Clean-soil Air Water最新文献

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Assessment of PM2.5 and PM10 Over Sri Lanka: Spatiotemporal Trends, Potential Source Regions, and Associated Health Effects 斯里兰卡上空PM2.5和PM10的评估:时空趋势、潜在源区和相关健康影响
IF 1.4 4区 环境科学与生态学
Clean-soil Air Water Pub Date : 2025-10-13 DOI: 10.1002/clen.70051
Thrividya Nirmani, Shazia Shifa, Lovleen Gupta
{"title":"Assessment of PM2.5 and PM10 Over Sri Lanka: Spatiotemporal Trends, Potential Source Regions, and Associated Health Effects","authors":"Thrividya Nirmani,&nbsp;Shazia Shifa,&nbsp;Lovleen Gupta","doi":"10.1002/clen.70051","DOIUrl":"https://doi.org/10.1002/clen.70051","url":null,"abstract":"<div>\u0000 \u0000 <p>This study analyzed particulate matter (PM<sub>2.5</sub> and PM<sub>10</sub>) concentrations at 17 locations in Sri Lanka over 2 years (January 2021–December 2022); the effects of meteorological parameters on the PM, potential source regions for high PM, and the associated human health risk. The highest annual mean PM<sub>2.5</sub> (29.9 ± 19.4 µgm<sup>−3</sup>), PM<sub>10</sub> (55.8 ± 37.8 µgm<sup>−3</sup>) in 2022, and PM<sub>2.5</sub> (21.4 ± 7.8 µgm<sup>−3</sup>) and PM<sub>10</sub> (41.1 ± 14.8 µgm<sup>−3</sup>) in 2021 were reported in Jaffna and Kurunegala, respectively. Throughout both years, the PM concentrations were always higher than the World Health Organization guidelines. Seasonally, the Northeast monsoon experienced the highest average PM<sub>2.5</sub> (54.7 µgm<sup>−3</sup>) and PM<sub>10</sub> (104.2 µgm<sup>−3</sup>) in 2022, which may be attributed to low rainfall (∼4.5 mm), moderate temperature (∼26°C), and low wind speed (∼3 mph). The conditional bivariate probability function (CBPF) revealed probable sources to be motor vehicles (in Colombo, Galle, and Kurunegala), biomass burning (at all sites), textile units (in Colombo, Kurunegala), cement manufacturing plants (in Galle, Puttalam), and coal-fired power plants (in Puttalam). A period of 72-hr backward trajectories at 500, 1000, and 1500 m using the hybrid single-particle Lagrangian–integrated trajectory (HYSPLIT) revealed air mass pathways tracing back to eastern India and the Bay of Bengal, confirming transboundary pollutant movement into Sri Lanka. The health effects of PM<sub>2.5</sub> exposure were estimated via AirQ+, which revealed the highest mortality in Jaffna in 2022. The findings of this study provide valuable insights to local and national governments for appropriate policy intervention needed to manage air pollution in Sri Lanka, considering the health risks associated with PM<sub>2.5</sub> exposure.</p>\u0000 </div>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 10","pages":""},"PeriodicalIF":1.4,"publicationDate":"2025-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145316973","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Filter Cake Biochar Reduces Cadmium Bioavailability and Accumulation in Vegetables Grown in Contaminated Soil 滤饼生物炭降低污染土壤中蔬菜镉的生物利用度和积累
IF 1.4 4区 环境科学与生态学
Clean-soil Air Water Pub Date : 2025-10-13 DOI: 10.1002/clen.70052
Venâncio de Lima Veloso, Fernando Bruno Vieira da Silva, Simone Aparecida da Silva Lins, Clístenes Williams Araújo do Nascimento
{"title":"Filter Cake Biochar Reduces Cadmium Bioavailability and Accumulation in Vegetables Grown in Contaminated Soil","authors":"Venâncio de Lima Veloso,&nbsp;Fernando Bruno Vieira da Silva,&nbsp;Simone Aparecida da Silva Lins,&nbsp;Clístenes Williams Araújo do Nascimento","doi":"10.1002/clen.70052","DOIUrl":"https://doi.org/10.1002/clen.70052","url":null,"abstract":"<p>Cadmium (Cd) contamination in agricultural soils poses serious risks to food safety and human health, particularly in regions with acidic soils that favor metal mobility. This study evaluated the effectiveness of filter cake biochar (FCB) in remediating Cd-contaminated soil and mitigating