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Computational Tools and Techniques in Designing Ligands for the Selective Separation of Actinide and Lanthanide: A Review 设计用于选择性分离锕系元素和镧系元素的配体的计算工具和技术：综述
IF 5.4 3区 化学
Comments on Inorganic Chemistry Pub Date : 2024-01-29 DOI: 10.1080/02603594.2024.2305884
Cheriyan Ebenezer, R. Vijay Solomon
{"title":"Computational Tools and Techniques in Designing Ligands for the Selective Separation of Actinide and Lanthanide: A Review","authors":"Cheriyan Ebenezer, R. Vijay Solomon","doi":"10.1080/02603594.2024.2305884","DOIUrl":"https://doi.org/10.1080/02603594.2024.2305884","url":null,"abstract":"The development of density functional theory (DFT) has significantly enhanced the use of computational chemistry as a tool in the design and development of ligands for the separation of actinides (...","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"3 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2024-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139752514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design and Reactivity of Early-Late Bimetallics as Structural and Functional Models of Mo Cu CODH 作为 Mo Cu CODH 结构和功能模型的早-晚期双金属的设计与反应性
IF 5.4 3区 化学
Comments on Inorganic Chemistry Pub Date : 2024-01-03 DOI: 10.1080/02603594.2023.2298366
Umesh I. Kaluarachchige Don, A. M. Buddhika Chandima, Dmitri Gelman, Richard L. Lord, Stanislav Groysman
{"title":"Design and Reactivity of Early-Late Bimetallics as Structural and Functional Models of Mo Cu CODH","authors":"Umesh I. Kaluarachchige Don, A. M. Buddhika Chandima, Dmitri Gelman, Richard L. Lord, Stanislav Groysman","doi":"10.1080/02603594.2023.2298366","DOIUrl":"https://doi.org/10.1080/02603594.2023.2298366","url":null,"abstract":"This review focuses on the synthetic inorganic chemistry of structural and functional models of Mo-Cu CO dehydrogenase (CODH). Mo-Cu CODH is an aerobic enzyme that catalyzes CO oxidation. The activ...","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"53 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2024-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139105170","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Current Trends on Ag 3 PO 4 -GO Based Heterojunction Photocatalyst for Photocatalytic Degradation of Organic Pollutants: A Review 基于 Ag 3 PO 4 -GO 的异质结光催化剂光催化降解有机污染物的当前趋势：综述
IF 5.4 3区 化学
Comments on Inorganic Chemistry Pub Date : 2023-12-10 DOI: 10.1080/02603594.2023.2291025
Jayaprakash Avinash, T. Chellapandi, G. Madhumitha, E. J. J. Samuel, S. P. V. Chamundeeswari, S. Roopan
{"title":"Current Trends on Ag\u0000 3\u0000 PO\u0000 4\u0000 -GO Based Heterojunction Photocatalyst for Photocatalytic Degradation of Organic Pollutants: A Review","authors":"Jayaprakash Avinash, T. Chellapandi, G. Madhumitha, E. J. J. Samuel, S. P. V. Chamundeeswari, S. Roopan","doi":"10.1080/02603594.2023.2291025","DOIUrl":"https://doi.org/10.1080/02603594.2023.2291025","url":null,"abstract":"","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"2 6","pages":""},"PeriodicalIF":5.4,"publicationDate":"2023-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138584911","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optoelectronic Alteration of Metal-Organic Frameworks for Enhanced Photocatalytic Water Splitting Activity Under Solar Radiation 金属-有机骨架在太阳辐射下增强光催化水分解活性的光电改变
IF 5.4 3区 化学
Comments on Inorganic Chemistry Pub Date : 2023-11-29 DOI: 10.1080/02603594.2023.2285064
Yahya Absalan, Faezeh Mokari, Behnaz Delaram, Mostafa Gholizadeh, Kambiz Suri
{"title":"Optoelectronic Alteration of Metal-Organic Frameworks for Enhanced Photocatalytic Water Splitting Activity Under Solar Radiation","authors":"Yahya Absalan, Faezeh Mokari, Behnaz Delaram, Mostafa Gholizadeh, Kambiz Suri","doi":"10.1080/02603594.2023.2285064","DOIUrl":"https://doi.org/10.1080/02603594.2023.2285064","url":null,"abstract":"Metal-organic frameworks (MOFs) have been increasingly popular in photocatalytic water-splitting research areas due to their unique, tunable porosity, high stability, large surface activity, and ma...","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"19 3","pages":""},"PeriodicalIF":5.4,"publicationDate":"2023-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138496457","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Separation of Propylene and Propane Using Metal–Organic Frameworks 利用金属有机骨架分离丙烯和丙烷
3区 化学
Comments on Inorganic Chemistry Pub Date : 2023-09-27 DOI: 10.1080/02603594.2023.2261103
Na Sun, Hongyan Yu, Andrei S. Potapov, Yaguang Sun
