{"title":"Preparation of Graphene-based Cu-MOF Derivative Catalysts and Their Catalytic Performance for Cyclotrimethylenetrinitramine Thermal Decomposition","authors":"Jiao Zhang, Taixin Liang","doi":"10.22211/cejem/198409","DOIUrl":"https://doi.org/10.22211/cejem/198409","url":null,"abstract":"In order to improve the thermal decomposition performance of cyclotrimethylenetrinitramine (RDX), graphene-based Cu-MOF derivative catalysts were prepared by solvothermal and heat treatment.Transition metal ions were ligated to the surface of graphene oxide (GO) by organic ligands, and then heat-treated to obtain two-dimensional reduction-oxidation graphene-based metal cluster catalysts.The morphology and structure of these catalysts at different temperatures and their effects on the thermal decomposition of RDX were studied.The results showed that the prepared GO/Cu-MOF has a small particle size and good dispersibility.At 300 , the catalyst exhibited a porous structure.Thermal analysis showed that the decomposition temperature of RDX was reduced by the addition of a small amount of this catalyst, which may be due to the good conductivity of graphene oxide and the strong gain and loss electron ability of the metal clusters.The presence of graphene oxide increases the catalytic activity of metal clusters, and the metal clusters and graphene oxide have a positive synergistic effect, thus improving the thermal decomposition performance of RDX.","PeriodicalId":9679,"journal":{"name":"Central European Journal of Energetic Materials","volume":"21 4","pages":"429-449"},"PeriodicalIF":0.0,"publicationDate":"2024-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://doi.org/10.22211/cejem/198409","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147911074","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Oxidant-Accelerated Polymerization of Dopamine for Coating DNAN with Enhanced Toughness","authors":"Jinshan Li, Chun Xiao, Guoqiang Liu, Shuyi Duan, Baohui Zheng, Qing Zhu","doi":"10.22211/cejem/190547","DOIUrl":"https://doi.org/10.22211/cejem/190547","url":null,"abstract":"Due to the significantly reduced toxicity and shock sensitivity compared to TNT, DNAN is getting more and more attention in the study of insensitive munitions.However, the brittleness problem of DNAN limits its wide application.Inspired by mussels, DNAN particles with a thin and uniform coating based on the self-polymerization of dopamine were prepared by an oxidant-accelerated method in this work.XRD patterns indicated that the DNAN polymorph did not change during the coating process.FT-IR and XPS spectra manifested that the PDA was successfully distributed on the crystal surface.The results of TG-DSC analysis demonstrated that the mass ratio of PDA coating was as low as 1.71%.Meanwhile, Brazilian disk splitting test showed that the tensile strength, tensile strain, and fracture energy of DNAN@PDA cylinder were 16.1%, 32.0% and 53.0% higher than those of pure DNAN cylinder, respectively.The morphology of fracture surface after tensile test indicated that toughness fracture occurred in DNAN@PDA cylinder, while remarkable brittle fracture occurred in pure DNAN cylinder.The surface modification method could enhance the toughness of DNANbased explosives, and the fast fabrication of DNAN@PDA particles on a large scale could satisfy the application demands of insensitive munitions.","PeriodicalId":9679,"journal":{"name":"Central European Journal of Energetic Materials","volume":"21 2","pages":"210-229"},"PeriodicalIF":0.0,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"http://dx.doi.org/10.22211/cejem/190547","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147902700","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Bo Li, Yanzhong Wei, Changfan Xin, Zhifang Wei, Yukun Shi
{"title":"Experimental Study on the Diverse Output Performance of a Firearm Firing-Ignition System","authors":"Bo Li, Yanzhong Wei, Changfan Xin, Zhifang Wei, Yukun Shi","doi":"10.22211/cejem/176915","DOIUrl":"https://doi.org/10.22211/cejem/176915","url":null,"abstract":"","PeriodicalId":9679,"journal":{"name":"Central European Journal of Energetic Materials","volume":"31 12","pages":""},"PeriodicalIF":0.8,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138952778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. Boiko, V. Kravets, O. Han, Anatolii Han, R. Zakusylo
{"title":"Efficiency of Using Explosive Foam Compositions for Compacting Structurally Unstable Soil","authors":"V. Boiko, V. Kravets, O. Han, Anatolii Han, R. Zakusylo","doi":"10.22211/cejem/176913","DOIUrl":"https://doi.org/10.22211/cejem/176913","url":null,"abstract":"","PeriodicalId":9679,"journal":{"name":"Central European Journal of Energetic Materials","volume":"28 6","pages":""},"PeriodicalIF":0.8,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138951781","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Radosław Warchoł, Paweł Żochowski, Jan Bagrowski, Maciej Gędziorowski, Tomasz Sałaciński
