Acta Crystallographica Section C Structural Chemistry最新文献

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A twofold interpenetrated three-dimensional barium(II) metal-organic framework constructed from 2,2'-[terephthaloylbis(azanediyl)]diacetate: synthesis, structure, dihydrogen bonding and spectroscopic properties. 由2,2'-[对苯二甲酸双(azanediyl)]二乙酸酯构建的双互穿三维钡金属有机骨架:合成、结构、二氢键和光谱性质。
IF 0.7 4区 化学
Acta Crystallographica Section C Structural Chemistry Pub Date : 2025-01-01 DOI: 10.1107/S205322962401235X
Xin Yi Zhao, Hai Yan Yu, Hong Tao Zhang
{"title":"A twofold interpenetrated three-dimensional barium(II) metal-organic framework constructed from 2,2'-[terephthaloylbis(azanediyl)]diacetate: synthesis, structure, dihydrogen bonding and spectroscopic properties.","authors":"Xin Yi Zhao, Hai Yan Yu, Hong Tao Zhang","doi":"10.1107/S205322962401235X","DOIUrl":"https://doi.org/10.1107/S205322962401235X","url":null,"abstract":"<p><p>A new twofold interpenetrated 3D metal-organic framework (MOF), namely, poly[[μ-aqua-diaqua{μ<sub>4</sub>-2,2'-[terephthaloylbis(azanediyl)]diacetato}barium(II)] dihydrate], {[Ba(C<sub>12</sub>H<sub>10</sub>N<sub>2</sub>O<sub>6</sub>)(H<sub>2</sub>O)<sub>3</sub>]·2H<sub>2</sub>O}<sub>n</sub>, (I), has been assembled through a combination of the reaction of 2,2'-[terephthaloylbis(azanediyl)]diacetic acid (TPBA, H<sub>2</sub>L) with barium hydroxide and crystallization at low temperature. In the crystal structure of (I), the nine-coordinated Ba<sup>II</sup> ions are bridged by two μ<sub>2</sub>-aqua ligands and two carboxylate μ<sub>2</sub>-O atoms to form a 1D loop-like Ba-O chain, which, together with the other two coordinated water molecules and μ<sub>2</sub>-carboxylate groups, produces a rod-like secondary building unit (SBU). The resultant 1D polynuclear SBUs are further extended into a 3D MOF via the terephthalamide moiety of the ligand as a spacer. Two intramolecular dihydrogen bonds (DHBs) between the imine H atoms and the arene H atoms contribute to maintaining the 3D structure. In the crystal, two independent MOFs interpenetrate each other, thereby producing a twofold interpenetrated 3D architecture with a 4-connected PtS-X topology. Intermolecular hydrogen bonding and π-π interactions contribute to the stability of the twofold interpenetrated 3D architecture. The noncovalent interactions in the coordination polymer (CP) were further investigated by Hirshfeld surface analysis and the results show that the prominent interactions are H...O (39.6%) and H...H (34.4%), as well as Ba...O (9.8%), contacts. The 3D CP (I) exhibits a fluorescence emission with a quantum yield of 0.134.</p>","PeriodicalId":7115,"journal":{"name":"Acta Crystallographica Section C Structural Chemistry","volume":"81 Pt 1","pages":"43-53"},"PeriodicalIF":0.7,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142926276","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A personal account of the history of X-ray crystallography at the University of La Plata, Argentina. 阿根廷拉普拉塔大学x射线晶体学历史的个人叙述。
IF 0.7 4区 化学
Acta Crystallographica Section C Structural Chemistry Pub Date : 2025-01-01 DOI: 10.1107/S2053229624011495
Oscar Enrique Piro
