ChemPhotoChem最新文献_第4页

Fluorescent and Chemiluminescent Dyes with Aryl Phthalimide and Aryl Luminol Chromophores 芳基酞酰亚胺和芳基鲁米诺发色团的荧光和化学发光染料

IF 3 4区化学

ChemPhotoChem Pub Date : 2025-05-09 DOI: 10.1002/cptc.202500064

Ben C. Bimberg, Florian K. Blaser, Pavel S. Pidenko, Javier Recio Ramos, Elena Fedotova, Bastian Mueller, Natalia A. Burmistrova, Antje Baeumner, Axel Duerkop, Axel Jacobi von Wangelin

{"title":"Fluorescent and Chemiluminescent Dyes with Aryl Phthalimide and Aryl Luminol Chromophores","authors":"Ben C. Bimberg, Florian K. Blaser, Pavel S. Pidenko, Javier Recio Ramos, Elena Fedotova, Bastian Mueller, Natalia A. Burmistrova, Antje Baeumner, Axel Duerkop, Axel Jacobi von Wangelin","doi":"10.1002/cptc.202500064","DOIUrl":"10.1002/cptc.202500064","url":null,"abstract":"Luminol is one of the most widely established and most well-known chemiluminescent molecules with diverse applications in modern analytical sciences such as forensics and cell assays. Structural and electronic modifications of the parent luminol can effectively enhance the (photo)physical and (photo)chemical properties. Herein, a straightforward route to stereoelectronically modulated luminol derivatives is developed by utilization of an effective cross-coupling at a versatile bromo phthalimide precursor. The modular synthesis enabled convenient access to two distinct classes of photoactive molecules: highly fluorescent 6–aryl–4–amino N-methyl phthalimides and chemiluminescent 7–aryl luminol derivatives. Electron-rich aryl substituents are shown to significantly enhance chemiluminescence (CL) quantum yields and exhibit good limits of detection in a CL hydrogen peroxide assay. The stereoelectronic effects on absorption, fluorescence, and CL properties are evaluated by experimental and theoretical studies.","PeriodicalId":10108,"journal":{"name":"ChemPhotoChem","volume":"9 8","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cptc.202500064","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144869267","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Chemical Composition Regulation for Tuning the Luminescent Properties of Organic–Inorganic Metal Halides 调节有机-无机金属卤化物发光性能的化学成分调控

IF 3 4区化学

ChemPhotoChem Pub Date : 2025-05-04 DOI: 10.1002/cptc.202500056

Zhizhuan Zhang, Guohong Zou

{"title":"Chemical Composition Regulation for Tuning the Luminescent Properties of Organic–Inorganic Metal Halides","authors":"Zhizhuan Zhang, Guohong Zou","doi":"10.1002/cptc.202500056","DOIUrl":"10.1002/cptc.202500056","url":null,"abstract":"Organic–inorganic metal halides (OIMHs) exhibiting superior optoelectronic properties have shown broad applications in sensing, photovoltaic devices, information storage, and biological imaging. Compared with pure inorganic or pure organic materials, OIMHs are distinguished by their hybrid feature, with processability of organic components and robustness of inorganic units, as well as plentiful luminescent sources derived from organic ligands, self-trapped excitons (STEs) of inorganic lattices, or the energy transfer between organic and inorganic species. Thereinto, chemical composition tunability of organic component, metal ions, and halogen provides multiple adjustable sites to tailor their structures and physicochemical properties. However, how to realizing effective and tunable luminescence in OIMHs for desired applications through rational chemical composition regulation has become a challenge. In this review, starting from the structurally tunable sites of OIMHs, the feasible methods for regulating the luminescent properties of OIMHs are summarized, which include the change of organic components, tunable dimensionality and configurations of inorganic species, heterometal inorganic units, as well as the systematic multisite fine-tuning based on a specific matrix. Finally, the challenges to synthesize OIMHs with promising luminescence performance through chemical composition regulation are discussed.","PeriodicalId":10108,"journal":{"name":"ChemPhotoChem","volume":"9 8","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144869399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Anthraquinone Sulfonates as Water-Soluble Photocatalysts: Synthetic Applications and Perspectives 蒽醌磺酸盐水溶性光催化剂的合成、应用及展望