{"title":"Influence of a non-Explosive Filling Included in the Conical Liner Cavity of a Shaped Charge on its Penetrative Capability","authors":"Radosław Warchoł, Paweł Żochowski, Jan Bagrowski, Maciej Gędziorowski, Tomasz Sałaciński","doi":"10.22211/cejem/176911","DOIUrl":"https://doi.org/10.22211/cejem/176911","url":null,"abstract":"","PeriodicalId":9679,"journal":{"name":"Central European Journal of Energetic Materials","volume":"83 9","pages":""},"PeriodicalIF":0.8,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138952730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wei Ji, Yuxuan Xu, Lei LIU, Changping Guo, Xianfeng WEI, Dunju WANG
{"title":"The Influence of Three Binders on the Properties of BTF-Based Composite Explosive","authors":"Wei Ji, Yuxuan Xu, Lei LIU, Changping Guo, Xianfeng WEI, Dunju WANG","doi":"10.22211/cejem/176594","DOIUrl":"https://doi.org/10.22211/cejem/176594","url":null,"abstract":"","PeriodicalId":9679,"journal":{"name":"Central European Journal of Energetic Materials","volume":"71 5","pages":""},"PeriodicalIF":0.8,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138953031","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yuri Voitenko, Yuri Sydorenko, R. Zakusylo, Sergii Goshovskii, Stefan Zaychenko, Viktor Boyko
{"title":"On the Influence of the Liner Shape and Charge Detonation Scheme on the Kinetic Characteristics of Shaped Charge Jets and Explosively Formed Penetrators","authors":"Yuri Voitenko, Yuri Sydorenko, R. Zakusylo, Sergii Goshovskii, Stefan Zaychenko, Viktor Boyko","doi":"10.22211/cejem/173190","DOIUrl":"https://doi.org/10.22211/cejem/173190","url":null,"abstract":"","PeriodicalId":9679,"journal":{"name":"Central European Journal of Energetic Materials","volume":"39 7","pages":""},"PeriodicalIF":0.8,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138949793","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Computational Determination of the Specific Impulse of Solid Rocket Propellant Compositions of closo-Dodecaborate ([B12H12]2‒) Salts with HTPB Binder and Ammonium Perchlorate as an Oxidizer","authors":"Muddamarri Hanumantha Rao","doi":"10.22211/cejem/176917","DOIUrl":"https://doi.org/10.22211/cejem/176917","url":null,"abstract":"","PeriodicalId":9679,"journal":{"name":"Central European Journal of Energetic Materials","volume":"53 16","pages":""},"PeriodicalIF":0.8,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138948697","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mohsin Shaikh, Kanav Kumar, Rajan Kannan, Azmat Doctor, Amulya Singh, Sultan A Pradhan
{"title":"The Submental Flap for Reconstruction of Tongue Defects- Surgical Outcome and Quality of Life Assessment.","authors":"Mohsin Shaikh, Kanav Kumar, Rajan Kannan, Azmat Doctor, Amulya Singh, Sultan A Pradhan","doi":"10.1007/s12070-023-03858-3","DOIUrl":"10.1007/s12070-023-03858-3","url":null,"abstract":"<p><p>Tongue defects following resection of cancers, have a major effect on speech and swallowing, impairing the quality of life. Free flaps such as the free radial artery forearm flap and anterolateral thigh flap have been ideal for the reconstruction of such defects depending upon the volume of tissue loss. Local flaps such as the submental flap and pectoralis major myocutaneous flap serve as an alternative in decreasing morbidity and improving functional outcomes. Surgical outcomes associated with submental flaps used in the reconstruction of tongue defects were evaluated in our study. This is a retrospective analysis of 545 patients, where the submental flap was used for the repair of tongue defects for cancer resections. Oncological safety was studied in 375 patients with a median follow-up of 48 months. 140 patients were studied for their functional outcomes using the parameters, adapted from the University of Washington- Quality of Life questionnaire. Complete flap loss was seen in 15(2.75%) patients while 22(4.03%) patients had partial loss of flap. Locoregional Recurrences, second primary, and distant metastases were noted in 91 of the 375 patients studied. The mean score for swallowing, speech, and taste were 72,71, and 69 respectively. The submental flap is an effective and reliable alternative for the reconstruction of tongue defects.</p><p><strong>Supplementary information: </strong>The online version contains supplementary material available at 10.1007/s12070-023-03858-3.</p>","PeriodicalId":9679,"journal":{"name":"Central European Journal of Energetic Materials","volume":"13 1","pages":"2895-2900"},"PeriodicalIF":0.7,"publicationDate":"2023-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10645927/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90137926","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jie Zhou, Shuai Wang, Zide Liu, Haiyan Zhang, Aiguo Pi
{"title":"The Flow and Heat Transfer Behavior of Liquid COMP-B3 in Slow Cook-off","authors":"Jie Zhou, Shuai Wang, Zide Liu, Haiyan Zhang, Aiguo Pi","doi":"10.22211/cejem/173058","DOIUrl":"https://doi.org/10.22211/cejem/173058","url":null,"abstract":"","PeriodicalId":9679,"journal":{"name":"Central European Journal of Energetic Materials","volume":"132 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135294097","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}