{"title":"A personal account of the history of X-ray crystallography at the University of La Plata, Argentina.","authors":"Oscar Enrique Piro","doi":"10.1107/S2053229624011495","DOIUrl":"10.1107/S2053229624011495","url":null,"abstract":"<p><p>Prompted by visionary political leaders and a flowering economy, the University of La Plata was founded in 1905, the third Argentinian university after the Universities of Cordoba (1613) and Buenos Aires (1821). Differing from the older universities, more prone to professional formation, the new university was oriented towards teaching and scientific research following western European academic tradition. Along with the university was created the Institute of Physics, the first of its kind in Latin America. To pursue the foundational plan, the university recruited distinguished German physicists, some of whom became the first directors. From the start, the institute became acquainted with Röntgen rays, their generation and use, initially for radiographic images and later in occasional diffraction studies. The first dedicated crystallographic X-ray diffraction laboratory was set up in the early 1970s, when it solved the first molecular structures. Soon the fascination brought about by a methodology that afforded the visualization of atoms, molecules and crystals lured the local and national physical chemistry communities. In close partnership with an equally oriented laboratory at the University of Sao Paulo, Brazil, and in collaboration with several physical chemistry laboratories from Argentina and the Latin American region, and also from Europe, we undertook studies on the crystal structures and physicochemical and spectroscopic properties of a wide range of materials, including inorganic, organic, bioinorganic, metal-organic, organic-metal, supramolecular, pharmaceutical, organic minerals and liquid crystals. The present essay is a personal account of the origin and development of structural X-ray crystallography at the University of La Plata and its impact on the scientific research of Argentina and Latin America.</p>","PeriodicalId":7115,"journal":{"name":"Acta Crystallographica Section C Structural Chemistry","volume":" ","pages":"14-21"},"PeriodicalIF":0.7,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142783563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Diprotonation of taurine: 2-[dihydroxy(oxo)sulfanyliumyl]ethanaminium bis[hexafluoroarsenate(V)]. 牛磺酸的二质子化作用:2-[二羟基(氧代)硫铵基]乙铵双[六氟砷酸盐(V)]。
IF 0.7 4区 化学
Acta Crystallographica Section C Structural Chemistry Pub Date : 2024-12-01 Epub Date: 2024-11-20 DOI: 10.1107/S2053229624010489
Valentin Bockmair, Andreas Klöck, Dirk Hollenwäger, Andreas J Kornath
{"title":"Diprotonation of taurine: 2-[dihydroxy(oxo)sulfanyliumyl]ethanaminium bis[hexafluoroarsenate(V)].","authors":"Valentin Bockmair, Andreas Klöck, Dirk Hollenwäger, Andreas J Kornath","doi":"10.1107/S2053229624010489","DOIUrl":"10.1107/S2053229624010489","url":null,"abstract":"<p><p>Taurine is part of the cysteine cycle and is one of the few naturally occuring organosulfur-based molecules in the human body. As implied by modern studies, protonated taurine is of biological impact. The first attempts to isolate its protonated species in the binary superacidic system HF/SbF<sub>5</sub> were performed by Hopfinger, resulting in the isolation of monoprotonated taurine. Since the chosen conditions seemed rather harsh, investigations in less acidic systems were performed at room temperature to explore the involved protonated species. Herein, we present the structure of 2-[dihydroxy(oxo)sulfanyliumyl]ethanaminium bis[hexafluoridoarsenate(V)], [H<sub>2</sub>O<sub>3</sub>SC<sub>2</sub>H<sub>4</sub>NH<sub>3</sub>][AsF<sub>6</sub>]<sub>2</sub>, the diprotonated form of 2-aminoethanesulfonic acid (taurine). It was synthesized in the binary superacidic system HF/AsF<sub>5</sub> and crystallizes as colourless needles. Diprotonated taurine was structurally characterized by single-crystal X-ray diffraction analysis, low-temperature vibrational spectroscopy and NMR spectroscopy.