CrystEngComm最新文献_第7页

Stepwise introduction of dipole blades into triptycenes: opening the variety of crystalline molecular packing modes 偶极子叶片逐步引入三叶草：打开晶体分子堆积模式的多样性

IF 2.6 3区化学

CrystEngComm Pub Date : 2026-04-23 DOI: 10.1039/D6CE00126B

Hikaru Yamamoto, Yoshichika Tsubakihara, Ayana Sato-Tomita and Mingoo Jin

引用次数: 0

Second-harmonic generation responses in low-dimensional metal bromides functionalized with l-arginine 用l-精氨酸功能化的低维金属溴化物的二次谐波产生响应

IF 2.6 3区化学

CrystEngComm Pub Date : 2026-04-23 DOI: 10.1039/D6CE00227G

Juan Cheng, Yingjie Wang, Qinglan Zhong, Ziyu Zhou, Hongmei Zeng, Guohong Zou and Zhien Lin

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Enhanced photorefractive performance and optical damage resistance in zirconium and uranium co-doped lithium niobate crystals 锆和铀共掺铌酸锂晶体的光折变性能和抗光学损伤性能

IF 2.6 3区化学

CrystEngComm Pub Date : 2026-04-22 DOI: 10.1039/D6CE00116E

Tian Tian, Dong Zhang, Tingfeng Wu, Weiwei Wang, Hongde Liu, Dahuai Zheng, Yaoqing Chu, Hui Shen and Jiayue Xu

引用次数: 0

Fluid shear driven secondary nucleation using α-and γ-glycine seeds confirmed with rigorous control experiments 流体剪切驱动α- γ-甘氨酸种子的二次成核得到了严格的控制实验的证实

IF 2.6 3区化学

CrystEngComm Pub Date : 2026-04-22 DOI: 10.1039/D6CE00279J

Lucas Nahas, Mei Lee, Mark D. Haw and Jan Sefcik

{"title":"Fluid shear driven secondary nucleation using α-and γ-glycine seeds confirmed with rigorous control experiments","authors":"Lucas Nahas, Mei Lee, Mark D. Haw and Jan Sefcik","doi":"10.1039/D6CE00279J","DOIUrl":"https://doi.org/10.1039/D6CE00279J","url":null,"abstract":"The effect of fluid shear on secondary nucleation has long been debated in the crystallization literature. In this work, we investigated the influence of seed polymorphism on secondary nucleation under flow conditions in the absence of mechanical impact, using a “seed-on-a-stick” technique to isolate the effect of fluid shear on secondary nucleation induced by a single glycine seed crystal in aqueous solutions. In situ imaging and particle count analysis were used to assess the impact of seed polymorphism on secondary nucleation kinetics. The presence of glycine seeds induced earlier nucleation under all conditions investigated here, as evidenced by shorter delay times compared to those for control and unseeded experiments. By seeding with either α- or γ-glycine, we found that the solid form of the seed had no significant impact on secondary nucleation rates or delay times and α-glycine consistently nucleated irrespective of the seed solid form. This indicates that cross-nucleation of metastable α-glycine can occur with γ-glycine seeds under flow conditions. We propose that fluid shear driven secondary nucleation may operate similarly to primary nucleation near a solution–solid interface, where enhancement of nucleation is due to stabilisation and aggregation of solute clusters in the interfacial solution region.","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 22","pages":" 3475-3485"},"PeriodicalIF":2.6,"publicationDate":"2026-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2026/ce/d6ce00279j?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148193720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Microwave-assisted rapid synthesis of ultralong hydroxyapatite nanowires using glycerophosphate and their ordered assembly into flexible macroscopic fibers 微波辅助下用甘油磷酸盐快速合成超长羟基磷灰石纳米线及其有序组装成柔性宏观纤维

