Clean-soil Air Water最新文献

Extraction and Preconcentration of Polycyclic Aromatic Hydrocarbons in Saffron and Tea Samples Using Magnetite-Sporopollenin/Graphene Oxide 磁铁矿-孢粉列宁/氧化石墨烯萃取和预富集藏红花和茶叶样品中的多环芳烃

IF 1.5 4区环境科学与生态学

Clean-soil Air Water Pub Date : 2025-06-24 DOI: 10.1002/clen.70002

Haleh Omoori Sarabi, Javad Feizy, Zarrin Es'haghi

{"title":"Extraction and Preconcentration of Polycyclic Aromatic Hydrocarbons in Saffron and Tea Samples Using Magnetite-Sporopollenin/Graphene Oxide","authors":"Haleh Omoori Sarabi, Javad Feizy, Zarrin Es'haghi","doi":"10.1002/clen.70002","DOIUrl":"https://doi.org/10.1002/clen.70002","url":null,"abstract":"<div>\u0000 \u0000 A synthesized adsorbent based on magnetite-saffron stamen sporopollenin/graphene oxide (Fe3O4-SSSP/GO) was successfully developed and validated for the determination of polycyclic aromatic hydrocarbons (PAHs) in various environmental matrices using gas chromatography–mass spectrometry. The saffron stamen was utilized to obtain sporopollenin, which was then magnetized employing Fe3O4 followed by GO to produce a sorbent of the Fe3O4-SSSP/GO type. The result indicates that the Fe3O4-SSSP/GO is a suitable sorbent for solid-phase extraction of four PAHs: benzo[a]anthracene (BaA), chrysene (Chr), benzo[b]fluoranthene (BbF), and benzo[a]pyrene (BaP), found in tea and saffron samples. Scanning electron microscopy and Fourier-transform infrared spectroscopy were used to characterize the sorbent. Taguchi analysis was employed to optimize the main parameters for extraction, such as sample volume, sorbent amount, desorption volume, and pH of the investigated PAHs. The calibration curve for determining BaA, Chr, BbF, and BaP was investigated in the 0.5 to 500 ng mL−1 range. The limit of detection (LOD, S/N = 3) and limit of quantification (LOQ, S/N = 10) were between 0.03 and 0.14 ng mL−1. The sorbent was successfully applied to saffron and tea samples with good precisions calculated by relative standard deviation (RSD) less than 8.2% and acceptable accuracy with relative recovery ranging from 73.2 to 111.0% for saffron and 58.4 to 93.0% for tea.\u0000 </div>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 6","pages":""},"PeriodicalIF":1.5,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144472936","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Issue Information: Clean Soil Air Water. 6/2025 发行信息：清洁土壤空气水。6/2025

IF 1.5 4区环境科学与生态学

Clean-soil Air Water Pub Date : 2025-06-24 DOI: 10.1002/clen.70019

引用次数: 0

Issue Information: Clean Soil Air Water. 5/2025 发行信息：清洁土壤空气水。5/2025

IF 1.5 4区环境科学与生态学

Clean-soil Air Water Pub Date : 2025-06-01 DOI: 10.1002/clen.70014

引用次数: 0

Spatial Distribution and Source Identification of Trace Metals in Topsoil in Nanyang City, Henan Province, China 河南南阳市表层土壤中微量金属的空间分布及来源鉴定