IF 3 4区化学

ChemPhotoChem Pub Date : 2025-05-04 DOI: 10.1002/cptc.202500036

Daniel Kolb, Andrey Fedulin, Burkhard König

引用次数: 0

Chiral Intelligence: The Artificial Intelligence-Driven Future of Chiroptical Properties 手性智能：手性的人工智能驱动的未来

IF 3 4区化学

ChemPhotoChem Pub Date : 2025-05-01 DOI: 10.1002/cptc.202500079

Rafael G. Uceda, Alfonso Gijón, Sandra Míguez-Lago, Carlos M. Cruz, Luis Álvarez de Cienfuegos, Antonio J. Mota, Delia Miguel, Juan M. Cuerva

{"title":"Chiral Intelligence: The Artificial Intelligence-Driven Future of Chiroptical Properties","authors":"Rafael G. Uceda, Alfonso Gijón, Sandra Míguez-Lago, Carlos M. Cruz, Luis Álvarez de Cienfuegos, Antonio J. Mota, Delia Miguel, Juan M. Cuerva","doi":"10.1002/cptc.202500079","DOIUrl":"10.1002/cptc.202500079","url":null,"abstract":"Chirality plays a fundamental role in molecular sciences, with chiroptical properties offering valuable insights into the interaction between chiral molecules and polarized light. Designing chiral materials with enhanced properties requires a deep understanding of underlying physical principles, often revealed only through large datasets. In this context, artificial intelligence (AI) emerges as a powerful tool for accelerating discovery and optimization, efficiently exploring vast chemical spaces. This work explores the synergy between AI and chiroptical properties, highlighting recent advances in data-driven approaches for circular dichroism and circularly polarized luminescence. AI has demonstrated its ability to predict these phenomena accurately while uncovering structure–property relationships that can remain hidden under traditional methods. Various strategies are examined for integrating AI into chiroptical properties and the challenges and future directions of this field are discussed. In conclusion, combining chemical intuition with AI offers great potential for the rational design of next-generation chiral materials. This integration not only promises to unlock novel compounds with enhanced chiroptical properties but also provides new opportunities to deepen our understanding of chiroptical phenomena.","PeriodicalId":10108,"journal":{"name":"ChemPhotoChem","volume":"9 7","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cptc.202500079","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144673010","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Red-to-Near-Infrared Electroluminescence and Low-Threshold Amplified Spontaneous Emission from Solution-Processable Fluorescent Diketopyrrolopyrrole Derivatives 溶液处理荧光双酮吡咯衍生物的红-近红外电致发光和低阈值放大自发发光

IF 3 4区化学

ChemPhotoChem Pub Date : 2025-05-01 DOI: 10.1002/cptc.202500039

Anthony D’ Aléo, Virginie Placide, Hao Ye, Matteo Fornasarig, Danillo Valverde, Eunyoung Choi, Gabriel Canard, Jeong Weon Wu, Yoann Olivier, Chihaya Adachi, Jean-Charles Ribierre

