无机化学学报最新文献

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Effect of Strontium and Cobalt Co-doping on the Structural and Electrical Properties of PrAlO_3 Perovskite Oxides 锶和钴共掺杂对PrAlO_3钙钛矿氧化物结构和电性能的影响
IF 0.7 4区 化学
无机化学学报 Pub Date : 2013-01-01 DOI: 10.3969/J.ISSN.1001-4861.2013.00.155
Xu Jiahuan, X. Jun, Ye Qin, Guo Yin-tao
{"title":"Effect of Strontium and Cobalt Co-doping on the Structural and Electrical Properties of PrAlO_3 Perovskite Oxides","authors":"Xu Jiahuan, X. Jun, Ye Qin, Guo Yin-tao","doi":"10.3969/J.ISSN.1001-4861.2013.00.155","DOIUrl":"https://doi.org/10.3969/J.ISSN.1001-4861.2013.00.155","url":null,"abstract":"Novel Sr-and Co-codoped(Pr,Sr)(Al,Co)O3-δ perovskite oxide conducting ceramics were prepared by citrate process combined with subsequent high-temperature sintering.The phase composition,microstructure and electrical properties of the obtained ceramics were characterized by XRD,SEM and direct current four-wire method.The experimental results show that all the as-prepared Pr0.9Sr0.1Al1-yCoyO3-δ(y=0.1~0.5) ceramics are a single-phase rhombohedral perovskite structure,and their unit cell volumes,relative densities and electrical conductivities increase with increasing y in the doping range,while the increasing rate in electrical conductivity progressively decrease.Furthermore,these samples are a mixed conductor of oxygen ion and hole in air and their electrical conductivities are absolutely dominated by p-type conduction.The temperature dependence of electrical conductivity for Pr0.9Sr0.1Al1-yCoyO3-δ can be described by the small polaron hopping mechanism.For the as-prepared Pr1-xSrxAl0.5Co0.5O3-δ(x=0.1~0.4) ceramics,a second phase(Pr,Sr)CoO3obviously precipitates when x=0.2,indicating that the solid solubility limit of Sr on A site in this system is between 10at% and 20at%,and the(Pr,Sr)CoO3phase in samples increases gradually and finally becomes the main phase with further increase in Sr content.It is found that the electrical conductivity of Pr1-xSrxAl0.5Co0.5O3-δ ceramics roughly exhibits a trend of first increase and then decrease with increasing x in the whole examined temperature range,and reaches the maximum value at around x= 0.3.Additionally,the semiconductor-to-metal transition in the conduction behavior is obviously observed for the samples with x≥0.2,and the transition temperature gradually decreases with increasing Sr content.","PeriodicalId":9986,"journal":{"name":"无机化学学报","volume":"45 4 1","pages":""},"PeriodicalIF":0.7,"publicationDate":"2013-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90481170","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of TNP Electrochemical Sensor Based on Silver Nanoparticles/Graphene Oxide Nanocomposite 纳米银/氧化石墨烯复合材料制备TNP电化学传感器
IF 0.7 4区 化学
无机化学学报 Pub Date : 2013-01-01 DOI: 10.3969/J.ISSN.1001-4861.2013.00.220
Liao Hua, Kuang Zhi, F. Lan, L. M. Qin, Tang Ping, Deng Hong
{"title":"Preparation of TNP Electrochemical Sensor Based on Silver Nanoparticles/Graphene Oxide Nanocomposite","authors":"Liao Hua, Kuang Zhi, F. Lan, L. M. Qin, Tang Ping, Deng Hong","doi":"10.3969/J.ISSN.1001-4861.2013.00.220","DOIUrl":"https://doi.org/10.3969/J.ISSN.1001-4861.2013.00.220","url":null,"abstract":"","PeriodicalId":9986,"journal":{"name":"无机化学学报","volume":"9 1","pages":""},"PeriodicalIF":0.7,"publicationDate":"2013-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84280403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Preparation and the Third-Order Optical Nonlinearities of the Sodium Borosilicate Glass Doped with In2S3 Quantum Dots 掺杂In2S3量子点的硼硅酸钠玻璃的制备及其三阶光学非线性
IF 0.7 4区 化学
无机化学学报 Pub Date : 2012-08-10 DOI: 10.3969/J.ISSN.0251-0790.2012.08.006