IF 1.5 4区环境科学与生态学

Clean-soil Air Water Pub Date : 2025-05-30 DOI: 10.1002/clen.70016

Dongxue Yang, Guilin Han, Rui Qu, Yuqing Zhao, Qiuyao Dong, Chao Song

{"title":"Spatial Distribution and Source Identification of Trace Metals in Topsoil in Nanyang City, Henan Province, China","authors":"Dongxue Yang, Guilin Han, Rui Qu, Yuqing Zhao, Qiuyao Dong, Chao Song","doi":"10.1002/clen.70016","DOIUrl":"https://doi.org/10.1002/clen.70016","url":null,"abstract":"<div>\u0000 \u0000 Trace metals (TMs) in soil have garnered widespread attention due to their adverse impacts on crop production and human health. In this study, 385 topsoil samples (0–20 cm) and 118 deep soil samples (150–200 cm) were collected from Nanyang City to investigate the spatial distribution, contamination, and source allocation of TMs. Geographic information system analysis, contamination factor (CF), geo-accumulation index (Igeo), and positive matrix factorization (PMF) model were utilized. The results showed that the mean contents of Cu, Hg, Pb, and Zn in the study area's topsoil (25.50, 0.035, 28.51, and 79.46 mg kg−1) exceeded background values. CF and Igeo results indicated that over 60% of soil samples were contaminated by Hg, the main contaminant in soil. By combining correlation and PMF analysis, three sources of TMs were identified for (a) Pb (75.4%), Hg (63.7%), and Zn (55.6%), primarily associated with industrial emissions and atmospheric deposition; (b) Co (57.5%), Cr (50.8%), Cu (59.2%), and Ni (46.4%) mainly originated from natural sources; and (c) As (72.8%) primarily from agricultural activities. The proportions of the three sources were 36.27%, 39.76%, and 23.97%, respectively. Anthropogenic sources contributed the most to soil TMs (60.24%), higher than natural sources, indicating substantial accumulation of TMs in topsoil due to significant anthropogenic activities. This study provided useful information for environmental management planning, decision-making, and contamination assessment.\u0000 </div>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 5","pages":""},"PeriodicalIF":1.5,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144171546","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Biodegradation of the Pesticide Diazinon by Bacteria Isolated From a Contaminated Soil 从受污染土壤中分离出的细菌对杀虫剂 "敌百虫 "的生物降解作用

IF 1.5 4区环境科学与生态学

Clean-soil Air Water Pub Date : 2025-04-21 DOI: 10.1002/clen.70012

Mona Mansouri, Aptin Rahnavard, Masood Ghane

{"title":"Biodegradation of the Pesticide Diazinon by Bacteria Isolated From a Contaminated Soil","authors":"Mona Mansouri, Aptin Rahnavard, Masood Ghane","doi":"10.1002/clen.70012","DOIUrl":"https://doi.org/10.1002/clen.70012","url":null,"abstract":"<div>\u0000 \u0000 Our research focused on the identification and isolation of diazinon (DZ)-degrading bacteria, as DZ is one of the most commonly used organophosphate pesticides in orchards and farms. We collected samples from a garden in Iran where DZ has been used for a long time. This allowed us to extract three types of bacteria capable of degrading DZ. Through biochemical and molecular tests, these bacteria were identified as Pseudomonas oryzihabitans, Enterobacter kobei, and Serratia species. The bacteria were cultured for 10 days in broth and soil media with DZ concentrations of 10 and 20 ppm. The degradation and utilization of the toxin by the bacteria were measured using gas chromatography. The results indicated that P. oryzihabitans degraded the toxin at concentrations of 10 and 20 ppm in liquid medium by 47.1% and 27.45%, respectively. In soil medium, the bacteria degraded 96.5% and 97.1% of the toxin at the same concentrations. Serratia sp. degraded DZ in broth medium with initial concentrations of 10 and 20 ppm by 64.3% and 78.4%, respectively. Additionally, these bacteria were able to degrade DZ by 90.2% and 98.25% in soil. E. kobei consumed DZ in the broth and soil media at rates of 23.1% and 17.95% and 31.19% and 88.05%, respectively. According to the results, P. oryzihabitans exhibited the highest degradation capacity compared to the other bacteria. Collectively, these three bacteria demonstrate a significant ability to biologically remediate environments contaminated with DZ.\u0000 </div>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 4","pages":""},"PeriodicalIF":1.5,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143857105","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Issue Information: Clean Soil Air Water. 4/2025 发行信息：清洁土壤空气水。4/2025

