International Journal for Radiation Physics and Chemistry最新文献_第5页

Dr. H. Hering-Biography 赫林博士传记

International Journal for Radiation Physics and Chemistry Pub Date : 1976-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0020-7055(76)90052-8

J. Sutton

引用次数: 0

Gamma and pulse radiolysis of methanolic solutions of triphenylphosphine 三苯基膦甲醇溶液的伽马和脉冲辐射分解

International Journal for Radiation Physics and Chemistry Pub Date : 1976-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0020-7055(76)90039-5

M. Venturi, A. Breccia, F. Busi, Q.G. Mulazzani

引用次数: 3

Determination of superoxide (O2−) radical anion reaction rates using pulse radiolysis 脉冲辐射解法测定超氧(O2−)自由基阴离子反应速率

International Journal for Radiation Physics and Chemistry Pub Date : 1976-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0020-7055(76)90082-6

C.L. Greenstock, G.W. Ruddock

引用次数: 24

Pulse radiolysis studies on aqueous systems PtCl42−Cl− and PtCl42−Br− 脉冲辐射溶解水溶液PtCl42−Cl−和PtCl42−Br−的研究

International Journal for Radiation Physics and Chemistry Pub Date : 1976-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0020-7055(76)90081-4

R.K. Broszkiewicz, J. Grodkowski

引用次数: 12

Mobility of the electron in liquid and solid 3-methylpentane 电子在液体和固体3-甲基戊烷中的迁移率

International Journal for Radiation Physics and Chemistry Pub Date : 1976-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0020-7055(76)90016-4

G.F. Novikov, B.S. Yakovlev

{"title":"Mobility of the electron in liquid and solid 3-methylpentane","authors":"G.F. Novikov, B.S. Yakovlev","doi":"10.1016/0020-7055(76)90016-4","DOIUrl":"10.1016/0020-7055(76)90016-4","url":null,"abstract":"<div>The authors have investigated the current of electrical conductivity I induced by a pulse of 2 × 10−7 s of high energy electrons in 3-methylpentane (3MP) over the temperature range 94–296 K. The determination of the drift mobility of the excess electron u is based on measurement of the amplitude of I in conditions in which the lifetime of the excess electron in 3MP τ ⪢ 2 × 10−7 s and the total number of free charges q generated in the course of one pulse. In liquid 3MP q was measured by integrating I and in solid 3MP by integrating the current of thermostimulated conductivity on heating the sample to melting point. At T = 296 K the value u = 0·22 cm2 V−1 s−1 and agrees with the value obtained from measurements of the time of transit by the electron of the distance between electrodes d≈0·1 cm.In the temperature interval from 94–296 K the value u monotonically changes from 10−8 to 0·22 cm2 V−1 s−1. In the region of the melting point, the values of u in liquid and solid 3MP are much the same, whereas the activation energy changes from 0·14 to 0·4 eV on passing from liquid to solid 3MP. The activation energy of the mobility of the electron in solid 3MP is connected with the energy of the thermal release of the electron from the deepest structural traps.Extrapolation of the function u(T) by the Arrhenius law with an activation energy of 0·4 eV gives the value u ≈ 10−15 cm2 V−1 s−1 at 77 K which accords with the value obtained from measurement of the quasi-steady photo-conductivity and evaluation of the lifetime of the trapped electron in 3MP at 77 K.</div>","PeriodicalId":100688,"journal":{"name":"International Journal for Radiation Physics and Chemistry","volume":"8 4","pages":"Pages 517-518"},"PeriodicalIF":0.0,"publicationDate":"1976-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-7055(76)90016-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88749614","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 10

A pulse radiolysis investigation of 9,10-diphenylanthracene excited state formation in 3-methylpentane at low temperature 低温下3-甲基戊烷中9,10-二苯基蒽激发态的脉冲辐射分解研究

International Journal for Radiation Physics and Chemistry Pub Date : 1976-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0020-7055(76)90005-X

J. Kroh, J. Mayer, J.L. Gȩbicki, J. Grodkowski

引用次数: 11

Reactions intratrajectories dans la radiolyse de solutions aqueuses par les particules de recul de 10B(n, α)7Li 10B(n， α)7Li反冲粒子在水溶液辐射分解中的路径内反应

International Journal for Radiation Physics and Chemistry Pub Date : 1976-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0020-7055(76)90031-0

J. Pucheault, P. Sigli

引用次数: 4

Scavenging of ions in irradiated organic liquids 辐照有机液体中离子的清除

International Journal for Radiation Physics and Chemistry Pub Date : 1976-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0020-7055(76)90072-3

J. Kroh, E. Hankiewicz, J. Piekarska

{"title":"Scavenging of ions in irradiated organic liquids","authors":"J. Kroh, E. Hankiewicz, J. Piekarska","doi":"10.1016/0020-7055(76)90072-3","DOIUrl":"10.1016/0020-7055(76)90072-3","url":null,"abstract":"<div>The kinetics of positive ion and electron scavengin gin certain n-alkanes, cycloalkanes, branched alkanes, aromatic hydrocarbons and in some polar compounds (ethers, dimethyl-formamide) have been investigated.The non-homogeneous kinetic approach gives satisfactory agreement with experimental Results for n-hexane, cyclohexane, iso-octane and 2,3-dimethylbutane. Differences between positive ion and electron scavenging for ethers have been observed and ascribed to the complex structure of the corresponding positive ions. For benzene and dimethylformamide the homogeneous kinetic equation gives the best agreement with experimental results.Characteristic parameters such as Gfi, Ggi, reactivity coefficients α, rate constant of ion scavenging ks, geminate recombination parameters for several solvents λ, and the most probable distances of electron thermalization have been determined or calculated.The effect of molecular structure on the ionic reactions has been discussed.</div>","PeriodicalId":100688,"journal":{"name":"International Journal for Radiation Physics and Chemistry","volume":"8 3","pages":"Pages 289-304"},"PeriodicalIF":0.0,"publicationDate":"1976-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-7055(76)90072-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84508672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 4

The pulse radiolysis of aqueous solutions of simple RCN compounds 简单RCN化合物水溶液的脉冲辐射分解

International Journal for Radiation Physics and Chemistry Pub Date : 1976-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0020-7055(76)90077-2

I.G. Draganić, Z.D. Draganić, V.M. Marković

引用次数: 19

The mechanism of excited state formation in radiolysis of hydrocarbon liquids 烃类液体辐射分解激发态形成机理

International Journal for Radiation Physics and Chemistry Pub Date : 1976-01-01 Epub Date: 2002-10-09 DOI: 10.1016/0020-7055(76)90068-1

Lee Walter, Fumio Hirayama , Sanford Lipsky

引用次数: 21