Hong-jiao Tang , Gen Kou , Hao Zhou , Wen-wen Liu , Xin-guo Duan , Shi-yuan Zhan , Hai-yue Li , Quan-zhen Li
{"title":"Microscopic pore-throat classification and reservoir grading evaluation of the Fengcheng formation in shale oil reservoir","authors":"Hong-jiao Tang , Gen Kou , Hao Zhou , Wen-wen Liu , Xin-guo Duan , Shi-yuan Zhan , Hai-yue Li , Quan-zhen Li","doi":"10.1016/j.uncres.2024.100074","DOIUrl":"https://doi.org/10.1016/j.uncres.2024.100074","url":null,"abstract":"<div><p>Different basins in China have proposed various reservoir grading standards for shale oil. Based on a comprehensive understanding of the basic characteristics of the shale oil reservoir in the Mahu Depression, this paper uses data from high-pressure mercury injection, physical properties, nuclear magnetic resonance, depletion development, and CO<sub>2</sub> displacement development tests to analyze the microscopic pore structure features of the Fengcheng Formation shale oil reservoir. On this basis, the classification boundaries of the pore throats in the shale oil reservoir were analyzed, and a reservoir grading standard suitable for the Fengcheng Formation shale was proposed: large pore throats (greater than 1000 nm), medium pore throats(100∼1000 nm), small pore throats (20∼100 nm), and ultra-small pore throats (less than 20 nm). The medium pore throat is the lower limit for depletion development, the small pore throat is the lower limit under CO<sub>2</sub> displacement conditions, and the ultra-small pore throat cannot be utilized under current conditions. The classification effect of the shale oil reservoir is verified using the production characteristics of Well MY1, the liquid production profile, and the results of geological \"sweet spots\" studies. The results show that the classification scheme for the microscopic pore throats of the Fengcheng Formation shale oil is reliable and feasible.</p></div>","PeriodicalId":101263,"journal":{"name":"Unconventional Resources","volume":"4 ","pages":"Article 100074"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666519024000025/pdfft?md5=6111e3c5da6be7c2e4197acf4debf217&pid=1-s2.0-S2666519024000025-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139503366","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Suppressing solar PV output fluctuations by designing an efficient hybrid energy storage system controller","authors":"Mohammadreza Moghadam, Navid Ghaffarzadeh","doi":"10.1016/j.uncres.2024.100077","DOIUrl":"https://doi.org/10.1016/j.uncres.2024.100077","url":null,"abstract":"<div><p>The stochastic nature of solar photovoltaics (PV), marked by high-frequency voltage fluctuations due to dynamic climatic conditions such as cloud cover and temperature variations, presents a significant challenge to power quality stability, especially in microgrids. This variability poses a threat to the stability of power electronic devices responsible for power control and monitoring, potentially compromising the power grid's stability. To address this challenge, energy storage systems (ESS) are commonly employed. In this study, we develop a hybrid energy storage system (HESS) incorporating a battery, supercapacitor, and fuel cell. The primary aim is to adjust the inverter voltage for the photovoltaic system using newly developed proportional-integral (PI) and model predictive control (MPC) controllers within the HESS framework. Importantly, this controller eliminates the need for precise knowledge of system parameters and offers robustness, insensitivity to parameter changes, and resilience to time-varying external disturbances, ensuring satisfactory performance. By mitigating power fluctuations, the generated power can be seamlessly integrated into the grid, significantly reducing costs associated with device damage in the power path.</p><p>Notably, we integrate the proposed photovoltaic system with an RLC series load using an IGBT inverter. To assess the performance of the HESS in the proposed photovoltaic system, four distinct scenarios are examined. These scenarios involve altering the PV system's location and testing two energy storage systems, namely the battery and fuel cell, which are separately designed components of the HESS for a 14-bus microgrid.</p></div>","PeriodicalId":101263,"journal":{"name":"Unconventional Resources","volume":"4 ","pages":"Article 100077"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666519024000050/pdfft?md5=701a49ceb8cb92a00b10aa6ad2f64044&pid=1-s2.0-S2666519024000050-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140290932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Christian O. Asadu , Benjamin Nnamdi Ekwueme , Chinonso Anthony Ezema , Thomas O. Onah , Innocent Sunday Ike , Judith Obioma Ugwuele , Chikezie Christian Aka , Onoh Ikechukwu Maxwell , Emmanuel O. Umeagukwu , Churchill Chisom Ogbonna
