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Study on the Tunable LCST Properties of Phenylalaninate Derivative with Branching Oligoethyleneoxy Chains 支链低聚乙烯氧基苯丙酸衍生物的可调lst性质研究
American Chemical Science Journal Pub Date : 2016-01-10 DOI: 10.9734/ACSJ/2016/28842
Pan Yu, Kundan Hao, Zhou-Ru Yang, Liangchun Li
{"title":"Study on the Tunable LCST Properties of Phenylalaninate Derivative with Branching Oligoethyleneoxy Chains","authors":"Pan Yu, Kundan Hao, Zhou-Ru Yang, Liangchun Li","doi":"10.9734/ACSJ/2016/28842","DOIUrl":"https://doi.org/10.9734/ACSJ/2016/28842","url":null,"abstract":"","PeriodicalId":7399,"journal":{"name":"American Chemical Science Journal","volume":"43 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2016-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80914901","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and Characterization of Oil-Modified Alkyd Resin from Epoxidized Neem Oil 环氧印楝油改性醇酸树脂的合成与表征
American Chemical Science Journal Pub Date : 2016-01-10 DOI: 10.9734/ACSJ/2016/26431
A. Anya, I. Jack, O. Osagie
{"title":"Synthesis and Characterization of Oil-Modified Alkyd Resin from Epoxidized Neem Oil","authors":"A. Anya, I. Jack, O. Osagie","doi":"10.9734/ACSJ/2016/26431","DOIUrl":"https://doi.org/10.9734/ACSJ/2016/26431","url":null,"abstract":"","PeriodicalId":7399,"journal":{"name":"American Chemical Science Journal","volume":"29 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2016-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76088395","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Structure-toxicity Relationships of Naphthylisoquinoline Derivatives as Antimalarial Agents Using Molecular Descriptors 基于分子描述符的萘基异喹啉类抗疟药结构-毒性关系研究
American Chemical Science Journal Pub Date : 2016-01-10 DOI: 10.9734/acsj/2016/22639
Z. Ibrahim, A. Uzairu, S. Abechi
{"title":"Structure-toxicity Relationships of Naphthylisoquinoline Derivatives as Antimalarial Agents Using Molecular Descriptors","authors":"Z. Ibrahim, A. Uzairu, S. Abechi","doi":"10.9734/acsj/2016/22639","DOIUrl":"https://doi.org/10.9734/acsj/2016/22639","url":null,"abstract":"","PeriodicalId":7399,"journal":{"name":"American Chemical Science Journal","volume":"72 1","pages":"1-16"},"PeriodicalIF":0.0,"publicationDate":"2016-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79678325","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Transition Metal Complexes of 4-aminobenzenesulfonamide 1,3-benzodioxole-5-carbaldehyde: Synthesis, Characterization and Biological Activities 4-氨基苯磺酰胺1,3-苯二酚-5-乙醛过渡金属配合物的合成、表征及生物活性
American Chemical Science Journal Pub Date : 2016-01-10 DOI: 10.9734/acsj/2016/22807
J. Anandakumaran, M. Sundararajan, T. Jeyakumar, M. Uddin
{"title":"Transition Metal Complexes of 4-aminobenzenesulfonamide 1,3-benzodioxole-5-carbaldehyde: Synthesis, Characterization and Biological Activities","authors":"J. Anandakumaran, M. Sundararajan, T. Jeyakumar, M. Uddin","doi":"10.9734/acsj/2016/22807","DOIUrl":"https://doi.org/10.9734/acsj/2016/22807","url":null,"abstract":"","PeriodicalId":7399,"journal":{"name":"American Chemical Science Journal","volume":"4 1","pages":"1-14"},"PeriodicalIF":0.0,"publicationDate":"2016-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76609539","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
The Effects of Boric Acid on Fiberboard Made from Wood/Secondary Fiber Mixtures: Part 3. Utilization of Recycled Waste Office Paper Fibers 硼酸对木材/二次纤维混合物纤维板的影响:第3部分。废纸纤维的再生利用
American Chemical Science Journal Pub Date : 2016-01-10 DOI: 10.9734/ACSJ/2016/27758
A. Kaya, H. Şahin