IF 1.5 4区环境科学与生态学

Clean-soil Air Water Pub Date : 2025-04-07 DOI: 10.1002/clen.70013

引用次数: 0

Oxytetracycline Hydrochloride Adsorption by Biochar From Loofah Sponge Using Response Surface Method 响应面法：丝瓜海绵生物炭对盐酸土霉素的吸附作用

IF 1.5 4区环境科学与生态学

Clean-soil Air Water Pub Date : 2025-04-07 DOI: 10.1002/clen.70011

Fanbao Deng, Jihong Zhao, Xiaoqian Yin, Xue Song, Yongde Liu, Jie Zhang, Tianrun Bai, Liwen Zhang

{"title":"Oxytetracycline Hydrochloride Adsorption by Biochar From Loofah Sponge Using Response Surface Method","authors":"Fanbao Deng, Jihong Zhao, Xiaoqian Yin, Xue Song, Yongde Liu, Jie Zhang, Tianrun Bai, Liwen Zhang","doi":"10.1002/clen.70011","DOIUrl":"https://doi.org/10.1002/clen.70011","url":null,"abstract":"<div>\u0000 \u0000 A potential biochar (KLSF-BC) was prepared by pyrolysis of loofah sponge (LS) at 600°C using KOH as an activator to adsorb oxytetracycline hydrochloride (OTCH). The response surface method (RSM) was applied to obtain the best preparation parameters (the first pyrolysis temperature of 573°C and pyrolysis time of 138 min, LSF-BC/KOH, 1:3, m/m) and adsorption conditions (OTCH concentration: 100 mg L−1, adsorbent dosage: 0.84 g L−1, adsorption time: 28 min, initial solution pH: 5.1), under which the adsorption capacity of KLSF-BC for OTCH was 662.96 mg g−1. The adsorption data of OTCH on KLSF-BC conformed to the pseudo-second-order model and Freundlich model. The removal mechanisms of OTCH involved hydrogen bonding, π–π EDA interaction, pore filling, and electrostatic interactions. The study confirmed the great potential and significant application prospects of KLSF-BC for removing OTCH from wastewater, providing a valuable reference for biomass resource utilization and antibiotics treatment.\u0000 </div>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 4","pages":""},"PeriodicalIF":1.5,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143793548","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Asymmetric Association Between Trade Uncertainty and Environmental Quality: Evidence From Newly Industrialized Economies 贸易不确定性与环境质量的不对称关系：来自新兴工业化经济体的证据

IF 1.5 4区环境科学与生态学

Clean-soil Air Water Pub Date : 2025-03-24 DOI: 10.1002/clen.70010

Baoyi Ji, Sajid Ali

{"title":"Asymmetric Association Between Trade Uncertainty and Environmental Quality: Evidence From Newly Industrialized Economies","authors":"Baoyi Ji, Sajid Ali","doi":"10.1002/clen.70010","DOIUrl":"https://doi.org/10.1002/clen.70010","url":null,"abstract":"<div>\u0000 \u0000 The world has experienced a considerable increase in trade uncertainty (TUN) during the last several decades, with environmental and economic consequences. However, the prior research on the nexus between TUN and the environmental quality (ENQ) records contradictory results, which may be inconvenient when recommending environmental protection policies. The goal of this research was to look into the asymmetric link between TUN and ENQ in the selected newly industrialized economies. Previous studies utilized panel data methods, yielding similar conclusions about the linkage between TUN and ENQ, regardless of the truth that many economies did not develop such interconnectednhess individually. On the other hand, the current work employs a distinctive methodology, “quantile-on-quantile,” that allows researchers to analyze time-series dependency in every nation by providing universal yet economy-specific details on the association between the variables. As per estimates, TUN boosts ENQ in majority of our selected nations. Moreover, the results reveal that the degree of asymmetries amidst the variables differs by nation, highlighting the requirement for policymakers to pay particular attention while implementing trade and environment sustainability policies.\u0000 </div>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 3","pages":""},"PeriodicalIF":1.5,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143689920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Sustainable Path Analysis of Urban Agglomerations Based on the Spatial Spillover Effect on Air Pollution 基于空气污染空间溢出效应的城市群可持续路径分析