its transfer to vegetables. A greenhouse experiment was conducted using an Ultisol contaminated with 10 mg kg<sup>−1</sup> Cd. Four vegetables, Swiss chard (<i>Beta vulgaris</i>), okra (<i>Abelmoschus esculentus</i>), beetroot (<i>B. vulgaris</i>), and bell pepper (<i>Capsicum annuum</i>), were cultivated in pots with and without FCB amendment. FCB application reduced Cd availability in soil, from 4.5 to 0.5 mg kg<sup>−1</sup>, bringing concentrations below the regulatory guideline (1.3 mg kg<sup>−1</sup>). This was accompanied by a reduction of up to 87% in Cd concentrations in plant tissues. Improvements in soil fertility were also observed, including increased pH, organic carbon, and availability of P, Ca, Mg, Fe, and Mn. Cd accumulation in plant tissues varied by species, with bell pepper showing the lowest and Swiss chard the highest concentrations. Crucially, only vegetables cultivated in FCB-amended soil yielded edible produce, underscoring the biochar's role in mitigating phytotoxicity and enabling safe consumption. In addition to lowering Cd uptake, FCB enhanced biomass and nutrient accumulation in shoots. Correlation analysis confirmed strong positive relationships between soil fertility parameters and plant nutrient uptake, and negative correlations between Cd availability and plant performance. These results demonstrate that FCB is an effective strategy for reducing Cd risks in contaminated soils and improving the productivity and safety of vegetable crops.</p>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 10","pages":""},"PeriodicalIF":1.4,"publicationDate":"2025-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/clen.70052","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145316972","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Coupling Interaction Between Soil Water and Soil Organic Carbon Contents After Vegetation Restoration in the Loess Plateau Region of China 黄土高原区植被恢复后土壤水分与有机碳含量的耦合相互作用
IF 1.4 4区 环境科学与生态学
Clean-soil Air Water Pub Date : 2025-10-09 DOI: 10.1002/clen.70049
Yali Ma, Kun Qi, Na Feng, Jinmei Guo, Jiangbo Qiao, Changchun Shi
{"title":"Coupling Interaction Between Soil Water and Soil Organic Carbon Contents After Vegetation Restoration in the Loess Plateau Region of China","authors":"Yali Ma,&nbsp;Kun Qi,&nbsp;Na Feng,&nbsp;Jinmei Guo,&nbsp;Jiangbo Qiao,&nbsp;Changchun Shi","doi":"10.1002/clen.70049","DOIUrl":"https://doi.org/10.1002/clen.70049","url":null,"abstract":"<div>\u0000 \u0000 <p>The soil water content (SWC) and soil organic carbon (SOC) are two important factors to consider when revegetating degraded land in arid and semiarid areas. Understanding the responses of SWC and SOC to vegetation restoration as well as their coupling interaction is important for the sustainable restoration of vegetation. However, the responses of SWC and SOC are still unclear in different plantation types, especially for the deep soil layer. In this study, three common types of mature plantations containing <i>Pinus sylvestris</i>, <i>Pinus tabuliformis</i>, and <i>Populus simonii</i> were selected in the Loess Plateau region of China to evaluate the responses of SWC and SOC to vegetation restoration as well as their interactions, and thus determine the factors that influenced the variations in SWC and SOC. Compared with grassland, the deep soil water deficit was exacerbated in all three plantations, and the SOC increased under <i>Populus simonii</i> but decreased under the other types. The tradeoff relationship between SOC and SWC had the lowest root mean squared error under <i>Populus simonii</i>. Therefore, <i>Populus simonii</i> was identified as most suitable for revegetation in the study region. Soil texture had important effects on the variations in SOC in the deep soil layers (2–5 m), and SOC and the soil texture affected the variations in SWC in the whole soil profile. The results obtained in this study may facilitate the sustainable development of artificial forests in the Loess Plateau region as well as similar arid and semiarid areas.</p>\u0000 </div>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 10","pages":""},"PeriodicalIF":1.4,"publicationDate":"2025-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145272527","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Predicting Nitrogen Content in Rice Using Unmanned Aerial Vehicle Based Multispectral Imaging 利用无人机多光谱成像技术预测水稻氮素含量