</p>","PeriodicalId":7115,"journal":{"name":"Acta Crystallographica Section C Structural Chemistry","volume":" ","pages":"781-786"},"PeriodicalIF":0.7,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11619780/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142674811","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Protonated oxalyl chloride and the ClCO+ cation. 质子化草酰氯和 ClCO+ 阳离子。
IF 0.7 4区 化学
Acta Crystallographica Section C Structural Chemistry Pub Date : 2024-12-01 Epub Date: 2024-11-20 DOI: 10.1107/S2053229624010714
Sebastian Steiner, Kristina Djordjevic, Valentin Bockmair, Dirk Hollenwäger, Andreas J Kornath
{"title":"Protonated oxalyl chloride and the ClCO<sup>+</sup> cation.","authors":"Sebastian Steiner, Kristina Djordjevic, Valentin Bockmair, Dirk Hollenwäger, Andreas J Kornath","doi":"10.1107/S2053229624010714","DOIUrl":"10.1107/S2053229624010714","url":null,"abstract":"<p><p>The reactions of oxalyl chloride were investigated in the binary superacidic systems HF/SbF<sub>5</sub> and DF/SbF<sub>5</sub>. O-Monoprotonated oxalyl chloride was isolated and represents the first example of a protonated acyl chloride. Diprotonated oxalyl chloride is only stable in solution. Salts of the ClCO<sup>+</sup> cation were synthesized from the reactions of oxalyl chloride or COClF with SbF<sub>5</sub> in 1,1,1,2-tetrafluoroethane (R-134a, CF<sub>3</sub>CFH<sub>2</sub>). The colourless salts were characterized by low-temperature vibrational spectroscopy, NMR spectroscopy and single-crystal X-ray diffraction. (1,2-Dichloro-2-oxoethylidene)oxidanium hexafluoridoantimonate(V), [C<sub>2</sub>O(OH)Cl<sub>2</sub>][SbF<sub>6</sub>], crystallizes in the monoclinic space group P2<sub>1</sub> and carbonyl chloride hexadecafluoridotriarsenate(V) [ClCO][Sb<sub>3</sub>F<sub>16</sub>], in the trigonal space group P3<sub>1</sub>, with two and three formula units per unit cell, respectively. Monoprotonated oxalyl chloride and the ClCO<sup>+</sup> cation both display very short C-Cl bonds with a strong double-bond character.</p>","PeriodicalId":7115,"journal":{"name":"Acta Crystallographica Section C Structural Chemistry","volume":" ","pages":"792-797"},"PeriodicalIF":0.7,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11619778/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142674813","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A polymeric form of basic iron(III) acetate with an acetic acid ligand. 碱式醋酸铁(III)与醋酸配体的聚合物形式。
IF 0.7 4区 化学
Acta Crystallographica Section C Structural Chemistry Pub Date : 2024-12-01 Epub Date: 2024-11-20 DOI: 10.1107/S2053229624010672
Brendan F Abrahams, Richard Robson, Christopher J Commons
{"title":"A polymeric form of basic iron(III) acetate with an acetic acid ligand.","authors":"Brendan F Abrahams, Richard Robson, Christopher J Commons","doi":"10.1107/S2053229624010672","DOIUrl":"10.1107/S2053229624010672","url":null,"abstract":"<p><p>A new crystalline compound, catena-poly[hexa-μ-acetato-(acetic acid)-μ<sub>3</sub>-oxido-triangulo-triiron(III)]-μ-acetato], [Fe<sub>3</sub>(C<sub>2</sub>H<sub>3</sub>O<sub>2</sub>)<sub>7</sub>O(C<sub>2</sub>H<sub>4</sub>O<sub>2</sub>)]<sub>n</sub>, incorporating the basic ferric acetate unit, has been obtained from an acetic