IF 1.5 4区环境科学与生态学

Clean-soil Air Water Pub Date : 2025-03-17 DOI: 10.1002/clen.70009

Chen Lu, Yue Liu, Zixiao Zhang

{"title":"Sustainable Path Analysis of Urban Agglomerations Based on the Spatial Spillover Effect on Air Pollution","authors":"Chen Lu, Yue Liu, Zixiao Zhang","doi":"10.1002/clen.70009","DOIUrl":"https://doi.org/10.1002/clen.70009","url":null,"abstract":"<div>\u0000 \u0000 Rapid socioeconomic developments take the price of prominent environmental pollution problems, which necessitate a delicate equilibrium between urban development and environmental protection through governments’ scientific planning. This study delves into the sustainable trajectory for urban agglomerations, focusing on the Beijing–Tianjin–Hebei (BTH) urban agglomeration in China. Employing the STIRPAT model and Conley–Ligon model, it assesses the impact of socioeconomic factors on environmental pollution and their spillover effects. The study incorporates three distinct developmental scenarios designed to simulate regional economic growth and environmental protection. Our findings reveal a substantial influence of local socioeconomic development and spatial spillover effects from neighboring counties within the BTH region on local PM2.5 concentration. Economic development level and environmental governance expenditure emerge as pivotal factors affecting the increase and decrease of PM2.5 concentration, with spillover effects observed in neighboring counties. The effectiveness of balancing air pollution and the economy is better under the Zoning Cooperated scenario than under the local Government Planning scenario and trend extrapolation scenario. This means that more than 96% of the 100 million people in the counties will live in areas with clean air. In light of these findings, the research proposes pertinent policy recommendations, offering a novel and efficacious solution for urban agglomerations in rapidly developing countries or regions worldwide grappling with the intricate trade-off between air pollution and economic development.\u0000 </div>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 3","pages":""},"PeriodicalIF":1.5,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143638658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

An Experimental Study on Trench Weir With Flat Bars Under Free Flow Condition 自由流动条件下平坝沟堰的试验研究

IF 1.5 4区环境科学与生态学

Clean-soil Air Water Pub Date : 2025-03-05 DOI: 10.1002/clen.70004

Ashish Dabral, Pramod Kumar Sharma, Zulfequar Ahmad, Sanjeev Kumar

{"title":"An Experimental Study on Trench Weir With Flat Bars Under Free Flow Condition","authors":"Ashish Dabral, Pramod Kumar Sharma, Zulfequar Ahmad, Sanjeev Kumar","doi":"10.1002/clen.70004","DOIUrl":"https://doi.org/10.1002/clen.70004","url":null,"abstract":"<div>\u0000 \u0000 Trench weirs constructed across streams and rivers have been utilized for generations of hydropower due to their simplicity, cost-effectiveness, and minimal disruption to natural water courses. This type of weir consists of rack bars to control the deposition of sediments and floating debris. This article presents the investigations of the effects of different parameters, particularly the spacing of rack bars, specific energy of flow in the approach channel, velocity head, and porosity of rack bars on the discharging ability of trench weirs. Due to their greater flexural rigidity, flat bars are chosen in the current investigation from a structural perspective. The experiment was carried out in an open channel taking different combinations of bed slope, rack slope, and spacing of flat rack bars while testing under free flow conditions and having a pre-defined discharge in the approach channel. In addition, the discharge characteristics and coefficient of discharge (Cd) of the trench weir have been examined with varying clear spacing of rack bars, specific energy of approach flow, velocity head, and porosity of rack bars. The findings indicate that, in free flow conditions, Cd decreased as the porosity, clear spacing of rack bars, and specific energy of the approach flow increased. Further, during the analysis of experimental data, it was observed that Cd does not show any systematic pattern with velocity head. Thus, this study provides valuable insights on trench weir performance and the variables affecting discharge characteristics of trench weirs.\u0000 </div>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 3","pages":""},"PeriodicalIF":1.5,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143554518","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0