{"title":"The Effects of Boric Acid on Fiberboard Made from Wood/Secondary Fiber Mixtures: Part 3. Utilization of Recycled Waste Office Paper Fibers","authors":"A. Kaya, H. Şahin","doi":"10.9734/ACSJ/2016/27758","DOIUrl":"https://doi.org/10.9734/ACSJ/2016/27758","url":null,"abstract":"","PeriodicalId":7399,"journal":{"name":"American Chemical Science Journal","volume":"1 1","pages":"1-8"},"PeriodicalIF":0.0,"publicationDate":"2016-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77547978","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Chemical Constituents and Antimicrobial Activity of the Leaf Essential Oil of Garcinia kola Heckel (Clusiaceae) from Nigeria 尼日利亚藤黄叶精油的化学成分及抑菌活性研究
American Chemical Science Journal Pub Date : 2016-01-10 DOI: 10.9734/ACSJ/2016/24019
Samuel Ehiabhi Okhale, Chukkol Buba, P. Oladosu, H. Egharevba, Grace E. Ugbabe, J. Ibrahim, O. Kunle
{"title":"Chemical Constituents and Antimicrobial Activity of the Leaf Essential Oil of Garcinia kola Heckel (Clusiaceae) from Nigeria","authors":"Samuel Ehiabhi Okhale, Chukkol Buba, P. Oladosu, H. Egharevba, Grace E. Ugbabe, J. Ibrahim, O. Kunle","doi":"10.9734/ACSJ/2016/24019","DOIUrl":"https://doi.org/10.9734/ACSJ/2016/24019","url":null,"abstract":"All parts of Garcinia kola are used in traditional medicine for various ailments including inflammation and infections. The leaf essential oil (EO) of Garcinia kola was isolated by hydrodistillation using Clavenger type apparatus and subjected to GC-MS analyses. A total of twenty-seven compounds were identified representing 88.27% of the oil. The main components of Original Research Article Okhale et al.; ACSJ, 13(4): 1-7, 2016; Article no.ACSJ.24019 2 the essential oil were citronellic acid (48.3%), 5,9-undecadien-2-one (5.12%), α-ionone (4.38%), 3buten-2-one (3.25%), 2-pentadecanone (2.59%), squalene (2.27%), nonacosane (2.18%), octanal (1.9%), geraniol (1.52%), mesitylene (1.17%) and α-farnesene (1.02%). The oil contained many compounds that were active against Staphylococcus aureus, Pseudomonas aeruginosa, Klebsiella pneumonia, Escherichia coli, Candida albicans and Mycobacterium bovis with minimum inhibitory concentrations ranging from >400 to 50 μg/ml and could be exploited for the development of plantbased drugs.","PeriodicalId":7399,"journal":{"name":"American Chemical Science Journal","volume":"26 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2016-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79051132","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Brazilian Kaolin Wastes: Synthesis of Zeolite P at Low-Temperature 巴西高岭土废料:低温合成P型沸石
American Chemical Science Journal Pub Date : 2016-01-10 DOI: 10.9734/acsj/2016/22771
M. Rodrigues, A. G. Souza, I. M. Santos
{"title":"Brazilian Kaolin Wastes: Synthesis of Zeolite P at Low-Temperature","authors":"M. Rodrigues, A. G. Souza, I. M. Santos","doi":"10.9734/acsj/2016/22771","DOIUrl":"https://doi.org/10.9734/acsj/2016/22771","url":null,"abstract":"","PeriodicalId":7399,"journal":{"name":"American Chemical Science Journal","volume":"17 1","pages":"1-11"},"PeriodicalIF":0.0,"publicationDate":"2016-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76975142","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Corrosion Inhibition of Mild Steel in 1M H2SO4 Solution by Microdesmis puberula Leaf Extract 微柔草叶提取物对低碳钢在1M H2SO4溶液中的缓蚀作用
American Chemical Science Journal Pub Date : 2016-01-10 DOI: 10.9734/ACSJ/2016/28419
O. Abakedi, J. Asuquo
{"title":"Corrosion Inhibition of Mild Steel in 1M H2SO4 Solution by Microdesmis puberula Leaf Extract","authors":"O. Abakedi, J. Asuquo","doi":"10.9734/ACSJ/2016/28419","DOIUrl":"https://doi.org/10.9734/ACSJ/2016/28419","url":null,"abstract":"","PeriodicalId":7399,"journal":{"name":"American Chemical Science Journal","volume":"16 2","pages":"1-8"},"PeriodicalIF":0.0,"publicationDate":"2016-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72594324","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Spectroscopic Elucidation of the Biodeterioration Potentials of Aspergillus niger on Lagenaria siceraria Seed Oil 黑曲霉对木参籽油生物腐坏潜力的光谱分析
American Chemical Science Journal Pub Date : 2016-01-10 DOI: 10.9734/acsj/2016/25510
P. Dass, D. Kubmarawa, A. Akinterinwa, Buba Mohammed
