Journal of Natural Gas Geoscience最新文献

{"title":"Structural inheritance through 3D reservoir modeling and ant-tracking attribute implications for structural configuration of Upper Cretaceous Pab Sandstone, Kirthar Fold Belt, Pakistan","authors":"Muhammad Asif Khan ,&nbsp;Muhammad Raiees Amjad ,&nbsp;Khawaja Hasnain Iltaf ,&nbsp;Adeeb Ahmed ,&nbsp;Rizwan Sarwar Awan","doi":"10.1016/j.jnggs.2024.01.002","DOIUrl":"10.1016/j.jnggs.2024.01.002","url":null,"abstract":"<div><p>This research presents a comprehensive investigation to enhance understanding of subsurface structural complexities within the Upper Cretaceous Pab Sandstone reservoir level in a gas-producing field within the Kirthar Fold Belt of the Southern Indus Basin, Pakistan. The seismic interpretation for accurate structural delineation and characterization of intricate fault systems is often challenging in Fold and Thrust Belt settings. The 3D structural maps of Upper Cretaceous Pab Sandstone at the reservoir level and the application of the ant-tracking attribute for fault extraction improve the structural understanding of the gas-producing field in the Kirthar Fold Belt in the Southern Indus Basin, Pakistan. Attribute-assisted 3D seismic interpretation has revealed several subsurface structure elements, including a large thrusted anticline extended towards the north-south, the pattern of north-south oblique ramp thrusts on the southeastern flank, and a combination of easterly vergent thrusts with a counter-back thrust creating a local pop-up structure in the area. A 3D structural model at the reservoir level was generated using horizon and fault framework volume-based modeling approach, serving as a structural model for Pab sandstone. The structural smoothing, variance and ant-tracking attribute were applied iteratively to get the best results and correlated with manual interpretation. 3D seismic interpretation and application of ant-tracking for fault extraction identifies discrete structural styles and revealed that all thrusting occurred due to compressional tectonics of the Plio-Pleistocene period. The apparent different styles result from the reactivation of earlier extensional fault systems and probably during phased periods of compression. The resulting 3D reservoir model can be used as an input to populate petrophysical properties and results can be extended for future field development plans. Integration of well and 3D seismic data interpretation and the application of automatic fault extraction techniques are highly recommended in structurally complex areas and have an equal implication for worldwide basins with similar conditions for reliable structural interpretation in Fold and Thrust Belts with structural complexity.</p></div>","PeriodicalId":100808,"journal":{"name":"Journal of Natural Gas Geoscience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2468256X24000105/pdfft?md5=8fea863154a7835017d167e04aea649f&pid=1-s2.0-S2468256X24000105-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139632343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Seismic geological characteristics and gas reservoir distribution of Changxing Formation biological bio-reef reservoir in the Longhuichang-Tieshan area, northeastern Sichuan Basin, China","authors":"Hu Zhao ,&nbsp;Juncheng Yi ,&nbsp;Hang Zhang ,&nbsp;Rongrong Zhao ,&nbsp;Jiewei Zhang ,&nbsp;Jingyun Dai ,&nbsp;Le Lü ,&nbsp;Hongyi An","doi":"10.1016/j.jnggs.2024.03.004","DOIUrl":"10.1016/j.jnggs.2024.03.004","url":null,"abstract":"<div><p>This research aims to address the ambiguity surrounding the extent of development of Changxing Formation bio-reef reservoirs in the Longhuichang-Tieshan area of the northeastern Sichuan Basin, China, and to elucidate the relationship between these reservoirs and gas distribution. Utilizing drilling and logging data, this study provides a comprehensive summary of the seismic geological characteristics of bio-reef reservoirs. Furthermore, it investigates the effects of reservoir parameters, structural location, and strike-slip faults on the development of bio-reef gas reservoirs. The research shows that bio-reef reservoirs in the area predominantly manifest vertical development in the middle and upper parts of the Changxing Formation, with horizontal expansion occurring along the platform margin and local highland