anhydride solution of hydrated iron(III) nitrate. The crystals have the composition Fe<sub>3</sub>O(OAc)<sub>7</sub>(HOAc) (HOAc is acetic acid) and include the well-known [Fe<sub>3</sub>O(OAc)<sub>6</sub>]<sup>+</sup> unit, in which the Fe<sup>III</sup> centres are linked to a central coplanar μ<sub>3</sub>-oxido ligand. Acetate ions provide bridges between pairs of Fe<sup>III</sup> centres. These individual [Fe<sub>3</sub>O(OAc)<sub>6</sub>]<sup>+</sup> units are linked by additional bridging acetate anions to form zigzag chains. The bridging acetate ions coordinate to a position trans to the oxido group on two of the Fe<sup>III</sup> centres. Remarkably, the trans site on the third Fe<sup>III</sup> centre is occupied by the carbonyl group of an acetic acid molecule. This is the first reported case of an acetic acid molecule coordinating to an Fe<sup>III</sup> centre. Not surprisingly, the acetic acid molecule is only weakly coordinating, resulting in a short Fe-O(oxido) bond trans to the carbonyl group. The trans influence apparent in this structure provides an interesting contrast with the structurally similar Mn<sup>III</sup> analogue, in which the corresponding pair of trans bonds are both elongated because of the Jahn-Teller effect.</p>","PeriodicalId":7115,"journal":{"name":"Acta Crystallographica Section C Structural Chemistry","volume":" ","pages":"787-791"},"PeriodicalIF":0.7,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142674810","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A novel layered structure of the heterometallic oxalate compound [NH2(CH3)2]2[NaFe(C2O4)3]·0.33NH(CH3)2·0.33H2O: synthesis, crystal structure and thermal decomposition. 杂金属草酸盐化合物[NH2(CH3)2]2[NaFe(C2O4)3]-0.33NH(CH3)2-0.33H2O的新型层状结构:合成、晶体结构和热分解。
IF 0.7 4区 化学
Acta Crystallographica Section C Structural Chemistry Pub Date : 2024-12-01 Epub Date: 2024-11-25 DOI: 10.1107/S2053229624011185
Hamza Kherfi, Mohamed Al Amine Benhacine, Malika Hamadene
{"title":"A novel layered structure of the heterometallic oxalate compound [NH<sub>2</sub>(CH<sub>3</sub>)<sub>2</sub>]<sub>2</sub>[NaFe(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]·0.33NH(CH<sub>3</sub>)<sub>2</sub>·0.33H<sub>2</sub>O: synthesis, crystal structure and thermal decomposition.","authors":"Hamza Kherfi, Mohamed Al Amine Benhacine, Malika Hamadene","doi":"10.1107/S2053229624011185","DOIUrl":"10.1107/S2053229624011185","url":null,"abstract":"<p><p>The synthesis, single-crystal X-ray structure determination and thermal analysis are reported for a novel heteronuclear oxalate compound synthesized from a mixture of Fe and Na salts, oxalic acid and N,N-dimethylformamide (DMF) in aqueous solution. The new metallooxalate compound was obtained and identified as a dimethylammonium tris(oxalato)ferrate(III), namely, poly[[bis(dimethylammonium) [tri-μ-oxalato-sodium(I)iron(III)]]-dimethylamine-water (3/1/1)], [NH<sub>2</sub>(CH<sub>3</sub>)<sub>2</sub>]<sub>2</sub>[NaFe(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]·0.33NH(CH<sub>3</sub>)<sub>2</sub>·0.33H<sub>2</sub>O, which crystallizes in the orthorhombic noncentrosymmetric space group C222<sub>1</sub>. In this novel structure, each Fe atom is hexacoordinated by three non-equivalent bidentate oxalate ligands, while the four Na atoms adopt different coordination numbers, i.e. 6, 7 and 8. The structure consists of bimetallic anionic A layers, {[NaFe(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]<sup>2-</sup>}<sub>n</sub>, displaying a