{"title":"Recycled waste groundnut oil: A potential feedstock for green energy/biodiesel synthesis","authors":"Christian O. Asadu , Benjamin Nnamdi Ekwueme , Chinonso Anthony Ezema , Thomas O. Onah , Innocent Sunday Ike , Judith Obioma Ugwuele , Chikezie Christian Aka , Onoh Ikechukwu Maxwell , Emmanuel O. Umeagukwu , Churchill Chisom Ogbonna","doi":"10.1016/j.uncres.2024.100081","DOIUrl":"https://doi.org/10.1016/j.uncres.2024.100081","url":null,"abstract":"<div><p>This work focuses on the recycling of waste groundnut oil as a potential feedstock for biodiesel production using activated coconut husk as a regenerating agent. The coconut husk was functionalized using organic acid. The properties of the functionalized coconut husk were investigated via instrumental analysis. Non-parametric modeling involving 2-degree isotherm models were used. The regeneration/recycling of the waste oil were done in batch mode examining key factors of temperature, time, concentration and dosage. Biodiesel was synthesized from recycled waste groundnut oil using transesterification reaction. The properties of biodiesel were examined using ASTM and AOAC official standards. Brunauer-Emmett-Teller surface analysis revealed the surface area of the adsorbent as 371.88 m<sup>2</sup>/g and a porosity distribution of 0.567 <span><math><mrow><mi>η</mi></mrow></math></span> on the surface at a pH of 6.1. Batch mode analysis revealed that 97.5% of impurities was removed from waste groundnut oil under one batch process at 80 °C after 4 h with 6 g of the activated coconut husk. Langmuir isotherm model provided the best fit to the experimental data with adsorption capacity of 33.5 mg/g at R<sup>2</sup> of 0.996. Adsorption of waste groundnut oil impurities onto activated coconut husk was endothermic, as evidenced by the calculated ΔH of +2.7914 kJ/mol. A high cetane number of 48.4 obtained after transesterification is an indication of the good ignition quality of the obtained recycled waste groundnut oil methyl ester. Kinematic viscosity and acid value were revealed to be 4.65 mm<sup>2</sup> S<sup>−1</sup> and 0.31 mg KOH/g, while the calorific value stood at 38,053 kJ/kg. GC-MS analysis revealed a complex mixture of fatty acid methyl esters dominated by unsaturated fatty acids (58.78%). Recycling of waste cooking oil in this work using activated coconut husk demonstrated good quality as a regenerating agent. The properties of biodiesel obtained showed that it has all the good qualities comparable to other existing biodiesel based on the ASTM and AOAC official standards. More work on the recycling of other waste cooking oils for green energy synthesis to protect our environment from pollution emanating from the use of conventional petro-diesel and promote energy transition is highly recommended.</p></div>","PeriodicalId":101263,"journal":{"name":"Unconventional Resources","volume":"4 ","pages":"Article 100081"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666519024000098/pdfft?md5=e44754d193a7e1b8cd195e55f3d124ce&pid=1-s2.0-S2666519024000098-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140309424","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wenli Cai , Runcheng Xie , Huaji Li , Shiliang Dou , Siyuan Li , Shuanglin Deng , Tingting Ma
{"title":"Developmental characteristics of fractures in deep tight sandstone reservoirs in the second Member of the Xujiahe Formation of Zhongjiang Gas Field","authors":"Wenli Cai , Runcheng Xie , Huaji Li , Shiliang Dou , Siyuan Li , Shuanglin Deng , Tingting Ma","doi":"10.1016/j.uncres.2024.100073","DOIUrl":"10.1016/j.uncres.2024.100073","url":null,"abstract":"<div><p>The development characteristics, scale and control factors of fractures are the core subjects of reservoir sweet spot prediction. The sandstone reservoir of the TX<sub>2</sub> gas reservoir in the Zhongjiang Gas Field is a typical low porosity and low permeability tight reservoir with strong heterogeneity, but relatively high-quality reservoirs can be found in different well areas and well segments. In this paper, taking the second Member of the Xujiahe Formation (TX<sub>2</sub>) as an example, the control factors of fractures were systemically investigated via core observation, thin section, logging data, and fracture logging identifications. The results show that shear fractures are mainly developed in the cores, and they generally have high filling rate and poor effectiveness; microfractures can be found based on the vitrinite and cast thin section results. The intersection diagram (semi-quantitative) and the principal component and BP comprehensive identification (quantitative) methods can effectively identify different types of fractures. The combined application of principal component and BP comprehensive identification methods results in an 83.3 % fracture identification probability. Finally, we found that the development of fractures in TX<sub>2</sub> is comprehensively affected by lithology, rock thickness, porosity, and faults.</p></div>","PeriodicalId":101263,"journal":{"name":"Unconventional Resources","volume":"4 ","pages":"Article 100073"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666519024000013/pdfft?md5=878ca39ed51e18038394b43a690841ed&pid=1-s2.0-S2666519024000013-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139392356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zhao Ma , Chuanqing Zhu , Kefu Li , Chaohe Fang , Qian Cao