areas. Notably, potential exploration areas are identified, particularly the western wing of the Longhuichang structure and the southwestern side of the Tieshannan structure. By comparing and analyzing the relationship between bio-reef gas reservoirs in the study area, the study aims to clarify the controlling effects of reservoir parameters, structural location, strike-slip faults, and other pertinent factors on the development of bio-reef gas reservoirs. It is observed that while these factors do not exhibit a clear strong linear relationship, they have a comprehensive effect on the development of gas reservoirs. The enrichment mode and failure mode of favorable gas reservoirs in the study area have been analyzed and established, providing crucial technical support to facilitate further exploration of Changxing Formation bio-reef gas reservoirs in the northeastern Sichuan Basin.</p></div>","PeriodicalId":100808,"journal":{"name":"Journal of Natural Gas Geoscience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2468256X24000142/pdfft?md5=62068de65a2ab3302790d1e8d38f31c8&pid=1-s2.0-S2468256X24000142-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140400931","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The dominant three-element model of oil and gas accumulation in basement buried hills: A discussion on new exploration frontiers in the deepwater area of the northern South China Sea","authors":"Gongcheng Zhang ,&nbsp;Chengfu Lyu ,&nbsp;Dongsheng Yang ,&nbsp;Shuai Guo ,&nbsp;Long Wang","doi":"10.1016/j.jnggs.2024.03.003","DOIUrl":"10.1016/j.jnggs.2024.03.003","url":null,"abstract":"<div><p>Basement buried hill reservoirs represent significant emerging prospects among the newly discovered growth poles in the deepwater areas of the northern South China Sea. Addressing the unclear key factors contributing to their formation, this study dissects successful global exploration cases of basement buried hill reservoirs and analyzes the common characteristics of basement reservoir accumulation under different basin types, structural backgrounds, basement lithologies, and oil and gas geological conditions. A three-element coupling relationship, termed “source-reservoir-cap”, is proposed as the dominant mechanism controlling basement buried hill reservoir formation. The genesis of these reservoirs requires adequate oil and gas supply, appropriately sized accumulation bodies, and effective sealing layers. The optimal configuration of the “source-reservoir-cap” relationship directly influences the efficient charging and preservation of oil and gas within basement buried hill reservoirs. Four configurations are identified, including circumstances such as the source-underlying low-positioned basement buried hill with a “source-reservoir cover docking migration type”, the source-border middle-positioned basement buried hill with a “source-reservoir lateral window docking migration type”, and the source-outside high-positioned basement buried hill with both “source-reservoir short-distance transport and migration type” and “source-reservoir long-distance transport and migration type”. The first to three models present favorable accumulation conditions. Based on the “source-reservoir-cap” three-element coupled model, this study identifies the Yunkai basement buried hill in the Pearl River Mouth Basin, the central depression in the Qiongdongnan Basin, and the northern and southern basement buried hills belts as crucial exploration targets in the deepwater areas of the northern South China Sea.</p></div>","PeriodicalId":100808,"journal":{"name":"Journal of Natural Gas Geoscience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2468256X24000130/pdfft?md5=a0914958f7658017930ca04e9a86c02d&pid=1-s2.0-S2468256X24000130-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140401001","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Characteristics of geothermal field and tectono-thermal evolution in Baiyun Sag, Pearl River Mouth Basin, China","authors":"Xudong Wang ,&nbsp;Nansheng Qiu ,&nbsp;Guangrong Peng ,&nbsp;Xiangtao Zhang ,&nbsp;Kongsen Li ,&nbsp;Jian Chang ,&nbsp;Yinglin Zhang ,&nbsp;Qingsong He","doi":"10.1016/j.jnggs.2024.03.002","DOIUrl":"10.1016/j.jnggs.2024.03.002","url":null,"abstract":"<div><p>Baiyun Sag has become the primary focus of deepwater exploration