IF 1.4 4区 环境科学与生态学
Clean-soil Air Water Pub Date : 2025-10-09 DOI: 10.1002/clen.70048
Rahul Tripathi, Bismay Ranjan Tripathy, Shiv Sundar Jena, Chinmaya Kumar Swain, Sangita Mohanty, Rabi Narayan Sahoo, Shyamsundar Das Mohapatra, Amaresh Kumar Nayak
{"title":"Predicting Nitrogen Content in Rice Using Unmanned Aerial Vehicle Based Multispectral Imaging","authors":"Rahul Tripathi,&nbsp;Bismay Ranjan Tripathy,&nbsp;Shiv Sundar Jena,&nbsp;Chinmaya Kumar Swain,&nbsp;Sangita Mohanty,&nbsp;Rabi Narayan Sahoo,&nbsp;Shyamsundar Das Mohapatra,&nbsp;Amaresh Kumar Nayak","doi":"10.1002/clen.70048","DOIUrl":"https://doi.org/10.1002/clen.70048","url":null,"abstract":"<div>\u0000 \u0000 <p>Precise estimation of rice nitrogen (N) content is essential for optimizing fertilizer use. Traditional methods for estimating N content are time-consuming, laborious, and costly. Unmanned aerial vehicles (UAVs) are time and money efficient substitutes allowing more accurate and flexible monitoring for larger rice areas. The objectives of this study were to: (i) develop random forest (RF) and artificial neural network (ANN) models for predicting and mapping the nitrogen content (%) in rice using seven vegetation indices derived from UAV multispectral sensors and; (ii) assess the key vegetation indices (VI) and their interrelationships with the predicted nitrogen content. Experiments were conducted at two locations in Cuttack district of Odisha, India, with different nitrogen levels. The UAV images were collected synchronizing with the maximum tillering stage of rice and seven indices were generated. The rice sampling was done on the date of flying UAV images and nitrogen content was estimated in the laboratory. RF and ANN models were developed using the N content as dependent and the VIs as independent variables. Both the models exhibited robust predictive capabilities, however, the RF model exhibited better performance, compared to the ANN model. Nitrogen content prediction using the developed RF and ANN models in testing site at farmer's field ranged from 0.78% to 1.95% (<i>R</i><sup>2</sup> of 0.67%) and from 0.5% to 1.78% (<i>R</i><sup>2</sup> of 0.55%), respectively. Normalized difference red edge (NDRE) and normalized difference vegetation index (NDVI) turned out as significant contributors in the development of both the models.</p>\u0000 </div>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 10","pages":""},"PeriodicalIF":1.4,"publicationDate":"2025-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145272402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental Evaluation of the Shadow Effect on the Single-Slope Solar Still Performance 阴影效应对单斜面太阳能蒸馏器性能影响的实验研究
IF 1.4 4区 环境科学与生态学
Clean-soil Air Water Pub Date : 2025-10-09 DOI: 10.1002/clen.70046
Ahmed Rahmani, Lakhdar Bouzid, Zine Saadi
