Central European Journal of Chemistry最新文献

Crystallographic and structural characterization of heterometallic platinum complexes Part V. Heteropentanuclear complexes 异金属铂配合物的晶体学和结构表征。第五部分:异戊核配合物

Central European Journal of Chemistry Pub Date : 2015-06-01 DOI: 10.2478/s11532-013-0382-5

M. Melnik, P. Mikuš, C. Holloway

引用次数: 3

Preparation of selectively protected protoescigenin derivatives for synthesis of escin analogs and neoglycoconjugates 选择性保护原叶香素衍生物的制备，用于合成叶香素类似物和新糖缀合物

Central European Journal of Chemistry Pub Date : 2014-12-01 DOI: 10.2478/s11532-014-0572-9

K. Jatczak, Mariusz M. Gruza, Katarzyna Filip, P. Cmoch, G. Grynkiewicz

引用次数: 2

Erratum to: “Occurrence of 2-phenylphenol in food paper packages” “食品纸包装中2-苯酚的含量”的勘误表

Central European Journal of Chemistry Pub Date : 2014-12-01 DOI: 10.2478/s11532-014-0579-2

L. Votavová, K. Hanušová, Lukáš Vápenka, J. Dobiáš, F. Kvasnička

引用次数: 0

Investigations of ternary complexes of Co(II) and Ni(II) with oxydiacetate anion and 1,10-phenanthroline or 2,2′-bipyridine in solutions Co(II)和Ni(II)与氧化二乙酸阴离子和1,10-菲罗啉或2,2 ' -联吡啶三元配合物的研究

Central European Journal of Chemistry Pub Date : 2014-11-26 DOI: 10.2478/s11532-013-0353-x

D. Wyrzykowski, J. Pranczk, D. Jacewicz, A. Tesmar, B. Pilarski, L. Chmurzyński

{"title":"Investigations of ternary complexes of Co(II) and Ni(II) with oxydiacetate anion and 1,10-phenanthroline or 2,2′-bipyridine in solutions","authors":"D. Wyrzykowski, J. Pranczk, D. Jacewicz, A. Tesmar, B. Pilarski, L. Chmurzyński","doi":"10.2478/s11532-013-0353-x","DOIUrl":"https://doi.org/10.2478/s11532-013-0353-x","url":null,"abstract":"AbstractPotentiometric (PT) and conductometric (CT) titration methods have been used to determine the stoichiometry and formation constants in water for a series of ternary complexes of Co(II) and Ni(II) involving the oxydiacetate anion (ODA) and 1,10-phenanthroline (phen) or 2,2′-bipyridine (bipy) ligands, namely [Co(ODA)(phen)(H2O)], [Co(ODA)(bpy)(H2O)], [Ni(ODA)(phen)(H2O)] and [Ni(ODA)(bpy)(H2O)]. The ternary complex formation process was found to take place in a stepwise manner in which the oxydiacetate ligand acts as a primary ligand and the phen or bipy ligands act as auxiliary ones. The stability of the ternary complexes formed is discussed in the relation to the corresponding binary ones. Furthermore, the kinetics of the substitution reactions of the aqua ligands in the coordination sphere of the Ni-ODA and Co-ODA complexes to phen or bipy were studied by the stopped-flow method. The kinetic measurements were performed in the 288–303 K temperature range, at a constant concentration of phen or bipy and at seven different concentrations of the binary complexes (4–7 mM). The influence of experimental conditions and the kind of the auxiliary ligands (phen/bipy) on the substitution rate was discussed.\u0000","PeriodicalId":9888,"journal":{"name":"Central European Journal of Chemistry","volume":"3 1","pages":"107-114"},"PeriodicalIF":0.0,"publicationDate":"2014-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80374641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 14

Systematic investigation and in vitro biocompatibility studies on mesoporous europium doped hydroxyapatite 介孔铕掺杂羟基磷灰石的系统研究及体外生物相容性研究

Central European Journal of Chemistry Pub Date : 2014-10-01 DOI: 10.2478/s11532-014-0554-y