in the Pearl River Mouth Basin. However, its complex and high-variate geothermal characteristics have severely constrained further oil and gas exploration and resource evaluation. In this study, the present-day geothermal field and tectono-thermal evolution histories of Baiyun Sag were systematically studied based on measured rock thermal conductivity and heat generation data, borehole temperatures, low-temperature thermochronometer analyses, and geodynamic methodologies. The thermal conductivity of 251 core samples ranges from 1.131 to 4.478 W/(m·K), with an average of 2.258 W/(m·K), while the heat generation rate of 106 samples ranges from 0.868 to 1.735 μW/m³, averaging 1.499 μW/m³. The thermal conductivity in Baiyun Sag exhibits a gradual decrease from the Wenchang Formation to the Hanjiang Formation, whereas the heat generation rate decreases with depth. The present-day heat flow in Baiyun Sag ranges from 66.6 to 139.1 mW/m², with an average of 89.7 ± 14.7 mW/m², showing a gradual increasing trend from northwest to southeast. Formation temperature at depths of 1–5 km increases proportionally with depth. Thermal inversion, as inferred from low-temperature thermochronological data of six basement samples, reveals distinct temperature paths for each tectonic unit in Baiyun Sag. These paths are primarily linked to regional tectonic uplift-subsidence and basement heat flow variation. Geodynamic simulations further indicate two extensional events in Baiyun Sag during the Eocene and Middle Miocene, leading to a rapid increase in basement heat flow. This study systematically elucidates the present-day geothermal field characteristics and tectono-thermal evolution history of Baiyun Sag, bearing significant implications for regional tectonic evolution and future deepwater oil and gas explorations.</p></div>","PeriodicalId":100808,"journal":{"name":"Journal of Natural Gas Geoscience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2468256X24000129/pdfft?md5=1570bfa6b44e04f28accbb3219525911&pid=1-s2.0-S2468256X24000129-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140276674","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Depositional pattern and source-to-sink process of submarine fans in Lingshui and Sanya formations, Baodao Sag, Qiongdongnan Basin, China","authors":"Xingzong Yao ,&nbsp;Congjun Feng ,&nbsp;Hongjun Qu ,&nbsp;Jia Chen ,&nbsp;Mengsi Sun","doi":"10.1016/j.jnggs.2024.03.001","DOIUrl":"10.1016/j.jnggs.2024.03.001","url":null,"abstract":"<div><p>The deepwater area is one of the frontiers of oil and gas exploration, with the understanding of distribution and genesis of deepwater reservoirs being crucial for reservoir formation research. Despite Baodao Sag in the Qiongdongnan Basin being proven to be rich in hydrocarbon generation, significant oil and gas fields have yet to be discovered in the ultra-deepwater areas, and the distribution patterns of reservoirs in deep water remain unclear. Taking the southern slope area of the Baodao Sag as an example, the distribution characteristics of submarine fans are studied by employing seismic prediction methods, including seismic reflection structure analysis, seismic facies geometry, seismic attribute analysis, and the source-to-sink theory. The results show distinct characteristics: the fan delta exhibits parallel oblique progradational reflection, the slumping submarine fan displays lenticular reflection, and the submarine fan of the Sanya Formation demonstrates subparallel sheet reflection. The provenance of sediment is traced back to the denudation area of the Songnan low uplift and the Southern Uplift area in the southwest. The sediments were primarily transported through two main incised channel systems in the north and south, ultimately flowing into the southern slope area of the Baodao Sag. The application of seismic sedimentological prediction methods and source-sink theory has laid a solid geological foundation for oil and gas exploration and the analysis of reservoir forming conditions in the deepwater area of the Baodao Sag.