{"title":"Red-to-Near-Infrared Electroluminescence and Low-Threshold Amplified Spontaneous Emission from Solution-Processable Fluorescent Diketopyrrolopyrrole Derivatives","authors":"Anthony D’ Aléo, Virginie Placide, Hao Ye, Matteo Fornasarig, Danillo Valverde, Eunyoung Choi, Gabriel Canard, Jeong Weon Wu, Yoann Olivier, Chihaya Adachi, Jean-Charles Ribierre","doi":"10.1002/cptc.202500039","DOIUrl":"10.1002/cptc.202500039","url":null,"abstract":"A detailed investigation of the photophysical, electroluminescence, and amplified spontaneous emission (ASE) properties of two solution-processable fluorescent diketopyrrolopyrrole derivatives is reported. Photophysical measurements are carried out in solution and blend films containing a 4,4′-bis(N-carbazolyl)-1,10-biphenyl (CBP) or a poly[(9,9-di-n-octylfluorenyl-2,7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diyl)] host, to gain important insights into the excited state behavior of these dyes. Quantum chemical calculations are also carried out to support the experimental findings. An optimization of the doping concentration in the CBP blends is necessary to reduce the strong aggregation. This optimization led for both near-infrared-emitting dyes to a substantial increase of the photoluminescence quantum yield, which can reach values as high as 60%. It is also found that the blend films show excellent ASE properties with a threshold as low as 3.5–4.5 μJ cm−2 for peak wavelengths of 739 and 727 nm. In addition, the electroluminescence properties of the two organic laser dyes are examined in organic light-emitting diodes (OLEDs). The best OLED device shows a maximum external quantum efficiency value of around 2%. Overall, this study demonstrates the excellent potential of diketopyrrolopyrrole derivatives for high-performance near-infrared organic semiconductor lasers and provides useful information for the design of new efficient near-infrared emitters for optoelectronic applications.","PeriodicalId":10108,"journal":{"name":"ChemPhotoChem","volume":"9 7","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cptc.202500039","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144673011","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent Advances in Luminescence of Platinum Complexes in the Near Infrared Second Window 铂配合物近红外第二窗口发光研究进展

IF 3 4区化学

ChemPhotoChem Pub Date : 2025-05-01 DOI: 10.1002/cptc.202500041

Shingo Hattori, Kazuteru Shinozaki

引用次数: 0

Luminescent Dinuclear Chromium(III) Complexes with Ferromagnetic Exchange Interactions 具有铁磁交换作用的发光双核铬配合物

IF 3 4区化学

ChemPhotoChem Pub Date : 2025-04-27 DOI: 10.1002/cptc.202500094

Dennis Fritzler, Cui Wang

{"title":"Luminescent Dinuclear Chromium(III) Complexes with Ferromagnetic Exchange Interactions","authors":"Dennis Fritzler, Cui Wang","doi":"10.1002/cptc.202500094","DOIUrl":"10.1002/cptc.202500094","url":null,"abstract":"Recent advances with luminescent mononuclear chromium(III) complexes have provided important molecular design guidelines for enhancing their photoluminescence properties. Applying these modern aspects of coordination chemistry to dinuclear CrIII complexes, which are mostly not luminescent but show interesting magnetic properties, seems attractive for exploring functional coordination compounds with magnetic exchange interactions and light-induced activity. In this concept, the key structural requirements for dinuclear CrIII complexes with ferromagnetic exchange interactions and with photoluminescence properties, respectively, are analyzed. Rational merger of these key magneto-optical–structural correlations leads to new types of dinuclear CrIII complexes with ferromagnetic coupling and room temperature luminescence, and their photophysical properties make them promising photosensitizers for energy transfer. These design concepts open the door of exploring novel dinuclear CrIII complexes, which can allow the crosstalk of photophysics, photochemistry, and magnetic exchange interactions.","PeriodicalId":10108,"journal":{"name":"ChemPhotoChem","volume":"9 7","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cptc.202500094","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144671960","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Excitation-Dependent Luminescent Properties with Wide Range of Color Changes Using a Liquescent Cationic Gold(I) Complex 利用液态阳离子金(I)配合物研究具有大范围颜色变化的激发依赖性发光特性

IF 3 4区化学

ChemPhotoChem Pub Date : 2025-04-24 DOI: 10.1002/cptc.202500035

Shuichi Suzuki, Daiki Hishikawa, Naoki Ando, Soichiro Kawamorita, Takeshi Naota

引用次数: 0

Structure-Dependent Fluorescent Behavior of Heterotetraarylene-Quinolones: The Critical Role of Chemical Bond Linkages 异四芳烯-喹诺酮类化合物的结构依赖荧光行为：化学键键的关键作用