C. Popa, C. Ciobanu, S. Iconaru, M. Stan, A. Dinischiotu, C. Negrila, M. Motelica‐Heino, R. Guégan, D. Predoi

{"title":"Systematic investigation and in vitro biocompatibility studies on mesoporous europium doped hydroxyapatite","authors":"C. Popa, C. Ciobanu, S. Iconaru, M. Stan, A. Dinischiotu, C. Negrila, M. Motelica‐Heino, R. Guégan, D. Predoi","doi":"10.2478/s11532-014-0554-y","DOIUrl":"https://doi.org/10.2478/s11532-014-0554-y","url":null,"abstract":"AbstractThis paper reports the systematic investigation of europium doped hydroxyapatite (Eu:HAp). A set of complementary techniques, namely Fourier Transform Infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM) and the Brunauer-Emmett-Teller (BET) technique were used towards attaining a detailed understanding of Eu:HAp. The XPS analysis confirmed the substitution of Ca ions by Eu ions in the Eu:HAp samples. Secondly, Eu:HAp and pure HAp present type IV isotherms with a hysteresis loop at a relative pressure (P/P0) between 0.4 and 1.0, indicating the presence of mesopores. Finally, the in vitro biological effects of Eu:HAp nanoparticles were evaluated by focusing on the F-actin filament pattern and heat shock proteins (Hsp) expression in HEK293 human kidney cell line. Fluorescence microscopy studies of the actin protein revealed no changes of the immunolabelling profile in the renal cells cultured in the presence of Eu:HAp nanoparticles. Hsp60, Hsp70 and Hsp90 expressions measured by Western blot analysis were not affected after 24 and 48 hours exposure. Taken together, these results confirmed the lack of toxicity and the biocompatibility of the Eu:HAp nanoparticles. Consequently, the possibility of using these nanoparticles for medical purposes without affecting the renal function can be envisaged.\u0000","PeriodicalId":9888,"journal":{"name":"Central European Journal of Chemistry","volume":"18 1","pages":"1032-1046"},"PeriodicalIF":0.0,"publicationDate":"2014-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89729983","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 24

L-alaninium perrhenate: crystal structure and non-linear optical properties l -过铼酸铝:晶体结构和非线性光学性质

Central European Journal of Chemistry Pub Date : 2014-10-01 DOI: 10.2478/s11532-014-0548-9

V. Rodrigues, M. M. Costa, E. Gomes, D. Isakov, M. Belsley

引用次数: 2

Synthesis, characterization and controlled toxicity of a novel hybrid material based on cisplatin and docetaxel 新型顺铂-多西他赛杂化材料的合成、表征及毒性控制

Central European Journal of Chemistry Pub Date : 2014-10-01 DOI: 10.2478/s11532-014-0536-0

M. Prodana, A. Voiculet, S. Gârea, M. Radu, H. Iovu, I. Demetrescu, A. Dinischiotu

引用次数: 6

Controlled release of amoxicillin from bacterial cellulose membranes 细菌纤维素膜中阿莫西林的控制释放

Central European Journal of Chemistry Pub Date : 2014-09-01 DOI: 10.2478/s11532-014-0541-3

Ramona-Daniela Păvăloiu, A. Stoica, M. Stroescu, T. Dobre

引用次数: 23

High-pressure phase equilibrium calculations for carbon dioxide + cyclopentane binary system 二氧化碳+环戊烷二元体系的高压相平衡计算

Central European Journal of Chemistry Pub Date : 2014-09-01 DOI: 10.2478/s11532-013-0393-2

Sergiu Sima, Julia Cruz-Doblas, M. Cismondi, Catinca Secuianu

引用次数: 3

A multi-property fluorescent probe for the investigation of polymer dynamics near the glass transition 用于研究玻璃化转变附近聚合物动力学的多性能荧光探针

Central European Journal of Chemistry Pub Date : 2014-09-01 DOI: 10.2478/s11532-014-0544-0

J. Siekierzycka, Catharina Hippius, F. Würthner, René M. Williams, A. Brouwer

引用次数: 3