</p></div>","PeriodicalId":100808,"journal":{"name":"Journal of Natural Gas Geoscience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2468256X24000117/pdfft?md5=d9efa78ad3183009fc8a4a8240a42263&pid=1-s2.0-S2468256X24000117-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140280917","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Research progress of hydrocarbon generation kinetics based on gold tube","authors":"Yaoyu Li ,&nbsp;Shixin Zhou ,&nbsp;Jing Li ,&nbsp;Zexiang Sun ,&nbsp;Wenjun Pang","doi":"10.1016/j.jnggs.2023.11.005","DOIUrl":"10.1016/j.jnggs.2023.11.005","url":null,"abstract":"<div><p>Gold tube thermal simulation experiments represent a pivotal tool in exploring hydrocarbon generation kinetics in hydrocarbon source rocks. Compared to other reaction systems, the reaction environment and the pyrolysis product composition within the gold tube display a greater resemblance to actual geological conditions, especially for coal-based hydrocarbon rocks with poor hydrocarbon removal capacity. The kerogen is in close contact with various pyrolysis products and reacts with each other in the gold tube. Researchers have carried out extensive research and application in hydrocarbon generation kinetics based on gold tubes in recent years. But a systematic and comprehensive summary of these studies is lacking. This paper provides a review of the kinetic study based on golden tubes in recent years from the perspectives of research objects, influencing factors, applications and problems. The main targets of hydrocarbon generation kinetics based on gold tubes include CH₄, C_1-5, C₈₊ and so on. Elucidating the kinetics of diverse pyrolysis products aids comprehension of the mechanism of organic matter pyrolysis. Reaction condition, minerals and organic structure all influence hydrocarbon production kinetics. Clarifying the effects of these influencing factors is of great importance in understanding the pyrolysis mechanism of hydrocarbon source rocks and pyrolysis research in the domain of hydrocarbons. Golden tube-based kinetic studies of hydrocarbon production have good potential application, not only in determining the hydrocarbon generation history of hydrocarbons in the study area, but also in studying the genesis, origin, and reservoir formation mode of natural gas. This paper also summarizes some problems and solutions of the gold tube hydrocarbon generation kinetics, such as the inhomogeneity of the samples, the difference between the gold tube system and natural conditions, and the determination of the time point of oil secondary cracking. Continuous optimization of the solution enhances the authenticity of the golden tube simulation experiment. This review aims to offer a theoretical foundation and research suggestions for investigating pyrolysis kinetics of hydrocarbon source rocks and hydrocarbons based on golden tubes.</p></div>","PeriodicalId":100808,"journal":{"name":"Journal of Natural Gas Geoscience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2468256X23000780/pdfft?md5=e0e85fb76989fd125bfee519add5e99a&pid=1-s2.0-S2468256X23000780-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139016069","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Genesis and source of natural gas in Well Mitan-1 of Ordovician Majiagou Formation, middle-eastern Ordos Basin, China","authors":"Qiang Meng ,&nbsp;Yu Xiao ,&nbsp;Jianglong Shi ,&nbsp;Heng Zhao ,&nbsp;Yan Liu ,&nbsp;Yiqing Wang ,&nbsp;Xiaomin Xie ,&nbsp;Yaohui Xu","doi":"10.1016/j.jnggs.2023.12.001","DOIUrl":"10.1016/j.jnggs.2023.12.001","url":null,"abstract":"<div><p>The Well Mitan-1 has achieved a major breakthrough in the exploration of Ordovician subsalt natural gas in the mid-eastern Ordos Basin, demonstrating a high-yield industrial gas flow in fourth member of the Majiagou Formation of Ordovician (O₁<em>m</em>₄). Despite this success, there are ongoing disputes regarding the origin of the natural gas found in Well Mitan-1. Measured results show that the natural gas in Well Mitan-1 is mainly composed of alkane gas (95.18 %). The gas drying coefficient (C₁/C_1-5) is measured at 0.947, and the H₂S content is 3.49 %, with a small amount of N₂ and CO₂ in the non-hydrocarbon gas. The carbon isotopic compositions of methane, ethane, and propane in the natural gas are −45.5 ‰, −26.4 ‰, and −24.3 ‰, respectively. Based on the regional geological background, the characteristics of potential source rocks and the geochemical characteristics of natural gas, it is considered that the natural gas in Well Mitan-1 is self-generated and self-accumulated oil-associated gas in