layered structure with infinitely linked Fe<sub>2</sub>Na<sub>2</sub> tetramers on the ab plane. Two kinds of bimetallic parallel layers (A1 and A2) are present alternately and are found to be staggered, while only the A2 layer is crossed by a twofold axis parallel to the a axis through two Na atoms. The [NH<sub>2</sub>(CH<sub>3</sub>)<sub>2</sub>]<sup>+</sup> (HDMA) cations occupy the voids between the anionic layers, while the free molecules, i.e. NH(CH<sub>3</sub>)<sub>2</sub> (DMA) and H<sub>2</sub>O, are located between two different anionic layers. In addition to ionic bonds, the stability of the structure is ensured by hydrogen-bond interactions involving the oxalate ligands and the nitrogenous and water molecules. The layered structure appears to be different in the family of oxalate-bridged Na<sup>I</sup>-Fe<sup>III</sup> compounds. It is in agreement with the predicted 2D or layered structure of bimetallic complexes containing anionic tris(oxalato)metallate(III) with the [XR<sub>4</sub>]<sup>+</sup> counter-ion template (X = N, P or S, and R = alkyl group or H). The thermal decomposition of the compound shows the final residual product to be NaFeO<sub>2</sub>.</p>","PeriodicalId":7115,"journal":{"name":"Acta Crystallographica Section C Structural Chemistry","volume":" ","pages":"798-805"},"PeriodicalIF":0.7,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142708535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Construction of pyridine-functionalized metal-organic frameworks for the detection of flazasulfuron. 构建吡啶功能化金属有机框架以检测氟唑磺隆。
IF 0.7 4区 化学
Acta Crystallographica Section C Structural Chemistry Pub Date : 2024-12-01 Epub Date: 2024-11-27 DOI: 10.1107/S2053229624011082
Xiaoya Zhao, Boya Su, Qian Zhao, Wan Lv, Litong Chen, Lixin Huang, Xia Li, Shengyun Liao
{"title":"Construction of pyridine-functionalized metal-organic frameworks for the detection of flazasulfuron.","authors":"Xiaoya Zhao, Boya Su, Qian Zhao, Wan Lv, Litong Chen, Lixin Huang, Xia Li, Shengyun Liao","doi":"10.1107/S2053229624011082","DOIUrl":"10.1107/S2053229624011082","url":null,"abstract":"<p><p>Two novel Cu-based metal-organic frameworks (MOFs), namely, poly[[aquadichlorido[μ<sub>4</sub>-4'-(pyridin-4-yl)-[2,2':6',2''-terpyridine]-4,4''-dicarboxylato][μ<sub>3</sub>-4'-(pyridin-4-yl)-[2,2':6',2''-terpyridine]-4,4''-dicarboxylato]tricopper(II)] monohydrate], {[Cu<sub>3</sub>(C<sub>22</sub>H<sub>12</sub>N<sub>4</sub>O<sub>4</sub>)<sub>2</sub>Cl<sub>2</sub>(H<sub>2</sub>O)]·H<sub>2</sub>O}<sub>n</sub> or {[Cu<sub>3</sub>(PTP)<sub>2</sub>Cl<sub>2</sub>(H<sub>2</sub>O)]·H<sub>2</sub>O}<sub>n</sub>, (I), and poly[[diaquabis[μ<sub>2</sub>-4'-(pyridin-3-yl)-[2,2':6',2''-terpyridine]-4,4''-dicarboxylato]bis(μ<sub>2</sub>-terephthalato)tricopper(II)] dihydrate], {[Cu<sub>3</sub>(C<sub>22</sub>H<sub>12</sub>N<sub>4</sub>O<sub>4</sub>)<sub>2</sub>(C<sub>8</sub>H<sub>4</sub>O<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]·2H<sub>2</sub>O}<sub>n</sub> or {[Cu<sub>3</sub>(BDC)<sub>2</sub>(MTP)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]·2H<sub>2</sub>O}<sub>n</sub>, (II), have been synthesized successfully with 4'-(pyridin-4-yl)-[2,2':6',2''-terpyridine]-4,4''-dicarboxylic acid (H<sub>2</sub>PTP) and 4'-(pyridin-3-yl)-[2,2':6',2''-terpyridine]-4,4''-dicarboxylic acid (H<sub>2</sub>MTP) as the ligands, respectively. Crystal structure analysis reveals that (II) possesses a 2D coordinated layer structure, in which adjacent 2D coordination layers are linked into 3D