IF 2.6 3区化学

CrystEngComm Pub Date : 2026-04-22 DOI: 10.1039/D6CE00214E

Si-Yi Li, Yu Zhang, Ying-Jie Zhu and Han-Ping Yu

{"title":"Microwave-assisted rapid synthesis of ultralong hydroxyapatite nanowires using glycerophosphate and their ordered assembly into flexible macroscopic fibers","authors":"Si-Yi Li, Yu Zhang, Ying-Jie Zhu and Han-Ping Yu","doi":"10.1039/D6CE00214E","DOIUrl":"https://doi.org/10.1039/D6CE00214E","url":null,"abstract":"Hydroxyapatite (HAP) nanowires are promising biomaterials due to their biocompatibility and compositional/structural similarity to bone and dental tissues, yet conventional synthesis methods yield brittle, low-aspect-ratio structures limiting flexibility and functionality. Herein, we report a rapid, environmentally friendly microwave-assisted hydrothermal synthesis of flexible ultralong HAP nanowires (UHAPNWs) using β-glycerophosphate as an organic phosphorus source and calcium oleate precursor. Optimizing parameters such as the Ca/P molar ratio, hydrothermal temperature, and reaction time, we achieved UHAPNWs with lengths of several hundred micrometers and aspect ratios exceeding 10 000. These nanowires self-assemble into ordered bundles along the longitudinal direction and can be further fabricated into flexible macroscopic fibers via injection assembly. The resulting fibers exhibit superior mineralization capability in simulated body fluid, indicating potential for applications in bone regeneration and dental enamel repair. This method offers a versatile platform for developing functional HAP-based nanostructured biomaterials with enhanced flexibility and bioactivity.","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 21","pages":" 3305-3320"},"PeriodicalIF":2.6,"publicationDate":"2026-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148141603","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Diverting metal coordination site in flavin–copper complexes for distinct nanoparticle synthesis 转移黄铜配合物中的金属配位位点以合成不同的纳米颗粒

IF 2.6 3区化学

CrystEngComm Pub Date : 2026-04-21 DOI: 10.1039/D6CE00155F

Dipayan Mondal and Ashutosh Kumar Mishra

引用次数: 0

Bridgman-grown SbSnSe3 crystal: exploring its potential for thermoelectric and photosensitive applications 布里奇曼生长SbSnSe3晶体：探索其热电和光敏应用的潜力

IF 2.6 3区化学

CrystEngComm Pub Date : 2026-04-21 DOI: 10.1039/D6CE00057F

Kruti Bhupendrakumar Soni, Zubin R. Parekh, Sandip V. Bhatt, Swati J. Pandya, S. H. Chaki and M. P. Deshpande

{"title":"Bridgman-grown SbSnSe3 crystal: exploring its potential for thermoelectric and photosensitive applications","authors":"Kruti Bhupendrakumar Soni, Zubin R. Parekh, Sandip V. Bhatt, Swati J. Pandya, S. H. Chaki and M. P. Deshpande","doi":"10.1039/D6CE00057F","DOIUrl":"https://doi.org/10.1039/D6CE00057F","url":null,"abstract":"To the best of our knowledge, no prior reports on growth and characterization of the SbSnSe3 crystal are available in the literature, making this study the first comprehensive investigation of its structural, optical, thermoelectric, and photoconductive properties. The SbSnSe3 crystal was grown successfully by the vertical Bridgman technique. The orthorhombic phase of this grown crystal was confirmed through powder X-ray diffraction. Elemental assessment by EDAX reflected the near-stoichiometric composition of the grown crystal, whereas FESEM images illustrated a distinctly layered structure. The reflectance spectrum revealed a direct bandgap of about 1.48 eV, favourable for both photoresponse and thermoelectric applications. Over the range of 300–573 K, the measured Seebeck coefficient, electrical conductivity and thermal conductivity of the SbSnSe3 crystal exhibited semiconducting behavior. Based on these thermoelectric parameters, a maximum ZT value of 0.04 was obtained. Furthermore, TG-DTG-DTA analysis carried out between 300 K and 880 K revealed a consistent two-step thermal behavior across heating rates of 10, 15, and 20 K min−1, confirming the crystal's excellent thermal stability. Room temperature steady-state I–V analysis conducted under 50 mW cm−2 illumination showed an anisotropic photoresponse in SbSnSe3. The ⊥r configuration exhibited a responsivity of 186.8 μA W−1 and a detectivity of 10.03 × 106 Jones at 10 mV bias, confirming enhanced charge transport efficiency.","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 19","pages":" 3099-3116"},"PeriodicalIF":2.6,"publicationDate":"2026-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147967885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Post-synthetic sulfonation of MIL-101(Cr) enabling high-performance fructose conversion to 5-HMF MIL-101（Cr）的合成后磺化，使果糖高效转化为5-HMF

