{"title":"Hydrothermal preparation of the low-expansion NZP family of materials","authors":"Sridhar Komarneni","doi":"10.1016/0267-3762(88)90062-8","DOIUrl":"10.1016/0267-3762(88)90062-8","url":null,"abstract":"<div><p>This paper reports on the synthesis of low thermal expansion NaZr<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub> (NZP) and CaZr<sub>4</sub>(PO<sub>4</sub>)<sub>6</sub> (CZP) families of materials and their analogues for each of the alkali and alkaline earth metals by the hydrothermal method. Starting gels were prepared by mixing stoichiometric proportions of alkali and alkaline earth metal chlorides of nitrates with a 0·5<span>m</span> ZrOCl<sub>2</sub> solution and by titrating this mixture with a stoichiometric amount of 1·0<span>m</span> H<sub>3</sub>PO<sub>4</sub> while the solution was constantly stirred. The gels were dried to remove the HCl produced during the reaction between ZrOCl<sub>2</sub> and H<sub>3</sub>PO<sub>4</sub>, and were then heated with water in teflon-lined Parr bombs or gold capsules. In general, the hydrothermal method yielded 100–300 nm sized rhombohedral single crystals of different NZP materials at 175–200°C under saturated steam pressure conditions. The initial pH and the temperature of treatment are the most critical factors in the hydrothermal synthesis of these technologically important low expansion materials.</p></div>","PeriodicalId":100697,"journal":{"name":"International Journal of High Technology Ceramics","volume":"4 1","pages":"Pages 31-39"},"PeriodicalIF":0.0,"publicationDate":"1988-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0267-3762(88)90062-8","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78788325","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Crystal structure change of thermistor of MnCoz.sbnd;Ni oxides in firing process","authors":"Takeshi Meguro, Tadashi Sasamoto, Takashi Yokoyama, Satoru Yamada, Yoshiaki Abe, Naochika Torikai","doi":"10.1016/0267-3762(88)90073-2","DOIUrl":"10.1016/0267-3762(88)90073-2","url":null,"abstract":"","PeriodicalId":100697,"journal":{"name":"International Journal of High Technology Ceramics","volume":"4 1","pages":"Page 84"},"PeriodicalIF":0.0,"publicationDate":"1988-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0267-3762(88)90073-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73052187","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Contents of volume 4","authors":"","doi":"10.1016/0267-3762(88)90058-6","DOIUrl":"https://doi.org/10.1016/0267-3762(88)90058-6","url":null,"abstract":"","PeriodicalId":100697,"journal":{"name":"International Journal of High Technology Ceramics","volume":"4 2","pages":"Pages 359-360"},"PeriodicalIF":0.0,"publicationDate":"1988-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0267-3762(88)90058-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138336676","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Elastic properties of engineering ceramics at elevated temperature","authors":"Shuji Sakaguchi, Fumihiro Wakai, Yosoo Matsuno","doi":"10.1016/0267-3762(88)90090-2","DOIUrl":"10.1016/0267-3762(88)90090-2","url":null,"abstract":"","PeriodicalId":100697,"journal":{"name":"International Journal of High Technology Ceramics","volume":"4 1","pages":"Page 90"},"PeriodicalIF":0.0,"publicationDate":"1988-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0267-3762(88)90090-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79882493","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Machine design requirements for uniaxial testing of ceramics materials","authors":"J.E. Amaral, C.N. Pollock","doi":"10.1016/0267-3762(88)90042-2","DOIUrl":"10.1016/0267-3762(88)90042-2","url":null,"abstract":"","PeriodicalId":100697,"journal":{"name":"International Journal of High Technology Ceramics","volume":"4 2","pages":"Pages 143-160"},"PeriodicalIF":0.0,"publicationDate":"1988-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0267-3762(88)90042-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82994255","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"High-temperature flexural strength of engineering ceramics","authors":"A. Marsh, D.A. Bell","doi":"10.1016/0267-3762(88)90050-1","DOIUrl":"10.1016/0267-3762(88)90050-1","url":null,"abstract":"<div><p>The BCRL high-temperature flexural strength facility has been developed using the most suitable methods reported in the scientific literature. Temperature monitoring and control, together with stress-strain measurement are performed by a microcomputer with 16-bit analogue-to-digital converters, and the results are outputted to an intelligent plotter. The equipment is suitable for measurements on high strength ceramics and has been fully evaluated on a wide range of engineering ceramic materials.</p></div>","PeriodicalId":100697,"journal":{"name":"International Journal of High Technology Ceramics","volume":"4 2","pages":"Pages 269-273"},"PeriodicalIF":0.0,"publicationDate":"1988-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0267-3762(88)90050-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76064280","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effects of ZrO2 ultrafine particle additive on the formation of Al2O3 from sulfate","authors":"Keiji Daimon, Etsuro Kato","doi":"10.1016/0267-3762(88)90079-3","DOIUrl":"10.1016/0267-3762(88)90079-3","url":null,"abstract":"","PeriodicalId":100697,"journal":{"name":"International Journal of High Technology Ceramics","volume":"4 1","pages":"Page 86"},"PeriodicalIF":0.0,"publicationDate":"1988-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0267-3762(88)90079-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80117048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Successive phase transitions of BaTiO3 ceramics synthesized by powder-calcination","authors":"Akihiro Hamano, Tooru Atake, Yasutoshi Saito","doi":"10.1016/0267-3762(88)90063-X","DOIUrl":"10.1016/0267-3762(88)90063-X","url":null,"abstract":"<div><p>The BaTiO<sub>3</sub> ceramics has been synthesized by calcining the powdered reactants BaCO<sub>3</sub> and TiO<sub>2</sub> at various temperatures, to examine the influences of calcination temperature on the successive phase transitions. The properties of the products have been studied by differential thermal analysis, dielectric measurements, X-ray diffraction and scanning electron microscopy. While the cubic-tetragonal transition temperature shifts towards higher temperatures with increasing calcination temperature, the lower two transitions shift towards lower temperatures. The thermal and dielectric anomalies due to the phase transitions increase as the calcination temperature rises.</p></div>","PeriodicalId":100697,"journal":{"name":"International Journal of High Technology Ceramics","volume":"4 1","pages":"Pages 41-50"},"PeriodicalIF":0.0,"publicationDate":"1988-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0267-3762(88)90063-X","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91302501","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Solubility of MgO in single-crystal Al2O3","authors":"Ken Ando, Masataka Momoda","doi":"10.1016/0267-3762(88)90075-6","DOIUrl":"10.1016/0267-3762(88)90075-6","url":null,"abstract":"","PeriodicalId":100697,"journal":{"name":"International Journal of High Technology Ceramics","volume":"4 1","pages":"Page 84"},"PeriodicalIF":0.0,"publicationDate":"1988-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0267-3762(88)90075-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90178333","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Behavior of mirror-like region of sintered Si3N4 under rotary bending","authors":"Haeng-Nam Ko","doi":"10.1016/0267-3762(88)90089-6","DOIUrl":"10.1016/0267-3762(88)90089-6","url":null,"abstract":"","PeriodicalId":100697,"journal":{"name":"International Journal of High Technology Ceramics","volume":"4 1","pages":"Page 89"},"PeriodicalIF":0.0,"publicationDate":"1988-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0267-3762(88)90089-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74426901","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}