{"title":"Experimental Evaluation of the Shadow Effect on the Single-Slope Solar Still Performance","authors":"Ahmed Rahmani,&nbsp;Lakhdar Bouzid,&nbsp;Zine Saadi","doi":"10.1002/clen.70046","DOIUrl":"https://doi.org/10.1002/clen.70046","url":null,"abstract":"<div>\u0000 \u0000 <p>The shadow effect is one of the major problems hindering the operation of solar energy-based systems and affects the performance of solar stills. The shade cast by the still's lateral walls on the basin reduces the solar-exposed area and reduces the daily distillation yield. This article deals with an experimental study to evaluate the shadow effect on the conventional solar still (CSS) performance. A comparative analysis was conducted between the single-slope CSS and the modified one (modified solar still [MSS]) with three glasses. Therefore, outdoor experiments were performed in hot and cold weather conditions in Adrar—Algeria. The results showed that replacing wooden walls with transparent glass is not always efficient, and the still's thermal performance depends on the weather conditions. On the summer day, the daily productivity reached 3.57 kg/m<sup>2</sup> for the CSS and 4.42 kg/m<sup>2</sup> for the MSS (a reduction of about 24% compared with the MSS). On the winter test day, the glass side walls appeared to negatively impact the MSS distillate yield, which was 5.55% lower than the CSS yield (2.57 vs. 2.71 kg/m<sup>2</sup> for CSS). Energy and exergy analysis show that the MSS is more efficient than the CSS on summer days, whereas the opposite happens on winter days.</p>\u0000 </div>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 10","pages":""},"PeriodicalIF":1.4,"publicationDate":"2025-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145272400","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Feasibility of an Aquaponic System Composed of a Living Wall Coupled With an Ornamental Pond With Fish in Real-Life Conditions 在现实生活条件下,由活墙与观赏池相结合的水共生系统的可行性
IF 1.4 4区 环境科学与生态学
Clean-soil Air Water Pub Date : 2025-10-08 DOI: 10.1002/clen.70047
Víctor M. Fernández-Cabanás, Leonardo Martínez-Millán, Gina Patricia Suárez-Cáceres, Rafael Fernández-Cañero, Sabina Rossini-Oliva, Antonio José Fernández-Espinosa, Antonio Franco-Salas, Luis Pérez-Urrestarazu
{"title":"Feasibility of an Aquaponic System Composed of a Living Wall Coupled With an Ornamental Pond With Fish in Real-Life Conditions","authors":"Víctor M. Fernández-Cabanás,&nbsp;Leonardo Martínez-Millán,&nbsp;Gina Patricia Suárez-Cáceres,&nbsp;Rafael Fernández-Cañero,&nbsp;Sabina Rossini-Oliva,&nbsp;Antonio José Fernández-Espinosa,&nbsp;Antonio Franco-Salas,&nbsp;Luis Pérez-Urrestarazu","doi":"10.1002/clen.70047","DOIUrl":"https://doi.org/10.1002/clen.70047","url":null,"abstract":"<p>Green and blue infrastructures are often combined to create pleasant urban landscapes and provide new ecosystems in the built environment. New techniques for building integrated vegetation systems, such as vertical greening, are becoming common. In this work, we evaluate a case study of a combined aquaponic system composed of a living wall (LW) coupled to an ornamental pond with fish. The system allows the metabolic waste of fish and the unconsumed feed to be converted by a bacterial population into mineral nutrients that are used by the plants in the LW. For this purpose, the pond water was recirculated through a 7.2 m<sup>2</sup> LW planted with 11 different ornamental plant species. The objectives of the study were (1) assessing the performance of LW vegetation irrigated with water from a pond and (2) monitoring the pond water quality with the LW used as a biofilter. The evolution of vegetation growth was monitored for 1 year by image analysis, and the concentration of some nutrients in the water was determined pre- and post-coupling. Vegetation cover increased from 30% to almost 100% after 1 year. Iron, magnesium, and nitrogen content increased in the LW plants after coupling with the pond. Electrical conductivity increased slightly with time, keeping below 500 µS cm<sup>−1</sup>. Nitrates, nitrites, and phosphates in the water were significantly reduced after the pond was coupled with the LW. Overall, the combination of both systems proved to be successful, optimizing the use of water and fertilizers with a circular economy focus.</p>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 10","pages":""},"PeriodicalIF":1.4,"publicationDate":"2025-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/clen.70047","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145272045","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigating Multicriteria Decision-Making Methods for E-Waste Management to Reduce Environmental Impacts (Case Study: Markazi Province, Iran) 研究电子废物管理的多标准决策方法以减少环境影响(案例研究:伊朗马卡齐省)