{"title":"Heat production rate of deep rocks in Bohai Bay Basin and its relationship with terrestrial heat flow","authors":"Zhao Ma , Chuanqing Zhu , Kefu Li , Chaohe Fang , Qian Cao","doi":"10.1016/j.uncres.2023.100072","DOIUrl":"https://doi.org/10.1016/j.uncres.2023.100072","url":null,"abstract":"<div><p>The vertical distribution of rocks’ radioactive heat production rate in the continental crust is the basis for exploring the deep thermal structure and explaining terrestrial heat flow distribution characteristics. In this paper, taking the Bohai Bay Basin as an example, according to the content of U, Th and K in the rocks and the lithologic composition of each structural layer of the crust, calculating the range of radioactive heat-generating elements in each structural layer. Then, systematically analyze the distribution characteristics of heat production rate in the crust. Finally, establish the vertical distribution model of heat production rate and discuss the relationship between heat flow and heat production rate. The results show that the rock heat production rate is mainly related to lithology. U and Th are primarily enriched in the upper crust with exponential distribution, while K content is unchanged. Under exponential crustal heat production rate distribution, the D<sub>U</sub>, D<sub>Th</sub> and D<sub>A</sub> in the crust are 15.195 km, 15.29 km and 21.11 km, respectively. A linear relationship exists between heat flow and heat production rate but cannot infer the thermal condition of the middle and lower crust.</p></div>","PeriodicalId":101263,"journal":{"name":"Unconventional Resources","volume":"4 ","pages":"Article 100072"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666519023000511/pdfft?md5=1c635c15543dd5fd9456afb121348c29&pid=1-s2.0-S2666519023000511-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139398800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Productivity drivers in North American tight and shale plays: A comprehensive analysis of completion trends, stimulation parameters, and geological characteristics","authors":"Harpreet Singh, Peng Cheng","doi":"10.1016/j.uncres.2024.100087","DOIUrl":"https://doi.org/10.1016/j.uncres.2024.100087","url":null,"abstract":"<div><p>This study evaluates the productivity of ten major unconventional oil and gas plays in North America, emphasizing the role of completion, stimulation, and geological factors. The primary objective is to thoroughly assess the influence of various completion, stimulation, and geological parameters on well productivity while uncovering key insights and emerging trends unique to each play.</p><p>The dataset comprises 72,809 horizontal wells from 2015 to 2022 across 10 plays, encompassing 6 oil plays (Bakken, Delaware, Duvernay, Midland, Eagle Ford, and Scoop|Stack) and 4 gas plays (Haynesville, Barnett, Marcellus, and Utica). This study examines completion and fracture stimulation trends influencing the productivity of various plays, along with the significance of geological and mechanical properties.</p><p>Key findings reveal that while geological characteristics, such as total organic carbon (TOC) content and brittleness, significantly impact reservoir quality, operational practices like completion design and stimulation techniques, also play critical roles in well productivity. Key insights from the analysis challenge the traditional emphasis on TOC as a sole productivity indicator, which might not be as pronounced as commonly assumed. The analysis indicates that, contrary to common beliefs, plays exhibiting both a lower brittleness index and fewer wells per pad are associated with faster fracture growth rates. Adding more wells per pad increases the minimum horizontal stress in the neighborhood, which slows fracture growth and causes it to redirect upward. Horizontal spacing plays a crucial role in enhancing productivity, especially in less productive plays which benefit from denser well development. Co-completion of wells leads to superior performance by reducing fracture-driven interactions or “frac hits”. While longer laterals increase resource contact, productivity gains are not linear. The productivity impact of increasing clusters per stage is variable, potentially limited by the stress shadowing effect.