frameworks through π-π interactions, while the structure of (I) displays dual coordination layers, in which adjacent coordination layers are connected into a 3D framework through hydrogen-bonding interactions. The photophysical properties of the two MOFs were investigated by fluorescence spectroscopy. Complex (II) shows an obvious `turn-on' fluorescence enhancement effect towards flazasulfuron and its potential application for sensing flazasulfuron in water with high selectivity and sensitivity was also investigated in detail.</p>","PeriodicalId":7115,"journal":{"name":"Acta Crystallographica Section C Structural Chemistry","volume":" ","pages":"806-814"},"PeriodicalIF":0.7,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142738020","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Eu3+-doped bismuth silicate crystal structure and Mulliken charge analysis. 掺 Eu3+ 的硅酸铋晶体结构和 Mulliken 电荷分析。
IF 0.7 4区 化学
Acta Crystallographica Section C Structural Chemistry Pub Date : 2024-12-01 Epub Date: 2024-11-27 DOI: 10.1107/S2053229624011410
Yan Zhang, Xuefeng Xiao, Yan Huang, Jiashun Si, Shuaijie Liang, Qingyan Xu, Huan Zhang, Lingling Ma, Cui Yang, Xuefeng Zhang, Jiayue Xu, Tian Tian, Hui Shen
{"title":"Eu<sup>3+</sup>-doped bismuth silicate crystal structure and Mulliken charge analysis.","authors":"Yan Zhang, Xuefeng Xiao, Yan Huang, Jiashun Si, Shuaijie Liang, Qingyan Xu, Huan Zhang, Lingling Ma, Cui Yang, Xuefeng Zhang, Jiayue Xu, Tian Tian, Hui Shen","doi":"10.1107/S2053229624011410","DOIUrl":"10.1107/S2053229624011410","url":null,"abstract":"<p><p>The effects of Eu<sup>3+</sup> doping on the crystal structure and charge distribution of Bi<sub>4</sub>Si<sub>3</sub>O<sub>12</sub> (BSO) bisilicate, based on first principles and density functional theory (DFT), were calculated and analyzed using Materials Studio software. The effect of different proportions (1/12, 1/6 and 1/3) of Eu<sup>3+</sup> doping on BSO crystals was investigated using the virtual crystal approximation method. Through Mulliken charge analysis, it is found that a high proportion of Eu<sup>3+</sup> doping will destroy the symmetry of the crystal structure. With an increase of the Eu<sup>3+</sup>-doping ratio, the Eu-O bond length first increased and then decreased, showing the characteristics of covalent bonds, and the Eu-O bond length reached the minimum value when the Eu<sup>3+</sup>-doping ratio was increased to 1/3. With an increase in the Eu<sup>3+</sup>-doping ratio, the Bi-O bond length decreases sequentially and also reaches the minimum value when the Eu<sup>3+</sup>-doping ratio was increased to 1/3. This indicates that the covalence between the Eu-O and Bi-O atoms is enhanced when the doping ratio is 1/3 when BSO crystals are doped with Eu<sup>3+</sup>.</p>","PeriodicalId":7115,"journal":{"name":"Acta Crystallographica Section C Structural Chemistry","volume":" ","pages":"815-820"},"PeriodicalIF":0.7,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142738022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-throughput crystallization and crystal structure of N-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)-2-methylbenzamide: a benzamide bearing the 4-aminoantipyrine moiety. N-(1,5-二甲基-3-氧代-2-苯基-2,3-二氢-1H-吡唑-4-基)-2-甲基苯甲酰胺的高通量结晶和晶体结构:一种含有 4-氨基安替比林分子的苯甲酰胺。
IF 0.7 4区 化学
Acta Crystallographica Section C Structural Chemistry Pub Date : 2024-12-01 Epub Date: 2024-11-20 DOI: 10.1107/S2053229624010982
Hamad H Al Mamari, Shamsaa Al Sulaimi, Lina Mardiana, Paul G Waddell, Michael J Hall