IF 1.4 4区 环境科学与生态学
Clean-soil Air Water Pub Date : 2025-10-06 DOI: 10.1002/clen.70015
Amin Hashemi, Hamid Toranjzar, Amir Hossein Baghaie, Javad Varvani, Azadeh Kazemi
{"title":"Investigating Multicriteria Decision-Making Methods for E-Waste Management to Reduce Environmental Impacts (Case Study: Markazi Province, Iran)","authors":"Amin Hashemi,&nbsp;Hamid Toranjzar,&nbsp;Amir Hossein Baghaie,&nbsp;Javad Varvani,&nbsp;Azadeh Kazemi","doi":"10.1002/clen.70015","DOIUrl":"https://doi.org/10.1002/clen.70015","url":null,"abstract":"<div>\u0000 \u0000 <p>E-waste management is a critical global issue due to its environmental and human health impacts. This study employs multicriteria decision-making (MCDM) methods, specifically the analytical hierarchy process (AHP) and fuzzy AHP, to evaluate and prioritize e-waste management strategies in Markazi Province, Iran. The research follows a structured methodological framework, beginning with an extensive literature review and expert consultations to define key evaluation criteria, including feasibility, cost, environmental policies, public acceptance, and process complexity. AHP and fuzzy AHP methodologies were applied to analyze expert survey data, collected from 60 specialists across academia, government, and industry. The results reveal that recycling (0.34) and reuse (0.31) are the most effective strategies, followed by incineration (0.18) and electronic waste management (EWM) (0.15). The study underscores the importance of structured decision-making frameworks in environmental policy and highlights the necessity of sustainable e-waste management practices to mitigate adverse environmental effects. By integrating qualitative expert judgments with quantitative decision analysis, this research contributes to the global discourse on e-waste governance and offers insights applicable to developing regions facing similar challenges.</p>\u0000 </div>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 10","pages":""},"PeriodicalIF":1.4,"publicationDate":"2025-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145271791","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Issue Information: Clean Soil Air Water. 10/2025 发行信息:清洁土壤空气水。10/2025
IF 1.4 4区 环境科学与生态学
Clean-soil Air Water Pub Date : 2025-10-03 DOI: 10.1002/clen.70050
{"title":"Issue Information: Clean Soil Air Water. 10/2025","authors":"","doi":"10.1002/clen.70050","DOIUrl":"https://doi.org/10.1002/clen.70050","url":null,"abstract":"","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 10","pages":""},"PeriodicalIF":1.4,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/clen.70050","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145224126","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Anions on the Degradation of Ceftriaxone by UV/H2O2 Process Using a 222 nm Far-UVC KrCl* Excilamp 阴离子对222 nm远紫外KrCl* Excilamp紫外/H2O2工艺降解头孢曲松的影响
IF 1.4 4区 环境科学与生态学
Clean-soil Air Water Pub Date : 2025-10-03 DOI: 10.1002/clen.70043
Marina Sizykh, Agniya Batoeva, Galina Matafonova