IF 3 4区化学

ChemPhotoChem Pub Date : 2025-04-24 DOI: 10.1002/cptc.202500078

Siyuan Chen, Yan Zeng, Xuewen Wang, Qingyu Dou, Qianfu Luo

{"title":"Structure-Dependent Fluorescent Behavior of Heterotetraarylene-Quinolones: The Critical Role of Chemical Bond Linkages","authors":"Siyuan Chen, Yan Zeng, Xuewen Wang, Qingyu Dou, Qianfu Luo","doi":"10.1002/cptc.202500078","DOIUrl":"10.1002/cptc.202500078","url":null,"abstract":"Altering the manner in which groups are connected could offer a straightforward approach to achieving different functionality. Herein, heterotetraarylene molecules with varying bond-linked quinoline moieties are synthesized and designed to investigate their differential performances. The heterotetraarylene with carbon-carbon double bonded quinolines exhibits multifunctional properties: 1) all-visible light-induced photochromism, 2) acidochromism, and 3) acid–base gated photoswitch. Simultaneously, it achieves dual-mode fluorescence modulation through both photoexcitation and acid/base stimuli. However, the heterotetraarylene and quinoline connected by carbon carbon single bonds exhibit divergent properties, including light-induced emission enhancement and solvent-dependent fluorescence emission. This bond-selective functional divergence enables precise customization of stimulus-responsive fluorescence through simple connectivity control, establishing a novel design paradigm for smart molecular systems. Furthermore, the heterotetraarylene-linked quinolines with carbon carbon double bonds exhibit many properties, thus allowing for the construction of a new dual-responsive encryption system.","PeriodicalId":10108,"journal":{"name":"ChemPhotoChem","volume":"9 7","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144673099","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Photophysical Properties of Substituted Zinc Phthalocyanine-Dextran Systems 取代酞菁锌-右旋糖酐体系的光物理性质

IF 3 4区化学

ChemPhotoChem Pub Date : 2025-04-17 DOI: 10.1002/cptc.202400385

Tamara Potlog, Ion Lungu, Anton Airinei, Radu Tigoianu

{"title":"Photophysical Properties of Substituted Zinc Phthalocyanine-Dextran Systems","authors":"Tamara Potlog, Ion Lungu, Anton Airinei, Radu Tigoianu","doi":"10.1002/cptc.202400385","DOIUrl":"10.1002/cptc.202400385","url":null,"abstract":"This study presents the synthesis of tetracarboxy ZnPc/dextran and octacarboxy ZnPc/dextran solutions and the investigation of their photophysical properties using UV–vis, transient absorption (TA), and emission spectroscopy. Nanosecond TA measurements are conducted using pump–probe techniques. ZnPc(COOH)4 derivative exhibits efficient fluorescence, room-temperature phosphorescence in dimethyl sulfoxide/H2O solution, with a quantum efficiency of 14.8% and lifetimes of 1.18 and 8.89 μs. The addition of dextran to ZnPc(COOH)8 broadens the splitting of the two subbands in the Q band, leading to a characteristically strong far-redshift in the UV–vis absorption spectrum compared to the ZnPc(COOH)4/dextran (DX) system. The triplet-state properties of ZnPc(COOH)4/DX and ZnPc(COOH)8/DX systems with an absorption region within the phototherapeutic window, the average lifetimes values of 4.86 and 5.17 μs, respectively, reveal them attractive as photosensitizing materials in photodynamic therapy. TA spectra of ZnPc(COOH)4/DX and ZnPc(COOH)8/DX conjugates measured at a pump pulse of 355 nm show positive and negative signals, indicating triplet–triplet (T–T) absorption and triplet–singlet (T–S) emission.","PeriodicalId":10108,"journal":{"name":"ChemPhotoChem","volume":"9 7","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cptc.202400385","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144672022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0