{"title":"High-throughput crystallization and crystal structure of N-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)-2-methylbenzamide: a benzamide bearing the 4-aminoantipyrine moiety.","authors":"Hamad H Al Mamari, Shamsaa Al Sulaimi, Lina Mardiana, Paul G Waddell, Michael J Hall","doi":"10.1107/S2053229624010982","DOIUrl":"10.1107/S2053229624010982","url":null,"abstract":"<p><p>A recent communication on Ru-catalyzed C-H bond arylation with 4-aminoantipyrine (AP) reported the synthesis of AP benzamides. In order to provide additional support to the published structures of AP benzamides, crystallization by high-throughput (HTP) encapsulated nanodroplet crystallization (ENaCt) was undertaken. This allowed for conclusive structure determination by single-crystal X-ray diffraction analysis (SCXRD). This article describes the crystallization and X-ray crystal structure of N-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)-2-methylbenzamide, C<sub>19</sub>H<sub>19</sub>N<sub>3</sub>O<sub>2</sub>, as a benzamide bearing 4-aminoantipyrine, providing structural confirmation. X-ray structure analysis reveals intermolecular hydrogen-bonding interactions between the AP benzamide N-H proton and the carbonyl O atom of the AP moiety.</p>","PeriodicalId":7115,"journal":{"name":"Acta Crystallographica Section C Structural Chemistry","volume":" ","pages":"775-780"},"PeriodicalIF":0.7,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142674812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bonding properties and crystal packing in β-(SeCl4)4 derived from Hirshfeld Atom Refinement. Hirshfeld 原子细化法得出的β-(SeCl4)4 的键合性质和晶体堆积。
IF 0.7 4区 化学
Acta Crystallographica Section C Structural Chemistry Pub Date : 2024-12-01 Epub Date: 2024-11-11 DOI: 10.1107/S2053229624010428
Juan de Dios Guzmán-Hernández, Vojtech Jancik
{"title":"Bonding properties and crystal packing in β-(SeCl<sub>4</sub>)<sub>4</sub> derived from Hirshfeld Atom Refinement.","authors":"Juan de Dios Guzmán-Hernández, Vojtech Jancik","doi":"10.1107/S2053229624010428","DOIUrl":"10.1107/S2053229624010428","url":null,"abstract":"<p><p>Binary chalcogen halogen EX<sub>4</sub> species represent intriguing systems in terms of chemical bonding theories, such as hypervalency and stereoactivity of lone electron pairs. Instead of a simple molecular EX<sub>4</sub> structure, selenium tetrachloride forms an ionic pair, Cl<sub>3</sub>Se<sup>+</sup>Cl<sup>-</sup>, that assembles into a tetrameric (SeCl<sub>4</sub>)<sub>4</sub> structure, namely, tetra-μ<sub>3</sub>-chlorido-dodecachloridotetraselenium. This article describes the charge-density analysis of the tetrameric molecule of β-SeCl<sub>4</sub> based on the aspherical model obtained from Hirshfeld Atom Refinement of the tetrameric molecule and of an explicit cluster of 15 tetramers that simulates the crystal packing. Deformation density, electron localization function (ELF) and Quantum Theory of Atoms in Molecules (QTAIM) were used to evaluate the bonding situation, the electron-density distribution around the Se atom and the interaction energy of the tetramer.</p>","PeriodicalId":7115,"journal":{"name":"Acta Crystallographica Section C Structural Chemistry","volume":" ","pages":"766-774"},"PeriodicalIF":0.7,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11619779/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142612003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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