IF 2.6 3区化学

CrystEngComm Pub Date : 2026-04-20 DOI: 10.1039/D6CE00078A

Maryam Ghahremani, Majid Masteri-Farahani and Saeideh-Sadat Mortazavi

{"title":"Post-synthetic sulfonation of MIL-101(Cr) enabling high-performance fructose conversion to 5-HMF","authors":"Maryam Ghahremani, Majid Masteri-Farahani and Saeideh-Sadat Mortazavi","doi":"10.1039/D6CE00078A","DOIUrl":"https://doi.org/10.1039/D6CE00078A","url":null,"abstract":"The design of structurally resilient and catalytically efficient solid acid materials remains a central challenge in biomass valorization. Herein, a sulfonated MIL-101(Cr)-SO3H framework was constructed through a post-synthetic functionalization strategy, and its structural, textural, and thermal properties were comprehensively assessed. FT-IR and XRD analyses confirmed successful functionalization while preserving the crystalline architecture of MIL-101(Cr). SEM and elemental mapping analyses revealed uniform octahedral morphology with homogeneous distribution of Cr, C, O, N, and S, whereas N2 sorption analysis showed a decrease in surface area from 2063 to 727 m2 g−1 due to partial pore occupancy by grafted organic groups. The catalyst exhibited high activity toward the dehydration of fructose to 5-hydroxymethylfurfural (5-HMF), achieving a maximum yield of 98% under optimized conditions. Notably, the material retained its catalytic performance after four consecutive cycles with negligible loss of acidic sites and minimal structural alteration, as verified by post-reaction FT-IR and XRD analyses. Collectively, these findings establish MIL-101(Cr)-SO3H as a highly robust and efficient solid acid catalyst for biomass-derived HMF production.","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 19","pages":" 3089-3098"},"PeriodicalIF":2.6,"publicationDate":"2026-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147967884","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Selective crystallization of d-mannitol polymorphs in a water–isopropyl alcohol mixture through a swift cooling process d-甘露醇多晶在水-异丙醇混合物中通过快速冷却过程的选择性结晶

IF 2.6 3区化学

CrystEngComm Pub Date : 2026-04-20 DOI: 10.1039/D5CE01169H

Lavanisadevi Subiramaniyam and Srinivasan Karuppannan

{"title":"Selective crystallization of d-mannitol polymorphs in a water–isopropyl alcohol mixture through a swift cooling process","authors":"Lavanisadevi Subiramaniyam and Srinivasan Karuppannan","doi":"10.1039/D5CE01169H","DOIUrl":"https://doi.org/10.1039/D5CE01169H","url":null,"abstract":"In this study, we examine the polymorphic control and separation of D-mannitol in a 1 : 1 (v/v) ratio of water–isopropyl alcohol solvent mixture using a swift-cooling crystallization process. This method created supersaturation (0.01 < σ < 13.18), producing obvious changes in the crystallization outcome of D-mannitol polymorphs. At low supersaturation levels, only the stable form I nucleated. Under high supersaturation conditions, metastable form II was observed, while at extremely high supersaturation levels, the metastable form III was obtained. Notably, form III converted into form I through a solution-mediated transformation, confirming its transient stability and its tendency to transform into the thermodynamically stable form. Morphological analysis was conducted through in situ optical microscopy. The structural and thermal characteristics were confirmed by powder X-ray diffraction. The crystalline phases were further verified by Le Bail profile fitting and differential scanning calorimetry. This approach effectively describes the supersaturation region governing D-mannitol polymorph formation, enabling selective crystallization of the desired metastable form with enhanced control.","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 20","pages":" 3247-3258"},"PeriodicalIF":2.6,"publicationDate":"2026-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148011690","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of Dy3+ ion clusters in CaF2: Dy3+ crystals on yellow and mid-infrared laser characteristics CaF2: Dy3+晶体中Dy3+离子团簇对黄、中红外激光特性的影响

IF 2.6 3区化学

CrystEngComm Pub Date : 2026-04-18 DOI: 10.1039/D6CE00206D

Longxing Zheng, Yixiang Huang, Zhaojie Zhu, Yizhi Huang, Chaoyang Tu, G. Lakshminarayana and Yan Wang

{"title":"Effect of Dy3+ ion clusters in CaF2: Dy3+ crystals on yellow and mid-infrared laser characteristics","authors":"Longxing Zheng, Yixiang Huang, Zhaojie Zhu, Yizhi Huang, Chaoyang Tu, G. Lakshminarayana and Yan Wang","doi":"10.1039/D6CE00206D","DOIUrl":"https://doi.org/10.1039/D6CE00206D","url":null,"abstract":"CaF2 single crystals doped with Dy3+ in different concentrations (1–8 at%) were grown by the Bridgman method. Their structural and spectral features were studied to realize the concentration quenching mechanisms of yellow (∼570 nm) and mid-infrared (∼3 μm) emissions. XRD and Raman analyses confirmed that all crystals retained the fluorite structure. At high doping concentrations, charge compensation and cluster formation led to lattice expansion and increased disorder. In the absorption spectra, the peak positions, absorption cross-sections, and full widths at half maximum did not change with doping concentration. The yellow emission exhibited complex concentration-dependent behavior, confirming the existence of at least two types of Dy3+ clusters (L-type and M/N-type) with different fluorescence lifetimes in CaF2, which showed distinctly different yellow luminescence characteristics. In contrast, the mid-infrared emission at 2901 nm is less affected by cluster type, achieving optimal performance at a doping concentration of 6 at%, with a stable emission cross-section of approximately 3.1 × 10−21 cm2. This work provides a systematic understanding of the structure–property relationships in Dy3+: CaF2 crystals and offers a route for the development of dual-band yellow and mid-infrared laser materials.","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 21","pages":" 3364-3374"},"PeriodicalIF":2.6,"publicationDate":"2026-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148141610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0