</p><p>In summary, this study offers critical insights into the productivity-influencing factors across diverse shale plays, contributing to the optimization of well development and resource extraction in the future. This study not only provides technical guidance for the unconventional oil and gas developments in North America, but can also serve as a valuable guide for similar projects elsewhere.</p></div>","PeriodicalId":101263,"journal":{"name":"Unconventional Resources","volume":"4 ","pages":"Article 100087"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666519024000153/pdfft?md5=c8466fc92a82e27161c59a2838563a40&pid=1-s2.0-S2666519024000153-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140823082","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Daobing Wang , Zhan Qu , Cheng Liu , Zongxiao Ren , Bo Yu , Qing Liu , Yongliang Wang , Nai Hao
{"title":"A numerical investigation into the propagation of acid-etched wormholes in geothermal wells","authors":"Daobing Wang , Zhan Qu , Cheng Liu , Zongxiao Ren , Bo Yu , Qing Liu , Yongliang Wang , Nai Hao","doi":"10.1016/j.uncres.2024.100083","DOIUrl":"10.1016/j.uncres.2024.100083","url":null,"abstract":"<div><p>Carbonate geothermal reservoirs are widespread in the Beijing-Tianjin-Hebei region, and acidification stands out as the most effective method to enhance the heat recovery potential of these reservoirs. To understand the propagation patterns of acidized wormholes in geothermal reservoirs, a pore-Darcy scale mathematical model of acidizing reactions in geothermal reservoirs has been established. A normal random distribution function is introduced to depict the reservoir's heterogeneity. Using the finite element method, the study simulated the impact of injection rate, acid concentration, diffusion coefficient, and acid-rock reaction rate on wormhole morphology. The findings indicate that the reaction is uniform in the early stage of acidification, becoming non-uniform in the late stage, ultimately forming distinctive wormhole structures. The acidification radius is more extensive along a particular direction post-acidification. Increasing the acid injection rate, acid concentration, and initial specific surface area proves beneficial in enhancing the acidizing effect. The outcomes of this study hold theoretical and technical significance for optimizing the thermal recovery efficiency of geothermal reservoirs.</p></div>","PeriodicalId":101263,"journal":{"name":"Unconventional Resources","volume":"4 ","pages":"Article 100083"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666519024000116/pdfft?md5=6ca0f78f4d7c20783a1cd8816eb19524&pid=1-s2.0-S2666519024000116-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140405720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sheng Chen , Xinyu Li , Bo Yang , Xuan Li , Yaojun Wang , Yadi Yang , Wenhui Du , Yonggen Li , Xiujiao Wang , Lianqun Zhang
{"title":"Detailed analysis of seismic reflection characteristics of tight sandstone reservoirs in the upper paleozoic of the ordos basin: A case study of block X","authors":"Sheng Chen , Xinyu Li , Bo Yang , Xuan Li , Yaojun Wang , Yadi Yang , Wenhui Du , Yonggen Li , Xiujiao Wang , Lianqun Zhang","doi":"10.1016/j.uncres.2024.100085","DOIUrl":"10.1016/j.uncres.2024.100085","url":null,"abstract":"<div><p>Tight sandstone gas represents a crucial domain for augmenting reserves and boosting oil and gas production in the Ordos Basin. Currently, the primary focus for development lies in the Upper Paleozoic tight sandstone gas located in the southwestern Ordos basin. The gas reservoirs in this area present distinct characteristics, including significant burial depth exceeding 4000 m, modest-scale sand bodies, an average thin reservoir thickness of 5.8 m, and rapid lateral variations in sand body distribution. These factors contribute to challenges in establishing a clear correlation between reservoir scale and seismic reflection patterns, leading to uncertainties in reservoir prediction. In this study, three types of seismic reflection characteristics of the bottom interface associated with the development of the S<sub>1</sub><sup>3</sup> reservoir in Block X have been summarized by using Forward modeling: (1) strong reflection of peaks on seismic sections; (2) weak reflection of troughs on seismic sections; and (3) strong reflection of complex waves with the bottom of the Shanxi Formation. The main factors that cause the above seismic reflection characteristics include the thickness of the lower coal seam, the spatial distribution and thickness of the reservoir. The above analysis breaks the inherent understanding that traditional strong seismic reflections are indicative of reservoir development, and instead, based on the three types of seismic reflection waveforms, waveform clustering is used to realize the differentiation of zones in the study area. Furthermore, combining with the facies-controlled high-resolution inversion, we achieved high-precision identification of tight sandstone reservoirs in Block X. This approach can be applied to similar reservoirs both at China and abroad.