{"title":"Separation of Propylene and Propane Using Metal–Organic Frameworks","authors":"Na Sun, Hongyan Yu, Andrei S. Potapov, Yaguang Sun","doi":"10.1080/02603594.2023.2261103","DOIUrl":"https://doi.org/10.1080/02603594.2023.2261103","url":null,"abstract":"ABSTRACTPropylene (C3H6) is a crucial olefin raw material used in the production of polypropylene, which is the world’s second-most produced synthetic plastic. Separating propylene from propane (C3H8) is an important and significant challenge for industry due to the similar molecular sizes and physical properties of these gases. At present, the usual method for this separation is energy-intensive cryogenic distillation, which has low efficiency and high energy consumption. Therefore, an energy-efficient alternative way is in an urgent demand. Metal-organic frameworks (MOFs) are promising candidates for propylene/propane separation, thanks to the well-defined, designable, modifiable, and flexible structures. This review provides a summary of a recent development of MOFs that are able to discriminate between propylene and propane. The key factors that determine the separation performance of MOFs, primarily from the perspectives of pore size, presence of open metal sites (OMS) and MOFs membranes are summarized. Besides, the challenges that must be addressed for the further development of separations utilizing MOFs are also discussed.KEYWORDS: Metal-organic frameworksseparationadsorptionpore sizeopen metal sites Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by “The Belt and Road” Innovative Talent Exchange Foreign Experts Project (DL2022006007L), the Scientific Research Project of the Educational Department of Liaoning Province (LJ2019011), the National Natural Science Foundation of China (22301191, 21671139), the China postdoctoral Science Foundation (2023M731798). A.S.P. acknowledges the Ministry of Science and Higher Education of the Russian Federation (121031700321-3).","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"33 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135579373","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
CrownPhos: A Review of Crown Ether Derivatives Decorated with Phosphorus Donors 冠状磷:以磷供体修饰的冠状醚衍生物的研究进展
IF 5.4 3区 化学
Comments on Inorganic Chemistry Pub Date : 2023-09-06 DOI: 10.1080/02603594.2023.2255528
G. S. Ananthnag
{"title":"CrownPhos: A Review of Crown Ether Derivatives Decorated with Phosphorus Donors","authors":"G. S. Ananthnag","doi":"10.1080/02603594.2023.2255528","DOIUrl":"https://doi.org/10.1080/02603594.2023.2255528","url":null,"abstract":"","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"16 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2023-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73512559","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mono- and Bi-Iron Chalcogenofumarato Complexes: Synthesis and Characterization 单铁和双铁硫代糠醛配合物:合成和表征
IF 5.4 3区 化学
Comments on Inorganic Chemistry Pub Date : 2023-08-14 DOI: 10.1080/02603594.2023.2246902
M. El‐khateeb, Manar Ababneh, Phil Liebing, W. Weigand
{"title":"Mono- and Bi-Iron Chalcogenofumarato Complexes: Synthesis and Characterization","authors":"M. El‐khateeb, Manar Ababneh, Phil Liebing, W. Weigand","doi":"10.1080/02603594.2023.2246902","DOIUrl":"https://doi.org/10.1080/02603594.2023.2246902","url":null,"abstract":"","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"78 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2023-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82848320","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Inorganic and Organometallic Polymers as Energy Storage Materials and Enhancing Their Efficiency 无机和有机金属聚合物作为储能材料及其效率的提高
IF 5.4 3区 化学
Comments on Inorganic Chemistry Pub Date : 2023-06-10 DOI: 10.1080/02603594.2023.2220295
M. Khrizanforov, A. Zagidullin, R. Shekurov, F. Akhmatkhanova, I. Bezkishko, V. Ermolaev, V. Miluykov
{"title":"Inorganic and Organometallic Polymers as Energy Storage Materials and Enhancing Their Efficiency","authors":"M. Khrizanforov, A. Zagidullin, R. Shekurov, F. Akhmatkhanova, I. Bezkishko, V. Ermolaev, V. Miluykov","doi":"10.1080/02603594.2023.2220295","DOIUrl":"https://doi.org/10.1080/02603594.2023.2220295","url":null,"abstract":"","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"80 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2023-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80069585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Structural and Redox Interconversions of Sulfur Ligands of Transition Metal Complexes 过渡金属配合物中硫配体的结构和氧化还原相互转化
IF 5.4 3区 化学
Comments on Inorganic Chemistry Pub Date : 2023-04-20 DOI: 10.1080/02603594.2023.2200174
W. T. M. Seo, Emily Y. Tsui
{"title":"Structural and Redox Interconversions of Sulfur Ligands of Transition Metal Complexes","authors":"W. T. M. Seo, Emily Y. Tsui","doi":"10.1080/02603594.2023.2200174","DOIUrl":"https://doi.org/10.1080/02603594.2023.2200174","url":null,"abstract":"","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"85 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2023-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83910301","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Implication of counter-cations for polyoxometalate-based nano-electronics 反阳离子在多金属氧酸盐基纳米电子学中的意义
IF 5.4 3区 化学
Comments on Inorganic Chemistry Pub Date : 2022-12-22 DOI: 10.1080/02603594.2022.2157409
K. Monakhov
{"title":"Implication of counter-cations for polyoxometalate-based nano-electronics","authors":"K. Monakhov","doi":"10.1080/02603594.2022.2157409","DOIUrl":"https://doi.org/10.1080/02603594.2022.2157409","url":null,"abstract":"","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"68 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2022-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80341849","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
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