phenyl azo-embelin with the said transition metals. Embelin, EM, and EAM complexes were subjected to ultra violet visible spectroscopy, Fourier transform infrared spectroscopy, nuclear magnetic resonance, electrospray ionization mass spectrometry, thermogravimetric analysis, carbon hydrogen nitrogen sulfur analysis. With regard to bioprofiling, the test complexes were studied for the antioxidant and antimicrobial activities. Results revealed that the prepared EM and EAM complexes form octahedral complexes with embelin with the yield in the range of 45–75%. All the instrumental analyses authenticate the interaction of metals with bidentate embelin through its enolic and quinonic oxygen atoms as [M(Emb)2(H2O)2]H2O and [M(Emb-Azo)2(H2O)2]. The antioxidant profile studies suggested that upon complexation with metals, the free radical scavenging activity of embelin reduced significantly. But, with regard to antimicrobial activity, cobalt and nickel embelin complexes displayed>80% growth inhibition in comparison with embelin alone. The hemolytic activity studies suggested that both embelin and the metal complexes are non-hemolytic. The reason for the reduction in antioxidant and an increase in antimicrobial activities were discussed in detail.","PeriodicalId":10590,"journal":{"name":"Complex Metals","volume":"13 1","pages":"69 - 79"},"PeriodicalIF":0.0,"publicationDate":"2014-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79435621","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 18

Welcome to the inaugural issue of Complex Metals! 欢迎来到《复杂金属》杂志的创刊号!

Complex Metals Pub Date : 2014-03-18 DOI: 10.1080/2164232X.2014.899068

D. Harding, Jack Lu

引用次数: 0

Synthesis, characterization and antifungal studies of metalloquinolone [Cd2(nal)2(phen)2(Cl)2] 金属喹诺酮[Cd2(nal)2(phen)2(Cl)2]的合成、表征及抗真菌研究

Complex Metals Pub Date : 2014-03-18 DOI: 10.1080/2164232X.2014.889581

A. Debnath, F. Hussain, D. Masram

引用次数: 6

Theoretical calculations on layered perovskites: implications for photocatalysis 层状钙钛矿的理论计算:光催化的意义

Complex Metals Pub Date : 2014-03-18 DOI: 10.1080/2164232X.2014.891950

Xiang Liu, K. Sohlberg