Zhao Haijun, Lt, strong gt, Xiang Wei-Dong lt, Zhong Jiasong, Yang Xinyu, Guo Yu-Qing, Liang Xiaojuan, Huang Haiyu, Luo Hong-Yan, Zhao Xiu-Li, Chen Zhaoping
{"title":"Preparation and the Third-Order Optical Nonlinearities of the Sodium Borosilicate Glass Doped with In2S3 Quantum Dots","authors":"Zhao Haijun, Lt, strong gt, Xiang Wei-Dong lt, Zhong Jiasong, Yang Xinyu, Guo Yu-Qing, Liang Xiaojuan, Huang Haiyu, Luo Hong-Yan, Zhao Xiu-Li, Chen Zhaoping","doi":"10.3969/J.ISSN.0251-0790.2012.08.006","DOIUrl":"https://doi.org/10.3969/J.ISSN.0251-0790.2012.08.006","url":null,"abstract":"利用溶胶-凝胶法结合气氛控制合成了含Cu 7.2 S 4 量子点的玻璃. 通过热重-差热分析仪对干凝胶样品的热分解机制进行了分析, 并利用X射线粉末衍射仪、 X射线光电子能谱、 透射电子显微镜、 X射线能量色散谱)、 高分辨透射电子显微镜及选区电子衍射对 Cu 7.2 S 4 量子点在玻璃中的微结构进行了表征, 利用飞秒 Z 扫描技术研究了材料在800 nm的三阶非线性光学性质. 结果表明, 尺寸在9~21 nm之间的Cu 7.2 S 4 纳米晶已经在玻璃中形成, 该玻璃展示出了优异的三阶非线性光学性能, 其三阶非线性光学折射率( γ )、 三阶非线性吸收系数( β )和三阶非线性极化率[ X (3) ]分别为1.11×10 -15 m 2 /W, 8.91×10 -9 m/W和9.56×10 -18 m 2 /V 2 .","PeriodicalId":9986,"journal":{"name":"无机化学学报","volume":"190 1","pages":"2148-2154"},"PeriodicalIF":0.7,"publicationDate":"2012-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80030205","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and characterization of tungsten oxide nanostructures 氧化钨纳米结构的合成与表征
IF 0.7 4区 化学
无机化学学报 Pub Date : 2008-01-01 DOI: 10.5353/th_b4150877
Rong Hu, 胡蓉
{"title":"Synthesis and characterization of tungsten oxide nanostructures","authors":"Rong Hu, 胡蓉","doi":"10.5353/th_b4150877","DOIUrl":"https://doi.org/10.5353/th_b4150877","url":null,"abstract":"One-and two-dimensional tungsten oxide nanostructures were synthesized by solvothermal method using tungsten hexachloride(WCl6) as the precursor.The effects of the solvent and the concentration of WCl6 on the phase and the morphology of the as-synthesized tungsten oxide nanostructures were investigated and the NO2-sensing properties were evaluated.X-ray diffraction,field emission scanning electron microscope,transmission electron microscope,X-ray photoelectron spectroscopy were employed to characterize the as-synthesized products and the results indicate that the W18O49 nanorod,W18O49 nanowire and WO3 nanosheet with monoclinic structure can be formed by adjusting the solvent and WCl6 concentration.The NO2-sensing properties measurements show that the synthesized tungsten oxides have reversible response to NO2 at different concentrations.In comparison with WO3 nanosheet or W18O49 nanorod,the W18O49 nanowire exhibits much higher response to NO2 gas.","PeriodicalId":9986,"journal":{"name":"无机化学学报","volume":"15 1","pages":""},"PeriodicalIF":0.7,"publicationDate":"2008-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85492207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tuning Supramolecular Chiral Architecture of Molecular Corners from Achiral Dipalladium(II) and Diplatinum(II) Complexes with Achiral Anthracyl Pyrazole Ligand 非手性双钯(II)和双铂(II)配合物与非手性蒽酰吡唑配体分子角的超分子手性结构调整
IF 0.7 4区 化学
无机化学学报 Pub Date : 1900-01-01 DOI: 10.11862/CJIC.2015.185
Huang Jia-hua, Deng‐Ke Wei, Jiang Xuan-Feng, Yu Shu-yan
{"title":"Tuning Supramolecular Chiral Architecture of Molecular Corners from Achiral Dipalladium(II) and Diplatinum(II) Complexes with Achiral Anthracyl Pyrazole Ligand","authors":"Huang Jia-hua, Deng‐Ke Wei, Jiang Xuan-Feng, Yu Shu-yan","doi":"10.11862/CJIC.2015.185","DOIUrl":"https://doi.org/10.11862/CJIC.2015.185","url":null,"abstract":"","PeriodicalId":9986,"journal":{"name":"无机化学学报","volume":"41 1","pages":""},"PeriodicalIF":0.7,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73066115","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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