{"title":"Spectroscopic Elucidation of the Biodeterioration Potentials of Aspergillus niger on Lagenaria siceraria Seed Oil","authors":"P. Dass, D. Kubmarawa, A. Akinterinwa, Buba Mohammed","doi":"10.9734/acsj/2016/25510","DOIUrl":"https://doi.org/10.9734/acsj/2016/25510","url":null,"abstract":"Vegetable oil was extracted from Lagenaria siceraria seeds and some physico-chemical analysis determined. The refractive index of 1.47, saponification value of 465.9 mgKOH/g, iodine value of 15.86 I2 /100 g, Acid value mgKOH/g of 2.52 and density of 0.93 were obtained. GC-MS of both the un-inoculated and inoculated oil was measured before and after four weeks of incubation with Aspergillus niger. The disappearance and or appearance of some absorption peaks which correspond to hydroxyl, carbonyl, methyl, and carboxylic acid functional groups were identified. MS provided the mass fragments of the possible components formed during the degradation of the oil to include 12-methyl-methyl ester, tetradecanoic acid, hexadecanoic acid, heptadecanoic acid, oleic acid, 2, 6, 10-Dodecatrien-1-ol, 3, 7, 11-trimethyl (E.E) and pentadecanoic acid as biodegradation Original Research Article Dass et al.; ACSJ, 15(1): 1-11, 2016; Article no.ACSJ.25510 2 by-products. Despite, low acid value obtained which may have suggested stability of the oil to oxidation, its high iodine value indicated a rather high level of unsaturation i.e. presence of double bonds. The position of double bonds was viewed as possible sites for the initial attack by the microorganisms. These absorption bands disappeared after inoculation and incubation with Aspergillus niger after four weeks with prominent peaks noticed to be of fatty acids as a result of the action of Aspergillus niger on the Lagenaria siceraria oil. The fragmentation of the triglycerides suggested that the unsaturation is not on an even number of carbon atom along the chain length resulting in the propyl – like breakage with molecular weight of 42 (C3H7) whereas, fragmentation on even carbon atom resulting in ethyl-like breakage with molecular weight of 28 (C2H2). The GC-MS showed that acidic metabolites were mostly produced. This is similar to the hydrolysis of vegetable oil by other agents where sterol and fatty acids are usually produced in the ratio 1:3. Therefore, it is recommended that the storage of these oils in the presence of common mold such as Aspergillus niger at temperature above 37°C would lead to its deterioration. However, Lagenaria siceraria seed oil can be used as lubricants, for cooking and paint production.","PeriodicalId":7399,"journal":{"name":"American Chemical Science Journal","volume":"18 1","pages":"1-11"},"PeriodicalIF":0.0,"publicationDate":"2016-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72652852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Relationship between the Antimicrobial Properties of Benzylpenicillin and the Quantum Chemical Parameters of Its Structure (The DFT Method) 青霉素抗菌性能与其结构量子化学参数的关系(DFT法)
American Chemical Science Journal Pub Date : 2016-01-10 DOI: 10.9734/acsj/2016/22022
V. Babkin, D. Andreev, А. Pristanskov, L. Lisina, А. Rakhimov, N. Rakhimova, V. Belousova, G. Zaikov
{"title":"The Relationship between the Antimicrobial Properties of Benzylpenicillin and the Quantum Chemical Parameters of Its Structure (The DFT Method)","authors":"V. Babkin, D. Andreev, А. Pristanskov, L. Lisina, А. Rakhimov, N. Rakhimova, V. Belousova, G. Zaikov","doi":"10.9734/acsj/2016/22022","DOIUrl":"https://doi.org/10.9734/acsj/2016/22022","url":null,"abstract":"","PeriodicalId":7399,"journal":{"name":"American Chemical Science Journal","volume":"1 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2016-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72709183","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
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