</p></div>","PeriodicalId":101263,"journal":{"name":"Unconventional Resources","volume":"4 ","pages":"Article 100085"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S266651902400013X/pdfft?md5=66eee292570a5e1f855946d76a84ab27&pid=1-s2.0-S266651902400013X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140778442","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Sedimentary: Carbonate microfacies and mineralogy of the southern Benue Trough and eastern Dahomey basin, Nigeria","authors":"G.O. Aigbadon , A. Ocheli , G.U. Ozulu , Z.J. Sanni , J.D. Akor , S.K. Owolabi","doi":"10.1016/j.uncres.2024.100082","DOIUrl":"https://doi.org/10.1016/j.uncres.2024.100082","url":null,"abstract":"<div><p>This study presents a detailed investigation into the microfacies, geochemistry, and depositional environments of carbonate rocks from the southern Benue Trough and eastern Dahomey Basin. This analysis involved a combination of techniques, including X-ray diffraction, X-ray fluorescence, scanning electron microscopy with energy-dispersive X-ray spectroscopy and thin-section petrographic examination. Samples from the Igumale Formation of the southern Benue Trough and samples from Ewekoro Formation of the eastern Dahomey Basin were analyzed, offering insights into their mineral compositions, elemental distributions, and depositional environments. In each basin, two carbonate microfacies were identified. The two microfacies found in the Igumale Formation were recognized as micritic bioclastic packstone and sandy bioclastic wackestone. In the Ewekoro Formation, the two microfacies recognized were bioclastic packstone and sparitic peloidal wackestone. The X-ray diffraction analysis of samples from both basins revealed a dominance of calcite. X-ray fluorescence analysis showcased calcium oxide and calcium as the predominant oxide and elements in both basins with varying concentrations. Scanning electron microscopy-energy-dispersive X-ray spectroscopy results unveiled the elemental composition with calcium and silicon emerging as major constituents. The photomicrographs suggest distinct depositional conditions for both samples with those from the Igumale Formation showing evidence of shallow marine and that of the Ewekoro Formation suggesting calm marine environments comprised of fined grained carbonate rocks containing fossils. This study has provided detailed understanding on the nature, microfacies types, mineralogical composition, depositional environment and diagenetic processes of Cretaceous-Paleocene carbonate rocks within the studied basins.</p></div>","PeriodicalId":101263,"journal":{"name":"Unconventional Resources","volume":"4 ","pages":"Article 100082"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666519024000104/pdfft?md5=c5af232cec092c6c311dbc5f82ab7de6&pid=1-s2.0-S2666519024000104-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140339620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Process modelling of waste tyre pyrolysis for gas production using response surface methodology","authors":"Odunayo T. Ore , Festus M. Adebiyi","doi":"10.1016/j.uncres.2024.100080","DOIUrl":"https://doi.org/10.1016/j.uncres.2024.100080","url":null,"abstract":"<div><p>The search for cleaner and renewable energy sources coupled with the need for environmental protection has necessitated the conversion of municipal solid wastes to energy sources. In this study, the pyrolysis of waste tyres in a fixed-bed reactor was carried out in a bid to generate non-condensable gases. The influence of process variables such as sample weight, reaction temperature, and reaction time were modelled and optimized using the central composite design of the response surface methodology. Based on the central composite design of the response surface methodology, the R<sup>2</sup>, adjusted R<sup>2</sup> and predicted R<sup>2</sup> values of 0.968, 0.941 and 0.750 respectively, indicated that the model properly fitted the experimental data. This implied the accuracy of the model prediction. The maximum predicted gas yield of 10.212 wt% was estimated under optimal conditions with desirability of 0.697, a dimensionless value indicating the closeness of the combination of input variables to the desired values for the response variables. The gases obtained upon pyrolysis of waste tyres can serve as a source of hydrocarbon gases in the petroleum and petrochemical industry.</p></div>","PeriodicalId":101263,"journal":{"name":"Unconventional Resources","volume":"4 ","pages":"Article 100080"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666519024000086/pdfft?md5=2732e1c0b7e3730271fdab0531f8ccbe&pid=1-s2.0-S2666519024000086-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140162724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}