Ordovician subsalt carbonate rocks. However, certain geochemical anomalies, such as the lighter methane carbon isotope value (<em>δ</em>¹³C₁) and coal-type gas characteristics in ethane carbon isotope (<em>δ</em>¹³C₂), raise questions. Further insights from thermal simulation experiments on hydrocarbon generation and the analysis of residual gas in rocks suggest a close relationship between the special geochemical characteristics of Well Mitan-1 and the presence of gypsum rocks. The ubiquitous gypsum rock serves a dual purpose: acting as an effective caprock, facilitating the retention of early-generated natural gas, and promoting the generation of heavy hydrocarbon gases (C₂₊) and H₂S. The relatively low H₂S content (less than 5 %) and higher C₂₊ content indicate that thermochemical sulfate reduction (TSR), if present, is not strong enough to significantly impact methane. The <em>δ</em>¹³C₂ is identified as a potentially sensitive parameter for identifying TSR.</p></div>","PeriodicalId":100808,"journal":{"name":"Journal of Natural Gas Geoscience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2468256X23000779/pdfft?md5=a464f79b1c6ee6243f72a630ee2b4016&pid=1-s2.0-S2468256X23000779-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139013519","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The coupling action of helium and nitrogen enrichment and its significance","authors":"Shengfei Qin ,&nbsp;Guoxiao Zhou ,&nbsp;Jiyuan Li ,&nbsp;Gang Tao ,&nbsp;Zizhuo Zhao","doi":"10.1016/j.jnggs.2023.12.003","DOIUrl":"10.1016/j.jnggs.2023.12.003","url":null,"abstract":"<div><p>Helium, a critical rare strategic resource primarily sourced from natural gas, is currently a subject of intense research regarding its enrichment processes within gas reservoirs. Investigating the enrichment of helium is urgent and vital for advancing helium exploration. This study involved the collection of natural gas samples from the Qaidam, Sichuan, and Junggar basins for helium and nitrogen content testing and analysis. The findings were combined with studies on natural gas fractions and helium content in local and international major helium-rich fields. The investigation revealed a strong correlation between helium content and nitrogen presence in helium-rich fields, a phenomenon that also extends to some helium-poor fields. Accordingly, this study proposes a coupling relationship between helium and nitrogen, suggesting that both elements are simultaneously enriched in natural gas. Furthermore, both are associated with groundwater and may share a common origin in source rocks. This proposed coupling relationship holds the potential to unveil the mystery of helium enrichment, offering a new perspective for the exploration of helium-rich resources and providing a foundational framework for helium enrichment theory.</p></div>","PeriodicalId":100808,"journal":{"name":"Journal of Natural Gas Geoscience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2468256X23000809/pdfft?md5=4c25a533bac14d91041b8ee38b7990b9&pid=1-s2.0-S2468256X23000809-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139394541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Geological characteristics and main controlling factors of the helium-rich gas reservoirs in Sozak Gas Field, Kazakhstan","authors":"Xiaodan Gu ,&nbsp;Chengzao Jia ,&nbsp;Jianfa Chen ,&nbsp;Lin Jiang","doi":"10.1016/j.jnggs.2023.12.002","DOIUrl":"10.1016/j.jnggs.2023.12.002","url":null,"abstract":"<div><p>Based on core data, physical properties, well logging, gas testing, composition, and helium distribution from 13 newly drilled wells, in combination with regional tectonic evolution, depositional background, and typical gas reservoir profiles, helium-rich gas reservoirs geology characteristics and main controlling factors have been explored. The results show that three gas reservoirs formed from bottom to top, i.e., granite and metamorphite fractured reservoir in the basement, tight sandstone structural reservoirs in the Devonian, and huge continuous carbonate reservoirs in the Lower Carboniferous. Fractures developed on structural points control high-production, and gas is prominently displayed in low structural areas. The dry gas exhibits richness in helium, with decreasing helium content from the basement to the Carboniferous. The pre-Devonian large-scale granite and metamorphite basement serve as the primary helium source, while the high-gamma sandstones of the Devonian and the Carboniferous act as secondary sources. Fractures play a dual role, being filled up and conducting in two ways: gas from the Carboniferous source rocks migrates downward, and helium migrate upward. Thick interbedded gypsum-tight limestone on top of the Lower Carboniferous act as the regional caprock, effectively preserving the helium-rich gas reservoirs.