{"title":"Effect of Anions on the Degradation of Ceftriaxone by UV/H2O2 Process Using a 222 nm Far-UVC KrCl* Excilamp","authors":"Marina Sizykh,&nbsp;Agniya Batoeva,&nbsp;Galina Matafonova","doi":"10.1002/clen.70043","DOIUrl":"https://doi.org/10.1002/clen.70043","url":null,"abstract":"<div>\u0000 \u0000 <p>Over the last few years, the KrCl* excilamp (222 nm) has emerged as a promising Far-UVC source to drive advanced oxidation processes (AOPs) for degrading organic contaminants in water. In the present study, we explored the effect of common anions (Cl<sup>−</sup>, SO<sub>4</sub><sup>2−</sup>, NO<sub>3</sub><sup>−</sup>, HCO<sub>3</sub><sup>−</sup>) in the concentration range of 1–100 mM on the kinetics of degradation and mineralization of ceftriaxone (CEF) by Far-UVC/H<sub>2</sub>O<sub>2</sub> process using excilamp in synthetic (deionized water + anions) and real (tap) water. Nitrate at 1 mM and other anions at all concentrations exhibited a promotion effect by accelerating the degradation rate. It can be attributed to the contribution of secondary radicals generated by anions under Far-UVC exposure. However, the mineralization in terms of total organic carbon (TOC) removal decreased in the presence of HCO<sub>3</sub><sup>−</sup> and NO<sub>3</sub><sup>−</sup>. When reducing the H<sub>2</sub>O<sub>2</sub> dose, chloride ions provided significant process intensification by increasing the rate constant by 3.5 times and reaching 30% TOC removal along with complete CEF degradation. Examining tap water revealed the high performance of the Far-UVC/H<sub>2</sub>O<sub>2</sub> process for degrading and mineralizing CEF without the inhibition effect of matrix components. Results demonstrate that anions as radical precursors tend to promote the oxidation processes rather than inhibit them. This opens up good prospects for practical application of KrCl* excilamp in water treatment.</p>\u0000 </div>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 10","pages":""},"PeriodicalIF":1.4,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145224127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Waste Materials for the Phosphorus Adsorption Study 废材料对磷的吸附研究
IF 1.4 4区 环境科学与生态学
Clean-soil Air Water Pub Date : 2025-10-03 DOI: 10.1002/clen.70045
Vandana Patyal, Dipika Jaspal, Kanchan Khare
{"title":"Waste Materials for the Phosphorus Adsorption Study","authors":"Vandana Patyal,&nbsp;Dipika Jaspal,&nbsp;Kanchan Khare","doi":"10.1002/clen.70045","DOIUrl":"https://doi.org/10.1002/clen.70045","url":null,"abstract":"<div>\u0000 \u0000 <p>Using waste materials as adsorbents helps in attaining the goal of the circular economy for sustainable environmental development. Numerous wastes have undergone testing for their potential for the adsorption of contaminants and toxicants. The motive of the presented work was to appraise the phosphorus (P) adsorption capacities and physicochemical characteristics of brick and tile waste for use as a substrate in the constructed wetlands (CWs). The data showed that the P adsorption capacity for materials increased with the initial concentration. The nonlinear regression analysis of the experimental data revealed that the Langmuir isotherm was more suitable for the brick waste and tile waste study. For brick waste, the maximum adsorption was 1.86 mg/g, and for tile waste, it was 0.65 mg/g. The P adsorption capacity of both materials was reduced in batch studies with domestic wastewater. The increase in pH of the solution greatly reduced the adsorption capacity of brick waste, whereas the reduction was marginal for tile waste. The microstructure of both materials showed the presence of pores on the uneven surface, which increased the specific surface area and facilitated adsorption. The ability of both materials to adsorb in column studies was less compared to the Langmuir isotherm adsorption value due to the dynamic environment setting. Both materials showed the potential for use as substrates in the CW for the elimination of P.</p>\u0000 </div>","PeriodicalId":10306,"journal":{"name":"Clean-soil Air Water","volume":"53 10","pages":""},"PeriodicalIF":1.4,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145224079","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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