</p></div>","PeriodicalId":100808,"journal":{"name":"Journal of Natural Gas Geoscience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2468256X23000792/pdfft?md5=5fdf6683496eea4c2ef7e799b25148aa&pid=1-s2.0-S2468256X23000792-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139015809","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Geochemical characteristics of shale gas hydraulic fracturing flowback/produced water in Zheng’an block, northern Guizhou Province, China","authors":"Yunyan Ni ,&nbsp;Song Liu ,&nbsp;Linzhi Li ,&nbsp;Bo Zhang ,&nbsp;Limiao Yao ,&nbsp;Jianli Sui ,&nbsp;Jianping Chen","doi":"10.1016/j.jnggs.2024.01.001","DOIUrl":"10.1016/j.jnggs.2024.01.001","url":null,"abstract":"<div><p>Guizhou Province of China is rich in shale gas resources. In recent years, important progress has been made in the exploration and development of shale gas in the Upper Ordovician Wufeng Formation-Lower Silurian Longmaxi Formation in Zheng'an block in northern Guizhou, adjacent to Sichuan Basin. Due to the complex geological conditions and fragile ecological environment in the shale gas distribution area, serious environmental pollution risks may exist in shale gas exploitation. Therefore, this paper conducted element, hydrogen and oxygen isotope analyses for shale gas fracturing flowback/produced water of Well AY7-4 in Zheng'an block. The results showed that the contents of K, Na, Ca, Mg and <span><math><mrow><mi>N</mi><msubsup><mi>H</mi><mn>4</mn><mo>+</mo></msubsup></mrow></math></span> in the flowback/produced water of Well AY7-4 were very high, with an average of 118 mg/L, 7616 mg/L, 266 mg/L, 47 mg/L and 76 mg/L, respectively. The content of Na, Ca and Mg is similar to that of shale gas flowback/produced water in Weiyuan, but lower than that in Changning and Fuling. <span><math><mrow><mi>N</mi><msubsup><mi>H</mi><mn>4</mn><mo>+</mo></msubsup></mrow></math></span> content was similar to that in Changning, but much higher than that in Weiyuan. The average Cl content was 11605 mg/L, which was similar to that in Weiyuan, but lower than that in Changning and Fuling. The average Br content is 48 mg/L, slightly lower than that of Weiyuan, and about half of that of Changning and Fuling. Correspondingly, the Br/Cl value of Well AY7-4 is the lowest, reflecting its relatively low Br content. The average content of Li, B and Sr is 17 mg/L, 10 mg/L and 45 mg/L, respectively, which is similar to that of the Weiyuan, Changning and Fuling shale gas fields. The distribution model of Li and Sr is similar to that of Cl, Br and Na, but the B content and B/Cl value of Well AY7-4 are the lowest. The linear relationship between Br and Cl contents and between δD and δ¹⁸O of flowback/produced water of Well AY7-4, freshwater used for hydraulic fracturing and hydraulic fracturing injected fluid indicates that flowback/produced water of Well AY7-4 is mainly the mixed product between low salinity injected fracturing fluid and high salinity brine retained in shale formation. The hydrogen and oxygen isotopic compositions gradually become heavier over time, indicating that the proportion of high salt end formation brine in flowback/produced water is increasing. The contents of Cl, Br, Na and <span><math><mrow><mi>N</mi><msubsup><mi>H</mi><mn>4</mn><mo>+</mo></msubsup></mrow></math></span> in the flowback/produced water of Well AY7-4 are far higher than the allowable discharge value, which is a potential environmental pollution risk and cannot be discharged directly.</p></div>","PeriodicalId":100808,"journal":{"name":"Journal of Natural Gas Geoscience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2468256X24000014/pdfft?md5=305ce6f681afed2e8be53e9b2259b73c&pid=1-s2.0-S2468256X24000014-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139536998","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}